R. H. Crabtree, Aspects of Methane Chemistry, Chemical Reviews, vol.95, issue.4, pp.987-1007, 1995.
DOI : 10.1021/cr00036a005

H. M. Davies and R. E. Beckwith, Catalytic Enantioselective C???H Activation by Means of Metal???Carbenoid-Induced C???H Insertion, Chemical Reviews, vol.103, issue.8, pp.2861-2904, 2003.
DOI : 10.1021/cr0200217

P. Müller and C. Fruit, Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds, Chemical Reviews, vol.103, issue.8, pp.2905-2920, 2003.
DOI : 10.1021/cr020043t

W. C. Cheng, W. Y. Yu, C. K. Li, and C. M. Che, A Kinetic Study on the Reactivity of a cis-Dioxoruthenium(VI) Complex. Oxidation of Alcohols, Aromatic Hydrocarbons, and Alkenes by cis-[RuVI(Tet-Me6)O2]2+, The Journal of Organic Chemistry, vol.60, issue.21, pp.6840-6846, 1995.
DOI : 10.1021/jo00126a038

A. R. Dick and M. S. Sanford, Transition metal catalyzed oxidative functionalization of carbon???hydrogen bonds, Tetrahedron, vol.62, issue.11, pp.2439-2463, 2006.
DOI : 10.1016/j.tet.2005.11.027

J. A. Labinger and J. Bercaw, Understanding and exploiting C???H bond activation, Nature, vol.101, issue.6888, pp.507-514, 2002.
DOI : 10.1039/a900631a

R. Jazzar, J. Hitce, A. Renaudat, J. Sofack-kreutzer, and O. Baudoin, Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)???H Activation, Chemistry - A European Journal, vol.38, issue.9, pp.2654-2672, 2010.
DOI : 10.1002/chem.200902374
URL : https://hal.archives-ouvertes.fr/hal-00691427

G. Dyker, Palladium-Catalyzed C?H Activation of Methoxy Groups: A Facile Synthesis of Substituted 6H-Dibenzo[b,d]pyrans, Angewandte Chemie International Edition in English, vol.25, issue.8, pp.1023-1025, 1992.
DOI : 10.1002/anie.199210231

G. Dyker, Palladium-catalyzed carbon-hydrogen activation at methoxy groups for cross-coupling reactions: a new approach to substituted benzo[b]furans, The Journal of Organic Chemistry, vol.58, issue.23, pp.6426-6428, 1993.
DOI : 10.1021/jo00075a044

T. E. Barder, S. D. Walker, J. R. Martinelli, and S. L. Buchwald, Catalysts for Suzuki???Miyaura Coupling Processes:?? Scope and Studies of the Effect of Ligand Structure, Journal of the American Chemical Society, vol.127, issue.13, pp.4685-4696, 2005.
DOI : 10.1021/ja042491j

J. Pan, M. Su, and S. L. Buchwald, Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C???sp???3???H Bonds, Angewandte Chemie International Edition, vol.39, issue.37, pp.8647-8651, 2011.
DOI : 10.1002/anie.201102880

C. Dong and Q. Hu, Annulative Tandem Reactions Based on Pd0/tBu3P-Catalyzed Cross-Coupling and C(sp3)???H Bond Activation, Angewandte Chemie International Edition, vol.33, issue.14, pp.2289-2292, 2006.
DOI : 10.1002/anie.200504310

C. Dong, P. Yeung, and Q. Hu, -Stilbenoid Hydrocarbons from the Same Internal Alkynes and Hindered Grignard Reagents, Organic Letters, vol.9, issue.2, pp.363-366, 2007.
DOI : 10.1021/ol062885a
URL : https://hal.archives-ouvertes.fr/medihal-01357719

F. Liron and P. Knochel, Reactivity of stable neopentyl-Pd intermediates in the absence of nucleophile, Tetrahedron Letters, vol.48, issue.28, pp.4943-4946, 2007.
DOI : 10.1016/j.tetlet.2007.05.018

H. S. Kim, S. Gowrisankar, S. H. Kim, and J. N. Kim, Synthesis of 6-oxacyclopropa[a]indene derivatives starting from Baylis???Hillman adducts via Pd-mediated C(sp3)???H activation, Tetrahedron Letters, vol.49, issue.24, pp.3858-3861, 2008.
DOI : 10.1016/j.tetlet.2008.04.080

Q. Huang and R. C. Larock, Synthesis of cyclopropanes by Pd-catalyzed activation of alkyl C???H bonds, Tetrahedron Letters, vol.50, issue.52, pp.7235-7238, 2009.
DOI : 10.1016/j.tetlet.2009.10.013

