W. C. Ackerman, D. M. Smith, J. C. Huling, Y. W. Kim, J. K. Bailey et al., Gas/vapor adsorption in imogolite: a microporous tubular aluminosilicate, Langmuir, vol.9, issue.4, pp.1051-1057, 1993.
DOI : 10.1021/la00028a029

F. Alvarez-ramirez, Ab initio simulation of the structural and electronic properties of aluminosilicate and aluminogermanate natotubes with imogolitelike structure, Physical Review B, issue.12, p.76, 2007.

E. L. Amweg, D. L. Stuart, W. , and D. P. , Comparative bioavailability of selenium to aquatic organisms after biological treatment of agricultural drainage water, Aquatic Toxicology, vol.63, issue.1, pp.13-25, 2003.
DOI : 10.1016/S0166-445X(02)00110-8

Y. Arai, M. Mcbeath, J. R. Bargar, J. Joye, D. et al., Uranyl adsorption and surface speciation at the imogolite???water interface: Self-consistent spectroscopic and surface complexation models, Geochimica et Cosmochimica Acta, vol.70, issue.10, pp.70-2492, 2006.
DOI : 10.1016/j.gca.2006.02.013

L. S. Balistrieri and T. T. Chao, Selenium Adsorption by Goethite1, Soil Science Society of America Journal, vol.51, issue.5, pp.1145-1151, 1987.
DOI : 10.2136/sssaj1987.03615995005100050009x

R. J. Barham, Schwertmannite: A unique mineral, contains a replaceable ligand, transforms to jarosites, hematites, and/or basic iron sulfate, Journal of Materials Research, vol.55, issue.10, pp.2751-2758, 1997.
DOI : 10.1557/JMR.1997.0366

B. R. Bickmore, C. J. Tadanier, K. M. Rosso, W. D. Monn, and D. L. Eggett, Bond-Valence methods for pK(a) prediction: critical reanalysis and a new approach, Geochimica et Cosmochimica Acta, issue.9, pp.68-2025, 2004.

H. G. Byers, J. T. Miller, K. T. Williams, and H. W. Lakin, Selenium occurrence in certain soils in the United States with a discussion of related topics, 1938.

J. Chorover and G. Sposito, Surface charge characteristics of kaolinitic tropical soils, Geochimica et Cosmochimica Acta, vol.59, issue.5, pp.875-884, 1995.
DOI : 10.1016/0016-7037(94)00357-2

G. F. Combs, C. Garbisu, B. C. Yee, A. Yee, D. E. Carlson et al., Bioavailability of selenium accumulated by selenite-reducing bacteria, Biological Trace Element Research, vol.20, issue.3, pp.209-225, 1996.
DOI : 10.1007/BF02789163

P. D. Cradwick, K. Wada, J. D. Russell, . N. Yoshinag, C. R. Masson et al., Imogolite, a hydrated aluminum silicate of tubular structure, Nature- Physical Science, issue.104, pp.240-187, 1972.

B. Creton, D. Bougeard, K. S. Smirnov, J. Guilment, and O. Poncelet, Molecular dynamics study of hydrated imogolite : 2. Structure and dynamics of confined water, Physical Chemistry Chemical Physics, vol.102, issue.32, pp.10-4879, 2008.
DOI : 10.1021/jp800802u

URL : https://hal.archives-ouvertes.fr/hal-00316024

R. A. Dahlgren and F. C. Ugolini, Formation and stability of imogolite in a tephritic spodosol, Cascade Range, Geochimica et Cosmochimica Acta, issue.8, pp.53-1897, 1989.

D. F. Davidson and H. A. Powers, Selenium content of some volcanic rocks from Western United States and Hawaiian Islands, Bulletin of the Geological Survey of U.S, pp.1084-69, 1959.

S. K. Dhillon and K. S. Dhillon, Selenium adsorption in soils as influenced by different anions, Journal of Plant Nutrition and Soil Science, vol.163, issue.6, pp.577-582, 2000.
DOI : 10.1002/1522-2624(200012)163:6<577::AID-JPLN577>3.0.CO;2-H

M. Duc, G. Lefevre, M. Fedoroff, J. Jeanjean, J. C. Rouchaud et al., Sorption of selenium anionic species on apatites and iron oxides from aqueous solutions, Journal of Environmental Radioactivity, vol.70, issue.1-2, pp.61-72, 2003.
DOI : 10.1016/S0265-931X(03)00125-5

V. C. Farmer, M. J. Adams, A. R. Fraser, and F. Palmieri, Synthetic Imogolite: Properties, Synthesis, and Possible Applications, Clay Minerals, vol.18, issue.4, pp.459-472, 1983.
DOI : 10.1180/claymin.1983.018.4.11

A. Gehin, J. M. Greneche, C. Tournassat, J. Brendle, D. G. Rancourt et al., Reversible surface-sorption-induced electron-transfer oxidation of Fe(II) at reactive sites on a synthetic clay mineral, Geochimica et Cosmochimica Acta, vol.71, issue.4, pp.863-876, 2007.
DOI : 10.1016/j.gca.2006.10.019

URL : https://hal.archives-ouvertes.fr/hal-00597192

J. P. Gustafsson, The Surface Chemistry of Imogolite, Clays and Clay Minerals, vol.49, issue.1, pp.73-80, 2001.
DOI : 10.1346/CCMN.2001.0490106

D. D. Hansmann, A. , and M. A. , Using electrophoresis in modeling sulfate, selenite, and phosphate adsorption onto goethite, Environmental Science & Technology, vol.19, issue.6, pp.544-551, 1985.
DOI : 10.1021/es00136a010

J. B. Harsh, S. J. Traina, J. Boyle, Y. , and Y. , Adsorption of cations on imogolite and their effect on surface-charge characteristics, Clays and Clay Minerals, issue.6, pp.40-700, 1992.

T. Hiemstra and W. H. Vanriemsdijk, A Surface Structural Approach to Ion Adsorption: The Charge Distribution (CD) Model, Journal of Colloid and Interface Science, vol.179, issue.2, pp.488-508, 1996.
DOI : 10.1006/jcis.1996.0242

T. Hiemstra, P. Venema, and W. H. Vanriemsdijk, Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle, Journal of Colloid and Interface Science, vol.184, issue.2, 1996.
DOI : 10.1006/jcis.1996.0666

M. Ihnat, Occurence and distribution of Selenium, 1989.

C. C. Johnson, X. Ge, K. A. Green, and X. Liu, Selenium distribution in the local environment of selected villages of the Keshan Disease belt, 2000.

M. Wolthers, S. J. Van-der-gaast, R. , and D. , The structure of disordered mackinawite, American Mineralogist, vol.88, issue.11-12, pp.11-12, 2003.
DOI : 10.2138/am-2003-11-1245

J. Zang, S. Konduri, S. Nair, and D. S. Sholl, Self-Diffusion of Water and Simple Alcohols in Single-Walled Aluminosilicate Nanotubes, ACS Nano, vol.3, issue.6, pp.1548-1556, 2009.
DOI : 10.1021/nn9001837

E. S. Zhang, H. L. Wang, X. X. Yan, and L. D. Zhang, Comparison of short-term toxicity between Nano-Se and selenite in mice, Life Sciences, vol.76, issue.10, pp.76-1099, 2005.
DOI : 10.1016/j.lfs.2004.08.015

R. T. Cygan, J. J. Liang, and A. G. Kalinichev, Molecular Models of Hydroxide, Oxyhydroxide, and Clay Phases and the Development of a General Force Field, The Journal of Physical Chemistry B, vol.108, issue.4, pp.1255-1266, 2004.
DOI : 10.1021/jp0363287

P. Debye, X-ray dispersal, Annalen Der Physik, vol.46, issue.6, pp.809-823, 1915.

B. Delley, An all???electron numerical method for solving the local density functional for polyatomic molecules, The Journal of Chemical Physics, vol.92, issue.1, pp.508-517, 1990.
DOI : 10.1063/1.458452

T. Egami and S. J. Billinge, Underneath the Bragg Peaks, Materials Today, vol.6, issue.6, 2003.
DOI : 10.1016/S1369-7021(03)00635-7

P. Hohenberg and W. Kohn, Inhomogeneous Electron Gas, Physical Review, vol.136, issue.3B, p.864, 1964.
DOI : 10.1103/PhysRev.136.B864

S. D. Kelly, D. Hesterberg, and B. Ravel, Analysis of Soils and Minerals Using X-ray Absorption Spectroscopy in Methods of Soil Analysis, 2008.

