J. L. Dussossoy, S. Schuller, and E. T. Advocat, The formulation of new high level glasses with an increased waste loading charge, International Congress of Glass XXI, 2007.

R. J. Short, R. J. Hand, and N. C. Hyatt, Molybdenum in nuclear waste glasses. Incorporation and redox state Mat, Res. Soc. Symp. Proc, vol.757, pp.141-143, 2003.

G. Calas, M. Le-grand, L. Galoisy, and E. D. Ghaleb, Structural role of molybdenum in nuclear glasses: an EXAFS study, Journal of Nuclear Materials, vol.322, issue.1, pp.15-20, 2003.
DOI : 10.1016/S0022-3115(03)00277-0

URL : https://hal.archives-ouvertes.fr/hal-00085114

C. Lemoine, M. Jarousse, N. Grasse, E. W. Wieschalla, and . Petry, Development of umo/al dispersion fuel: An oxide layer as a protective barrier around the umo particles, THE RERTR-2006 INTERNATIONAL MEETING, 2006.

R. D. Quang, V. Petitjean, F. Hollebecque, O. Pinet, and T. Flament, Prod'homme, Vitritrifation of hlw produced by uranium/molybdenum fuel reprocessing in cogema's cold crucible melter Waste management, Symposium, 2003.

S. Schuller, O. Pinet, A. Grandjean, and E. T. Blisson, Phase separation and crystallization of borosilicate glass enriched in MoO3, P2O5, ZrO2, CaO, Journal of Non-Crystalline Solids, vol.354, issue.2-9, pp.296-300, 2008.
DOI : 10.1016/j.jnoncrysol.2007.07.041

N. Henry, P. Deniard, S. Jobic, R. Brec, C. Fillet et al., Heat treatments versus microstructure in a molybdenum-rich borosilicate, Journal of Non-Crystalline Solids, vol.333, issue.2, pp.199-205, 2004.
DOI : 10.1016/j.jnoncrysol.2003.09.055

X. Orlhac, C. Fillet, and E. J. Phalippou, Study of crystallization mechanisms in the french nuclear waste glass, MRS Proceedings, vol.353, pp.263-270, 1999.
DOI : 10.1016/0022-3093(80)90522-0

X. Orlhac, Etude de la stabilité thermique du verre nucléaire. Modélisation de son évolution à long terme, 1999.

X. Orlhac, C. Fillet, P. Deniard, A. M. Dulac, and E. R. Brec, Determination of the crystallized fractions of a largely amorphous multiphase material by the Rietveld method, Journal of Applied Crystallography, vol.34, issue.2, pp.114-118, 2001.
DOI : 10.1107/S0021889800017908

R. M. Tyson, W. R. Hemphill, and A. F. Theisen, Effect of the w-mo ratio on the shift of excitation and emission-spectra in the scheelite-powellite series, American Mineralogist, vol.73, pp.9-10, 1988.

. Voloshinovskii, X-ray excited luminescence of some molybdates. Nuclear Instruments and Methods in Physics Research A, pp.295-297, 2002.

P. Yang, G. Yao, and J. Lin, Photoluminescence and combustion synthesis of CaMoO4 doped with Pb2+, Inorganic Chemistry Communications, vol.7, issue.3, pp.389-391, 2004.
DOI : 10.1016/j.inoche.2003.12.021

V. B. Mikhailik, H. Kraus, G. Miller, M. S. Mykhaylyk, E. D. Wahl-campos et al., Luminescence of cawo4, camoo4, and znwo4 scintillating crystals under different excitations 97(8): p. 8. 19 Mechanisms behind blue, green, and red photoluminescence emissions in cawo4 and camoo4 powders Comparative study of optical spectra and electronic structures of camoo4 and cawo4 crystals, Journal of Applied Physics Applied Physics Letters Phys. stat. sol. (c), vol.91, issue.58, pp.243-1898, 2005.

C. Valrona, Recherche, croissance cristalline et caractérisation de nouveaux matériaux pour microlasers bleu et infrarouge, 2006.

V. B. Mikhailika, S. Henrya, H. Krausa, and E. I. Solskii, Temperature dependence of camoo4 scintillation properties. Nuclear Instruments and Methods in, Physics Research A, vol.583, pp.350-355, 2007.

