K. Ikada, H. Jamshidi, S. Tsuji, and . Hyon, Stereocomplex formation between enantiomeric poly(lactides), Macromolecules, vol.20, issue.4, p.904, 1987.
DOI : 10.1021/ma00170a034

H. Tsuji, Poly(lactide) Stereocomplexes: Formation, Structure, Properties, Degradation, and Applications, Macromolecular Bioscience, vol.4, issue.7, p.569, 2005.
DOI : 10.1002/mabi.200500062

URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.455.2304

V. Lapinte, V. Montembault, A. Houdayer, L. Fontaine, J. Mol et al., A : Chem, 2007.

P. W. Dyer, S. Handra, T. B. Reeve, S. Suhard, and T. Lett, Synthesis of salen-supported aluminium complexes for subsequent attachment to a solid support and cyclic esters/carbonates polymerization activity (12) a), Adv. Synth. Catal, vol.46, issue.348, pp.4753-1760, 2005.

S. Rajagopal, K. Selvaraj, and . Dhahagani, Asymmetric cyanosilylation of ketones catalyzed by recyclable polymer-supported copper(II) salen complexes, Tetrahedron: Asymmetry, vol.21, issue.18, p.2265, 2010.
DOI : 10.1016/j.tetasy.2010.07.029

V. N. Panchenko, I. Borbath, M. N. Timofeeva, S. Göbölös, J. Mol et al., A : Chem, J. Appl. Polym. Sci, vol.319, issue.119, pp.96-1897, 2005.

T. Ando, M. Yagyu, and . Maeda, Characterization of oxovanadium (IV)???Schiff-base complexes and those bound on resin, and their use in sulfide oxidation, Inorganica Chimica Acta, vol.357, issue.8, p.2237, 2004.
DOI : 10.1016/j.ica.2003.12.031

T. Madhavan, C. D. Takatani, M. Sherrill, and . Weck, Macrocyclic Cyclooctene-Supported AlCl-Salen Catalysts for Conjugated Addition Reactions: Effect of Linker and Support Structure on Catalysis, Chemistry - A European Journal, vol.11, issue.5, pp.1186-576, 2006.
DOI : 10.1002/chem.200801611

T. Lübbe and . Tsumaki, Justus Liebig's Annalen der Chemie, 1933.

R. Breinbauer and E. N. Jacobsen, htm (24) a), Tetrahedron Lett. Angew. Chem. Int. Ed, vol.445, issue.20, p.39, 2000.

X. Holbach, C. Zheng, C. W. Burd, M. Jones, and . Weck, A Practical One-Pot Synthesis of Enantiopure Unsymmetrical Salen Ligands, The Journal of Organic Chemistry, vol.71, issue.7, p.2903, 2006.
DOI : 10.1021/jo052614y

B. B. De, S. Lohray, and P. K. Sivaram, Polymeric catalysts for chemo- and enantioselective epoxidation of olefins: New crosslinked chiral transition metal complexing polymers, Journal of Polymer Science Part A: Polymer Chemistry, vol.35, issue.9, p.1809, 1997.
DOI : 10.1002/(SICI)1099-0518(19970715)35:9<1809::AID-POLA21>3.0.CO;2-8

I. Palard, M. Schappacher, B. Belloncle, A. Soum, and S. M. Guillaume, Unprecedented Polymerization of Trimethylene Carbonate Initiated by a Samarium Borohydride Complex: Mechanistic Insights and Copolymerization with ??-Caprolactone, Chemistry - A European Journal, vol.202, issue.5, pp.1511-8828, 2007.
DOI : 10.1002/chem.200600843

URL : https://hal.archives-ouvertes.fr/hal-00275433

M. H. Habibi, S. Tangestaninejad, I. Mohammadpoor-baltork, V. Mirkhani, B. Yadollahi et al., Potassium dodecatangestocobaltate trihydrate (K5CoW12O40??3H2O): a mild and efficient catalyst for deprotection of dioxolanes and trimethylsilyl ethers, Tetrahedron Letters, vol.42, issue.38, pp.6771-1177, 1968.
DOI : 10.1016/S0040-4039(01)01379-X

T. W. Greene and P. G. Wuts, Protective groups in organic synthesis, pp.77-83, 1991.
DOI : 10.1002/0471220574

C. L. Liotta and H. P. Harris, Chemistry of naked anions. I. Reactions of the 18-crown-6 complex of potassium fluoride with organic substrates in aprotic organic solvents, Journal of the American Chemical Society, vol.96, issue.7, p.2250, 1974.
DOI : 10.1021/ja00814a044

). S. Maifeld, R. L. Miller, D. Lee, and T. Lett, Chapter, pp.6363-74, 2002.