W. Kohn and L. J. Sham, Self-Consistent Equations Including Exchange and Correlation Effects, Physical Review, vol.140, issue.4A, pp.140-1133, 1965.
DOI : 10.1103/PhysRev.140.A1133

G. Kresse and J. Hafner, Ab initio molecular dynamics for liquid metals, Journal of Non-Crystalline Solids, vol.192, issue.193, pp.558-561, 1993.
DOI : 10.1016/0022-3093(95)00355-X

S. Plimpton, Fast Parallel Algorithms for Short-Range Molecular Dynamics, Journal of Computational Physics, vol.117, issue.1, pp.1-19, 1995.
DOI : 10.1006/jcph.1995.1039

J. J. Rehr, A. , and R. C. , Theoretical approaches to x-ray absorption fine structure, Reviews of Modern Physics, vol.72, issue.3, pp.621-654, 2000.
DOI : 10.1103/RevModPhys.72.621

B. K. Teo, EXAFS: basic principles and data analysis, 1986.
DOI : 10.1007/978-3-642-50031-2

F. Alvarez-ramirez, Ab initio simulation of the structural and electronic properties of aluminosilicate and aluminogermanate natotubes with imogolitelike structure, Physical Review B, issue.12, p.76, 2007.

A. L. Ankudinov, C. E. Bouldin, J. J. Rehr, J. Sims, H. et al., Parallel calculation of electron multiple scattering using Lanczos algorithms, Physical Review B, vol.65, issue.10, pp.65-76, 2002.
DOI : 10.1103/PhysRevB.65.104107

Y. Arai, M. Mcbeath, J. R. Bargar, J. Joye, D. et al., Uranyl adsorption and surface speciation at the imogolite???water interface: Self-consistent spectroscopic and surface complexation models, Geochimica et Cosmochimica Acta, vol.70, issue.10, pp.70-2492, 2006.
DOI : 10.1016/j.gca.2006.02.013

L. S. Balistrieri and T. T. Chao, Selenium Adsorption by Goethite1, Soil Science Society of America Journal, vol.51, issue.5, pp.1145-1151, 1987.
DOI : 10.2136/sssaj1987.03615995005100050009x

B. R. Bickmore, C. J. Tadanier, K. M. Rosso, W. D. Monn, and D. L. Eggett, Bond-Valence methods for pK(a) prediction: critical reanalysis and a new approach, Geochimica et Cosmochimica Acta, issue.9, pp.68-2025, 2004.

E. J. Boyle-wight, L. E. Katz, H. , and K. F. , Spectroscopic studies of the effects of selenate and selenite on cobalt sorption to gamma-Al2O3, Environmental Science & Technology, issue.6, pp.36-1219, 2002.

C. J. Brinker and G. W. Scherer, Sol-gel Science: The Physics and Chemistry of Sol-Gel Processing, 1990.

L. A. Bursill, J. L. Peng, and L. N. Bourgeois, Imogolite: an aluminosilicate nanotube material. Philosophical Magazine a-Physics of Condensed Matter Structure Defects and Mechanical Properties, pp.105-117, 2000.
DOI : 10.1080/01418610008212043

H. G. Byers, J. T. Miller, K. T. Williams, and H. W. Lakin, Selenium occurrence in certain soils in the United States with a discussion of related topics, 1938.

J. G. Catalano, Z. Zhang, P. Fenter, and M. J. Bedzyk, Inner-sphere adsorption geometry of Se(IV) at the hematite (100)???water interface, Journal of Colloid and Interface Science, vol.297, issue.2, pp.665-671, 2006.
DOI : 10.1016/j.jcis.2005.11.026

L. Charlet, A. C. Scheinost, C. Tournassat, J. M. Greneche, A. Gehin et al., Electron transfer at the mineral/water interface: Selenium reduction by ferrous iron sorbed on clay, Geochimica et Cosmochimica Acta, vol.71, issue.23, pp.71-5731, 2007.
DOI : 10.1016/j.gca.2007.08.024

URL : https://hal.archives-ouvertes.fr/hal-00261713

P. D. Cradwick, K. Wada, J. D. Russell, . N. Yoshinag, C. R. Masson et al., Imogolite, a hydrated aluminum silicate of tubular structure, Nature- Physical Science, issue.104, pp.240-187, 1972.

B. Creton, D. Bougeard, K. S. Smirnov, J. Guilment, and O. Poncelet, Molecular dynamics study of hydrated imogolite : 2. Structure and dynamics of confined water, Physical Chemistry Chemical Physics, vol.102, issue.32, pp.10-4879, 2008.
DOI : 10.1021/jp800802u

URL : https://hal.archives-ouvertes.fr/hal-00316024

R. A. Dahlgren and F. C. Ugolini, Formation and stability of imogolite in a tephritic spodosol, Cascade Range, Geochimica et Cosmochimica Acta, issue.8, pp.53-1897, 1989.

K. Fukushi and D. A. Sverjensky, A surface complexation model for sulfate and selenate on iron oxides consistent with spectroscopic and theoretical molecular evidence, Geochimica et Cosmochimica Acta, vol.71, issue.1, pp.1-24, 2007.
DOI : 10.1016/j.gca.2006.08.048

Y. Gan and G. V. Franks, Charging Behavior of the Gibbsite Basal (001) Surface in NaCl Solution Investigated by AFM Colloidal Probe Technique, Langmuir, vol.22, issue.14, pp.22-6087, 2006.
DOI : 10.1021/la053391+

B. Q. Gu and T. O. Cheng, The International Textbook of Cardiology, 1987.

J. P. Gustafsson, The Surface Chemistry of Imogolite, Clays and Clay Minerals, vol.49, issue.1, pp.73-80, 2001.
DOI : 10.1346/CCMN.2001.0490106

D. D. Hansmann, A. , and M. A. , Using electrophoresis in modeling sulfate, selenite, and phosphate adsorption onto goethite, Environmental Science & Technology, vol.19, issue.6, pp.544-551, 1985.
DOI : 10.1021/es00136a010

K. F. Hayes, C. Papelis, and J. O. Leckie, Modeling ionic strength effects on anion adsorption at hydrous oxide/solution interfaces, Journal of Colloid and Interface Science, vol.125, issue.2, pp.717-726, 1988.
DOI : 10.1016/0021-9797(88)90039-2

K. F. Hayes, A. L. Roe, G. E. Brown, K. O. Hodgson, J. O. Leckie et al., In-situ X-Ray Absorption Study of Surface Complexes -Selenium Oxyanions on Alpha-FeOOH, Science, issue.4828, pp.238-783, 1987.