C. Cui, J. Bi, and E. D. Gao, Room-temperature synthesis of crystallized luminescent CaMoO4 film by a simple chemical method, Applied Surface Science, vol.255, issue.5, pp.3463-3465, 2008.
DOI : 10.1016/j.apsusc.2008.07.166

C. Xu, D. Zou, H. Guo, F. Jie, and E. T. Ying, Luminescence properties of hierarchical CaMoO4 microspheres derived by ionic liquid-assisted process, Journal of Luminescence, vol.129, issue.5, pp.474-477, 2009.
DOI : 10.1016/j.jlumin.2008.11.017

Z. Zhang, H. Chen, X. Yang, and J. Zhao, Preparation and luminescent properties of Eu3+ and Tb3+ ions in the host of CaMoO4, Materials Science and Engineering: B, vol.145, issue.1-3, pp.34-40, 2007.
DOI : 10.1016/j.mseb.2007.09.091

M. Thomas, P. Prabhakar-rao, M. Deepa, M. R. Chandran, and E. P. Koshy, Novel powellite-based red-emitting phosphors: CaLa1???xNbMoO8:xEu3+ for white light emitting diodes, Journal of Solid State Chemistry, vol.182, issue.1, pp.203-207, 2009.
DOI : 10.1016/j.jssc.2008.10.015

J. Liu, H. Lian, and E. C. Shi, Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4:Eu3+, Optical Materials, vol.29, issue.12, pp.29-1591, 2007.
DOI : 10.1016/j.optmat.2006.06.021

S. Yan, J. Zhang, X. Zhang, S. Lu, X. Ren et al., Enhanced red emission in camoo 4 :Bi 3+ ,eu 3+, Journal of Physical Chemistry, issue.111, pp.13256-13260, 2007.

J. Wang, X. Jing, C. Yan, J. Lin, and E. F. Liao, Photoluminescent Properties of Phosphors in the System Ca[sub x]Cd[sub 1???x]MoO[sub 4]:Eu[sup 3+],???Li[sup +], Journal of The Electrochemical Society, vol.152, issue.7, pp.534-536, 2005.
DOI : 10.1149/1.1923708

Z. Ci, Y. Wang, J. Zhang, and E. Y. Sun, Ca1???xMo1???ySiyO4:Eux3+: A novel red phosphor for white light emitting diodes, Physica B: Condensed Matter, vol.403, issue.4, pp.670-674, 2008.
DOI : 10.1016/j.physb.2007.09.071

F. Lei, H. Yan, and . Chen, Solid-state synthesis, characterization and luminescent properties of Eu3+-doped gadolinium tungstate and molybdate phosphors: Gd(2???x)MO6:Eux3+ (M=W, Mo), Journal of Solid State Chemistry, vol.181, issue.10, pp.181-2845, 2008.
DOI : 10.1016/j.jssc.2008.07.008

L. Zhou, F. Wei, J. Gong, L. Huang, and . Yi, A potential red phosphor znmoo4:Eu3+ for light-emitting diode applicati, Journal of solid state chemistry, issue.6, pp.181-1337, 2008.

A. Xie, X. Yuan, S. Hai, J. Wang, F. Wang et al., phosphor via Bi co-doping and Si substitution for application to white LEDs, Journal of Physics D: Applied Physics, vol.42, issue.10, pp.42-105, 2009.
DOI : 10.1088/0022-3727/42/10/105107

E. E. Leite and . Longo, Europium(iii) concentration effect on the spectroscopic and photoluminescent properties of bamoo4:Eu, Journal of Fluorescence, vol.19, issue.3, pp.495-500, 2009.

E. Cavalli, P. Boutinaud, M. Bettinelli, and E. P. Dorenbos, The excited state dynamics of KLa(MoO4)2:Pr3+: From a case study to the determination of the energy levels of rare earth impurities relative to the bandgap in oxidising host lattices, Journal of Solid State Chemistry, vol.181, issue.5, pp.1025-1031, 2008.
DOI : 10.1016/j.jssc.2008.02.007

X. Yang, X. Yu, H. Yang, Y. Guo, and E. Y. Zhou, The investigation of optical properties by doping halogen in the BaMoO4:Pr3+ phosphor system, Journal of Alloys and Compounds, vol.479, issue.1-2, pp.1-2, 2009.
DOI : 10.1016/j.jallcom.2008.12.034

X. Li, Z. Yang, L. Guan, J. Guo, Y. Wang et al., Synthesis and luminescent properties of CaMoO4:Tb3+, R+ (Li+, Na+, K+), Journal of Alloys and Compounds, vol.478, issue.1-2, pp.684-686, 2009.
DOI : 10.1016/j.jallcom.2008.11.109

H. Yunsheng, Z. Weidong, and Y. Hongqi, Luminescent properties of samarium ion in calcium molybdate, Journal of Rare Earths, vol.22, issue.6, pp.821-824, 2004.