S. Enthaler, B. Hagemann, G. Erre, K. Junge, and M. Beller, An Environmentally Benign Process for the Hydrogenation of Ketones with Homogeneous Iron Catalysts, Chemistry ??? An Asian Journal, vol.10, issue.4, p.598, 2006.
DOI : 10.1002/asia.200600105

E. Bianchini, M. Farnetti, M. Graziani, A. Peruzzini, and . Polo, Chemoselective hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones catalyzed by isostructural iron(II), ruthenium(II), and osmium(II) cis-hydride (.eta.2-dihydrogen) complexes, Organometallics, vol.12, issue.9, p.3753, 1993.
DOI : 10.1021/om00033a054

P. Liang, Y. Chien, and . Huang, Intermolecular Arene C???H Activation by Nickel(II), Journal of the American Chemical Society, vol.128, issue.49, p.15562, 2006.
DOI : 10.1021/ja065505p

L. Fan, S. Parkin, and O. V. Ozerov, Halobenzenes and Ir(I):?? Kinetic C???H Oxidative Addition and Thermodynamic C???Hal Oxidative Addition, b) S. Gatard, R, p.16772, 2005.
DOI : 10.1021/ja0557637

D. W. Morales-morales, Z. Lee, C. M. Wang, and . Jensen, }, Organometallics, vol.20, issue.6, p.1144, 2001.
DOI : 10.1021/om000940s

B. Kanzelberger, M. Singh, K. Czerw, A. S. Krogh-jespersen, and . Goldman, ), Journal of the American Chemical Society, vol.122, issue.44, p.11017, 2000.
DOI : 10.1021/ja001626s

H. B. Kagan, O. Riant, Y. Hayashi, J. J. Rohde, E. J. Corey et al., Catalytic asymmetric Diels Alder reactions, Chemical Reviews, vol.92, issue.5, p.1007, 1992.
DOI : 10.1021/cr00013a013

M. Deloux and . Srebnik, Asymmetric boron-catalyzed reactions, Chemical Reviews, vol.93, issue.2, p.763, 1993.
DOI : 10.1021/cr00018a007

D. E. Bergbreiter, P. L. Osburn, A. Wilson, and E. M. Sink, Palladium-Catalyzed C???C Coupling under Thermomorphic Conditions, c) I. P, pp.9058-1619, 2000.
DOI : 10.1021/ja001708g

). C. Hayes and D. B. Leznoff, Diamido-Ether Uranium(IV) Alkyl Complexes as Single-Component Ethylene Polymerization Catalysts, Organometallics, vol.29, issue.4, p.767, 2010.
DOI : 10.1021/om900546p

). N. Emig, H. Nguyen, H. Krautscheid, R. Réau, J. Cazaux et al., )-Lactide, Organometallics, vol.17, issue.16, p.3599, 1998.
DOI : 10.1021/om980401b

B. Dechy-cabaret, D. Martin-vaca, and . Bourissou, Controlled Ring-Opening Polymerization of Lactide and Glycolide, Chemical Reviews, vol.104, issue.12, p.6147, 2004.
DOI : 10.1021/cr040002s

N. Nomura, A. Akita, R. Ishii, M. H. Mizuno, M. Sun et al., 1750. s) W, Dalton Trans J. Am. Chem. Soc. Chem. Rev, vol.132, issue.4037, pp.39-533, 2008.

