D. M. Bernardi and M. W. Verbrugge, A Mathematical Model of the Solid-Polymer-Electrolyte Fuel Cell, Journal of The Electrochemical Society, vol.139, issue.9, pp.2477-2491, 1992.
DOI : 10.1149/1.2221251

A. A. Franco, PEMFC degradation modeling and analysis Polymer electrolyte membrane and direct methanol fuel cell technology (PEMFCs and DMFCs), 2011.

A. A. Franco and M. Gerard, Multiscale Model of Carbon Corrosion in a PEFC: Coupling with Electrocatalysis and Impact on Performance Degradation, Journal of The Electrochemical Society, vol.155, issue.4, pp.155-367, 2008.
DOI : 10.1149/1.2838165

. Mailley, Pt x Co y Catalysts Degradation in PEFC Environments: Mechanistic Insights, Journal of The Electrochemical Society, vol.156, pp.410-424, 2009.

A. A. Franco and M. Tembely, Transient Multiscale Modeling of Aging Mechanisms in a PEFC Cathode, Journal of The Electrochemical Society, vol.154, issue.7, pp.712-723, 2007.
DOI : 10.1149/1.2731040

A. A. Franco, PEMFC degradation modeling an analysis Polymer electrolyte membrane and direct methanol fuel cell technology, 2011.

A. A. Franco, M. Guinard, B. Barthe, and O. Lemaire, Impact of carbon monoxide on PEFC catalyst carbon support degradation under current-cycled operating conditions, Electrochimica Acta, vol.54, issue.22, pp.54-5267, 2009.
DOI : 10.1016/j.electacta.2009.04.001

K. Malek and A. A. Franco, Microstructure-Based Modeling of Aging Mechanisms in Catalyst Layers of Polymer Electrolyte Fuel Cells, The Journal of Physical Chemistry B, vol.115, issue.25, pp.8088-8101, 2011.
DOI : 10.1021/jp111400k

T. D. Gierke, G. E. Munn, and F. C. Wilson, The morphology in nafion perfluorinated membrane products, as determined by wide- and small-angle x-ray studies, Journal of Polymer Science: Polymer Physics Edition, vol.19, issue.11, pp.19-1687, 1981.
DOI : 10.1002/pol.1981.180191103

H. G. Haubold, T. Vad, H. Jungbluth, and P. Hiller, Nano structure of NAFION: a SAXS study, Electrochimica Acta, vol.46, issue.10-11, pp.46-1559, 2001.
DOI : 10.1016/S0013-4686(00)00753-2

L. Rubatat, A. L. Rollet, G. Gebel, and O. Diat, Evidence of Elongated Polymeric Aggregates in Nafion, Macromolecules, vol.35, issue.10, pp.35-4050, 2002.
DOI : 10.1021/ma011578b

K. Schmidt-rohr and Q. Chen, Parallel cylindrical water nanochannels in Nafion fuel-cell membranes, Nat Mater, vol.7, pp.75-83, 2008.
DOI : 10.1142/9789814317665_0033

H. L. Yeager and A. Steck, Cation and Water Diffusion in Nafion Ion Exchange Membranes

A. P. Young, J. Stumper, S. Knights, and E. Gyenge, Ionomer Degradation in Polymer Electrolyte Membrane Fuel Cells, Journal of The Electrochemical Society, vol.157, issue.3, pp.157-425, 2010.
DOI : 10.1149/1.3281899

O. Antoine and R. Durand, RRDE study of oxygen reduction on Pt nanoparticles inside Nafion®: H2O2 production in PEMFC cathode conditions, Journal of Applied Electrochemistry, vol.30, issue.7, pp.839-844, 2000.
DOI : 10.1023/A:1003999818560

W. Liu and D. Zuckerbrod, In Situ Detection of Hydrogen Peroxide in PEM Fuel Cells, Journal of The Electrochemical Society, vol.152, issue.6, pp.1165-1170, 2005.
DOI : 10.1149/1.1904988

V. A. Sethuraman, J. W. Weidner, A. T. Haug, S. Motupally, and L. V. Protsailo, Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode, Journal of The Electrochemical Society, vol.155, issue.1, pp.155-50, 2008.
DOI : 10.1149/1.2801980

R. Andreozzi, A. D-'apuzzo, and R. Marotta, A kinetic model for the degradation of benzothiazole by

H. J. Fenton, LXXIII.???Oxidation of tartaric acid in presence of iron, J. Chem. Soc., Trans., vol.65, issue.0, pp.65-899, 1894.
DOI : 10.1039/CT8946500899

W. Gernjak, T. Krutzler, A. Glaser, S. Malato, J. Caceres et al., Photo-Fenton treatment of water containing natural phenolic pollutants, Chemosphere, vol.50, issue.1, pp.50-71, 2003.
DOI : 10.1016/S0045-6535(02)00403-4

P. L. Huston and J. J. Pignatello, Degradation of selected pesticide active ingredients and commercial formulations in water by the photo-assisted Fenton reaction, Water Research, vol.33, issue.5, pp.1238-1246, 1999.
DOI : 10.1016/S0043-1354(98)00330-3