R. J. Thornton, W. D. Fountain, G. W. Flint, and T. G. Crow, Properties of Neodymium Laser Materials, Applied Optics, vol.8, issue.6, pp.1087-1102, 1969.
DOI : 10.1364/AO.8.001087

L. H. Andrade, M. S. Li, Y. Guyot, A. Brenier, and E. G. Boulon, charge compensator, Journal of Physics: Condensed Matter, vol.18, issue.34, pp.18-7883, 2006.
DOI : 10.1088/0953-8984/18/34/003

A. A. Blistanov, B. I. Galagan, B. I. Denker, L. I. Ivleva, V. V. Osiko et al., single crystals, Soviet Journal of Quantum Electronics, vol.19, issue.6, pp.19-747, 1989.
DOI : 10.1070/QE1989v019n06ABEH008127

E. Cavalli, E. Bovero, and E. A. Belletti, Optical spectroscopy of CaMoO4:Dy3+ single crystals, Journal of Physics: Condensed Matter, vol.14, issue.20, pp.14-5221, 2002.
DOI : 10.1088/0953-8984/14/20/317

X. Ma, J. Li, Z. Zhu, Z. You, Y. Wang et al., Optical properties of er3+:Srmoo4 single crystal. The Journal of physics and chemistry of solids, pp.69-2411, 2008.

X. Ma, Z. You, Z. Zhu, J. Li, B. Wu et al., Thermal and optical properties of Tm3+:SrMoO4 crystal, Journal of Alloys and Compounds, vol.465, issue.1-2, pp.406-411, 2008.
DOI : 10.1016/j.jallcom.2007.10.094

R. Z. Zhuang, L. Z. Zhang, Z. B. Lin, and G. F. Wang, crystal, Materials Research Innovations, vol.22, issue.2, pp.62-65, 2008.
DOI : 10.1179/143307507X199407

V. L. Vinograd, D. Bosbach, B. Winkler, and J. D. Gale, Subsolidus phase relations in ca2mo2o8-naeumo2o8-powellite solid solution predicted from static lattice energy calculations and monte carlo simulations 10: p. 3509-3518. 49 Contribution of neodymium optical spectroscopy to the crystal growth study of a silicate apatite in a glassy matrix, Physical Chemistry Chemical Physics Optical Materials, vol.30, pp.1694-1698, 2008.

J. Weinberg-de-bonfils, G. Panczer, D. De-ligny, S. Peuget, and E. B. Champagnon, Behaviour of simplified nuclear waste glasses under gold ions implantation: A microluminescence study, Effets d'irradiations sur la structure de verres borosilicatés comportement à long terme des matrices vitreuses de stockage de déchets nucléaires, pp.1946-1978, 1997.

S. Peuget, P. Noël, J. Loubet, S. Pavan, P. Nivet et al., Effects of deposited nuclear and electronic energy on the hardness of r7t7-type containment glass. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with, Materials and Atoms, vol.246, issue.2, pp.376-386, 2006.

E. J. Delaye and -. Bart, Irradiation stability of r7t7-type borosilicated glass, Journal of Nuclear Materials, vol.354, pp.1-13, 2006.

H. Matzke, E. Et, and . Vernaz, Thermal and physicochemical properties important for the long term behavior of nuclear waste glasses, Journal of Nuclear Materials, vol.201, pp.295-309, 1993.
DOI : 10.1016/0022-3115(93)90186-3

N. Jacquet-fillon, Les verres dans les stockages. CEA rapport interne R-5656, p.190, 1994.

D. Petit-maire, Structure locale autour d'actinides et d'éléments nucléants dans des verres borosilicatés d'intérêt nucléaire: Résultats de spectroscopie d'absorption des rayons x, Thèse de doctorat de l'Université Pierre et Marie Curie, p.198, 1988.

R. C. Ewing, W. J. Weber, and F. W. Clinard, Radiation effects in nuclear waste forms for high-level radioactive waste Effect of chemical composition on borosilicate glass behavior under irradiation, Progress in Nuclear Energy, pp.63-127, 1995.

W. J. Weber, Radiation effects in nuclear waste glasses. Nuclear Instruments and Methods in, Physics Research, pp.471-479, 1988.

. Zinkle, Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium, Journal of materials research, vol.13, issue.6, pp.1434-1484, 1998.

J. P. Evans, J. A. Et, J. P. Marples-evans, K. A. Boult, E. L. Paige et al., The preparation of fully active synroc and its radiation stability, in Progress report Harwell Laboratory: Harwell. 63 The preparation of fully active synroc and its radiation stability, Progress Report, 1985.

A. M. Seydoux-guillaume, R. Wirth, A. Deutsh, and E. U. Schärer, Microstructure of 24-1928 Ma concordant monazites; implications for geochronology and nuclear waste deposits, Geochimica et Cosmochimica Acta, vol.68, issue.11, pp.68-2517, 2004.
DOI : 10.1016/j.gca.2003.10.042

URL : https://hal.archives-ouvertes.fr/hal-00005518

A. M. Seydoux-guillaume, R. Wirth, L. Nasdala, M. Gottschalk, J. M. Montel et al., An XRD, TEM and Raman study of experimentally annealed natural monazite, Physics and Chemistry of Minerals, vol.29, issue.4, pp.240-253, 2002.
DOI : 10.1007/s00269-001-0232-4