T. Henmi, K. Tange, T. Minagawa, Y. , and N. , Effect of SiO2/Al2O3 Ratio on the Thermal Reactions of Allophane. II. Infrared and X-Ray Powder Diffraction Data, Clays and Clay Minerals, vol.29, issue.2, pp.124-128, 1981.
DOI : 10.1346/CCMN.1981.0290206

T. Hiemstra, R. Rietra, V. Riemsdijk, and W. H. , Surface complexation of selenite on goethite: MO/DFT geometry and charge distribution, Croatica Chemica Acta, vol.80, pp.3-4, 2007.

T. Hiemstra, V. Riemsdijk, and W. H. , Surface Structural Ion Adsorption Modeling of Competitive Binding of Oxyanions by Metal (Hydr)oxides, Journal of Colloid and Interface Science, vol.210, issue.1, pp.182-193, 1999.
DOI : 10.1006/jcis.1998.5904

T. Hiemstra, P. Venema, and W. H. Vanriemsdijk, Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle, Journal of Colloid and Interface Science, vol.184, issue.2, 1996.
DOI : 10.1006/jcis.1996.0666

M. Ihnat, Occurence and distribution of Selenium, 1989.

M. K. John, W. M. Saunders, and J. H. Watkinson, Selenium adsorption by New Zealand soils, New Zealand Journal of Agricultural Research, vol.14, issue.1, pp.143-151, 1975.
DOI : 10.1080/00288233.1967.10423083

J. Kohrle, R. Brigelius-flohe, A. Bock, R. Gartner, O. Meyer et al., Selenium in Biology: Facts and Medical Perspectives, Biological Chemistry, vol.381, issue.9-10, pp.9-10, 2000.
DOI : 10.1515/BC.2000.107

J. D. Kubicki, K. D. Kwon, K. W. Paul, and D. L. Sparks, Surface complex structures modelled with quantum chemical calculations: carbonate, phosphate, sulphate, arsenate and arsenite, European Journal of Soil Science, vol.66, issue.4, pp.932-944, 2007.
DOI : 10.1021/la0353834

H. W. Lakin, Selenium Accumulation in Soils and Its Absorption by Plants and Animals, Geological Society of America Bulletin, vol.83, issue.1, pp.181-189, 1972.
DOI : 10.1130/0016-7606(1972)83[181:SAISAI]2.0.CO;2

S. L. Lo, C. , and T. Y. , Adsorption of Se(IV) and Se(VI) on an iron-coated sand from water, Chemosphere, vol.35, issue.5, pp.35-919, 1997.
DOI : 10.1016/S0045-6535(97)00190-2

A. Manceau, C. , and L. , The Mechanism of Selenate Adsorption on Goethite and Hydrous Ferric Oxide, Journal of Colloid and Interface Science, vol.168, issue.1, pp.87-93, 1994.
DOI : 10.1006/jcis.1994.1396

G. Meunier and M. Bertaud, Crystal chemistry of selenium (+IV). 2. Crystal structure of ZnSe 2 O 5, Acta Crystallographica Section B-Structural Science, issue.DEC15, pp.30-2840, 1974.

G. Meunier, M. Bertaud, and J. Galy, Crystal chemistry of selenium (+IV), 1974.

R. Moreno-reyes, C. Suetens, F. Mathieu, F. Begaux, D. Zhu et al., Kashin???Beck Osteoarthropathy in Rural Tibet in Relation to Selenium and Iodine Status, New England Journal of Medicine, vol.339, issue.16, pp.339-1112, 1998.
DOI : 10.1056/NEJM199810153391604

A. Abdelfattah and K. Wada, ADSORPTION OF LEAD, COPPER, ZINC, COBALT, AND CADMIUM BY SOILS THAT DIFFER IN CATION-EXCHANGE MATERIALS, Journal of Soil Science, vol.16, issue.2, pp.271-283, 1981.
DOI : 10.1111/j.1365-2389.1981.tb01706.x

F. F. Abraham, The interfacial density profile of a Lennard???Jones fluid in contact with a (100) Lennard???Jones wall and its relationship to idealized fluid/wall systems: A Monte Carlo simulation, The Journal of Chemical Physics, vol.68, issue.8, 1978.
DOI : 10.1063/1.436229

F. Alvarez-ramirez, Ab initio simulation of the structural and electronic properties of aluminosilicate and aluminogermanate natotubes with imogolitelike structure, Physical Review B, issue.12, p.76, 2007.

Y. Arai, M. Mcbeath, J. R. Bargar, J. Joye, D. et al., Uranyl adsorption and surface speciation at the imogolite???water interface: Self-consistent spectroscopic and surface complexation models, Geochimica et Cosmochimica Acta, vol.70, issue.10, pp.70-2492, 2006.
DOI : 10.1016/j.gca.2006.02.013

E. Balan, M. Lazzeri, G. Morin, and F. Mauri, First-principles study of the OH-stretching modes of gibbsite, American Mineralogist, vol.91, issue.1, pp.115-119, 2006.
DOI : 10.2138/am.2006.1922

URL : https://hal.archives-ouvertes.fr/hal-00022563

J. Baltrusaitis, J. Schuttlefield, J. H. Jensen, and V. H. Grassian, FTIR spectroscopy combined with quantum chemical calculations to investigate adsorbed nitrate on aluminium oxide surfaces in the presence and absence of coadsorbed water, Physical Chemistry Chemical Physics, issue.36, pp.9-4970, 2007.

I. Basile-doelsch, R. Amundson, W. E. Stone, C. A. Masiello, J. Y. Bottero et al., Mineralogical control of organic carbon dynamics in a volcanic ash soil on La Reunion, European Journal of Soil Science, vol.8, issue.0, pp.56-689, 2005.
DOI : 10.1016/0009-2541(87)90106-9

D. Beaglehole and H. K. Christenson, Vapor adsorption on mica and silicon: entropy effects, layering, and surface forces, The Journal of Physical Chemistry, vol.96, issue.8, pp.96-3395, 1992.
DOI : 10.1021/j100187a040

J. D. Bernal, F. , and R. H. , A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions, The Journal of Chemical Physics, vol.1, issue.8, pp.515-548, 1933.
DOI : 10.1063/1.1749327

B. R. Bickmore, K. M. Rosso, C. J. Tadanier, E. J. Bylaska, and D. Doud, Bondvalence methods for pK(a) prediction. II. Bond-valence, electrostatic, molecular geometry, and solvation effects, Geochimica et Cosmochimica Acta, issue.16, pp.70-4057, 2006.

B. R. Bickmore, C. J. Tadanier, K. M. Rosso, W. D. Monn, and D. L. Eggett, Bond-Valence methods for pK(a) prediction: critical reanalysis and a new approach, Geochimica et Cosmochimica Acta, issue.9, pp.68-2025, 2004.

I. D. Brown, The Chemical Bond in Inorganic Chemistry: The Bond Valence Model, 2002.

I. D. Brown, A. , and D. , Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal-Stucture Database, Acta Crystallographica Section B-Structural Science, pp.41-244, 1985.

W. Cantrell and G. E. Ewing, Thin Film Water on Muscovite Mica, The Journal of Physical Chemistry B, vol.105, issue.23, pp.5434-5439, 2001.
DOI : 10.1021/jp004305b

J. G. Catalano, P. Fenter, and C. Park, Water ordering and surface relaxations at the hematite (110)???water interface, Geochimica et Cosmochimica Acta, vol.73, issue.8, pp.73-2242, 2009.
DOI : 10.1016/j.gca.2009.02.001

T. Chevallier, T. Woignier, J. Toucet, E. Blanchart, and P. Dieudonne, Fractal structure in natural gels: effect on carbon sequestration in volcanic soils, 14th International Sol-Gel Conference, pp.231-238, 2007.
DOI : 10.1007/s10971-008-1795-z

P. D. Cradwick, K. Wada, J. D. Russell, . N. Yoshinag, C. R. Masson et al., Imogolite, a hydrated aluminum silicate of tubular structure, Nature- Physical Science, issue.104, pp.240-187, 1972.