J. Kiwi, C. Pulgarin, and P. Peringer, Effect of Fenton and photo-Fenton reactions on the degradation and biodegradability of 2 and 4-nitrophenols in water treatment, Applied Catalysis B: Environmental, vol.3, issue.4, pp.335-350, 1994.
DOI : 10.1016/0926-3373(94)00008-5

K. C. Namkung and P. Sharratt, Fenton and Photo-Fenton Processes for Treatment of Aqueous Wastes

C. C. Winterbourn, Toxicity of iron and hydrogen peroxide: the Fenton reaction, Toxicology Letters, vol.82, issue.83, p.83, 1995.
DOI : 10.1016/0378-4274(95)03532-X

M. Danilczuk, F. D. Coms, and S. Schlick, Visualizing Chemical Reactions and Crossover Processes in a Fuel Cell Inserted in the ESR Resonator: Detection by Spin Trapping of Oxygen Radicals, Nafion-Derived Fragments, and Hydrogen and Deuterium Atoms, The Journal of Physical Chemistry B, vol.113, issue.23, pp.8031-8042, 2009.
DOI : 10.1021/jp901597f

M. Kitazawa, A. Nosaka, and Y. Nosaka, Radical formation in polymer electrolyte fuel cell components as studied by ESR spectroscopy, Journal of Applied Electrochemistry, vol.7, issue.4, pp.491-496, 2008.
DOI : 10.1007/s10800-007-9464-4

A. Panchenko, H. Dilger, J. Kerres, M. Hein, A. Ullrich et al., In-situ spin trap electron paramagnetic resonance study of fuel cell processes, Physical Chemistry Chemical Physics, vol.6, issue.11, pp.2891-2894, 2004.
DOI : 10.1039/b404253k

D. A. Schiraldi, Perfluorinated Polymer Electrolyte Membrane Durability, Journal of Macromolecular Science, Part C: Polymer Reviews, vol.5, issue.3, pp.46-315, 2006.
DOI : 10.1002/fuce.200400078

T. Xie and C. A. Hayden, A kinetic model for the chemical degradation of perfluorinated sulfonic acid ionomers: Weak end groups versus side chain cleavage, Polymer, vol.48, issue.19, pp.48-5497, 2007.
DOI : 10.1016/j.polymer.2007.07.043

C. Chen and T. Fuller, H2O2 Formation under Fuel-Cell Conditions, ECS Transactions, pp.1127-1137, 2007.
DOI : 10.1149/1.2781025

C. Chen and T. F. Fuller, The effect of humidity on the degradation of Nafion?? membrane, Polymer Degradation and Stability, vol.94, issue.9, pp.94-1436, 2009.
DOI : 10.1016/j.polymdegradstab.2009.05.016

C. Chen and T. F. Fuller, XPS Analysis of Polymer Membrane Degradation in PEMFCs, Journal of The Electrochemical Society, vol.156, issue.10, pp.1218-1224, 2009.
DOI : 10.1149/1.3187731

C. Chen and T. F. Fuller, Modeling of H2O2 formation in PEMFCs, Electrochimica Acta, vol.54, issue.16, pp.3984-3995, 2009.
DOI : 10.1016/j.electacta.2009.02.021

C. Chen, G. Levitin, D. W. Hess, and T. F. Fuller, XPS investigation of Nafion?? membrane degradation, Journal of Power Sources, vol.169, issue.2, pp.169-288, 2007.
DOI : 10.1016/j.jpowsour.2007.03.037

L. Gubler, S. M. Dockheer, and W. H. , Radical (HO???, H??? and HOO???) Formation and Ionomer Degradation in Polymer Electrolyte Fuel Cells, Journal of The Electrochemical Society, vol.158, issue.7, pp.158-755, 2011.
DOI : 10.1149/1.3581040

A. A. Shah, T. R. Ralph, and F. C. Walsh, Modeling and Simulation of the Degradation of Perfluorinated Ion-Exchange Membranes in PEM Fuel Cells, Journal of The Electrochemical Society, vol.156, issue.4, pp.156-465, 2009.
DOI : 10.1149/1.3077573

F. Fouda-onana and N. Guillet, Method for depositing a metal onto a porous carbon layer, 2009.

H. Pu, W. H. Meyer, and G. Wegner, Proton transport in polybenzimidazole blended with H3PO4 or H2SO4, Journal of Polymer Science Part B: Polymer Physics, pp.40-663, 2002.