M. A. Campo, H. Zhang, T. Yao, A. Ibdah, R. D. Mcculla et al., -Halobiaryls, Journal of the American Chemical Society, vol.129, issue.19, pp.6298-6307, 2007.
DOI : 10.1021/ja069238z
URL : https://hal.archives-ouvertes.fr/hal-00807111

H. Ren and P. Knochel, Chemoselective Benzylic C???H Activations for the Preparation of Condensed N-Heterocycles, Angewandte Chemie International Edition, vol.52, issue.21, pp.3462-3465, 2006.
DOI : 10.1002/anie.200600111

M. Lafrance, S. I. Gorelsky, and K. Fagnou, High-Yielding Palladium-Catalyzed Intramolecular Alkane Arylation:?? Reaction Development and Mechanistic Studies, Journal of the American Chemical Society, vol.129, issue.47, pp.14570-14571, 2007.
DOI : 10.1021/ja076588s

T. Watanabe, S. Oishi, N. Fujii, and H. Ohno, -Alkyl-2-bromoanilines, Organic Letters, vol.10, issue.9, pp.1759-1762, 2008.
DOI : 10.1021/ol800425z
URL : https://hal.archives-ouvertes.fr/in2p3-00310862

M. Nakanishi, D. Katayev, C. Besnard, and E. P. Kündig, Fused Indolines by Palladium-Catalyzed Asymmetric C???C Coupling Involving an Unactivated Methylene Group, Angewandte Chemie International Edition, vol.128, issue.32, pp.7438-7441, 2011.
DOI : 10.1002/anie.201102639

A. Salcedo, L. Neuville, and J. Zhu, -Arylation of Benzylic Carbon: Synthesis of 3-Benzoxazolylisoindolinones by a Sequence of Ugi-4CR/Postfunctionalization, The Journal of Organic Chemistry, vol.73, issue.9, pp.3600-3603, 2008.
DOI : 10.1021/jo800266y
URL : https://hal.archives-ouvertes.fr/hal-01247608

S. Rousseaux, S. I. Gorelsky, B. K. Chung, and K. Fagnou, )???H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides, Journal of the American Chemical Society, vol.132, issue.31, pp.10692-10705, 2010.
DOI : 10.1021/ja103081n

O. Baudoin, A. Herrbach, and F. Gueritte, The Palladium-Catalyzed C???H Activation of Benzylicgem-Dialkyl Groups, Angewandte Chemie, vol.115, issue.46, pp.5914-5918, 2003.
DOI : 10.1002/ange.200352461

J. Hitce, P. Retailleau, and O. Baudoin, Palladium-Catalyzed Intramolecular C(sp3)???H Functionalization: Catalyst Development and Synthetic Applications, Chemistry - A European Journal, vol.63, issue.3, pp.792-799, 2007.
DOI : 10.1002/chem.200600811
URL : https://hal.archives-ouvertes.fr/hal-00135100

K. G. Moloy and J. L. Petersen, N-Pyrrolyl Phosphines: An Unexploited Class of Phosphine Ligands with Exceptional .pi.-Acceptor Character, Journal of the American Chemical Society, vol.117, issue.29, pp.7696-7710, 1995.
DOI : 10.1021/ja00134a014

J. Hitce and O. Baudoin, Substituted Benzocarbocycles by Palladium-Catalyzed Cascade Reactions Featuring a C(sp3)???H Activation Step, Advanced Synthesis & Catalysis, vol.103, issue.11-12, pp.2054-2060, 2007.
DOI : 10.1002/adsc.200700099

G. Mehta and S. Kotha, Recent chemistry of benzocyclobutenes, Tetrahedron, vol.57, issue.4, pp.625-659, 2001.
DOI : 10.1016/S0040-4020(00)00958-3

G. Dyker, Palladium-Catalyzed C?H Activation oftert-Butyl Groups: A Simple Synthesis of 1,2-Dihydrocyclobutabenzene Derivatives, Angewandte Chemie International Edition in English, vol.111, issue.1, pp.103-105, 1994.
DOI : 10.1002/anie.199401031

N. Mariet, M. Ibrahim-ouali, and M. Santelli, First [2+2]-cycloaddition of a 3,4-didehydropyridine and a ketene dialkyl acetal, Tetrahedron Letters, vol.43, issue.33, pp.5789-5791, 2002.
DOI : 10.1016/S0040-4039(02)01176-0