B. Creton, D. Bougeard, K. S. Smirnov, J. Guilment, and O. Poncelet, Molecular dynamics study of hydrated imogolite : 2. Structure and dynamics of confined water, Physical Chemistry Chemical Physics, vol.102, issue.32, pp.10-4879, 2008.
DOI : 10.1021/jp800802u

URL : https://hal.archives-ouvertes.fr/hal-00316024

E. R. Cruz-chu, A. Aksimentiev, and K. Schulten, Water???Silica Force Field for Simulating Nanodevices, The Journal of Physical Chemistry B, vol.110, issue.43, pp.21497-21508, 2006.
DOI : 10.1021/jp063896o

R. T. Cygan, J. A. Greathouse, H. Heinz, and A. G. Kalinichev, Molecular models and simulations of layered materials, Journal of Materials Chemistry, vol.262, issue.236, pp.2470-2481, 2009.
DOI : 10.1039/b819076c

R. T. Cygan, J. J. Liang, and A. G. Kalinichev, Molecular Models of Hydroxide, Oxyhydroxide, and Clay Phases and the Development of a General Force Field, The Journal of Physical Chemistry B, vol.108, issue.4, pp.1255-1266, 2004.
DOI : 10.1021/jp0363287

R. A. Dahlgren and F. C. Ugolini, Formation and stability of imogolite in a tephritic spodosol, Cascade Range, Geochimica et Cosmochimica Acta, issue.8, pp.53-1897, 1989.

J. A. Davis, R. O. James, and J. O. Leckie, Surface ionization and complexation at the oxide/water interface, Journal of Colloid and Interface Science, vol.63, issue.3, pp.480-499, 1978.
DOI : 10.1016/S0021-9797(78)80009-5

M. Egli, M. Nater, A. Mirabella, S. Raimondi, M. Ploetze et al., Clay minerals, oxyhydroxide formation, element leaching and humus development in volcanic soils, Geoderma, vol.143, issue.1-2, pp.101-114, 2008.
DOI : 10.1016/j.geoderma.2007.10.020

P. Fenter, C. Park, K. L. Nagy, and N. C. Sturchio, Resonant anomalous X-ray reflectivity as a probe of ion adsorption at solid???liquid interfaces, 9th International Conference on Surface X-Ray and Neutton Scattering, pp.5654-5659, 2006.
DOI : 10.1016/j.tsf.2006.12.118

P. Fenter, C. Park, and N. C. Sturchio, Adsorption of Rb+ and Sr2+ at the orthoclase (001)???solution interface, Geochimica et Cosmochimica Acta, vol.72, issue.7, pp.72-1848, 2008.
DOI : 10.1016/j.gca.2007.12.016

P. Fenter, C. Park, Z. Zhang, W. , and S. , Observation of subnanometre-high surface topography with X-ray reflection phase-contrast microscopy, Nature Physics, vol.263, issue.10, pp.700-704, 2006.
DOI : 10.1016/S0016-7037(99)00225-2

P. Fenter and N. C. Sturchio, Mineral???water interfacial structures revealed by synchrotron X-ray scattering, Progress in Surface Science, vol.77, issue.5-8, pp.5-8, 2004.
DOI : 10.1016/j.progsurf.2004.12.001

Y. Gan and G. V. Franks, Charging Behavior of the Gibbsite Basal (001) Surface in NaCl Solution Investigated by AFM Colloidal Probe Technique, Langmuir, vol.22, issue.14, pp.22-6087, 2006.
DOI : 10.1021/la053391+

P. Geissbuhler, P. Fenter, E. Dimasi, G. Srajer, L. B. Sorensen et al., Three-dimensional structure of the calcite???water interface by surface X-ray scattering, Surface Science, vol.573, issue.2, pp.191-203, 2004.
DOI : 10.1016/j.susc.2004.09.036

W. R. Good, A comparison of contact angle interpretations, Journal of Colloid and Interface Science, vol.44, issue.1, pp.63-71, 1973.
DOI : 10.1016/0021-9797(73)90192-6

A. L. Goodman, E. T. Bernard, and V. H. Grassian, Spectroscopic Study of Nitric Acid and Water Adsorption on Oxide Particles:?? Enhanced Nitric Acid Uptake Kinetics in the Presence of Adsorbed Water, The Journal of Physical Chemistry A, vol.105, issue.26, pp.105-6443, 2001.
DOI : 10.1021/jp003722l

J. P. Gustafsson, The Surface Chemistry of Imogolite, Clays and Clay Minerals, vol.49, issue.1, pp.73-80, 2001.
DOI : 10.1346/CCMN.2001.0490106

T. Hiemstra, J. C. Dewit, and W. H. Vanriemsdijk, Multisite proton adsorption modeling at the solid/solution interface of (hydr)oxides: A new approach, Journal of Colloid and Interface Science, vol.133, issue.1, pp.105-117, 1989.
DOI : 10.1016/0021-9797(89)90285-3

T. Hiemstra and W. H. Vanriemsdijk, A Surface Structural Approach to Ion Adsorption: The Charge Distribution (CD) Model, Journal of Colloid and Interface Science, vol.179, issue.2, pp.488-508, 1996.
DOI : 10.1006/jcis.1996.0242

T. A. Kendall, M. , and S. T. , Water-Induced Reconstruction that Affects Mobile Ions on the Surface of Calcite, The Journal of Physical Chemistry A, vol.111, issue.3, pp.505-514, 2007.
DOI : 10.1021/jp0647129

G. Kresse and J. Hafner, Ab initio molecular dynamics for liquid metals, Journal of Non-Crystalline Solids, vol.192, issue.193, pp.558-561, 1993.
DOI : 10.1016/0022-3093(95)00355-X

G. Kresse and D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method, Physical Review B, vol.59, issue.3, pp.1758-1775, 1999.
DOI : 10.1103/PhysRevB.59.1758

C. Levard, E. Doelsch, J. Rose, A. Masion, I. Basile-doelsch et al., Role of natural nanoparticles on the speciation of Ni in andosols of la Reunion, Geochimica et Cosmochimica Acta, vol.73, issue.16, pp.73-4750, 2009.
DOI : 10.1016/j.gca.2009.05.053

URL : https://hal.archives-ouvertes.fr/hal-00741166

D. F. Liu, G. Ma, M. Xu, A. , and H. C. , Surfaces:?? Observation of Molecular Orientation and Surface Hydroxyl Groups as Sorption Sites, Environmental Science & Technology, vol.39, issue.1, pp.206-212, 2005.
DOI : 10.1021/es049066a

L. J. Michot, F. Villieras, M. Francois, J. Yvon, R. Ledred et al., The Structural Microscopic Hydrophilicity of Talc, Langmuir, vol.10, issue.10, pp.10-3765, 1994.
DOI : 10.1021/la00022a061

S. Plimpton, Fast Parallel Algorithms for Short-Range Molecular Dynamics, Journal of Computational Physics, vol.117, issue.1, pp.1-19, 1995.
DOI : 10.1006/jcph.1995.1039