S. J. Paddison and T. A. Jr, Molecular modeling of the pendant chain in Nafion??, Solid State Ionics, vol.113, issue.1-2, pp.113-115, 1998.
DOI : 10.1016/S0167-2738(98)00298-7

A. Vishnyakov and A. V. Neimark, Molecular Simulation Study of Nafion Membrane Solvation in Water and Methanol, The Journal of Physical Chemistry B, vol.104, issue.18, pp.4471-4478, 2000.
DOI : 10.1021/jp993625w

K. Malek, M. Eikerling, Q. Wang, T. Navessin, and Z. Liu, Self-Organization in Catalyst Layers of Polymer Electrolyte Fuel Cells, The Journal of Physical Chemistry C, vol.111, issue.36, pp.111-13627, 2007.
DOI : 10.1021/jp072692k

S. Schlick, G. Gebel, M. Pineri, and F. Volino, Fluorine-19 NMR spectroscopy of acid Nafion membranes and solutions, Macromolecules, vol.24, issue.12, pp.24-3517, 1991.
DOI : 10.1021/ma00012a008

N. G. Boyle, V. J. Mcbrierty, and A. Eisenberg, NMR investigation of molecular motion in Nafion membranes, Macromolecules, vol.16, issue.1, pp.16-80, 1983.
DOI : 10.1021/ma00235a016

Q. Chen and K. Schmidt-rohr, 19 F and 13 C NMR Signal Assignment and Analysis in a

Q. Chen and K. Schmidt-rohr, Backbone Dynamics of the Nafion Ionomer Studied by 19 F-13 C

J. A. Elliott, D. Wu, S. J. Paddison, and R. B. Moore, A unified morphological description of Nafion membranes from SAXS and mesoscale simulations, Soft Matter, vol.42, issue.15, 2011.
DOI : 10.1039/c1sm00002k

G. Gebel and O. Diat, Neutron and X-ray Scattering: Suitable Tools for Studying Ionomer Membranes, Fuel Cells, vol.46, issue.324, pp.261-276, 2005.
DOI : 10.1002/fuce.200400080

J. Halim, F. N. Büchi, O. Haas, M. Stamm, and G. G. Scherer, Characterization of perfluorosulfonic acid membranes by conductivity measurements and small-angle x-ray scattering, Electrochimica Acta, vol.39, issue.8-9, pp.39-1303, 1994.
DOI : 10.1016/0013-4686(94)E0051-Z

K. A. Page, F. A. Landis, A. K. Phillips, and R. B. Moore, SAXS Analysis of the Thermal Relaxation of Anisotropic Morphologies in Oriented Nafion Membranes, Macromolecules, vol.39, issue.11, pp.39-3939, 2006.
DOI : 10.1021/ma052359j

E. J. Roche, M. Pineri, R. Duplessix, and A. M. Levelut, Small-angle scattering studies of nafion membranes, Journal of Polymer Science: Polymer Physics Edition, vol.19, issue.1, pp.19-20, 1981.
DOI : 10.1002/pol.1981.180190101

A. Eisenberg, B. Hird, and R. B. Moore, A new multiplet-cluster model for the morphology of random ionomers, Macromolecules, vol.23, issue.18, pp.23-4098, 1990.
DOI : 10.1021/ma00220a012

W. Y. Hsu and T. D. Gierke, Elastic theory for ionic clustering in perfluorinated ionomers, Macromolecules, vol.15, issue.1, pp.15-101, 1982.
DOI : 10.1021/ma00229a020

W. Y. Hsu and T. D. Gierke, Ion transport and clustering in nafion perfluorinated membranes, Journal of Membrane Science, vol.13, issue.3, pp.13-307, 1983.
DOI : 10.1016/S0376-7388(00)81563-X

K. A. Mauritz and R. B. Moore, State of Understanding of Nafion, Chemical Reviews, vol.104, issue.10, pp.4535-4586, 2004.
DOI : 10.1021/cr0207123

D. Gierke, T. , Y. Hsu, and W. , The Cluster???Network Model of Ion Clustering in Perfluorosulfonated Membranes, Perfluorinated Ionomer Membranes, pp.283-307, 1982.
DOI : 10.1021/bk-1982-0180.ch013

M. Fujimura, T. Hashimoto, and H. Kawai, Small-angle x-ray scattering study of perfluorinated ionomer membranes. 1. Origin of two scattering maxima, Macromolecules, vol.14, issue.5, pp.14-1309, 1981.
DOI : 10.1021/ma50006a032

M. Fujimura, T. Hashimoto, and H. Kawai, Small-angle x-ray scattering study of perfluorinated ionomer membranes. 2. Models for ionic scattering maximum, Macromolecules, vol.15, issue.1, pp.15-136, 1982.
DOI : 10.1021/ma00229a028

Z. Siroma, N. Fujiwara, T. Ioroi, S. Yamazaki, K. Yasuda et al., Dissolution of Nafion?? membrane and recast Nafion?? film in mixtures of methanol and water, Journal of Power Sources, vol.126, issue.1-2, pp.126-167, 2004.
DOI : 10.1016/j.jpowsour.2003.08.024

L. Rubatat, G. Gebel, and O. Diat, Fibrillar Structure of Nafion:?? Matching Fourier and Real Space Studies of Corresponding Films and Solutions, Macromolecules, vol.37, issue.20, pp.37-7772, 2004.
DOI : 10.1021/ma049683j

A. Z. Weber and J. Newman, Transport in Polymer-Electrolyte Membranes, Journal of The Electrochemical Society, vol.150, issue.7, pp.1008-1015, 2003.
DOI : 10.1149/1.1580822

A. Z. Weber and J. Newman, Transport in Polymer-Electrolyte Membranes, Journal of The Electrochemical Society, pp.151-311, 2004.