URL : https://hal.archives-ouvertes.fr/hal-00005511

V. Picot, X. Deschanels, S. Peuget, B. Glorieux, A. M. Seydoux-guillaume et al., Ion beam radiation effects in monazite, Journal of Nuclear Materials, vol.381, issue.3, pp.290-296, 2008.
DOI : 10.1016/j.jnucmat.2008.09.001

URL : https://hal.archives-ouvertes.fr/hal-00606691

G. R. Lumpkin, Alpha-decay damage and aqueous durability of actinide host phases in natural systems, Journal of Nuclear Materials, vol.289, issue.1-2, pp.136-166, 2001.
DOI : 10.1016/S0022-3115(00)00693-0

L. Thomé, S. Moll, G. Sattonay, L. Vincent, F. Garrido et al., Radiation effects in cubic zirconia: A model system for ceramic oxides, Journal of Nuclear Materials, vol.389, issue.2, pp.297-302, 2009.
DOI : 10.1016/j.jnucmat.2009.02.013

W. J. Weber, R. P. Turcotte, L. R. Bunnell, F. P. Roberts, and J. H. Westsik, Radiation effects in vitreous and devitrified simulated waste glass, Ceramics in nuclear waste management, pp.294-299, 1979.

P. G. Embrey, A. G. Et, and . Couper, The morphology of a large powellite crystal from nasik, india. The Mineralogical Record, pp.311-313, 1982.

R. Z. Kothavala, The discovery of powellite at nasik, india The Mineralogical Record, pp.303-309, 1982.

A. A. Evseev, Kazakhstan and middle east -a brief mineralogical guide, World of Stones, vol.8, p.24, 1995.

F. J. Dahlkamp, Uranium deposits of the world, 2009.

N. P. Laverov, V. I. Velichkin, V. I. Vetrov, V. V. Krotkov, A. L. Lapin et al., central eurasia: Engineering & equipment. Uranium raw material base, JPRS Report, 1991.

I. Bardez-giboire, D. Rigaud, A. Cauli, V. Brethenoux, L. et al., Mise au point d'un protocole de fabrication de psatilles denses de powellite camoo 4 en soutien au programme umo, in Note Technique DTCD/SECM, Luminescence techniques in earth sciences Spectroscopic methods in mineralogy, A. Beran et E. Libowitzky, pp.43-92, 2004.

G. H. Diecke, Spectra and Energy Levels of Rare Earth Ions in Crystals, American Journal of Physics, vol.38, issue.3, 1968.
DOI : 10.1119/1.1976350

T. C. Damen and S. P. Porto, Raman Effect in Zinc Oxide, Physical Review, vol.142, issue.2, pp.570-574, 1966.
DOI : 10.1103/PhysRev.142.570

J. Protas, Diffraction des rayonnements. Introduction aux concepts et méthodes, 1999.

E. J. Sawyer and . Michael, Scanning electron microscopy and x-ray microanalysis, 1981.

F. Ziegler, J. P. Biersack, and E. U. Littmark, The Stopping and Range of Ions in Matter, 1985.
DOI : 10.1007/978-1-4615-8103-1_3

J. M. Delaye, D. Et, and . Ghaleb, Combining two types of molecular dynamics for rapid computation of high-energy displacement cascades. I. Description of the method, Physical Review B, vol.71, issue.22, p.224203, 2005.
DOI : 10.1103/PhysRevB.71.224203

J. M. Delaye, D. Et, and . Ghaleb, Combining two types of molecular dynamics for rapid computation of high-energy displacement cascades. II. Application of the method to a 70-keV cascade in a simplified nuclear glass, Physical Review B, vol.71, issue.22, p.224204, 2005.
DOI : 10.1103/PhysRevB.71.224204

R. L. Fleischer, P. B. Price, and R. M. Walker, Ion Explosion Spike Mechanism for Formation of Charged???Particle Tracks in Solids, Journal of Applied Physics, vol.36, issue.11, pp.36-3645, 1965.
DOI : 10.1063/1.1703059

B. E. Fischer, R. Et, and . Spohr, Production and use of nuclear tracks: Imprinting structure on solids. Preview of Modern Physics, pp.907-945, 1983.

Y. Zhu, Z. X. Cai, R. C. Budhani, M. Suenaga, and D. O. Welch, Structures and effects of radiation damage in cuprate superdonductors irradiated with several-hundred-mev heavy ions, Physical Review B, issue.9, pp.48-6436, 1993.

B. F. Kostenko, J. Pribis, and I. N. Goncharov, Thermal spike model of track formation in yba 2 cu 3 o 7?x *. Physics of Particles and Nuclei Letters, pp.18-26, 2006.

