G. Castany and J. Margat, Dictionnaire français d'hydrogéologie, Editions du BRGM. Service Géologique National, vol.249, 1977.

J. J. Carrillo-rivera, A. Cardona, and W. M. Edmunds, Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potos???? basin, Mexico, Journal of Hydrology, vol.261, issue.1-4, pp.24-47, 2001.
DOI : 10.1016/S0022-1694(01)00566-2

A. Charmoille, Traçage hydrochimique des interactions hydrauliques et mécaniques entre les volumes perméables et peu perméables au sein des aquifères fracturés carbonatés, Thèse, 2005.

A. Chermette, Les ressources de la France en spath-fluor, 1960.

L. Chery, Interprétation des résultats des analyses isotopiques Etude de la salinité verticale de l'Eocène moyen dans la zone bordelaise (Gironde), 1993.

L. Chery, P. Dusseau, and B. Sourisseau, Diagnostic de l'accroissement de la salinité des nappes profondes de l'Eocène moyen en Gironde, Programmes de la Communauté Urbaine de Bordeaux (CUB) et du Fond National de développement de l'Assainissement et de l'Eau (FNDAE). Rapport BRGM/RR-37998-FR, 1994.

L. Chery and A. Gadalia, Aide à la définition du périmètre de protection de la source de Fontbanne à Budos (33) -Interprétation des résultats d'analyses chimiques et isotopiques, 2001.

L. Chery, A. Gadalia, C. Mazurier, and B. Sourisseau, Ressources thermominérales du Bas-Adour. Grille d'observation de la qualité des eaux, 1999.

P. Choukroune and M. Mattauer, Tectonique des plaques et Pyrenees; sur le fonctionnement de la faille transformante nord-pyreneenne; comparaisons avec des modeles actuels, Bulletin de la Societe Geologique de France, vol.7, issue.5, pp.689-700, 1978.
DOI : 10.2113/gssgfbull.S7-XX.5.689

I. D. Clark and P. Fritz, Groundwater quality, Environmental Isotopes in Hydrology, 1997.

P. Corbier, A. Akar, A. Mazurier, C. Platel, J. P. La-collaboration-de-caperan et al., Contrôle qualité et gestion des nappes d'eaux souterraines en Gironde -Etat des connaissances à fin, et Fondin A, vol.328, 2006.

P. J. Cook and M. W. Mc-elhinny, A reevaluation of the spatial and temporal distribution of sedimentary phosphate deposits in the light of plate tectonics, Economic Geology, vol.74, issue.2, pp.315-330, 1979.
DOI : 10.2113/gsecongeo.74.2.315

P. Corbier, J. P. Capdeville, N. Pédron, J. P. Platel, A. Winckel et al., SAGE Nappes profondes de Gironde -Atlas des zones à risques, 2005.

P. Corbier, A. Winckel, C. Mazurier, B. Mauroux, J. P. Platel et al., Contrôle qualité et gestion des nappes d'eaux souterraines en Gironde Investigations préalables à la mise en place d'un réseau qualité sur la, 2004.

A. W. Harbaugh and M. D. Mcdonald, User's documents for MODFLOW-96, 1996.

. Hodge, Rhénium, molybdenum, and uranium in groundwater from the south Great Basin, USA : Evidence for conservative behavior, GCA, vol.60, issue.17, pp.3197-3214, 1996.

B. Housse and P. Maget, Potentiel géothermique du Bassin aquitain. BRGM SNEA ELF. Compte rendu de fin de contrat d'une étude financée par la Délégation Générale à la Recherche Scientifique et Technique, 1977.

C. Innocent and E. Malcuit, U isotope systematics on groundwaters from southwestern France Mixing processes and residence times, AGU 2011 ? Fall Meeting, pp.5-9, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00636915

C. Innocent, U-series constraints on aquifer groundwater residence time: the Adour-Garonne district case (southwest France), GES8 -Geochemistry of the Earth's Surface -Middlesex -England, 2008.
DOI : 10.1180/minmag.2008.072.1.321

URL : https://hal.archives-ouvertes.fr/hal-00643083

C. Innocent, Négrel Ph., soumis. U Isotopic constraints on groundwater residence time: the case of the

M. Jébrak and E. Marcoux, Géologie des ressources minérales, Association géologique du Canada, Ressources naturelles et Faune Québec, pp.369-378, 2008.

K. Jensen and P. L. Bjerg, Large-scale dispersion experiments in a sandy aquifer in Denmark: Observed tracer movements and numerical analyses, Water Resources Research, vol.12, issue.13, pp.673-696, 1993.
DOI : 10.1029/92WR02468

H. Jirakova, F. Huneau, H. Celle-jeanton, Z. Hrkal, L. Coustumer et al., Palaeorecharge conditions of the deep aquifers of the Northern Aquitaine region (France), Journal of Hydrology, vol.368, issue.1-4, pp.1-4, 2009.
DOI : 10.1016/j.jhydrol.2009.01.017

URL : https://hal.archives-ouvertes.fr/hal-00453290

S. K. Jha, V. K. Mishra, D. K. Sharma, and T. Damodaran, Fluoride in the Environment and Its Metabolism in Humans, Reviews of Environmental Contamination and Toxicology, pp.211-121, 2011.
DOI : 10.1007/978-1-4419-8011-3_4

A. Klingebiel, Lithostratigraphie comparée des formations éocènes de la vallée de la Dordogne, Thèse 3è cycle, n° 98, Faculté des. Sciences de Bordeaux, 1961.

A. Klingebiel, Lithostratigraphie comparée du Sidérolithique Nord-Aquitain et des formations éocènes du Bordelais, C.R. Som. Soc. Géol. France, p.111, 1961.

A. Klingebiel, Observations sur la sédimentation argileuse du début des temps tertiaires en Aquitaine, Bull Soc. Géol. Fr, vol.7, issue.5, pp.303-306, 1963.

P. Matheron, Note sur les dépôts tertiaires du médoc et des environs de Blaye et sur leurs rapports avec les couches fluvio-lacustres du Nord-Est de l'Aquitaine et, 1867.

C. Mayeux and A. Klingebiel, Observations sur les formations infra-éocènes dans le, 1967.

B. Inst and . Géol, Bassin d'Aquitaine, n°3

M. D. Mcdonald and A. W. Harbaugh, A modular three-dimensional finite-difference flow model, Techniques of Water Resources Investigations of the U.S. Geological Survey, 1988.

J. L. Melvin, Evaporites, Petroleum and Mineral Resources, 1991.

F. Mer, Contribution à l'étude des caractéristiques de la nappe des Sables inférieurs d'Aquitaine, 1964.

M. Meybeck, Composition chimique des ruisseaux non pollués de France, Sci. Géol., Bull, vol.39, issue.1, pp.3-77, 1986.

R. Millot, E. Petelet-giraud, C. Guerrot, and P. Negrel, Multi-isotopic composition (delta Li-7-delta B- 11-delta D-delta O-18) of rainwaters in France: Origin and spatio-temporal characterization, Applied Geochem, vol.25, pp.10-1510, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00553187

C. Monciardini, Géologie comparée des gisements de phosphate et de pértôle, Coll. Int. Orléans documents du BRGM, vol.67, issue.259, 1979.