B. Chu, C. Wu, and W. Buck, Light-scattering characterization of poly(tetrafluoroethylene

B. Rosi-schwartz and G. R. Mitchell, Extracting and validating force fields for disordered polymeric materials from neutron scattering data, Philosophical Magazine Part B, vol.37, issue.1, pp.37-1857, 1996.
DOI : 10.1063/1.436863

K. Yasuda, N. Kimijima, and . Iwashita, Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation, Chemical Reviews, vol.107, pp.3904-3951, 2007.

H. Tang, S. Peikang, S. P. Jiang, F. Wang, and M. Pan, A degradation study of Nafion proton exchange membrane of PEM fuel cells, Journal of Power Sources, vol.170, issue.1, pp.85-92, 2007.
DOI : 10.1016/j.jpowsour.2007.03.061

M. Inaba, T. Kinumoto, M. Kiriake, R. Umebayashi, A. Tasaka et al., Gas crossover and membrane degradation in polymer electrolyte fuel cells, Electrochimica Acta, vol.51, issue.26, pp.51-5746, 2006.
DOI : 10.1016/j.electacta.2006.03.008

M. Schulze, N. Wagner, T. Kaz, and K. A. Friedrich, Combined electrochemical and surface analysis investigation of degradation processes in polymer electrolyte membrane fuel cells, Electrochimica Acta, vol.52, issue.6, pp.52-2328, 2007.
DOI : 10.1016/j.electacta.2006.05.063

S. Zhang, X. Yuan, J. N. Hin, H. Wang, K. A. Friedrich et al., A review of platinumbased catalyst layer degradation in proton exchange membrane fuel cells, Journal of Power Sources, pp.194-588, 2009.

S. S. Kocha, J. Deliang-yang, and J. S. Yi, Characterization of gas crossover and its implications in PEM fuel cells, AIChE Journal, vol.3, issue.6, pp.52-1916, 2006.
DOI : 10.1002/aic.10780

. Ptru, Nafion composite membrane for a direct methanol fuel cell, International Journal of Hydrogen Energy, vol.32, pp.903-907, 2007.

A. C. Fernandes and E. A. Ticianelli, A performance and degradation study of Nafion 212 membrane for proton exchange membrane fuel cells, Journal of Power Sources, vol.193, issue.2, pp.193-547, 2009.
DOI : 10.1016/j.jpowsour.2009.04.038

V. O. Mittal, H. R. Kunz, and J. M. Fenton, Is H[sub 2]O[sub 2] Involved in the Membrane Degradation Mechanism in PEMFC?, Electrochemical and Solid-State Letters, vol.9, issue.6, pp.9-299, 2006.
DOI : 10.1149/1.2192696

M. O. Davies, M. Clark, E. Yeager, and F. Hovorka, The Oxygen Electrode, Journal of The Electrochemical Society, vol.106, issue.1, pp.56-61, 1959.
DOI : 10.1149/1.2427266

E. Yeager, Dioxygen electrocatalysis: mechanisms in relation to catalyst structure, Journal of Molecular Catalysis, vol.38, issue.1-2, pp.5-25, 1986.
DOI : 10.1016/0304-5102(86)87045-6

I. Morcos and E. Yeager, Kinetic studies of the oxygen???peroxide couple on pyrolytic graphite, Electrochimica Acta, vol.15, issue.6, pp.953-975, 1970.
DOI : 10.1016/0013-4686(70)80037-8

E. Yeager, Electrocatalysts for O2 reduction, Electrochimica Acta, vol.29, issue.11, pp.1527-1537, 1984.
DOI : 10.1016/0013-4686(84)85006-9

E. Yeager, P. Krouse, and K. V. Rao, The kinetics of the oxygen???peroxide couple on carbon, Electrochimica Acta, vol.9, issue.8, pp.1057-1070, 1964.
DOI : 10.1016/0013-4686(64)80075-X

R. Ferreira-de-morais, A. A. Franco, P. Sautet, and D. Loffreda, Water vs Hydrogen Peroxide Formation on Pt(111) From a First-Principles Study. 2. Coverage Kinetics

R. Ferreira-de-morais, P. Sautet, D. Loffreda, and A. A. Franco, A multiscale theoretical methodology for the calculation of electrochemical observables from ab initio data: Application to the oxygen reduction reaction in a Pt(111)-based polymer electrolyte membrane fuel cell, Electrochimica Acta, 2011.

V. R. Stamenkovic, B. Fowler, B. S. Mun, G. Wang, P. N. Ross et al., Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability, Science, vol.315, issue.5811, pp.315-493, 2007.
DOI : 10.1126/science.1135941

Y. Wang and P. B. Balbuena, :?? Direct or Series Pathway?, The Journal of Physical Chemistry B, vol.109, issue.31, pp.14896-14907, 2005.
DOI : 10.1021/jp050241z

A. Pozio, R. F. Silva, M. De-francesco, and L. Giorgi, Nafion degradation in PEFCs from end plate iron contamination, Electrochimica Acta, vol.48, issue.11, pp.48-1543, 2003.
DOI : 10.1016/S0013-4686(03)00026-4

F. N. Büchi, M. Inaba, T. J. Schmidt, J. Scherer, D. Münter et al., Influence of Metallic Bipolar Plates on the Durability of Polymer Electrolyte Fuel Cells, in: Polymer Electrolyte Fuel Cell Durability, pp.243-255, 2009.