C. A. Prestidge and J. And-ralston, Contact angle studies of particulate sulphide minerals, Minerals Engineering, vol.9, issue.1, pp.85-102, 1995.
DOI : 10.1016/0892-6875(95)00133-6

A. Rahaman, V. H. Grassian, and C. J. Margulis, Dynamics of Water Adsorption onto a Calcite Surface as a Function of Relative Humidity, The Journal of Physical Chemistry C, vol.112, issue.6, pp.2109-2115, 2008.
DOI : 10.1021/jp077594d

S. Rahman, H. Takaki, M. Tamai, and Y. Nagatomo, Distribution of Zinc, Manganese, Copper, Cobalt, and Nickel in Andosols Profiles, Soil Science and Plant Nutrition, vol.5, issue.4, pp.881-891, 1996.
DOI : 10.2136/sssaj1969.03615995003300010017x

M. Rini, B. Z. Magnes, E. Pines, and E. T. Nibbering, Real-Time Observation of Bimodal Proton Transfer in Acid-Base Pairs in Water, Science, vol.301, issue.5631, pp.301-349, 2003.
DOI : 10.1126/science.1085762

J. Rosenqvist, P. Persson, and S. Sjoberg, Protonation and charging of nanosized gibbsite (alpha-Al(OH)(3)) particles in aqueous suspension, 2002.

H. Saalfeld and M. Wedde, Refinement of crystal-structure of gibbsite, Al(OH) 3 . Zeitschrift Fur Kristallographie, pp.129-135, 1974.

P. W. Schindler and W. Stumm, Aquatic Surface Chemistry, Chemical Processes at the Particle-Water Interface, 1987.

D. E. Smith, Molecular Computer Simulations of the Swelling Properties and Interlayer Structure of Cesium Montmorillonite, Langmuir, vol.14, issue.20, pp.5959-5967, 1998.
DOI : 10.1021/la980015z

D. Spagnoli, J. F. Banfield, P. , and S. C. , Free Energy Change of Aggregation of Nanoparticles, The Journal of Physical Chemistry C, vol.112, issue.38, pp.14731-14736, 2008.
DOI : 10.1021/jp804966c

G. Sposito, The surface chemistry of natural particles. 242 p, 2004.

G. Sposito, N. T. Skipper, R. Sutton, S. H. Park, A. K. Soper et al., Surface geochemistry of the clay minerals. National-Academy-of- Sciences Colloquium on Geology, Mineralogy, and Human Welfare, pp.3358-3364, 1998.

D. A. Sverjensky, Prediction of surface charge on oxides in salt solutions: Revisions for 1:1 (M+L???) electrolytes, Geochimica et Cosmochimica Acta, vol.69, issue.2, pp.225-257, 2005.
DOI : 10.1016/j.gca.2004.05.040

B. K. Theng and G. D. Yuan, Nanoparticles in the Soil Environment, Elements, vol.4, issue.6, pp.395-399, 2008.
DOI : 10.2113/gselements.4.6.395

F. C. Ugolini and R. A. Dahlgren, Weathering Environments and Occurrence of Imogolite/Allophane in Selected Andisols and Spodosols, Soil Science Society of America Journal, vol.55, issue.4, pp.1166-1171, 1991.
DOI : 10.2136/sssaj1991.03615995005500040045x

E. Veilly, J. Roques, M. C. Jodin-caumon, B. Humbert, R. Drot et al., Uranyl interaction with the hydrated (001) basal face of gibbsite: A combined theoretical and spectroscopic study, The Journal of Chemical Physics, vol.129, issue.24, p.129, 2008.
DOI : 10.1063/1.3042142

URL : https://hal.archives-ouvertes.fr/in2p3-00359072

M. Villalobos, M. A. Cheney, and J. Alcaraz-cienfuegos, Goethite surface reactivity: II. A microscopic site-density model that describes its surface area-normalized variability, Journal of Colloid and Interface Science, vol.336, issue.2, pp.412-422, 2009.
DOI : 10.1016/j.jcis.2009.04.052

K. Wada, Y. , and N. , Structure of imogolite, American Mineralogist, vol.54, issue.12, p.50, 1969.

M. C. Wander, C. , and A. E. , Structural and Dielectric Properties of Quartz???Water Interfaces, The Journal of Physical Chemistry C, vol.112, issue.50, pp.19986-19994, 2008.
DOI : 10.1021/jp803642c

C. Wang, J. A. Mckeague, and H. Kodama, Pedogenic Imogolite and Soil Environments: Case Study of Spodosols in Quebec, Canada1, Soil Science Society of America Journal, vol.50, issue.3, pp.711-718, 1986.
DOI : 10.2136/sssaj1986.03615995005000030032x

J. W. Wang, A. G. Kalinichev, and R. J. Kirkpatrick, Effects of substrate structure and composition on the structure, dynamics, and energetics of water at mineral surfaces: A molecular dynamics modeling study, Geochimica et Cosmochimica Acta, vol.70, issue.3, pp.562-582, 2006.
DOI : 10.1016/j.gca.2005.10.006

H. D. Whitley and D. E. Smith, Free energy, energy, and entropy of swelling in Cs???, Na???, and Sr???montmorillonite clays, The Journal of Chemical Physics, vol.120, issue.11, pp.5387-5395, 2004.
DOI : 10.1063/1.1648013

M. A. Wilson, N. H. Tran, A. S. Milev, G. S. Kannangara, H. Volk et al., Nanomaterials in soils, Geoderma, vol.146, issue.1-2, pp.291-302, 2008.
DOI : 10.1016/j.geoderma.2008.06.004

M. Xu, D. F. Liu, A. , and H. C. , Ethylenediamine at Air/Liquid and Air/Silica Interfaces:?? Protonation Versus Hydrogen Bonding Investigated by Sum Frequency Generation Spectroscopy, Environmental Science & Technology, vol.40, issue.5, pp.40-1566, 2006.
DOI : 10.1021/es051537l

C. J. Yu, A. G. Richter, A. Datta, M. K. Durbin, and P. Dutta, Observation of Molecular Layering in Thin Liquid Films Using X-Ray Reflectivity, Physical Review Letters, vol.82, issue.11, pp.82-2326, 1999.
DOI : 10.1103/PhysRevLett.82.2326

Z. Zhang, P. Fenter, L. Cheng, N. C. Sturchio, M. J. Bedzyk et al., Ion Adsorption at the Rutile???Water Interface:?? Linking Molecular and Macroscopic Properties, Langmuir, vol.20, issue.12, pp.20-4954, 2004.
DOI : 10.1021/la0353834

P. Acero, C. Ayora, C. Torrento, and J. M. Nieto, The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite, Geochimica et Cosmochimica Acta, vol.70, issue.16, pp.70-4130, 2006.
DOI : 10.1016/j.gca.2006.06.1367

R. J. Barham, Schwertmannite: A unique mineral, contains a replaceable ligand, transforms to jarosites, hematites, and/or basic iron sulfate, Journal of Materials Research, vol.55, issue.10, pp.2751-2758, 1997.
DOI : 10.1557/JMR.1997.0366

J. M. Bigham, L. Carlson, and E. Murad, Schwertmannite, a New Iron Oxyhydroxysulphate from Pyh??salmi, Finland, and Other Localities, Mineralogical Magazine, vol.58, issue.393, pp.58-641, 1994.
DOI : 10.1180/minmag.1994.058.393.14

J. M. Bigham, U. Schwertmann, L. Carlson, and E. Murad, A poorly crystallized oxyhydroxysulfate of iron formed by bacterial oxidation of Fe(II) in acid-mine waters, Geochimica et Cosmochimica Acta, issue.10, pp.54-2743, 1990.