W. G. Mook, The dissolution-exchange model for groundwater with 14 C Interpréation of Environmental Isotopes and Hydrochemical Data In Groundwater Hydrology, pp.213-225, 1976.

W. G. Mook, J. C. Bommerson, and W. H. Staverman, Carbon isotope fractionation between dissolved bicarbonate and gaseous carbon dioxide, Earth and Planetary Science Letters, vol.22, issue.2, pp.169-76, 1974.
DOI : 10.1016/0012-821X(74)90078-8

J. S. Morabito, Le bassin évaporitique de Saint-Sabine (Dordogne) : un exemple typique de playa continentale, pp.71-90, 1999.

B. Moussie, Le système aquifère de l'Eocène moyen et supérieur du Bassin Nord-Aquitain. Influence du cadre géologique sur les modalités de circulation, Thèse, 1972.

C. Moussie, Effet de l'infiltration par les argiles au sein des nappes d'eau tertiaires du Bassin aquitain. Sciences de la terre, XVI, issue.2, pp.159-192, 1972.

J. Mudry, Apport du traçage physico-chimique naturel à la connaissance hydrocinématique des aquifères carbonatés, Thèse de doctorat d'état, 1987.

M. Munoz, A. J. Boyce, P. Courjault-rade, A. Fallick, and F. Tollon, Le filon (Zn, F) de Peyrebrune (SW Massif central, France): caract??risation g??ochimique des fluides au cours du M??sozo??que ?? la bordure orientale du bassin d'Aquitaine, Comptes Rendus de l'Acad??mie des Sciences - Series IIA - Earth and Planetary Science, vol.324, issue.11, pp.899-906, 1997.
DOI : 10.1016/S1251-8050(97)82503-7

M. Munoz, A. J. Boyce, P. Courjault-rade, A. Fallick, and F. Tollon, Continental basinal origin of ore fluids from southwestern Massif central fluorite veins (Albigeois, France): evidence from fluid inclusion and stable isotope analyses, Applied Geochemistry, vol.14, issue.4, pp.447-458, 1998.
DOI : 10.1016/S0883-2927(98)00070-5

Y. Nathan and J. Lucas, Synthese de l'apatite a partir du gypse; application au probleme de la formation des apatites carbonatees par precipitation directe, Chemical Geology, vol.9, issue.1-4, pp.99-112, 1972.
DOI : 10.1016/0009-2541(72)90040-X

A. Rechiniac, Etude minéralogique des principales formations détritiques du Paléogène Aquitain, p.2, 1964.

C. K. Richardson and H. D. Holand, The solubility of fluorite in hydrothermal solutions, an experimental study, Geochimica et Cosmochimica Acta, vol.43, issue.8, pp.1313-1325, 1979.
DOI : 10.1016/0016-7037(79)90121-2

C. K. Richardson and H. D. Holand, Fluorite deposition in hydrothermal systems, Geochimica et Cosmochimica Acta, vol.43, issue.8, 1979.
DOI : 10.1016/0016-7037(79)90122-4

M. R. Rosen, D. E. Miser, M. A. Starcher, and J. K. Warren, Formation of dolomite in the Coorong region, South Australia, Geochimica et Cosmochimica Acta, vol.53, issue.3, pp.661-669, 1988.
DOI : 10.1016/0016-7037(89)90009-4

S. Géologique-de-france, Collection Interactions, pp.2-7117, 2005.

N. K. Sahu and M. A. Karin, Fluoride incidence in natural waters, J Geol Soc India, vol.33, pp.450-456, 1989.

M. Saltel, Impact de structures géologiques sur l'alimentation de systèmes aquifères profonds ? Fonctionnement hydrogéologique des antiformes du sud de Bordeaux, Thèse de doctorat, 2008.

V. Sanchez, E. Cardellach, M. Corbella, E. Vindel, T. Martin-crespo et al., Variability in fluid sources in the fluorite deposits from Asturias (N Spain): Further evidences from REE, radiogenic (Sr, Sm, Nd) and stable (S, C, O) isotope data, Ore Geology Reviews, vol.37, issue.2, pp.87-100, 2010.
DOI : 10.1016/j.oregeorev.2009.12.001

N. Schnebelen, B. Mauroux, and J. Seguin, Contrôle qualité et gestion des nappes d'eau souterraine en Gironde, Etat des connaissances à fin, 2000.

N. Schnebelen, J. P. Platel, H. Bonnery, B. Sourisseau, S. Benhammouda et al., Gestion des eaux souterraines en Aquitaine -Année 4 -Opération sectorielle. Relations entre l'estuaire de la Gironde et la nappe de l'Eocène, 2000.

N. Schnebelen, B. Mauroux, J. J. Seguin, J. Dubreuilh, P. Dufour et al., Contrôle qualité et gestion des nappes d'eau souterraine en Gironde, Etat des connaissances à fin 2000. BRGM/RP-51307-FR. 2 vol, 2001.

N. Schnebelen, J. P. Platel, E. Petelet-giraud, J. Dubreuilh, S. Benhammouda et al., Gestion des eaux souterraines en Aquitaine -Année 5 -Opération sectorielle. Relations entre l'estuaire de la Gironde et la nappe de l'Eocène. Réalisation d'un piézomètre complémentaire, suivi du réseau d'alerte et synthèse des résultats, protocoles, 2002.

N. Schnebelen, J. P. Platel, E. Petelet-giraud, J. Dubreuilh, S. Benhammouda et al., Gestion des eaux souterraines en Aquitaine -Année 5 -Opération sectorielle. Relations entre l'estuaire de la Gironde et la nappe de l'Eocène. Réalisation d'un piézomètre complémentaire, suivi du réseau d'alerte et synthèse des résultats, protocoles d'actions pour l'avenir, 2002.

H. Schoeller, Les conditions de formations des molasses du Sidérolithique de la bordure Nord-Est du Bassin aquitain, Bull. Soc. de la Carte Geol. de France, issue.11, pp.32-34, 1941.

H. Schoeller, L'âge de la partie supérieure des Sables à Nummulites du Blayais (Gironde), C.R. SC. Géol, 1949.

H. Schoeller, Contribution à l'étude du fluor dans les eaux souterraines, Ann. Inst. Hydrol. Climat, vol.23, 1952.

H. Schoeller, Les limites septentrionales de l'Eocène du Bassin d'Aquitaine, Bull. Soc. De la Carte Géol, Fr, pp.1-3, 1956.

O. Serrano, Le Crétacé supérieur -Paléogène du bassin compressif nord-pyrénéen, 2001.
DOI : 10.1016/s1251-8050(00)01487-7

. Plomb, Rubidium (0.05 ; µg/l) Strontium ( 1 ; µg/l) Sélénium ( 0.1 ; µg/l) Vanadium (0.01

E. Malcuit, CARISMEAU 2 -Thèse « Zone minéralisée de l'Entre-Deux-Mers, 2009.

E. Malcuit, CARISMEAU 2 -Projet de recherche et thèse associée : « Zone minéralisée de, 2010.

». Mers, Rapport d'étape -Janvier 2010

E. Malcuit, CARISMEAU 2 -Projet de recherche et thèse associée : « Zone minéralisée de, 2010.

». Mers, Rapport d'étape -Juillet 2010

E. Malcuit, CARISMEAU 2 -Projet de recherche et thèse associée : « Zone Minéralisée de, 2010.

». Mers, Rapport d'étape -Décembre 2010 Rapport BRGM/RP-59176-FR, 138 p., 99 ill

E. Malcuit, N. Ph, E. Petelet-giraud, J. M. Gandolfi, N. Pédron et al., Caractérisation isotopique et géochimique des masses d'eau dans le Bassin Adour-Garonne : interconnexions et hétérogénéités - CARISMEAU. Rapport final, Approche couplée hydrogéologique et géochimique isotopique des Sables Infra-Molassiques du Bassin Adour-Garonne. Rapport BRGM/RP-56737-FR, 136 p., 74 figures, 2008.

