Skip to Main content Skip to Navigation
Theses

Evaluation des Metal-Organic Frameworks en adsorption et séparation des hydrocarbures

Abstract : The aim of this thesis was to evaluate several Metal Organic Frameworks (MOFs), selected based on criteria of pore size, pore volume and thermal stability, in adsorption and separation of hydrocarbons. For studying the general behavior of MOFs in hydrocarbon adsorption, we have chosen MOFs with open metal sites, MOFs with anionic frameworks and neutral ZIFs. The MOFs with open metal sites behave similar to polar zeolites, the ZIFs behave like apolar zeolites and/or like molecular sieves. Finally we selected the most interesting MOFs and tested them in several separations with industrial interest: xylene isomers, paraffin isomers and selective adsorption of thiophene for the purpose of fuel desulfuration.
Document type :
Theses
Complete list of metadatas

https://tel.archives-ouvertes.fr/tel-00730462
Contributor : Abes Star :  Contact
Submitted on : Monday, September 10, 2012 - 12:37:16 PM
Last modification on : Wednesday, November 13, 2019 - 11:58:21 AM
Long-term archiving on: : Tuesday, December 11, 2012 - 3:39:29 AM

File

2011MULH5711_these_PERALTA.pdf
Version validated by the jury (STAR)

Identifiers

  • HAL Id : tel-00730462, version 1

Collections

Citation

David Peralta. Evaluation des Metal-Organic Frameworks en adsorption et séparation des hydrocarbures. Autre. Université de Haute Alsace - Mulhouse, 2011. Français. ⟨NNT : 2011MULH5711⟩. ⟨tel-00730462⟩

Share

Metrics

Record views

1136

Files downloads

7757