J. M. Bigham, U. Schwertmann, S. J. Traina, R. L. Winland, and M. Wolf, Schwertmannite and the chemical modeling of iron in acid sulfate waters, Geochimica et Cosmochimica Acta, vol.60, issue.12, 1996.
DOI : 10.1016/0016-7037(96)00091-9

E. D. Burton, R. T. Bush, L. A. Sullivan, M. , and D. R. , Reductive transformation of iron and sulfur in schwertmannite-rich accumulations associated with acidified coastal lowlands, Geochimica et Cosmochimica Acta, vol.71, issue.18, pp.71-4456, 2007.
DOI : 10.1016/j.gca.2007.07.007

L. Carlson, J. M. Bigham, U. Schwertmann, A. Kyek, and F. Wagner, Scavenging of As from Acid Mine Drainage by Schwertmannite and Ferrihydrite:?? A Comparison with Synthetic Analogues, Environmental Science & Technology, vol.36, issue.8, pp.36-1712, 2002.
DOI : 10.1021/es0110271

P. J. Chupas, X. Y. Qiu, J. C. Hanson, P. L. Lee, C. P. Grey et al., Rapid-acquisition pair distribution function (RA-PDF) analysis, Journal of Applied Crystallography, vol.36, issue.6, pp.1342-1347, 2003.
DOI : 10.1107/S0021889803017564

URL : http://arxiv.org/abs/cond-mat/0304638

S. J. Clark, M. D. Segall, C. J. Pickard, P. J. Hasnip, M. J. Probert et al., Abstract, Zeitschrift f??r Kristallographie - Crystalline Materials, vol.220, issue.5/6, pp.5-6, 2005.
DOI : 10.1524/zkri.220.5.567.65075

J. E. Daniels and M. Drakopoulos, High-energy X-ray diffraction using the Pixium 4700 flat-panel detector, Journal of Synchrotron Radiation, vol.16, issue.4, pp.1-6, 2009.
DOI : 10.1107/S0909049509015519

T. Egami and S. J. Billinge, Underneath the Bragg Peaks, Materials Today, vol.6, issue.6, 2003.
DOI : 10.1016/S1369-7021(03)00635-7

C. L. Farrow, P. Juhas, J. W. Liu, D. Bryndin, E. S. Bozin et al., PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals, Journal of Physics: Condensed Matter, vol.19, issue.33, pp.335219-335226, 2007.
DOI : 10.1088/0953-8984/19/33/335219

W. B. Gagliano, M. R. Brill, J. M. Bigham, F. S. Jones, and S. J. Traina, Chemistry and mineralogy of ochreous sediments in a constructed mine drainage wetland, Geochimica et Cosmochimica Acta, vol.68, issue.9, 2004.
DOI : 10.1016/j.gca.2003.10.038

B. Gilbert, Finite size effects on the real-space pair distribution function of nanoparticles, Journal of Applied Crystallography, vol.41, issue.3, pp.554-562, 2008.
DOI : 10.1107/S0021889808007905

C. Greffie, M. Amouric, and C. Parron, HRTEM study of freeze-dried and untreated synthetic ferrihydrites: consequences of sample processing, Clay Minerals, vol.36, issue.3, pp.381-387, 2001.
DOI : 10.1180/000985501750539472

A. P. Hammersley, S. O. Svensson, M. Hanfland, A. N. Fitch, and D. Hausermann, Two-dimensional detector software: From real detector to idealised image or two-theta scan, 4th Workshop of the IUCr High Pressure Group on Synchrotron and Neutron Sources, pp.235-248, 1995.
DOI : 10.1107/S0021889886089458

J. Jonsson, P. Persson, S. Sjoberg, and L. Lovgren, Schwertmannite precipitated from acid mine drainage: phase transformation, sulphate release and surface properties, Applied Geochemistry, vol.20, issue.1, pp.179-191, 2005.
DOI : 10.1016/j.apgeochem.2004.04.008

M. Loan, J. M. Cowley, R. Hart, and G. M. Parkinson, Evidence on the structure of synthetic schwertmannite, American Mineralogist, vol.89, issue.11-12, pp.11-12, 2004.
DOI : 10.2138/am-2004-11-1220

F. M. Michel, S. M. Antao, P. J. Chupas, P. L. Lee, J. B. Parise et al., Short- to Medium-Range Atomic Order and Crystallite Size of the Initial FeS Precipitate from Pair Distribution Function Analysis, Chemistry of Materials, vol.17, issue.25, pp.17-6246, 2005.
DOI : 10.1021/cm050886b

F. M. Michel, L. Ehm, S. M. Antao, P. L. Lee, P. J. Chupas et al., The structure of ferrihydrite, a nanocrystalline material, Science, issue.5832, pp.316-1726, 2007.

F. M. Michel, L. Ehm, G. Liu, W. Q. Han, S. M. Antao et al., Similarities in 2- and 6-Line Ferrihydrite Based on Pair Distribution Function Analysis of X-ray Total Scattering, Chemistry of Materials, vol.19, issue.6, pp.1489-1496, 2007.
DOI : 10.1021/cm062585n

D. Peak, R. G. Ford, and D. L. Sparks, An in Situ ATR-FTIR Investigation of Sulfate Bonding Mechanisms on Goethite, Journal of Colloid and Interface Science, vol.218, issue.1, pp.289-299, 1999.
DOI : 10.1006/jcis.1999.6405

J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized Gradient Approximation Made Simple, Physical Review Letters, vol.77, issue.18, pp.77-3865, 1996.
DOI : 10.1103/PhysRevLett.77.3865

J. E. Post, P. J. Heaney, R. B. Von-dreele, H. , and J. C. , Neutron and temperature-resolved synchrotron X-ray powder diffraction study of akagan??ite, American Mineralogist, vol.88, issue.5-6, 2003.
DOI : 10.2138/am-2003-5-607

X. Y. Qiu, E. S. Bozin, P. Juhas, T. Proffen, and S. J. Billinge, Reciprocal-space instrumental effects on the real-space neutron atomic pair distribution function, Journal of Applied Crystallography, vol.37, issue.1, pp.110-116, 2004.
DOI : 10.1107/S0021889803026670

S. Regenspurg and S. Peiffer, Arsenate and chromate incorporation in schwertmannite, Applied Geochemistry, vol.20, issue.6, pp.1226-1239, 2005.
DOI : 10.1016/j.apgeochem.2004.12.002

T. S. Rotting, M. A. Caraballo, J. A. Serrano, C. Ayora, and J. Carrera, Field application of calcite Dispersed Alkaline Substrate (calcite-DAS) for passive treatment of acid mine drainage with high Al and metal concentrations, Applied Geochemistry, vol.23, issue.6, pp.1660-1674, 2008.
DOI : 10.1016/j.apgeochem.2008.02.023

A. C. Scheinost, R. Kirsch, D. Banerjee, A. Fernandez-martinez, H. Zaenker et al., X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by Fe-II-bearing minerals, Journal of Contaminant Hydrology, vol.102, pp.3-4, 2008.

U. Schwertmann, C. , and R. M. , Iron Oxides in Laboratory, Soil Science, vol.156, issue.5, 1991.
DOI : 10.1097/00010694-199311000-00012

B. H. Toby and T. Egami, Accuracy of Pair Distribution Function analysis applied to crystalline and noncrystalline materials, Acta Crystallographica Section A, vol.48, pp.336-346, 1992.