N. Ph, R. Millot, C. Guerrot, E. Petelet-giraud, A. Brenot et al., Heterogeneities and interconnections in groundwaters: Coupled B, Li and stable-isotope variations in a large aquifer system (Eocene Sand aquifer, Southwestern France), Chemical Geology, 2012.

. Sr, 86 Sr ratio in large sedimentary aquifers (Adour-Garonne district, SW France): origin of salinity and dynamic of groundwater circulation

P. Durst, E. Malcuit, N. Ph, and E. Petelet-giraud, Impact of sedimentologic and structural evolution of the Aquitaine Basin on actual water quality. Eocene sand aquifer, south western France, In EGU General Assembly, vol.13, pp.3-8, 2011.

C. Innocent and E. Malcuit, U isotope systematics on groundwaters from southwestern France Mixing processes and residence times, AGU 2011 ? Fall Meeting, pp.5-9, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00636915

E. Malcuit, N. Ph, and O. Atteia, CARISMEAU 2 -La " Zone minéralisée de l'Entre-Deux-Mers, 2010.

E. Malcuit, N. Ph, C. Innocent, E. Petelet-giraud, and P. Durst, Dating tools applied to mineralized Eocene groundwater, for a sustainable management of the Entre-Deux-Mers drinking water, Aquitaine Basin, South western France, EGU General Assembly 2011, pp.3-8, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00593470

E. Malcuit, N. Ph, E. Petelet-giraud, O. Atteia, M. Franceschi et al., The CARISMEAU 2 research project -Geochemical, multi-isotopic and hydrogeological characterization of mineralized groundwaters, XXXVIII IAH Congress -Groundwater Quality Sustainability, pp.12-17, 2010.

E. Malcuit, N. Ph, E. Petelet-giraud, O. Atteia, M. Franceschi et al., Zone minéralisée de l'Entre-Deux-Mers" : Caractérisation hydrogéologique, géochimique et isotopique -CARISMEAU 2, CFH- AIH 2010, pp.25-27, 2010.

E. Malcuit, N. Ph, E. Petelet-giraud, and P. Durst, Large sedimentary aquifer system and sustainable management: investigations of hydrogeological and geochemical variations in Eocene sand aquifer, south western France, AGU 2010 ? Fall Meeting, pp.13-17, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00593478

N. Ph, R. Millot, C. Guerrot, E. Petelet-giraud, A. Brenot et al., Heterogeneities and interconnections in groundwater: Coupled B, and Li isotope variations in a large aquifer system (Eocene sand aquifer, south western France, AGU 2010 ? Fall Meeting, pp.13-17, 2010.

P. Négrel, S. Roy, E. Petelet-giraud, R. Millot, and E. Malcuit, Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin (Southern France), pp.2011-2016, 2011.

E. Petelet-giraud, N. Ph, R. Millot, C. Guerrot, A. Brenot et al., Large sedimentary aquifer systems functioning. Contraints by classical isotopic and chemical tools and REE in the Eocene sand aquifer, SW France, AGU 2010 ? Fall Meeting, pp.13-17, 2010.

E. Malcuit, Projet de recherche CARISMEAU 2 -La " Zone minéralisée de l'Entre-Deux-Mers, 2010.

E. Malcuit, N. Ph, E. Petelet-giraud, O. Atteia, and M. Franceschi, Recherche de l'origine de la minéralisation dans la masse d'eau Eocène 5071. Cas de la "Zone minéralisée de l'Entre-Deux-Mers". Projet de recherche CARISMEAU 2 et thèse associée "Zone minéralisée de l'Entre-Deux-Mers, CFH-AIH 2010 - Cession du comité H2I, p.25, 2010.

. André, for the ? 34 S SO4 signature of the mineralized zone, the range is from -2 All ranges are compatible with those measured by For sulfate concentrations higher than 1 mmol. L -1 , the ? 34 S SO4 values range between +12.6 and +31.3? (Fig. 3). ? 34 S SO4 values of gypsum measured locally for the upper part of the Eocene sands, this study) and isotopic signature documented for evaporite of Eocene and Paleocene ages (+17 to +22?, Claypool et al., 1980), suggest that dissolution of evaporite layers is probably one of the uppermost source of sulfates in the basin. Thus, end-member 3 identified on Figure 3 display S-isotopic signature that fully agrees with values of marine evaporites from the Eocene age) and thus may represent evaporite dissolution, and for ? 18 O SO4 signature, from +2.6? (SIM-4) to +16.1? (SIM-8)9? (EMZM42) to +16.9? (EMZM7) and for ? 18 O SO4 signature, from +5.2? (OLZM1) to +17.9? (OLZM2) Most of the points from the mineralized zone plots in the evaporite dissolution field represented by end-member 3, 1980.

. Otero, measured a sulfate concentration of 0.03 mmol. L -1 for rainwater collected in the Llobregat basin, located in the south-eastern part of the Pyrenees. The observed sulfates concentrations in groundwater (0.1-0.4 mmol. L -1 ) are one order of magnitude higher than concentrations expected for rainwater (<0.03 mmol. L -1 ), nevertheless hypothesis of contribution of sulfates from rainwater inputs is still relevant if we take into account dry atmospheric deposition of sulfate and loss of water through evapo-transpiration. Published ? 34 S SO4 data for rainwater in the south?eastern part of the Pyrenees Analytical Methods Committee, 03 mmol. L -1 l for Dax) and in the eastern part of France (Brenot et al., 2007) lie between +2 and +7?. Thus, contribution of sulfates from atmospheric inputs References AMC, 2002.