D. Caurant, O. Majérus, P. Loiseau, I. Bardez, N. Baffier et al., Crystallization of neodymium-rich phases in silicate glasses developed for nuclear waste immobilization, Journal of Nuclear Materials, vol.354, issue.1-3, pp.143-162, 2006.
DOI : 10.1016/j.jnucmat.2006.03.014

URL : https://hal.archives-ouvertes.fr/hal-00090360

R. J. Short, R. J. Hand, N. C. Hyatt, and E. G. Möbus, Environment and oxidation state of molybdenum in simulated high level nuclear waste glass compositions, Journal of Nuclear Materials, vol.340, issue.2-3, pp.179-186, 2005.
DOI : 10.1016/j.jnucmat.2004.11.008

D. Li, E. G. Sengers, and F. J. Janssen, De Waal, Morphologies of camo04 crystals in simulated nuclear waste disposal glass, Journal of Materials Science Letters, issue.11, pp.928-929, 1992.

D. Caurant, O. Majérus, E. Fadel, and E. M. Lenoir, Effect of molybdenum on the structure and on the crystallization of sio 2 -na 2 o-cao-b 2 o 3 glasses, Journal of American Ceramic Society, issue.3, pp.90-774, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00326968

F. H. Pough, Crystallized powellite from tonopah, nevada, American Mineralogist, vol.22, pp.57-64, 1937.

J. Kim, J. Choi, J. Jeong, Y. Kim, I. Suh et al., Electron crystallography of camoo4 using high voltage electron microscopy, Bull. Korean Chem. Soc, issue.3, pp.28-391, 2007.

R. M. Hazen, L. W. Finger, and J. W. Mariathasan, High-pressure crystal chemistry of scheelite-type tungstates and molybdates, Journal of Physics and Chemistry of Solids, vol.46, issue.2, pp.253-263, 1985.
DOI : 10.1016/0022-3697(85)90039-3

A. W. Sleight, Accurate cell dimensions for ABO4 molybdates and tungstates, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.28, issue.10, p.2899, 1972.
DOI : 10.1107/S0567740872007186

E. Gürmen, E. Daniels, and J. S. King, by Neutron Diffraction, The Journal of Chemical Physics, vol.55, issue.3, p.1093, 1971.
DOI : 10.1063/1.1676191

D. Christofilos, G. A. Kourouklis, and E. S. Ves, A high pressure Raman study of calcium molybdate, Journal of Physics and Chemistry of Solids, vol.56, issue.8, pp.56-1125, 1995.
DOI : 10.1016/0022-3697(95)00034-8

M. Liegeois-duyckaerts, P. Et, and . Tarte, Vibrational studies of molybdates, tungstates and related compounds-ii. New raman data and assignments for the scheelite-type compounds, Spectrochimica Acta, pp.2037-2051, 1972.

E. Sarantopoulou, C. Raptis, S. Ves, D. Christofilos, and G. A. Kourouklis, : an anharmonicity study, Journal of Physics: Condensed Matter, vol.14, issue.39, pp.14-8925, 2002.
DOI : 10.1088/0953-8984/14/39/302

V. B. Mikhailik, H. Kraus, M. Itoh, D. Iri, and E. M. Uchida, crystals, Journal of Physics: Condensed Matter, vol.17, issue.46, pp.7209-7218, 2005.
DOI : 10.1088/0953-8984/17/46/005

V. B. Mikhailik, H. Kraus, D. Wahl, and M. S. Mykhaylyk, Studies of electronic excitations in MgMoO4, CaMoO4 and CdMoO4 crystals using VUV synchrotron radiation, physica status solidi (b), vol.69, issue.2, pp.17-19, 2005.
DOI : 10.1002/pssb.200409087

D. Spassky, S. Ivanov, I. Kitaeva, V. Kolobanov, V. Mikhailin et al., Optical and luminescent properties of a series of molybdate single crystals of scheelite crystal structure, physica status solidi (c), vol.2, issue.1, pp.65-68, 2005.
DOI : 10.1002/pssc.200460112

M. Wiegel, G. Et, and . Blasse, The luminescence properties of octahedral and tetrahedral molybdate complexes, Journal of Solid State Chemistry, vol.99, issue.2, pp.388-394, 1992.
DOI : 10.1016/0022-4596(92)90327-R

J. Brugger, R. Giere, B. Grobety, and E. E. Uspensky, Scheelite-powellite and paraniite-(Y) from the Fe-Mn deposit at Fianel, Eastern Swiss Alps, American Mineralogist, vol.83, issue.9-10, pp.9-10, 1998.
DOI : 10.2138/am-1998-9-1019

E. Uspensky, J. Brugger, and E. S. Graeser, Ree geochemistry systematics of scheelite from the alps using luminescence spectroscopy: From global regularities to local control, Schweiz. Mineral. Petrogr. Mitt, vol.78, pp.31-54, 1998.