M. Aoki, H. Uchida, and M. Watanabe, Decomposition mechanism of perfluorosulfonic acid electrolyte in polymer electrolyte fuel cells, Electrochemistry Communications, vol.8, issue.9, pp.1509-1513, 2006.
DOI : 10.1016/j.elecom.2006.07.017

A. Panchenko, H. Dilger, E. Möller, T. Sixt, and E. Roduner, In situ EPR investigation of polymer electrolyte membrane degradation in fuel cell applications, Journal of Power Sources, vol.127, issue.1-2, pp.127-325, 2004.
DOI : 10.1016/j.jpowsour.2003.09.047

B. Vogel, E. Aleksandrova, S. Mitov, M. Krafft, A. Dreizler et al., Observation of Fuel Cell Membrane Degradation by Ex Situ and In Situ Electron Paramagnetic Resonance, Journal of The Electrochemical Society, vol.155, issue.6, pp.155-570, 2008.
DOI : 10.1149/1.2901061

H. Liu, H. A. Gasteiger, A. Laconti, and J. Zhang, Factors Impacting Chemical Degradation Of Perfluorinated Sulfonic Acid Ionomers, ECS Transactions, pp.283-293, 2006.
DOI : 10.1149/1.2214561

F. N. Büchi, M. Inaba, T. J. Schmidt, and M. Inaba, Chemical Degradation of Perfluorinated Sulfonic Acid Membranes, in: Polymer Electrolyte Fuel Cell Durability, pp.57-69, 2009.

F. N. Büchi, M. Inaba, T. J. Schmidt, H. Liu, F. D. Coms et al., Chemical Degradation: Correlations Between Electrolyzer and Fuel Cell Findings, Polymer Electrolyte Fuel Cell Durability, pp.71-118, 2009.

T. Kinumoto, M. Inaba, Y. Nakayama, K. Ogata, R. Umebayashi et al., Durability of perfluorinated ionomer membrane against hydrogen peroxide, Journal of Power Sources, vol.158, issue.2, pp.158-1222, 2006.
DOI : 10.1016/j.jpowsour.2005.10.043

S. Kundu, M. W. Fowler, L. C. Simon, R. Abouatallah, and N. Beydokhti, Open circuit voltage durability study and model of catalyst coated membranes at different humidification levels, Journal of Power Sources, vol.195, issue.21, pp.195-7323, 2010.
DOI : 10.1016/j.jpowsour.2010.05.027

T. Madden, D. Weiss, N. Cipollini, D. Condit, M. Gummalla et al., Degradation of Polymer-Electrolyte Membranes in Fuel Cells, Journal of The Electrochemical Society, vol.156, issue.5, pp.156-657, 2009.
DOI : 10.1149/1.3095466

S. Kundu, L. C. Simon, and M. W. Fowler, Comparison of two accelerated Nafion??? degradation experiments, Polymer Degradation and Stability, vol.93, issue.1, pp.93-214, 2008.
DOI : 10.1016/j.polymdegradstab.2007.10.001

T. Ishimoto, R. Nagumo, T. Ogura, T. Ishihara, B. Kim et al., Chemical Degradation Mechanism of Model Compound, CF 3 (CF 2 ) 3 O(CF 2 ) 2 OCF 2 SO 3 H, of PFSA Polymer by Attack of Hydroxyl Radical in PEMFCs, Journal of The Electrochemical Society, pp.157-1305, 2010.

. Koppenol, Damage to fuel cell membranes Reaction of HO· with an oligomer of poly(sodium styrene sulfonate) and subsequent reaction with O 2, Physical Chemistry Chemical Physics, pp.12-11609, 2010.

M. W. Fowler, R. F. Mann, J. C. Amphlett, B. A. Peppley, and P. R. Roberge, Incorporation of voltage degradation into a generalised steady state electrochemical model for a PEM fuel cell, Journal of Power Sources, vol.106, issue.1-2, pp.106-274, 2002.
DOI : 10.1016/S0378-7753(01)01029-1

G. V. Buxton, L. Clive, W. Greenstock, P. Helman, and A. B. Ross, in Aqueous Solution, Journal of Physical and Chemical Reference Data, vol.17, issue.2
DOI : 10.1063/1.555805

H. Christensen, K. Sehested, and H. Corfitzen, Reactions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures, The Journal of Physical Chemistry, vol.86, issue.9, pp.1588-1590, 1982.
DOI : 10.1021/j100206a023