L. André, Contribution de la géochimie à la connaissance des écoulements souterrains profonds, 2002.

L. André, M. Franceschi, P. Pouchan, and O. Atteia, Origine et ??volution du soufre au sein de l'aquif??re des Sables infra-molassiques du Bassin aquitain, Comptes Rendus Geoscience, vol.334, issue.10, pp.749-756, 2002.
DOI : 10.1016/S1631-0713(02)01814-X

L. André, M. Franceschi, P. Pouchan, and O. Atteia, Using geochemical data and modelling to enhance the understanding of groundwater flow in a regional deep aquifer, Aquitaine Basin, south-west of France, Journal of Hydrology, vol.305, issue.1-4, pp.40-62, 2005.
DOI : 10.1016/j.jhydrol.2004.08.027

D. Aubert, P. Stille, and A. Probst, REE fractionation during granite weathering and removal by waters and suspended loads: Sr and Nd isotopic evidence, Geochimica et Cosmochimica Acta, vol.65, issue.3, pp.387-406, 2001.
DOI : 10.1016/S0016-7037(00)00546-9

Z. A. Berner, D. Stüben, M. A. Leosson, and H. Klinge, S- and O-isotopic character of dissolved sulphate in the cover rock aquifers of a Zechstein salt dome, Applied Geochemistry, vol.17, issue.12, pp.1515-1528, 2002.
DOI : 10.1016/S0883-2927(02)00046-X

J. D. Blum, Y. Erel, and K. Brown, 87Sr/86Sr ratios of sierra nevada stream waters: Implications for relative mineral weathering rates, Geochimica et Cosmochimica Acta, vol.57, issue.21-22, pp.5019-5025, 1994.
DOI : 10.1016/S0016-7037(05)80014-6

A. Brenot, J. Carignan, C. France-lanord, and M. Benoît, Geological and land use control on ??34S and ??18O of river dissolved sulfate: The Moselle river basin, France, Chemical Geology, vol.244, issue.1-2, pp.25-41, 2007.
DOI : 10.1016/j.chemgeo.2007.06.003

A. Brenot, N. Baran, P. Giraud, E. Négrel, and P. , Interaction between different water bodies in a small catchment in the Paris basin (Br??villes, France): Tracing of multiple Sr sources through Sr isotopes coupled with Mg/Sr and Ca/Sr ratios, Applied Geochemistry, vol.23, issue.1, pp.58-75, 2008.
DOI : 10.1016/j.apgeochem.2007.09.006

T. Bullen, A. White, A. Blum, J. Harden, and M. Schulz, Chemical weathering of a soil chronosequence on granitoid alluvium: II. Mineralogic and isotopic constraints on the behavior of strontium, Geochimica et Cosmochimica Acta, vol.61, issue.2, pp.291-306, 1997.
DOI : 10.1016/S0016-7037(96)00344-4

A. Burg, J. Leyreloup, J. Marchand, and P. Matte, Inverted metamorphic zonation and large-scale thrusting in the Variscan Belt: an example in the French Massif Central, Variscan Tectonics of the North Atlantic Region, pp.47-61, 1984.
DOI : 10.1144/GSL.SP.1984.014.01.05

W. H. Burke, R. E. Denison, E. A. Hetherington, R. B. Koepnick, N. F. Nelson et al., Variation of seawater 87Sr/86Sr throughout Phanerozoic time, Geology, vol.10, issue.10, pp.516-519, 1982.
DOI : 10.1130/0091-7613(1982)10<516:VOSSTP>2.0.CO;2

O. Cabaret, Quantification du rôle des aquitards dans la gestion de l'exploitation de l'exploitation de l'aquifere multicouches nord -aquitain : caractérisations physiques et approches numeriques, 2011.

I. D. Clark and P. Fritz, Groundwater Quality in Environmental Isotopes in Hydrology, 1997.

G. E. Claypool, W. T. Holser, I. R. Kaplan, H. Sakai, and I. Zak, The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation, Chemical Geology, vol.28, pp.199-260, 1980.
DOI : 10.1016/0009-2541(80)90047-9

A. Cocherie, Interaction manteau-croûte : son rôle dans la génèse d'associations plutoniques calcoalcalines , contraintes géochimiques (éléments traces et isotopes du strontium et de l'oxygène), Thèse Doct. Etat Univ. Rennes I. 246 p, 1984.

D. Caritat, P. Kirste, D. Carr, G. Mcculloch, and M. , Groundwater in the Broken Hill region, Australia: recognising interaction with bedrock and mineralisation using S, Sr and Pb isotopes, Applied Geochemistry, vol.20, issue.4, pp.767-787, 2005.
DOI : 10.1016/j.apgeochem.2004.11.003

D. J. Depaolo, Detailed record of the Neogene Sr isotopic evolution of seawater from DSDP Site 590B, Geology, vol.14, issue.2, pp.103-106, 1986.
DOI : 10.1130/0091-7613(1986)14<103:DROTNS>2.0.CO;2

S. S. Dogramaci, A. L. Herczeg, S. L. Schiff, and Y. Bone, Controls on ??34S and ??18O of dissolved sulfate in aquifers of the Murray Basin, Australia and their use as indicators of flow processes, Applied Geochemistry, vol.16, issue.4, pp.475-488, 2001.
DOI : 10.1016/S0883-2927(00)00052-4

F. Einsiedl and B. Mayer, Sources and Processes Affecting Sulfate in a Karstic Groundwater System of the Franconian Alb, Southern Germany, Environmental Science & Technology, vol.39, issue.18, pp.7118-7125, 2005.
DOI : 10.1021/es050426j

G. Faure, Principles of Isotope Geology, 1986.

F. M. Mcnutt, R. H. , K. D. Gascoyne, M. Frape, and S. K. , Groundwater 87 Sr/ 86 Sr values in the Eye-Dashwa Lakes pluton, Canada: Evidence for plagioclase-water reaction, Chemical Geology, vol.86, pp.111-122, 1991.

P. Fritz and J. Fontes, Introduction, Handbook of Environmental Isotope Geochemistry, pp.1-19, 1980.

B. Fry, W. Ruf, H. Gest, and J. M. Hayes, Sulfur isotope effects associated with oxidation of sulfide by O2 in aqueous solution, Chemical Geology: Isotope Geoscience section, vol.73, issue.3, pp.205-210, 1988.
DOI : 10.1016/0168-9622(88)90001-2

J. Gaillardet, B. Dupre, and C. J. Allegre, Chemical and physical denudation in the Amazon River Basin, Chemical Geology, vol.142, issue.3-4, pp.141-173, 1997.
DOI : 10.1016/S0009-2541(97)00074-0

J. Gaillardet, B. Dupré, P. Louvat, and C. J. Allègre, Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers, Chemical Geology, vol.159, issue.1-4, pp.3-30, 1999.
DOI : 10.1016/S0009-2541(99)00031-5

D. A. Hodell, G. A. Mead, and P. A. Mueller, Variation in the strontium isotopic composition of seawater, 1990.

E. P. Horwitz, R. Chiarizia, and M. L. Dietz, A novel strontium-selective extraction chromatographic resin, pp.313-336, 1992.

W. Kloppmann, N. Ph, J. Casanova, H. Klinge, K. Schelkes et al., Halite dissolution derived brines in the vicinity of a Permian salt dome (N German Basin). Evidence from boron, strontium, oxygen, and hydrogen isotopes, Geochimica et Cosmochimica Acta, vol.65, issue.22, pp.4087-4101, 2001.
DOI : 10.1016/S0016-7037(01)00640-8

W. Kloppmann, P. Bromblet, J. M. Vallet, V. Vergès-belmin, O. Rolland et al., Building materials as intrinsic sources of sulphate: A hidden face of salt weathering of historical monuments investigated through multi-isotope tracing (B, O, S), Science of The Total Environment, vol.409, issue.9, pp.1658-1669, 2011.
DOI : 10.1016/j.scitotenv.2011.01.008

URL : https://hal.archives-ouvertes.fr/hal-00681372

H. R. Krouse and V. A. Grinenko, Stables Isotopes. Natural and Anthrophogenic Sulphur in the Environment, SCOPE, vol.43, issue.440, 1991.