E. Gürmen, E. Et, and . Daniels, by Neutron Diffraction, The Journal of Chemical Physics, vol.55, issue.3, p.1093, 1971.
DOI : 10.1063/1.1676191

R. D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides et chalcogenides, Acta Cryst, pp.751-767, 1976.

M. H. Battey, A. A. Et, and . Moss, Powellite from Traprain Law, Haddingtonshire, Scotland, Mineralogical Magazine, vol.33, issue.257, pp.158-161, 1962.
DOI : 10.1180/minmag.1962.033.257.09

F. H. Vermaas, South african scheelites and x-ray method for determining members of the scheelite-powellite series, American Mineralogist, vol.37, pp.9-10, 1952.

D. R. Uhlmann, KINETICS OF GLASS FORMATION AND DEVITRIFICATION BEHAVIOR, Le Journal de Physique Colloques, vol.43, issue.C9, pp.9-175, 1982.
DOI : 10.1051/jphyscol:1982933

URL : https://hal.archives-ouvertes.fr/jpa-00222462

P. Porcher, P. Et, and . Caro, . II. Intensity parameters, The Journal of Chemical Physics, vol.68, issue.9, pp.4176-4182, 1978.
DOI : 10.1063/1.436279

URL : https://hal.archives-ouvertes.fr/inserm-00733482

P. Porcher, P. Et, and . Caro, . III. Radiative and nonradiative transition probabilities, The Journal of Chemical Physics, vol.68, issue.9, pp.4183-4187, 1978.
DOI : 10.1063/1.436280

R. Ternane, M. Ferid, G. Panczer, M. Trabelsi-ayadi, and E. G. Boulon, Site-selective spectroscopy of Eu3+-doped orthorhombic lanthanum and monoclinic yttrium polyphosphates, Optical Materials, vol.27, issue.12, pp.27-1832, 2005.
DOI : 10.1016/j.optmat.2004.11.005

A. Bednarkiewicz, D. Hreniak, P. Deren, and E. W. Strek, Hot emission in Nd3+/Yb3+:YAG nanocrystalline ceramics, Journal of Luminescence, vol.102, issue.103, pp.101-103, 2003.
DOI : 10.1016/S0022-2313(02)00585-9

A. Bednarkiewicz and W. Strek, : YAG nanocrystallite ceramics, Journal of Physics D: Applied Physics, vol.35, issue.20, pp.35-2503, 2002.
DOI : 10.1088/0022-3727/35/20/307

G. I. Abutalybov, A. A. Et, and . Mamedov, Temperature depletion of the upper laser level 4 F 3/2 of neodymium in the La2S3 ?? 2Ga2O3 glass, Glass Physics and Chemistry, vol.33, issue.6, pp.661-662, 2007.
DOI : 10.1134/S1087659607060193

D. Hreniak, R. Fedyk, A. Bednarkiewicz, W. Strek, and E. W. Lojkowski, Luminescence properties of Nd:YAG nanoceramics prepared by low temperature high pressure sintering method, Optical Materials, vol.29, issue.10, pp.29-1244, 2007.
DOI : 10.1016/j.optmat.2006.05.014

L. Nasdala, J. M. Hanchar, A. Kronz, and M. J. Whitehouse, Long-term stability of alpha particle damage in natural zircon, Chemical Geology, vol.220, issue.1-2, pp.83-103, 2005.
DOI : 10.1016/j.chemgeo.2005.03.012

M. Tichomirowa, M. J. Whitehouse, and E. L. Nasdala, Resorption, growth, solid state recrystallisation, and annealing of granulite facies zircon???a case study from the Central Erzgebirge, Bohemian Massif, Lithos, vol.82, issue.1-2, pp.25-50, 2005.
DOI : 10.1016/j.lithos.2004.12.005

L. Nasdala, M. Zhang, U. Kempe, G. Panczer, M. Gaft et al., Spectroscopic methods applied to zircon, Reviews in Mineralogy and Geochemistry, vol.53, issue.1, pp.427-468, 2003.
DOI : 10.2113/0530427

R. A. Devine, Ion implantation- and radiation-induced structural modifications in amorphous SiO2, Journal of Non-Crystalline Solids, vol.152, issue.1, pp.50-58, 1993.
DOI : 10.1016/0022-3093(93)90443-2

D. H. Day, A. E. Hughes, J. W. Leake, J. A. Marples, G. P. Marsh et al., The management of radioactive wastes, Reports on Progress in Physics, vol.48, issue.1, pp.101-169, 1985.
DOI : 10.1088/0034-4885/48/1/003

J. F. Shackelford, Gas solubility in glasses ??? principles and structural implications, Journal of Non-Crystalline Solids, vol.253, issue.1-3, pp.231-241, 1999.
DOI : 10.1016/S0022-3093(99)00355-5

H. Trinkaus, Local stress relaxation in thermal spikes as a possible cause for creep and macroscopic stress relaxation of amorphous solids under irradiation, Journal of Nuclear Materials, vol.223, issue.2, pp.196-201, 1995.
DOI : 10.1016/0022-3115(95)00013-5

H. Trinkaus, Thermal spike model for irradiation creep of amorphous solids: Comparison to experimental data for ion irradiated vitreous silica, Journal of Nuclear Materials, vol.246, issue.2-3, pp.244-246, 1997.
DOI : 10.1016/S0022-3115(97)00187-6

S. Oishi, D. Iida, T. Suzuki, and E. T. Shishido, Growth of calcium molybdate crystals from a sodium chloride flux, Bulletin of the Society of Sea Water Science, vol.56, issue.1, pp.26-31, 2002.