J. De-laat and H. Gallard, Catalytic Decomposition of Hydrogen Peroxide by Fe(III) in

F. Haber and J. Weiss, The Catalytic Decomposition of Hydrogen Peroxide by Iron Salts, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.147, issue.861, pp.332-351, 1934.
DOI : 10.1098/rspa.1934.0221

S. Lin and M. D. , Catalytic Decomposition of Hydrogen Peroxide on Iron Oxide:?? Kinetics, Mechanism, and Implications, Environmental Science & Technology, vol.32, issue.10, pp.32-1417, 1998.
DOI : 10.1021/es970648k

T. E. Springer, T. A. Zawodzinski, and S. Gottesfeld, Polymer Electrolyte Fuel Cell Model, Journal of The Electrochemical Society, vol.138, issue.8, pp.2334-2342, 1991.
DOI : 10.1149/1.2085971

M. Eikerling, Y. I. Kharkats, A. A. Kornyshev, and Y. M. Volfkovich, Phenomenological Theory of Electro-osmotic Effect and Water Management in Polymer Electrolyte Proton-Conducting Membranes, Journal of The Electrochemical Society, vol.145, issue.8, pp.145-2684, 1998.
DOI : 10.1149/1.1838700

W. Weppner and R. A. Huggins, Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb, Journal of The Electrochemical Society, vol.124, issue.10, pp.124-1569, 1977.
DOI : 10.1149/1.2133112

S. Motupally, A. J. Becker, and J. W. Weidner, Diffusion of Water in Nafion 115 Membranes, Journal of The Electrochemical Society, vol.147, issue.9, pp.3171-3177, 2000.
DOI : 10.1149/1.1393879

T. A. Zawodzinski, M. Neeman, L. O. Sillerud, and S. Gottesfeld, Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes, The Journal of Physical Chemistry, vol.95, issue.15, pp.95-6040, 1991.
DOI : 10.1021/j100168a060

T. V. Nguyen and R. E. White, A Water and Heat Management Model for

M. Ise, K. D. Kreuer, and J. Maier, Electroosmotic drag in polymer electrolyte membranes: an electrophoretic NMR study, Solid State Ionics, vol.125, issue.1-4, pp.213-223, 1999.
DOI : 10.1016/S0167-2738(99)00178-2

T. A. Zawodzinski, J. Davey, J. Valerio, and S. Gottesfeld, The water content dependence of electro-osmotic drag in proton-conducting polymer electrolytes, Electrochimica Acta, vol.40, issue.3, pp.40-297, 1995.
DOI : 10.1016/0013-4686(94)00277-8

S. Ge, B. Yi, and P. Ming, Experimental Determination of Electro-Osmotic Drag Coefficient in Nafion Membrane for Fuel Cells, Journal of The Electrochemical Society, vol.153, issue.8, pp.153-1443, 2006.
DOI : 10.1149/1.2203934

C. Vallieres, D. Winkelmann, D. Roizard, E. Favre, P. Scharfer et al., On Schroeder's paradox, Journal of Membrane Science, vol.278, issue.1-2, pp.278-357, 2006.
DOI : 10.1016/j.memsci.2005.11.020

M. H. Eikerling and P. Berg, Poroelectroelastic theory of water sorption and swelling in polymer electrolyte membranes, Soft Matter, vol.160, issue.13, pp.5976-5990, 2011.
DOI : 10.1039/c1sm05273j

M. Holz, Electrophoretic NMR, Chemical Society Reviews, vol.23, issue.3, pp.165-174, 1994.
DOI : 10.1039/cs9942300165

F. Meier and G. Eigenberger, Transport parameters for the modelling of water transport in ionomer membranes for PEM-fuel cells, Electrochimica Acta, vol.49, issue.11, pp.49-1731, 2004.
DOI : 10.1016/j.electacta.2003.12.004

A. Ohma, S. Yamamoto, and K. Shinohara, Membrane degradation mechanism during open-circuit voltage hold test, Journal of Power Sources, vol.182, issue.1, pp.39-47, 2008.
DOI : 10.1016/j.jpowsour.2008.03.078

K. Hongsirikarn, X. Mo, J. G. Goodwin-jr, and S. Creager, Effect of H 2 O 2 on Nafion properties and conductivity at fuel cell conditions, Journal of Power Sources, pp.196-3060, 2010.

M. Aoki, H. Uchida, and M. Watanabe, Novel evaluation method for degradation rate of polymer electrolytes in fuel cells, Electrochemistry Communications, vol.7, issue.12, pp.1434-1438, 2005.
DOI : 10.1016/j.elecom.2005.10.008

E. T. Denisov, T. G. Denisova, and T. S. Pokidova, Handbook of Free Radical Initiators, in: Handbook of Free Radical Initiators, pp.pp. i-xxii, 2005.
DOI : 10.1002/0471721476

F. Haber and J. Weiss, ???ber die Katalyse des Hydroperoxydes, Die Naturwissenschaften, vol.45, issue.51, pp.948-950, 1932.
DOI : 10.1007/BF01504715

S. Prager, Diffusion in Inhomogeneous Media, The Journal of Chemical Physics, vol.33, issue.1, pp.122-127, 1960.
DOI : 10.1063/1.1731066

H. Yasuda, C. E. Lamaze, and L. D. Ikenberry, Permeability of solutes through hydrated polymer membranes. Part I. Diffusion of sodium chloride, Die Makromolekulare Chemie, pp.118-137, 1968.