B. C. Bailey, J. C. Huffman, D. J. Mindiola, W. Weng, and O. V. Ozerov, Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene, and Imide Functionalities, Organometallics, vol.24, issue.7, pp.1390-5573, 2004.
DOI : 10.1021/om0490583

S. Dagorne and . Bellemin-laponnaz, Group 13 Metal-Mediated Organic reactions. In The Group 13 Metals Aluminium, Gallium, Indium and Thallium : Chemical Patterns and Peculiarities

L. Dagorne, Coordinated Group 13 Compounds, Encyclopedia of Inorganic Chemistry, p.2714, 2005.

C. Dagorne, Topics in Organometallic Chemistry, pp.1-47, 2012.

). F. Hild, L. Brelot, and S. Dagorne, Novel N,O,N-Supported Tetracoordinate Aluminum Complexes for the Highly Controlled and Immortal ROP of Trimethylene Carbonate (TMC) under Mild Conditions: Access to Narrowly Disperse poly-TMC and Derived Copolymers, Organometallics, vol.30, issue.20, p.5457, 2011.
DOI : 10.1021/om200703d

). P. Power, ??-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements, Chemical Reviews, vol.99, issue.12, pp.3463-155, 1999.
DOI : 10.1021/cr9408989

B. J. O-'keefe, M. A. Hillmeyer, W. B. Tolman, and D. Trans, 2215. b) O. Dechy- Cabaret, Chem. Rev, vol.104, p.6147, 2001.

J. Darensbourg, W. Choi, O. Karroonnirun, and N. Bhuvanesh, Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate), and Their Copolymers, Macromolecules, vol.41, issue.10, p.3493, 2008.
DOI : 10.1021/ma800078t

A. P. Pego, A. A. Poot, D. W. Grijpma, and J. J. Feijen, Biodegradable elastomeric scaffolds for soft tissue engineering, Journal of Controlled Release, vol.87, issue.1-3, p.69, 2003.
DOI : 10.1016/S0168-3659(02)00351-6

A. Tyson, A. Finne-wistrand, and . Albertsson, -Lactide and Trimethylene Carbonate Copolymers Obtained by a Simple and Effective Method, Biomacromolecules, vol.10, issue.1, p.149, 2009.
DOI : 10.1021/bm801052m

URL : https://hal.archives-ouvertes.fr/hal-00649178

Y. Tyrrell, M. Shen, and . Radosz, Fabrication of micellar nanoparticles for drug delivery through the self-assembly of block copolymers, Progress in Polymer Science, vol.35, issue.9, p.1128, 2010.
DOI : 10.1016/j.progpolymsci.2010.06.003

L. Amgoune, C. M. Lavanant, Y. Thomas, R. Chi, S. Welter et al., An Aluminum Complex Supported by a Fluorous Diamino-Dialkoxide Ligand for the Highly Productive Ring-Opening Polymerization of ??-Caprolactone, Organometallics, vol.24, issue.25, p.6279, 2005.
DOI : 10.1021/om050512s

I. Palard, M. Schappacher, B. Belloncle, A. Soum, and S. M. Guillaume, Unprecedented Polymerization of Trimethylene Carbonate Initiated by a Samarium Borohydride Complex: Mechanistic Insights and Copolymerization with ??-Caprolactone, Chemistry - A European Journal, vol.202, issue.5, pp.1511-8828, 2007.
DOI : 10.1002/chem.200600843

URL : https://hal.archives-ouvertes.fr/hal-00275433

). T. Müller, K. C. Hultzsch, M. Yus, F. Foubelo, and M. Tada, Hydroamination: Direct Addition of Amines to Alkenes and Alkynes, Chemical Reviews, vol.108, issue.9, p.3795, 2008.
DOI : 10.1021/cr0306788

S. Severin, F. Doye, I. P. Alonso, M. Beletskaya, and . Yus, The catalytic hydroamination of alkynes, d) P. Pohlki, S. Doye, pp.1407-3079, 2003.
DOI : 10.1039/b600981f

-. Sheldrick, SHELXL97, Program for the refinment of Crystal Structures, 1997.

M. Save, M. Schappacher, and A. Soum, Controlled Ring-Opening Polymerization of Lactones and Lactides Initiated by Lanthanum Isopropoxide, 1. General Aspects and Kinetics, Macromolecular Chemistry and Physics, vol.203, issue.5-6, p.889, 2002.
DOI : 10.1002/1521-3935(20020401)203:5/6<889::AID-MACP889>3.0.CO;2-O

I. Palard, M. Schappacher, B. Belloncle, A. Soum, and S. M. Guillaume, Unprecedented Polymerization of Trimethylene Carbonate Initiated by a Samarium Borohydride Complex: Mechanistic Insights and Copolymerization with ??-Caprolactone, Chemistry - A European Journal, vol.202, issue.5, pp.1511-8828, 2007.
DOI : 10.1002/chem.200600843

URL : https://hal.archives-ouvertes.fr/hal-00275433