D. Lapointe and K. Fagnou, Overview of the Mechanistic Work on the Concerted Metallation???Deprotonation Pathway, Chemistry Letters, vol.39, issue.11, pp.1118-1126, 2010.
DOI : 10.1246/cl.2010.1118

D. García-cuadrado, A. A. Braga, F. Maseras, A. M. Echavarren, and D. García-cuadrado, Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation, Journal of the American Chemical Society, vol.128, issue.4, pp.1066-1067, 2006.
DOI : 10.1021/ja056165v

A. J. Mota, A. Dedieu, C. Bour, and J. Suffert, Cyclocarbopalladation Involving an Unusual 1,5-Palladium Vinyl to Aryl Shift as Termination Step:?? Theoretical Study of the Mechanism, Journal of the American Chemical Society, vol.127, issue.19, pp.7171-7182, 2005.
DOI : 10.1021/ja050453+
URL : https://hal.archives-ouvertes.fr/hal-00129940

F. Delpech, S. Sabo-etienne, B. Donnadieu, and B. Chaudret, ], Organometallics, vol.17, issue.23, pp.4926-4928, 1998.
DOI : 10.1021/om9805180

E. Clot, O. Eisenstein, T. Dubé, J. W. Faller, R. H. Crabtree et al., -Butyl but a Nonagostic Isopropyl Group, Organometallics, vol.21, issue.3, pp.575-580, 1965.
DOI : 10.1021/om010802i
URL : https://hal.archives-ouvertes.fr/halshs-00605357

M. Brookhart and M. L. Green, Carbon???hydrogen-transition metal bonds, Journal of Organometallic Chemistry, vol.250, issue.1, pp.395-408, 1983.
DOI : 10.1016/0022-328X(83)85065-7

L. J. Häller, M. J. Page, S. A. Macgregor, M. F. Mahon, and M. K. Whittlesey, Activation of an Alkyl C???H Bond Geminal to an Agostic Interaction: An Unusual Mode of Base-Induced C???H Activation, Journal of the American Chemical Society, vol.131, issue.13, pp.4604-4605, 2009.
DOI : 10.1021/ja900953d

M. Davi, Résultats en cours de publication

K. Okuro, M. Furuune, M. Miura, and M. Nomura, Copper-catalyzed reaction of aryl iodides with active methylene compounds, The Journal of Organic Chemistry, vol.58, issue.26, pp.7606-7607, 1993.
DOI : 10.1021/jo00078a053

C. Amatore, A. Jutand, and M. A. Barki, Evidence of the formation of zerovalent palladium from Pd(OAc)2 and triphenylphosphine, Organometallics, vol.11, issue.9, pp.3009-3013, 1992.
DOI : 10.1021/om00045a012

C. Amatore, E. Carre, A. Jutand, M. A. Barki, and G. Meyer, Evidence for the Ligation of Palladium(0) Complexes by Acetate Ions: Consequences on the Mechanism of Their Oxidative Addition with Phenyl Iodide and PhPd(OAc)(PPh3)2 as Intermediate in the Heck Reaction, Organometallics, vol.14, issue.12, pp.5605-5614, 1995.
DOI : 10.1021/om00012a029

A. Huang, J. J. Kodanko, and L. E. Overman, Asymmetric Synthesis of Pyrrolidinoindolines. Application for the Practical Total Synthesis of (???)-Phenserine, Journal of the American Chemical Society, vol.126, issue.43, pp.14043-14053, 2004.
DOI : 10.1021/ja046690e

R. K. Kunz and D. W. Macmillan, Enantioselective Organocatalytic Cyclopropanations. The Identification of a New Class of Iminium Catalyst Based upon Directed Electrostatic Activation, Herrera R. P. Synlett, pp.3240-3241, 2005.
DOI : 10.1021/ja042774b

F. J. Sagayo, Laborda P.; Calaza M. I.; Jiménez A. I.; Cativiela C, Eur. J. Org. Chem, pp.2011-2028, 2011.

K. Ersmark, J. R. Del-valle, and S. Hanessian, Chemistry and Biology of the Aeruginosin Family of Serine Protease Inhibitors, Angewandte Chemie International Edition, vol.1, issue.7, pp.1202-1223, 2008.
DOI : 10.1002/anie.200605219

G. He and G. Chen, A Practical Strategy for the Structural Diversification of Aliphatic Scaffolds through the Palladium-Catalyzed Picolinamide-Directed Remote Functionalization of Unactivated C(sp3)???H Bonds, Angewandte Chemie International Edition, vol.59, issue.22, pp.5192-5196, 2011.
DOI : 10.1002/anie.201100984