S. Koter, Transport of simple electrolyte solutions through ion-exchange membranes???the capillary model, Journal of Membrane Science, vol.206, issue.1-2, pp.201-215, 2002.
DOI : 10.1016/S0376-7388(01)00763-3

P. Choi, N. H. Jalani, and R. Datta, Thermodynamics and Proton Transport in Nafion, Journal of The Electrochemical Society, vol.152, issue.3, pp.123-130, 2005.
DOI : 10.1149/1.1859814

A. A. Franco, Un modèle physique multiéchelle de la dynamique électrochimique dans une pile à combustible à électrolyte polymère ? Une approche Bond Graph dimension infinie, 2005.

A. A. Franco, P. Schott, C. Jallut, and B. Maschke, A Dynamic Mechanistic Model of an Electrochemical Interface, Journal of The Electrochemical Society, vol.153, issue.6, pp.153-1053, 2006.
DOI : 10.1149/1.2188353

A. A. Franco, P. Schott, C. Jallut, and B. Maschke, A Multi-Scale Dynamic Mechanistic Model for the Transient Analysis of PEFCs, Fuel Cells, vol.150, issue.2, pp.99-117, 2007.
DOI : 10.1002/fuce.200500204

W. G. Bessler and S. Gewies, Gas Concentration Impedance of Solid Oxide Fuel Cell Anodes, Journal of The Electrochemical Society, vol.154, issue.6, pp.548-559, 2007.
DOI : 10.1149/1.2720639

W. G. Bessler, S. Gewies, C. Willich, G. Schiller, and K. A. Friedrich, Spatial Distribution of Electrochemical Performance in a Segmented SOFC: A??Combined Modeling and Experimental Study, Fuel Cells, vol.177, issue.3, pp.10-411, 2009.
DOI : 10.1002/fuce.200900083
URL : https://hal.archives-ouvertes.fr/hal-00552354

M. P. Eschenbach, R. Coulon, A. A. Franco, J. Kallo, and W. G. Bessler, Multi-scale simulation of fuel cells: From the cell to the system, Solid State Ionics, vol.192, issue.1, pp.192-615, 2011.
DOI : 10.1016/j.ssi.2010.06.041

A. Rollet, O. Diat, and G. , A New Insight into Nafion Structure, The Journal of Physical Chemistry B, vol.106, issue.12, pp.3033-3036, 2002.
DOI : 10.1021/jp020245t

P. Deuflhard, E. Hairer, and J. Zugck, One-step and extrapolation methods for differentialalgebraic systems, Numerische Mathematik, pp.51-501, 1987.

M. Inaba, M. Uno, J. Marayama, A. Tasaka, K. Katakura et al., Hydrogen oxidation on partially immersed Nafion??-coated electrodes, Journal of Electroanalytical Chemistry, vol.417, issue.1-2, pp.417-105, 1996.
DOI : 10.1016/S0022-0728(96)04746-8

D. A. Harrington and B. E. Conway, ac Impedance of Faradaic reactions involving electrosorbed intermediates???I. Kinetic theory, Electrochimica Acta, vol.32, issue.12, pp.1703-1712, 1987.
DOI : 10.1016/0013-4686(87)80005-1

L. Bai, D. A. Harrington, and B. E. Conway, Behavior of overpotential???deposited species in Faradaic reactions???II. ac Impedance measurements on H2 evolution kinetics at activated and unactivated Pt cathodes, Electrochimica Acta, vol.32, issue.12, pp.32-1713, 1987.
DOI : 10.1016/0013-4686(87)80006-3

D. A. Harrington and B. E. Conway, Kinetic theory of the open-circuit potential decay method for evaluation of behaviour of adsorbed intermediates, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.221, issue.1-2, pp.221-222, 1987.
DOI : 10.1016/0022-0728(87)80242-5

R. M. Mello and E. A. Ticianelli, Kinetic study of the hydrogen oxidation reaction on platinum and Nafion ?? covered platinum electrodes, Electrochimica Acta, vol.42, issue.6, pp.42-1031, 1997.
DOI : 10.1016/S0013-4686(96)00282-4

N. M. Markovic, B. N. Grgur, and P. N. Ross, Temperature-Dependent Hydrogen Electrochemistry on Platinum Low-Index Single-Crystal Surfaces in Acid Solutions, The Journal of Physical Chemistry B, vol.101, issue.27, pp.5405-5413, 1997.
DOI : 10.1021/jp970930d

H. Eyring, The Activated Complex in Chemical Reactions, J. Chem. Phys, vol.3, issue.107, 1935.

U. A. Paulus, T. J. Schmidt, H. A. Gasteiger, and R. J. Behm, Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study, Journal of Electroanalytical Chemistry, vol.495, issue.2, pp.495-134, 2001.
DOI : 10.1016/S0022-0728(00)00407-1