G. A. Waychunas, S. C. Myneni, S. J. Traina, J. M. Bigham, C. C. Fuller et al., Reanalysis of the Schwertmannite structure and the incorporation of SO 4 2- groups: An IR, XAS, WAXS and simulation study, Eleventh Annual V. M, 2001.

J. Y. Yu, B. Heo, I. K. Choi, J. P. Cho, C. et al., Apparent solubilities of schwertmannite and ferrihydrite in natural stream waters polluted by mine drainage, Geochimica et Cosmochimica Acta, vol.63, issue.19-20, 1999.
DOI : 10.1016/S0016-7037(99)00261-6

W. C. Ackerman, D. M. Smith, J. C. Huling, Y. W. Kim, J. K. Bailey et al., Gas/vapor adsorption in imogolite: a microporous tubular aluminosilicate, Langmuir, vol.9, issue.4, pp.1051-1057, 1993.
DOI : 10.1021/la00028a029

I. Basile-doelsch, R. Amundson, W. E. Stone, C. A. Masiello, J. Y. Bottero et al., Mineralogical control of organic carbon dynamics in a volcanic ash soil on La Reunion, European Journal of Soil Science, vol.8, issue.0, pp.56-689, 2005.
DOI : 10.1016/0009-2541(87)90106-9

J. J. Dynes and P. M. Huang, Influence of Organic Acids on Selenite Sorption by Poorly Ordered Aluminum Hydroxides, Soil Science Society of America Journal, vol.61, issue.3, pp.61-772, 1997.
DOI : 10.2136/sssaj1997.03615995006100030010x

B. Gilbert, F. Huang, H. Z. Zhang, G. A. Waychunas, and J. F. Banfield, Nanoparticles: Strained and Stiff, Science, vol.305, issue.5684, pp.305-651, 2004.
DOI : 10.1126/science.1098454

T. Hiemstra and W. H. Vanriemsdijk, A Surface Structural Approach to Ion Adsorption: The Charge Distribution (CD) Model, Journal of Colloid and Interface Science, vol.179, issue.2, pp.488-508, 1996.
DOI : 10.1006/jcis.1996.0242

C. Papelis, G. E. Brown, G. A. Parks, and J. O. Leckie, X-ray Absorption Spectroscopic Studies of Cadmium and Selenite Adsorption on Aluminum Oxides, Langmuir, vol.11, issue.6, pp.11-2041, 1995.
DOI : 10.1021/la00006a033

A. Rahaman, V. H. Grassian, and C. J. Margulis, Dynamics of Water Adsorption onto a Calcite Surface as a Function of Relative Humidity, The Journal of Physical Chemistry C, vol.112, issue.6, pp.2109-2115, 2008.
DOI : 10.1021/jp077594d

C. Reilly, Selenium in food and health. 360 p, 1997.

D. Spagnoli, J. F. Banfield, P. , and S. C. , Free Energy Change of Aggregation of Nanoparticles, The Journal of Physical Chemistry C, vol.112, issue.38, pp.14731-14736, 2008.
DOI : 10.1021/jp804966c

R. Stone, A Medical Mystery in Middle China, Science, vol.324, issue.5933, pp.1378-1381, 2009.
DOI : 10.1126/science.324_1378

G. A. Waychunas, S. C. Myneni, S. J. Traina, J. M. Bigham, C. C. Fuller et al., Reanalysis of the Schwertmannite structure and the incorporation of SO 4 2- groups: An IR, XAS, WAXS and simulation study, 2001.

W. C. Ackerman, D. M. Smith, J. C. Huling, Y. W. Kim, J. K. Bailey et al., Gas/vapor adsorption in imogolite: a microporous tubular aluminosilicate, Langmuir, vol.9, issue.4, pp.1051-1057, 1993.
DOI : 10.1021/la00028a029

F. Alvarez-ramirez, Ab initio simulation of the structural and electronic properties of aluminosilicate and aluminogermanate natotubes with imogolitelike structure, Physical Review B, issue.12, p.76, 2007.

S. M. Barrett, P. M. Budd, P. , and C. , The synthesis and characterization of imogolite, European Polymer Journal, vol.27, issue.7, pp.609-612, 1991.
DOI : 10.1016/0014-3057(91)90144-D

P. J. Chupas, X. Y. Qiu, J. C. Hanson, P. L. Lee, C. P. Grey et al., Rapid-acquisition pair distribution function (RA-PDF) analysis, Journal of Applied Crystallography, vol.36, issue.6, pp.1342-1347, 2003.
DOI : 10.1107/S0021889803017564

URL : http://arxiv.org/abs/cond-mat/0304638

P. D. Cradwick, K. Wada, J. D. Russell, . N. Yoshinag, C. R. Masson et al., Imogolite, a hydrated aluminum silicate of tubular structure, Nature- Physical Science, issue.104, pp.240-187, 1972.

B. Creton, D. Bougeard, K. S. Smirnov, J. Guilment, and O. Poncelet, Molecular dynamics study of hydrated imogolite : 2. Structure and dynamics of confined water, Physical Chemistry Chemical Physics, vol.102, issue.32, pp.10-4879, 2008.
DOI : 10.1021/jp800802u

URL : https://hal.archives-ouvertes.fr/hal-00316024

J. E. Daniels and M. Drakopoulos, High-energy X-ray diffraction using the Pixium 4700 flat-panel detector, Journal of Synchrotron Radiation, vol.16, issue.4, pp.1-6, 2009.
DOI : 10.1107/S0909049509015519

L. Denaix, I. Lamy, and J. Y. Bottero, Structure and affinity towards Cd2+, Cu2+, Pb2+ of synthetic colloidal amorphous aluminosilicates and their precursors, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.158, issue.3, pp.315-325, 1999.
DOI : 10.1016/S0927-7757(99)00096-5

V. C. Farmer, M. J. Adams, A. R. Fraser, and F. Palmieri, Synthetic Imogolite: Properties, Synthesis, and Possible Applications, Clay Minerals, vol.18, issue.4, pp.459-472, 1983.
DOI : 10.1180/claymin.1983.018.4.11

V. C. Farmer, A. R. Fraser, T. , and J. M. , Synthesis of imogolite -Tubular aluminum silicate polymer, Journal of the Chemical Society-Chemical Communications, issue.13, pp.462-463, 1977.

C. L. Farrow, P. Juhas, J. W. Liu, D. Bryndin, E. S. Bozin et al., PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals, Journal of Physics: Condensed Matter, vol.19, issue.33, pp.335219-335226, 2007.
DOI : 10.1088/0953-8984/19/33/335219

B. Gilbert, Finite size effects on the real-space pair distribution function of nanoparticles, Journal of Applied Crystallography, vol.41, issue.3, pp.554-562, 2008.
DOI : 10.1107/S0021889808007905

A. P. Hammersley, S. O. Svensson, M. Hanfland, A. N. Fitch, and D. Hausermann, Two-dimensional detector software: From real detector to idealised image or two-theta scan, 4th Workshop of the IUCr High Pressure Group on Synchrotron and Neutron Sources, pp.235-248, 1995.
DOI : 10.1107/S0021889886089458

T. Kogure, A. Suzuki, M. Mitome, and Y. Bando, Quantitative electron diffraction analyses of natural and synthetic imogolites, 13th Annual VM Goldschmidt Conference, pp.226-226, 2003.

S. Konduri, S. Mukherjee, and S. Nair, Strain energy minimum and vibrational properties of single-walled aluminosilicate nanotubes, Physical Review B, vol.74, issue.3, 2006.
DOI : 10.1103/PhysRevB.74.033401

F. M. Michel, L. Ehm, S. M. Antao, P. L. Lee, P. J. Chupas et al., The structure of ferrihydrite, a nanocrystalline material, Science, issue.5832, pp.316-1726, 2007.