M. Land, J. Ingri, P. S. Andersson, and B. Ohlander, Ba/Sr, Ca/Sr and 87Sr/86Sr ratios in soil water and groundwater: implications for relative contributions to stream water discharge, Applied Geochemistry, vol.15, issue.3, pp.311-325, 2000.
DOI : 10.1016/S0883-2927(99)00054-2

E. S. Lee and N. C. Krothe, Delineating the karstic flow system in the upper Lost River drainage basin, south central Indiana: using sulphate and ??34SSO4 as tracers, Applied Geochemistry, vol.18, issue.1, pp.145-153, 2003.
DOI : 10.1016/S0883-2927(02)00067-7

E. Malcuit, P. Négrel, E. Petelet-giraud, O. Atteia, M. Franceschi et al., Geochemical, multi-isotopic and hydrogeological characterization of the mineralized groundwaters of the Entre-Deux-Mers area, Gironde (South-West France) XXXVIII IAH Congress: Groundwater quality sustainability, 2010.

B. Mauroux, Gestion des eaux souterraines en Aquitaine -Année 3 -Réseaux de surveillance des niveaux de la qualité et des prélèvements -Contribution à la mise en place des réseaux de surveillance de la piézométrie et de la qualité en Aquitaine, 1999.

P. Négrel and E. Petelet-giraud, Isotopes in groundwater as indicators of climate changes, TrAC Trends in Analytical Chemistry, vol.30, issue.8, pp.1279-1290, 2011.
DOI : 10.1016/j.trac.2011.06.001

J. O. Nriagu, C. E. Rees, V. L. Mekhtiyeva, Y. Lein, A. Fritz et al., -Hydrosphère ?Ground water, Stables Isotopes: Natural and Anthropogenic Sulphur in the environment. SCOPE 43, pp.229-242, 1991.

P. Oliva, J. Viers, and B. Dupré, Chemical weathering in granitic environments, Chemical Geology, vol.202, issue.3-4, pp.225-256, 2003.
DOI : 10.1016/j.chemgeo.2002.08.001

N. Otero and A. Soler, Sulphur isotopes as tracers of the influence of potash mining in groundwater salinisation in the Llobregat Basin (NE Spain), Water Research, vol.36, issue.16, pp.3989-4000, 2002.
DOI : 10.1016/S0043-1354(02)00125-2

N. Otero, A. Soler, and A. Canals, Controls of ? 34 S and ? 18 O in dissolved sulphate: learning from a detailed survey in the Llobregat River (Spain) Applied Geochemistry (in press), 2008.

M. R. Palmer, C. Helvaci, and A. E. Fallick, Sulphur, sulphate oxygen and strontium isotope composition of Cenozoic Turkish evaporites, Chemical Geology, vol.209, issue.3-4, pp.341-356, 2004.
DOI : 10.1016/j.chemgeo.2004.06.027

E. Petelet-giraud, N. Ph, and J. Casanova, Sr in water draining granite revealed after a double correction for atmospheric and anthropogenic inputs, Hydrological Sciences Journal, vol.39, issue.5, pp.729-742, 2003.
DOI : 10.1016/0009-2541(94)00159-6

Z. E. Peterman, C. E. Hedge, and H. A. Tourtelot, Isotopic composition of strontium in sea water throughout Phanerozoic time, Geochimica et Cosmochimica Acta, vol.34, issue.1, pp.105-120, 1970.
DOI : 10.1016/0016-7037(70)90154-7

C. Pin and C. Bassin, Evaluation of a strontium-specific extraction chromatographic method for isotopic analysis in geological materials, Analytica Chimica Acta, vol.269, issue.2, pp.249-255, 1992.
DOI : 10.1016/0003-2670(92)85409-Y

M. Plaud and P. Pouchan, Bassin aquitain ?, Aquifères & eaux souterraines de la France. BRGM Editions, pp.429-479, 2006.

O. Serrano, J. Delmas, F. Hanot, R. Vially, J. P. Herbin et al., -Le Bassin d'Aquitaine : valorisation des données sismiques, cartographie structurale et potentiel pétrolier, BRGM, 245 p., 142 fig, 2006.
URL : https://hal.archives-ouvertes.fr/hal-01258434

B. E. Taylor and M. C. Wheeler, Stable isotope geochemistry of acid mine drainage: Experimental oxidation of pyrite, Geochimica et Cosmochimica Acta, vol.48, issue.12, 1984.
DOI : 10.1016/0016-7037(84)90315-6

J. K. Aggarwal, M. R. Palmer, T. D. Bullen, S. Arnórsson, and K. V. Ragnarsdóttir, The boron isotope systematics of Icelandic geothermal waters: 1. Meteoric water charged systems, Geochimica et Cosmochimica Acta, vol.64, issue.4, pp.579-585, 2000.
DOI : 10.1016/S0016-7037(99)00300-2

T. Allard, G. Calas, and P. Ildefonse, Reconstruction of past U migration in a sedimentary deposit (Coutras, France): Implications for a radwaste repository, Chemical Geology, vol.239, issue.1-2, pp.50-63, 2007.
DOI : 10.1016/j.chemgeo.2006.12.007

URL : https://hal.archives-ouvertes.fr/hal-00204681

L. André, Contribution de la géochimie à la connaissance des écoulements souterrains profonds. Application à l'aquifère des Sables Infra_Molassiques du Bassin Aquitain, p.pp, 2002.

L. André, M. Franceschi, P. Pouchan, and O. Atteia, Using geochemical data and modelling to enhance the understanding of groundwater flow in a regional deep aquifer, Aquitaine Basin, south-west of France, Journal of Hydrology, vol.305, issue.1-4, pp.40-62, 2005.
DOI : 10.1016/j.jhydrol.2004.08.027

S. R. Barth, Stable isotope geochemistry of sediment-hosted groundwater from a Late Paleozoic???Early Mesozoic section in central Europe, Journal of Hydrology, vol.235, issue.1-2, pp.72-87, 2000.
DOI : 10.1016/S0022-1694(00)00264-X

S. R. Barth, Geochemical and boron, oxygen and hydrogen isotopic constraints on the origin of salinity in groundwaters from the crystalline basement of the Alpine Foreland, Applied Geochemistry, vol.15, issue.7, pp.937-952, 2000.
DOI : 10.1016/S0883-2927(99)00101-8

L. Bouchaou, J. L. Michelot, A. Vengosh, Y. Hsissou, M. Qurtobi et al., Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss???Massa aquifer, southwest of Morocco, Journal of Hydrology, vol.352, issue.3-4, pp.267-287, 2008.
DOI : 10.1016/j.jhydrol.2008.01.022

URL : https://hal.archives-ouvertes.fr/hal-00357175

A. Brenot, P. Négrel, E. Petelet-giraud, R. Millot, S. Roy et al., Sulfate isotopic and geochemical constraints on dynamics and interconnections of water bodies in the Adour-Garonne district (SW France), J. Hydrol

J. Casanova, . Négrel, . Ph, E. Petelet-giraud, and W. Kloppmann, The evolution of boron isotopic signature of ground waters through silicate weathering, 6th International Symposium on the Geochemistry of the Earth's Surface, pp.7-12, 2002.