N. M. Markovic, H. A. Gasteiger, and P. N. Ross, Oxygen Reduction on Platinum Low-Index

A. Damjanovic, D. B. Sepa, and M. V. Vojnovic, New evidence supports the proposed mechanism for O2 reduction at oxide free platinum electrodes, Electrochimica Acta, vol.24, issue.8, pp.24-887, 1979.
DOI : 10.1016/0013-4686(79)87013-9

R. Ferreira-de-morais, P. Sautet, D. Loffreda, and A. A. Franco, A multiscale theoretical methodology for the calculation of electrochemical observables from ab initio data: Application to the oxygen reduction reaction in a Pt(111)-based polymer electrolyte membrane fuel cell, Electrochimica Acta, pp.56-10842, 2011.

P. Schott and P. Baurens, Fuel cell operation characterization using simulation, Journal of Power Sources, vol.156, issue.1, pp.85-91, 2006.
DOI : 10.1016/j.jpowsour.2005.08.034

W. G. Bessler, S. Gewies, and M. Vogler, A new framework for physically based modeling of solid oxide fuel cells, Electrochimica Acta, vol.53, issue.4, pp.53-1782, 2007.
DOI : 10.1016/j.electacta.2007.08.030

S. Gewies and W. G. Bessler, Physically Based Impedance Modeling of Ni/YSZ Cermet Anodes, Journal of The Electrochemical Society, vol.155, issue.9, pp.937-952, 2008.
DOI : 10.1149/1.2943411

E. Oliveros, O. Legrini, M. Hohl, T. Müller, and A. M. Braun, Industrial waste water treatment: large scale development of a light-enhanced Fenton reaction, Chemical Engineering and Processing: Process Intensification, pp.36-397, 1997.
DOI : 10.1016/S0255-2701(97)00011-1

K. Kodama, F. Miura, N. Hasegawa, M. Kawasumi, and Y. Morimoto, Degradation of Nafion Membranes in Hydrogen Peroxide, ECS Meeting Abstracts, pp.502-1185, 2006.

S. Zhang, X. Yuan, H. Wang, W. Mérida, H. Zhu et al., A review of accelerated stress tests of MEA durability in PEM fuel cells, International Journal of Hydrogen Energy, vol.34, issue.1, pp.34-388, 2009.
DOI : 10.1016/j.ijhydene.2008.10.012

S. Maass, F. Finsterwalder, G. Frank, R. Hartmann, and C. Merten, Carbon support oxidation in PEM fuel cell cathodes, Journal of Power Sources, vol.176, issue.2, pp.176-444, 2008.
DOI : 10.1016/j.jpowsour.2007.08.053

L. M. Roen, C. H. Paik, and T. D. Jarvi, Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes, Electrochemical and Solid-State Letters, vol.7, issue.1, pp.19-22, 2004.
DOI : 10.1149/1.1630412

H. Tang, Z. Qi, M. Ramani, and J. F. Elter, PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode, Journal of Power Sources, vol.158, issue.2, pp.158-1306, 2006.
DOI : 10.1016/j.jpowsour.2005.10.059

K. Yasuda, A. Taniguchi, T. Akita, T. Ioroi, and Z. Siroma, Platinum dissolution and deposition in the polymer electrolyte membrane of a PEM fuel cell as studied by potential cycling, Phys. Chem. Chem. Phys., vol.29, issue.6, pp.746-752, 2006.
DOI : 10.1039/B514342J

X. Wang, R. Kumar, and D. J. Myers, Effect of Voltage on Platinum Dissolution, Electrochemical and Solid-State Letters, vol.9, issue.5, pp.225-227, 2006.
DOI : 10.1149/1.2180536

W. Bi, G. E. Gray, and T. F. Fuller, PEM Fuel Cell Pt???C Dissolution and Deposition in Nafion Electrolyte, Electrochemical and Solid-State Letters, vol.10, issue.5, pp.10-101, 2007.
DOI : 10.1149/1.2712796

V. A. Dam and F. A. De-bruijn, The Stability of PEMFC Electrodes, Journal of The Electrochemical Society, vol.154, issue.5, pp.494-499, 2007.
DOI : 10.1149/1.2714327

M. Schulze, M. Lorenz, N. Wagner, and E. Gülzow, XPS analysis of the degradation of Nafion, Fresenius' Journal of Analytical Chemistry, vol.365, issue.1-3, pp.365-106, 1999.
DOI : 10.1007/s002160051454

M. Vogler, A. Bieberle-hutter, L. Gauckler, J. Warnatz, and W. G. Bessler, Modelling Study of Surface Reactions, Diffusion, and Spillover at a Ni/YSZ Patterned Anode, Journal of The Electrochemical Society, vol.156, issue.5, pp.156-663, 2009.
DOI : 10.1149/1.3095477

S. Banerjee and D. E. Curtin, Nafion?? perfluorinated membranes in fuel cells, Journal of Fluorine Chemistry, vol.125, issue.8, pp.1211-1216, 2004.
DOI : 10.1016/j.jfluchem.2004.05.018