N. Henry, P. Deniard, and S. Jobic, Heat treatments versus microstructure in a molybdenum-rich borosilicate, Journal of Non-Crystalline Solids, vol.333, issue.2, p.199, 2004.
DOI : 10.1016/j.jnoncrysol.2003.09.055

T. D. Springfield, Figure 1: Luminescence of the MoO 4 group in a natural powellite crystal (Excitation: 266 nm), p.294, 1979.

+. and R. 3+, MoO 4 solid solution is also the main phase that crystallizes during the elaboration of Mo-rich glasses studied as potential future nuclear wastes storage matrices, Powellite phase such as (Ca 2+ , Sr 2+

. Furthermore, The behaviour of powellite under irradiation is therefore essential to understand and to estimate the durability of the glass-ceramic under disposal conditions. A glass-ceramic was obtained after annealing a molybdenum rich borosilicate glass and two ceramic phases, Ca 0.99 Eu 0.01 MoO 4 and Ca 0 were synthesized as model crystalline phases. The rare earth elements are used as minor actinides and fission products surrogates as well as luminescent structural probes. The Ca 0, ceramic was synthesized as the simplest model to study the Eu 3+ luminescence in a powellite type structure. To simulate the effects of internal ? decays which are the main source of damages in containment matrices, the synthetics samples were externally implanted using heavy ions beams (Ar and Pb). Besides two submillimetric natural powellite crystals containing U and Th and therefore exposed to internal irradiation on a geological time scale were also studied as natural analogs

I. V. Pekov, Minerals First Discovered on the Territory of the Former Soviet Union, Ocean Pictures, 1998.

D. Caurant, O. Majerus, and E. Fadel, Glasses, Effect of Molybdenum on the Structure and on the Crystallization of SiO 2 ?Na 2 O?CaO?B 2 O 3 Glasses, pp.774-783, 2007.
DOI : 10.1111/j.1151-2916.1981.tb09605.x

URL : https://hal.archives-ouvertes.fr/cea-01510271

A. Abdelouas, J. Crovisier, W. Lutze, B. Grambow, J. Dran et al., Surface layers on a borosilicate nuclear waste glass corroded in MgCl2 solution, Journal of Nuclear Materials, vol.240, issue.2, pp.100-111, 1997.
DOI : 10.1016/S0022-3115(96)00672-1

D. Bosbach, B. Luckscheiter, B. Brendebach, M. A. Denecke, and N. Finck, High level nuclear waste glass corrosion in synthetic clay pore solution and retention of actinides in secondary phases, Journal of Nuclear Materials, vol.385, issue.2, pp.456-460, 2009.
DOI : 10.1016/j.jnucmat.2008.12.044

. Photoluminescence-in-rare-eaths, Photonic materials and device (PRE'10, Behaviour of Eu 3+ doped Mo-rich glass-ceramic and CaMoO 4 ceramic under Ar and Pb implantation, 2010.

M. Thomas, P. Prabhakarrao, M. Deepa, M. R. Chandran, and P. Koshy, Novel powellite-based red-emitting phosphors: CaLa1???xNbMoO8:xEu3+ for white light emitting diodes, Journal of Solid State Chemistry, vol.182, issue.1, pp.203-207, 2009.
DOI : 10.1016/j.jssc.2008.10.015

L. H. Andrade, M. S. Li, Y. Guyot, A. Brenier, and G. Boulon, charge compensator, Journal of Physics: Condensed Matter, vol.18, issue.34, pp.7883-7892, 2006.
DOI : 10.1088/0953-8984/18/34/003

E. Cavalli, E. Bovero, and A. Belletti, Optical spectroscopy of CaMoO4:Dy3+ single crystals, Journal of Physics: Condensed Matter, vol.14, issue.20, pp.5221-5228, 2002.
DOI : 10.1088/0953-8984/14/20/317

J. L. Dussossoy, S. Schuller, T. Advocat, R. J. Short, R. J. Hand et al., The formulation of new high level glasses with an increased waste loading charge, International Congress of Glass XXI, Molybdenum in nuclear waste glasses. Incorporation and redox state Mat. Res. Soc. Symp. Proc, pp.141-143, 2003.