J. Casanova, P. Négrel, and R. Blomqvist, Boron isotope fractionation in groundwaters as an indicator of past permafrost conditions in the fractured crystalline bedrock of the fennoscandian shield, Water Research, vol.39, issue.2-3, pp.362-370, 2005.
DOI : 10.1016/j.watres.2004.09.015

L. H. Chan and J. M. Edmond, Variation of lithium isotope composition in the marine environment: a preliminary report, Geochimica et Cosmochimica Acta, vol.52, pp.1711-1717, 1988.

L. H. Chan, J. M. Edmond, G. Thompson, and K. Gillis, Lithium isotopic composition of submarine basalts: implications for the lithium cycle in the oceans, Earth and Planetary Science Letters, vol.108, issue.1-3, pp.151-160, 1992.
DOI : 10.1016/0012-821X(92)90067-6

L. H. Chan, J. M. Edmond, and G. Thompson, A lithium isotope study of hot springs and metabasalts from Mid-Ocean Ridge Hydrothermal Systems, Journal of Geophysical Research, vol.92, issue.53, pp.9653-9659, 1993.
DOI : 10.1029/92JB00840

L. H. Chan, J. M. Gieskes, C. F. You, and J. M. Edmond, Lithium isotope geochemistry of sediments and hydrothermal fluids of the Guaymas Basin, Gulf of California, Geochimica et Cosmochimica Acta, vol.58, pp.4443-4454, 1994.

M. Chaussidon and B. Marty, Primitive Boron Isotope Composition of the Mantle, Science, vol.269, issue.5222, pp.383-386, 1995.
DOI : 10.1126/science.269.5222.383

B. Chetelat, J. Gaillardet, R. Freydier, and P. Négrel, Boron isotopes in precipitation: Experimental constraints and field evidence from French Guiana, Earth and Planetary Science Letters, vol.235, issue.1-2, pp.16-30, 2005.
DOI : 10.1016/j.epsl.2005.02.014

T. B. Coplen, J. A. Hopple, J. K. Böhlke, H. S. Peiser, S. E. Rieder et al., Compilation of minimum and maximum isotope ratios of selected elements in naturally occurring terrestrial materials and reagents, U.S. Geological Survey, Water-Resources Investigations, 2002.

A. Coudrain-ribstein and P. Gouze, Quantitative study of geochemical processes in the Dogger aquifer, Paris Basin, France, Applied Geochemistry, vol.8, issue.5, pp.495-506, 1993.
DOI : 10.1016/0883-2927(93)90078-U

H. Craig, Isotopic Variations in Meteoric Waters, Science, vol.133, issue.3465, pp.1702-1703, 1961.
DOI : 10.1126/science.133.3465.1702

O. Douez, Réponse d'un système aquifère multicouche aux variations paléoclimatiques et aux sollicitations anthropiques?Approche par modélisation couplée hydrodynamique, thermique et géochimique, 2007.

G. Faure, Principles of Isotope Geology, 1986.

J. Gaillardet and C. J. Allègre, Boron isotopic compositions of corals: seawater or diagenesis record? Earth and Planetary Science Letters 136, pp.665-676, 1995.

D. Gastmans, H. K. Chang, and I. Hutcheon, Groundwater geochemical evolution in the northern portion of the Guarani Aquifer System (Brazil) and its relationship to diagenetic features, Applied Geochemistry, vol.25, issue.1, pp.16-33, 2010.
DOI : 10.1016/j.apgeochem.2009.09.024

M. Ghyselinck-bardeau and A. Wuilleumier, Outil d'aide à la décision en matière de géothermie très basse à basse énergie (nappes alluviales et thermalisme) dans la région Midi-Pyrénées, BRGM Report BRGM, vol.307, p.pp, 2007.

R. Gonfiantini, S. Tonarini, M. Gröning, A. Adorni-braccesi, A. S. Al-ammar et al., Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results, Geostandards and Geoanalytical Research, vol.48, issue.1, pp.41-57, 2003.
DOI : 10.1111/j.1751-908X.2003.tb00711.x

N. G. Hemming and G. N. Hanson, Boron isotopic composition and concentration in modern marine carbonates, Geochimica et Cosmochimica Acta, vol.56, issue.1, pp.537-543, 1992.
DOI : 10.1016/0016-7037(92)90151-8

J. F. Hogan and J. D. Blum, Boron and lithium isotopes as groundwater tracers: a study at the Fresh Kills Landfill, Staten Island, New York, USA, Applied Geochemistry, vol.18, issue.4, pp.615-627, 2003.
DOI : 10.1016/S0883-2927(02)00153-1

Y. Huh, L. C. Chan, L. Zhang, and J. M. Edmond, Lithium and its isotopes in major world rivers: implications for weathering and the oceanic budget, Geochimica et Cosmochimica Acta, vol.62, issue.12, pp.2039-2051, 1998.
DOI : 10.1016/S0016-7037(98)00126-4

Y. Huh, L. C. Chan, and J. M. Edmond, Lithium isotopes as a probe of weathering processes: Orinoco River, Earth and Planetary Science Letters, vol.194, issue.1-2, pp.189-199, 2001.
DOI : 10.1016/S0012-821X(01)00523-4

R. H. James, M. D. Rudnicki, and M. R. Palmer, The alkali element and boron geochemistry of the Escanaba Trough sediment-hosted hydrothermal system, Earth and Planetary Science Letters, vol.171, issue.1, pp.157-169, 1999.
DOI : 10.1016/S0012-821X(99)00140-5

S. A. Kasemann, A. Meixner, J. Erzinger, J. G. Viramonte, R. N. Alonso et al., Boron isotope composition of geothermal fluids and borate minerals from salar deposits (central Andes/NW Argentina), Journal of South American Earth Sciences, vol.16, issue.8, pp.685-697, 2004.
DOI : 10.1016/j.jsames.2003.12.004

B. Kisakürek, M. Widdowson, and R. H. James, Behaviour of Li isotopes during continental weathering: the Bidar laterite profile, India, Chemical Geology, vol.212, issue.1-2, pp.27-44, 2004.
DOI : 10.1016/j.chemgeo.2004.08.027

B. Kisakürek, R. H. James, and N. B. Harris, Li and ? 7 Li in Himalayan rivers: proxies for silicate weathering? Earth and Planetary Science Letters, pp.387-401, 2005.

W. Kloppmann, L. Dever, and W. M. Edmunds, Residence time of Chalk groundwaters in the Paris Basin and the North German Basin: a geochemical approach, Applied Geochemistry, vol.13, issue.5, pp.593-606, 1998.
DOI : 10.1016/S0883-2927(97)00110-8

W. Kloppmann, . Négrel, . Ph, J. Casanova, H. Klinge et al., Halite dissolution derived brines in the vicinity of a Permian salt dome (N German Basin). Evidence from boron, strontium, oxygen, and hydrogen isotopes, Geochimica et Cosmochimica Acta, vol.65, issue.22, pp.4087-4101, 2001.
DOI : 10.1016/S0016-7037(01)00640-8

D. Larsen, G. H. Swihart, and X. Yingkai, Hydrochemistry and isotope composition of springs in the Tecopa basin, southeastern California, USA, Chemical Geology, vol.179, issue.1-4, pp.17-35, 2001.
DOI : 10.1016/S0009-2541(01)00313-8