F. M. Michel, L. Ehm, G. Liu, W. Q. Han, S. M. Antao et al., Similarities in 2- and 6-Line Ferrihydrite Based on Pair Distribution Function Analysis of X-ray Total Scattering, Chemistry of Materials, vol.19, issue.6, pp.1489-1496, 2007.
DOI : 10.1021/cm062585n

S. Mukherjee, V. A. Bartlow, and S. Nair, Phenomenology of the Growth of Single-Walled Aluminosilicate and Aluminogermanate Nanotubes of Precise Dimensions, Chemistry of Materials, vol.17, issue.20, pp.17-4900, 2005.
DOI : 10.1021/cm0505852

F. Ohashi, S. Tomura, K. Akaku, S. Hayashi, and S. I. Wada, Characterization of synthetic imogolite nanotubes as gas storage, Journal of Materials Science, vol.39, issue.5, pp.1799-1801, 2004.
DOI : 10.1023/B:JMSC.0000016188.04444.36

X. Y. Qiu, E. S. Bozin, P. Juhas, T. Proffen, and S. J. Billinge, Reciprocal-space instrumental effects on the real-space neutron atomic pair distribution function, Journal of Applied Crystallography, vol.37, issue.1, pp.110-116, 2004.
DOI : 10.1107/S0021889803026670

A. C. Scheinost, R. Kirsch, D. Banerjee, A. Fernandez-martinez, H. Zaenker et al., X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by Fe-II-bearing minerals, Journal of Contaminant Hydrology, vol.102, pp.3-4, 2008.

K. Tamura and K. Kawamura, Molecular Dynamics Modeling of Tubular Aluminum Silicate:?? Imogolite, The Journal of Physical Chemistry B, vol.106, issue.2, pp.271-278, 2002.
DOI : 10.1021/jp0124793

B. H. Toby and T. Egami, Accuracy of Pair Distribution Function analysis applied to crystalline and noncrystalline materials, Acta Crystallographica Section A, vol.48, pp.336-346, 1992.

F. C. Ugolini and R. A. Dahlgren, Weathering Environments and Occurrence of Imogolite/Allophane in Selected Andisols and Spodosols, Soil Science Society of America Journal, vol.55, issue.4, pp.1166-1171, 1991.
DOI : 10.2136/sssaj1991.03615995005500040045x

K. Wada, Allophane and imogolite, Minerals in soil environments, pp.1051-1087, 1989.

S. I. Wada, Imogolite Synthesis at 25??C, Clays and Clay Minerals, vol.35, issue.5, pp.379-384, 1987.
DOI : 10.1346/CCMN.1987.0350508

S. I. Wada, A. Eto, and K. Wada, SYNTHETIC ALLOPHANE AND IMOGOLITE, Journal of Soil Science, vol.41, issue.2, p.347, 1979.
DOI : 10.1111/j.1365-2389.1979.tb00991.x

N. Yoshinaga, Identification of imogolite in the filmy gel materials in the imaichi and shichihonzakura purlice beds, Soil Science and Plant Nutrition, vol.53, issue.65, pp.238-246, 1968.
DOI : 10.1080/00380768.1968.10432771

J. Zang, S. Konduri, S. Nair, and D. S. Sholl, Self-Diffusion of Water and Simple Alcohols in Single-Walled Aluminosilicate Nanotubes, ACS Nano, vol.3, issue.6, pp.1548-1556, 2009.
DOI : 10.1021/nn9001837

G. Montes-hernandez, A. Fernandez-martinez, and F. Renard, Novel Method to Estimate the Linear Growth Rate of Submicrometric Calcite Produced in a Triphasic Gas???Liquid???Solid System, Crystal Growth & Design, vol.9, issue.10
DOI : 10.1021/cg9005778

URL : https://hal.archives-ouvertes.fr/insu-00426614

A. Fernandez-martinez and L. Charlet, Selenium environmental cycling and bioavailability: a structural chemist point of view, Reviews in Environmental Science and Bio/Technology, vol.15, issue.C, pp.81-110, 2009.
DOI : 10.1007/s11157-009-9145-3

URL : https://hal.archives-ouvertes.fr/insu-00419346

L. Charlet, X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by Fe(II)-bearing minerals, Journal of Contaminant Hydrology, vol.102, pp.228-245, 2008.

F. Renard, Synthesis of a Se(0)/calcite composite using hydrothermal carbonation of Ca
URL : https://hal.archives-ouvertes.fr/insu-00351971

X. Turrillas, Arsenate incorporation in gypsum probed by neutron, X-ray scattering and DFT modelling, Journal of Physical Chemistry A, vol.112, pp.5159-5166, 2008.

L. Charlet, A. C. Scheinost, C. Tournassat, J. M. Greneche, A. Gehin et al., Electron transfer at the mineral/water interface: Selenium reduction by ferrous iron sorbed on clay. Geochimica Cosmochimica Acta, pp.5731-5749, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00261713

F. Bardelli, Arsenic uptake by gypsum and calcite: modeling and probing by neutron and xray scattering, Physica B: Condensed Matter, pp.385-386, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00194999

G. Roman-ross, G. J. Cuello, X. Turrillas, A. Fernandez-martinez, and L. Charlet, Arsenite sorption and co-precipitation with calcite, Chemical Geology, vol.233, issue.3-4, p.328, 2006.
DOI : 10.1016/j.chemgeo.2006.04.007

URL : https://hal.archives-ouvertes.fr/hal-00203399

G. Alonso, J. I. Zhang, J. Llobet, A. Jiang, and J. S. , Stress-induced large Curie temperature enhancement in Fe64Ni36 Invar alloy, Physical Review B, vol.80, p.64421, 2009.
URL : https://hal.archives-ouvertes.fr/insu-00419362

A. Fernandez-martinez, D. Martinez-blanco, M. J. Perez, G. J. Cuello, G. R. Castro et al., Structural and magnetic study of mechanically alloyed Fe30Cr70 by neutron thermo-diffractometry and magnetization measurements, Journal of Non-Crystalline Solids, vol.354, issue.47-51, pp.5156-5158, 2008.
DOI : 10.1016/j.jnoncrysol.2008.06.114

URL : https://hal.archives-ouvertes.fr/insu-00371298

I. Pozdnyakova, D. Zanghi, S. Brassamin, J. F. Brun, and D. L. Price, Ab-initio molecular dynamics simulations of the structure of liquid aluminates, Journal of Non-Crystalline Solids, vol.353, pp.1789-1792, 2007.
URL : https://hal.archives-ouvertes.fr/insu-00345856

G. J. Cuello, A. A. Piarristeguy, A. Fernandez-martinez, M. Fontana, and A. Pradel, Structure of chalcogenide glasses by neutron diffraction, Journal of Non-Crystalline Solids, vol.353, issue.8-10, pp.729-732, 2007.
DOI : 10.1016/j.jnoncrysol.2006.12.036

URL : https://hal.archives-ouvertes.fr/hal-00202335

A. Fernandez-martinez, P. Gorria, G. J. Cuello, J. D. Santos, and M. J. Perez, Kinetics of crystallization of FeB-based amorphous alloys studied by neutron thermo-diffractometry, Journal of Non-Crystalline Solids, vol.353, issue.8-10, pp.855-858, 2007.
DOI : 10.1016/j.jnoncrysol.2006.12.091

URL : https://hal.archives-ouvertes.fr/hal-00202332