J. D. Roberts and V. C. Chambers, Small-Ring Compounds. VIII. Some Nucleophilic Displacement Reactions of Cyclopropyl, Cyclobutyl, Cyclopentyl and Cyclohexyl p-Toluenesulfonates and Halides, Journal of the American Chemical Society, vol.73, issue.11, pp.5034-5040, 1951.
DOI : 10.1021/ja01155a005

E. N. Marvell, Thermal Electrocyclic Reactions, 1980.
DOI : 10.1016/0040-4020(73)80195-4

J. W. Hausser and N. J. Pinkowski, Solvolysis of cyclopropyl halides. 2-Phenylcyclopropyl chlorides, Journal of the American Chemical Society, vol.89, issue.26, pp.6981-6984, 1967.
DOI : 10.1021/ja01002a028

R. A. Olofson, J. T. Martz, J. P. Senet, M. Piteau, and T. Malfroot, A new reagent for the selective, high-yield N-dealkylation of tertiary amines: improved syntheses of naltrexone and nalbuphine, The Journal of Organic Chemistry, vol.49, issue.11, pp.2081-2082, 1984.
DOI : 10.1021/jo00185a072

S. K. Korneva, L. G. Menchikov, E. S. Koltun, and O. M. Nefedov, Regio- and Stereoselective Preparation of 3-Trimethylsilylallylic Alcohols by Solvolysis of 2-Trimethylsilylic Derivatives of 1-Bromo- and 1,1-Dibromocyclo-propanes in the Presence of CuSO4, Mendeleev Communications, vol.5, issue.4, p.135, 1985.
DOI : 10.1070/MC1995v005n04ABEH000492

M. Mori, M. Okita, K. Chiba, and I. Kayo, New synthesis of ??-lactams, Tetrahedron, vol.41, issue.2, pp.375-385, 1985.
DOI : 10.1016/S0040-4020(01)96429-4

D. L. Comins and M. A. Foley, The addition of alkylzinc iodides to 1-(phenoxycarbonyl)-2,3-dihydropyridinium salts. A synthesis of 2-alkyl-??3-piperidines., Tetrahedron Letters, vol.29, issue.51, pp.6711-6714, 1988.
DOI : 10.1016/S0040-4039(00)82435-1

J. C. Anderson, D. G. Lindsay, and C. B. Reese, The reaction between 2,3-dihydrofuran and dihalocarbenes, Tetrahedron, vol.20, issue.9, pp.2091-2096, 1964.
DOI : 10.1016/S0040-4020(01)98481-9

P. Wipf and J. Methot, Total Synthesis and Stereochemical Revision of (+)-Aeruginosin 298-A, Organic Letters, vol.2, issue.26, pp.4213-4216, 2000.
DOI : 10.1021/ol006759x

M. G. Banwell, X. Ma, R. M. Taylor, and A. C. Willis, Concise Assembly of the Polycyclic Frameworks Associated with the Hapalindole and Fischerindole Alkaloids, Organic Letters, vol.8, issue.21, pp.4959-4961, 2006.
DOI : 10.1021/ol062020x

J. Tang, J. Sabyasachi, S. Bhunia, . Md, S. Abu et al., -4,6-Dien-1-yn-3-ols:?? Pinacol Rearrangement and Formation of Bicyclo[4.1.0]heptenone and Reorganized Styrene Derivatives, Journal of the American Chemical Society, vol.129, issue.50, pp.15677-15683, 2007.
DOI : 10.1021/ja076175r
URL : https://hal.archives-ouvertes.fr/hal-00758268

D. S. Tsang, S. Yang, F. Alphonse, and A. K. Yudin, Stereoselective Isomerisation of N-Allyl Aziridines into Geometrically StableZ Enamines by Using Rhodium Hydride Catalysis, Chemistry - A European Journal, vol.124, issue.3, pp.886-894, 2008.
DOI : 10.1002/chem.200701322

J. Banks, D. V. Mel, and C. G. Frost, The ??-arylation of ??-bromo- and ??-chloroenones using palladium-catalysed cross-coupling, Tetrahedron Letters, vol.47, issue.17, pp.2863-2866, 2006.
DOI : 10.1016/j.tetlet.2006.02.134

S. E. Denmark and R. C. Klix, Silicon-directed nazarov cyclizations VII, Tetrahedron, vol.44, issue.13, pp.4043-4060, 1988.
DOI : 10.1016/S0040-4020(01)86655-2