D. Lemarchand and J. Gaillardet, Transient features of the erosion of shales in the Mackenzie basin (Canada), evidences from boron isotopes, Earth and Planetary Science Letters, vol.245, issue.1-2, pp.174-189, 2006.
DOI : 10.1016/j.epsl.2006.01.056

URL : https://hal.archives-ouvertes.fr/hal-00089195

D. Lemarchand, J. Gaillardet, E. Lewin, and C. J. Allègre, Boron isotope systematics in large rivers: implications for the marine boron budget and paleo-pH reconstruction over the Cenozoic, Chemical Geology, vol.190, issue.1-4, pp.123-140, 2002.
DOI : 10.1016/S0009-2541(02)00114-6

W. G. Liu, Y. K. Xiao, Z. C. Peng, Z. S. An, and X. X. He, Boron concentration and isotopic composition of halite from experiments and salt lakes in the Qaidam Basin, Geochimica et Cosmochimica Acta, vol.64, issue.13, pp.2177-2183, 2000.
DOI : 10.1016/S0016-7037(00)00363-X

J. M. Matray, M. Lambert, and J. H. Fontes, Stable isotope conservation and origin of saline waters from the Middle Jurassic aquifer of the Paris Basin, France, Applied Geochemistry, vol.9, issue.3, pp.297-309, 1994.
DOI : 10.1016/0883-2927(94)90040-X

R. Millot and J. P. Girard, Lithium isotope fractionation during adsorption onto mineral surfaces. Clay in natural & engineered barriers for radioactive waste confine- ment?3rd International Meeting?Lille, 2007.

R. Millot and P. Négrel, Multi-isotopic tracing (??7Li, ??11B, 87Sr/86Sr) and chemical geothermometry: evidence from hydro-geothermal systems in France, Chemical Geology, vol.244, issue.3-4, pp.664-678, 2007.
DOI : 10.1016/j.chemgeo.2007.07.015

R. Millot, C. Guerrot, and N. Vigier, Accurate and High-Precision Measurement of Lithium Isotopes in Two Reference Materials by MC-ICP-MS, Geostandards and Geoanalytical Research, vol.68, issue.1, pp.153-159, 2004.
DOI : 10.1016/S0012-821X(03)00035-9

R. Millot, P. Négrel, and E. Petelet-giraud, Multi-isotopic (Li, B, Sr, Nd) approach for geothermal reservoir characterization in the Limagne Basin (Massif Central, France), Applied Geochemistry, vol.22, issue.11, pp.2307-2325, 2007.
DOI : 10.1016/j.apgeochem.2007.04.022

R. Millot, N. Vigier, and J. Gaillardet, Behaviour of lithium and its isotopes during weathering in the Mackenzie Basin, Canada, Geochimica et Cosmochimica Acta, vol.74, issue.14, pp.3897-3912, 2010.
DOI : 10.1016/j.gca.2010.04.025

URL : https://hal.archives-ouvertes.fr/hal-00553199

R. Millot, B. Scaillet, and B. Sanjuan, Lithium isotopes in island arc geothermal systems: Guadeloupe, Martinique (French West Indies) and experimental approach, Geochimica et Cosmochimica Acta, vol.74, issue.6, pp.1852-1871, 2010.
DOI : 10.1016/j.gca.2009.12.007

URL : https://hal.archives-ouvertes.fr/insu-00442612

R. Millot, E. Petelet-giraud, and C. Guerrot, Multi-isotopic composition (??7Li?????11B?????D?????18O) of rainwaters in France: Origin and spatio-temporal characterization, Applied Geochemistry, vol.25, issue.10, pp.1510-1524
DOI : 10.1016/j.apgeochem.2010.08.002

URL : https://hal.archives-ouvertes.fr/hal-00553187

M. Min, X. Peng, X. Zhou, H. Qiao, J. Wang et al., Hydrochemistry and isotope compositions of groundwater from the Shihongtan sandstone-hosted uranium deposit, Xinjiang, NW China, Journal of Geochemical Exploration, vol.93, issue.2, pp.91-108, 2007.
DOI : 10.1016/j.gexplo.2006.12.001

P. Négrel and E. Petelet-giraud, Isotopes in groundwater as indicators of climate changes, TrAC Trends in Analytical Chemistry, vol.30, issue.8, pp.1279-1290, 2011.
DOI : 10.1016/j.trac.2011.06.001

P. Négrel, E. Petelet-giraud, J. Casanova, and W. Kloppmann, Boron isotope signatures in the coastal ground waters of French Guiana, Water Resources Research, vol.38, pp.10-1029, 2002.

P. Négrel, E. Petelet-giraud, A. Brenot, R. Millot, S. Roy et al., Multi isotopic and geochemical constraints of interconnection and heterogeneities of water bodies in the Adour-Garonne district (SW France)?The CARIS- MEAU research project, International Symposium on Advances in Isotope Hydrology and its Role in Sustainable Water Resources Management, 2007.

P. Négrel, E. Petelet-giraud, and A. Brenot, Use of isotopes for groundwater characterisation and monitoring, Groundwater Quality Assessment and Monitoring. Wiley & Sons Ltd publisher, pp.331-354, 2009.

P. Négrel, R. Millot, S. Roy, C. Guerrot, and H. Pauwels, Lead isotopes in groundwater as an indicator of water???rock interaction (Masheshwaram catchment, Andhra Pradesh, India), Chemical Geology, vol.274, issue.3-4, pp.136-148, 2010.
DOI : 10.1016/j.chemgeo.2010.03.012

D. L. Parkhurst and C. A. Appelo, User's guide to PHREEQC (version 2); a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, Water-Resources Investigations?U.S. Geological Survey, 2000.

M. Pennisi, W. P. Leeman, S. Tonarini, A. Pennisi, and P. Nabelek, Boron, Sr, O, and H isotope geochemistry of groundwaters from Mt. Etna (Sicily)???hydrologic implications, Geochimica et Cosmochimica Acta, vol.64, issue.6, pp.961-974, 2000.
DOI : 10.1016/S0016-7037(99)00382-8

M. Pennisi, G. Bianchini, A. Muti, W. Kloppmann, and R. Gonfiantini, Behaviour of boron and strontium isotopes in groundwater???aquifer interactions in the Cornia Plain (Tuscany, Italy), Applied Geochemistry, vol.21, issue.7, pp.1169-1183, 2006.
DOI : 10.1016/j.apgeochem.2006.03.001

M. Pennisi, R. Gonfiantini, S. Grassi, and P. Squarci, The utilization of boron and strontium isotopes for the assessment of boron contamination of the Cecina River alluvial aquifer (central-western Tuscany, Italy), Applied Geochemistry, vol.21, issue.4, pp.643-655, 2006.
DOI : 10.1016/j.apgeochem.2005.11.005

J. S. Pistiner and G. M. Henderson, Lithium-isotope fractionation during continental weathering processes, Earth and Planetary Science Letters, vol.214, issue.1-2, pp.327-339, 2003.
DOI : 10.1016/S0012-821X(03)00348-0

P. A. Pogge-von-strandmann, K. W. Burton, R. H. James, P. Van-calsteren, S. R. Gislason et al., Riverine behaviour of uranium and lithium isotopes in an actively glaciated basaltic terrain, Earth and Planetary Science Letters, vol.251, issue.1-2, pp.134-147, 2006.
DOI : 10.1016/j.epsl.2006.09.001

E. F. Rose, M. Chaussidon, and C. France-lanord, Fractionation of boron isotopes during erosion processes: the example of Himalayan rivers, Geochimica et Cosmochimica Acta, vol.64, issue.3, pp.397-408, 2000.
DOI : 10.1016/S0016-7037(99)00117-9

F. Sánchez-martos, A. Pulido-bosch, L. Molina-sánchez, and A. Vallejos-izquierdo, Identification of the origin of salinization in groundwater using minor ions (Lower Andarax, Southeast Spain), Science of The Total Environment, vol.297, issue.1-3, pp.43-58, 2002.
DOI : 10.1016/S0048-9697(01)01011-7

L. Simon, C. Lécuyer, C. Maréchal, and N. Coltice, Modelling the geochemical cycle of boron: Implications for the long-term ??11B evolution of seawater and oceanic crust, Chemical Geology, vol.225, issue.1-2, pp.61-76, 2006.
DOI : 10.1016/j.chemgeo.2005.08.011

URL : https://hal.archives-ouvertes.fr/hal-00142437

A. J. Spivack and C. F. You, Boron isotopic geochemistry of carbonates and pore waters, Ocean Drilling Program Site 851, Earth and Planetary Science Letters, vol.152, issue.1-4, pp.113-122, 1997.
DOI : 10.1016/S0012-821X(97)00134-9

A. J. Spivack, M. R. Palmer, and J. M. Edmond, The sedimentary cycle of the boron isotopes, Geochimica et Cosmochimica Acta, vol.51, issue.7, pp.1939-1949, 1987.
DOI : 10.1016/0016-7037(87)90183-9

A. M. Stueber, L. M. Walter, T. J. Huston, and P. Pushkar, Formation waters from Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on evolution and migration, Geochimica et Cosmochimica Acta, vol.57, issue.4, pp.763-784, 1993.
DOI : 10.1016/0016-7037(93)90167-U

M. Stute and M. Deak, Environmental Isotope Study (14C, 13C, 18O, D, Noble Gases) on Deep Groundwater Circulation Systems in Hungary With Reference to Paleoclimate, Radiocarbon, vol.36, issue.03, pp.902-918, 1989.
DOI : 10.1017/S0033822200012522

G. H. Swihart, P. B. Moore, and E. L. Callis, Boron isotopic composition of marine and nonmarine evaporite borates, Geochimica et Cosmochimica Acta, vol.50, issue.6, pp.1297-1301, 1986.
DOI : 10.1016/0016-7037(86)90413-8

P. B. Tomascak, Developments in the Understanding and Application of Lithium Isotopes in the Earth and Planetary Sciences, Reviews in Mineralogy and Geochemistry, vol.55, issue.1, pp.153-195, 2004.
DOI : 10.2138/gsrmg.55.1.153

S. Tonarini, M. Pennisi, A. Adorni-braccesi, A. Dini, G. Ferrara et al., Intercomparison of Boron Isotope and Concentration Measurements. Part I: Selection, Preparation and Homogeneity Tests of the Intercomparison Materials, Geostandards and Geoanalytical Research, vol.20, issue.48, pp.421-439, 2003.
DOI : 10.1111/j.1751-908X.2003.tb00710.x

S. Tonarini, W. P. Leeman, L. Civetta, M. Antonio, G. Ferrara et al., B/Nb and ??11B systematics in the Phlegrean Volcanic District, Italy, Nb and ? 11 B systematics in the Phlegrean Volcanic District, pp.123-139, 2004.
DOI : 10.1016/S0377-0273(03)00394-9

A. Vengosh, A. Starinsky, Y. Kolodny, and A. R. Chiras, Boron isotope geochemistry as a tracer for the evolution of brines and associated hot springs from the Dead Sea, Israel, Geochimica et Cosmochimica Acta, vol.55, issue.6, pp.1689-1695, 1991.
DOI : 10.1016/0016-7037(91)90139-V

A. Vengosh, Y. Kolodny, A. Starinsky, A. R. Chivas, and M. T. Mcculloch, Coprecipitation and isotopic fractionation of boron in modern biogenic carbonates, Geochimica et Cosmochimica Acta, vol.55, issue.10, pp.2901-2910, 1991.
DOI : 10.1016/0016-7037(91)90455-E

A. Vengosh, A. R. Chivas, M. T. Mcculloch, A. Starinsky, and Y. Kolodny, Boron isotope geochemistry of Australian salt lakes, Geochimica et Cosmochimica Acta, vol.55, issue.9, pp.2591-2606, 1991.
DOI : 10.1016/0016-7037(91)90375-F

A. Vengosh, A. Starisnky, Y. Kolodny, A. R. Chivas, and M. Raab, Boron isotope variations during fractional evaporation of sea water: New constraints on the marine vs. nonmarine debate, Geology, vol.20, issue.9, pp.799-802, 1992.
DOI : 10.1130/0091-7613(1992)020<0799:BIVDFE>2.3.CO;2

A. Vengosh, K. G. Heumann, S. Juraske, and R. Kasher, Boron Isotope Application for Tracing Sources of Contamination in Groundwater, Environmental Science & Technology, vol.28, issue.11, pp.1968-1974, 1994.
DOI : 10.1021/es00060a030

A. Vengosh, A. R. Chivas, A. Starinsky, Y. Kolodny, Z. Baozhen et al., Chemical and boron isotope compositions of non-marine brines from the Qaidam Basin, Qinghai, China, Chemical Geology, vol.120, issue.1-2, pp.135-154, 1995.
DOI : 10.1016/0009-2541(94)00118-R

A. Vengosh, A. J. Spivack, Y. Artzi, and A. Ayalon, Geochemical and boron, strontium, and oxygen isotopic constraints on the origin of the salinity in groundwater from the Mediterranean Coast of Israel, Water Resources Research, vol.155, issue.6, pp.1877-1894, 1999.
DOI : 10.1029/1999WR900024

N. Vigier, A. Decarreau, R. Millot, J. Carignan, S. Petit et al., Quantifying Li isotope fractionation during smectite formation and implications for the Li cycle, Geochimica et Cosmochimica Acta, vol.72, issue.3, pp.780-792, 2008.
DOI : 10.1016/j.gca.2007.11.011

URL : https://hal.archives-ouvertes.fr/hal-00345697

N. Vigier, S. R. Gislason, K. W. Burton, R. Millot, and F. Mokadem, The relationship between riverine lithium isotope composition and silicate weathering rates in Iceland, Earth and Planetary Science Letters, vol.287, issue.3-4, pp.434-441, 2009.
DOI : 10.1016/j.epsl.2009.08.026

URL : https://hal.archives-ouvertes.fr/hal-00516910

L. B. Williams and R. L. Hervig, Boron isotope composition of coals: a potential tracer of organic contaminated fluids, Applied Geochemistry, vol.19, issue.10, pp.1625-1636, 2004.
DOI : 10.1016/j.apgeochem.2004.02.007

B. Wunder, A. Meixner, R. L. Romer, and W. Heinrich, Temperature-dependent isotopic fractionation of lithium between clinopyroxene and high-pressure hydrous fluids, Contributions to Mineralogy and Petrology, vol.208, issue.1, pp.112-120, 2006.
DOI : 10.1007/s00410-005-0049-0