G. Calas, M. Le-grand, L. Galoisy, and D. Ghaleb, Structural role of molybdenum in nuclear glasses: an EXAFS study, Journal of Nuclear Materials, vol.322, issue.1, pp.15-20, 2003.
DOI : 10.1016/S0022-3115(03)00277-0

URL : https://hal.archives-ouvertes.fr/hal-00085114

C. Orlhac, J. Fillet, and . Phalippou, Study of crystallization mechanisms in the french nuclear waste glass, MRS Proceedings, vol.353, pp.263-270, 1999.
DOI : 10.1016/0022-3093(80)90522-0

X. Orlhac, Etude de la stabilité thermique du verre nucléaire. Modélisation de son évolution à long terme, 1999.

X. Orlhac, C. Fillet, P. Deniard, A. M. Dulac, R. Brec et al., Determination of the crystallized fractions of a largely amorphous multiphase material by the Rietveld method, Journal of Applied Crystallography, vol.34, issue.2, pp.114-118, 2001.
DOI : 10.1107/S0021889800017908

S. Schuller, O. Pinet, A. Grandjean, and T. Blisson, Phase separation and crystallization of borosilicate glass enriched in MoO3, P2O5, ZrO2, CaO, Journal of Non-Crystalline Solids, vol.354, issue.2-9, pp.296-300, 2008.
DOI : 10.1016/j.jnoncrysol.2007.07.041

N. Henry, P. Deniard, S. Jobic, R. Brec, C. Fillet et al., Heat treatments versus microstructure in a molybdenum-rich borosilicate, Journal of Non-Crystalline Solids, vol.333, issue.2, pp.199-205, 2004.
DOI : 10.1016/j.jnoncrysol.2003.09.055

S. Peuget, J. Cachia, C. Jégou, X. Deschanels, D. Roudil et al., Irradiation stability of R7T7-type borosilicate glass, Journal of Nuclear Materials, vol.354, issue.1-3, pp.1-13, 2006.
DOI : 10.1016/j.jnucmat.2006.01.021

D. Ligny, G. Panczer, D. Caurant, and D. Neuville, Contribution of neodymium optical spectroscopy to the crystal growth study of a silicate apatite in a glassy matrix, Optical Materials, vol.30, issue.11, pp.1694-1698, 2008.
DOI : 10.1016/j.optmat.2007.07.008

J. Liu, H. Lian, and C. Shi, Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4:Eu3+, Optical Materials, vol.29, issue.12, pp.1591-1594, 2007.
DOI : 10.1016/j.optmat.2006.06.021

E. Cavalli, A. Bovero, and . Belletti, Optical spectroscopy of CaMoO4:Dy3+ single crystals, Journal of Physics: Condensed Matter, vol.14, issue.20, pp.5221-5228, 2002.
DOI : 10.1088/0953-8984/14/20/317

G. Guyot and . Boulon, Spectroscopic study of floating zone technique-grown Nd3+-doped CaMoO4, Eur. Phys, J.-Appl. Phys, vol.29, pp.55-64, 2005.

H. C. Andrade, M. S. Li, Y. Guyot, A. Brenier, and G. Boulon, charge compensator, Journal of Physics: Condensed Matter, vol.18, issue.34, pp.7883-7892, 2006.
DOI : 10.1088/0953-8984/18/34/003

D. Singh-mudher, M. Keskar, K. Krishnan, and V. Venugopal, Thermal and X-ray diffraction studies on Na2MoO4, Na2Mo2O7 and Na2Mo4O13, Journal of Alloys and Compounds, vol.396, issue.1-2, pp.275-279, 2005.
DOI : 10.1016/j.jallcom.2004.12.024

L. Vinograd, D. Bosbach, B. Winkler, and J. D. Gale, Subsolidus phase relations in Ca2Mo2O8???NaEuMo2O8-powellite solid solution predicted from static lattice energy calculations and Monte Carlo simulations, Physical Chemistry Chemical Physics, vol.6, issue.9, pp.3509-3518, 2008.
DOI : 10.1039/b801912f

E. Gürmen and . Daniels, by Neutron Diffraction, The Journal of Chemical Physics, vol.55, issue.3, p.1093, 1971.
DOI : 10.1063/1.1676191

D. Caurant and O. Majérus, Glasses, Journal of the American Ceramic Society, vol.77, issue.3, pp.774-783, 2007.
DOI : 10.1111/j.1151-2916.1981.tb09605.x

URL : https://hal.archives-ouvertes.fr/cea-01510271

F. J. Dahlkamp, Uranium deposits of the world, 2009.

D. De-ligny and G. Panczer, Contribution of neodymium optical spectroscopy to the crystal growth study of a silicate apatite in a glassy matrix, Optical Materials, vol.30, issue.11, pp.1694-1698, 2008.
DOI : 10.1016/j.optmat.2007.07.008

J. L. Dussossoy and S. Schuller, The formulation of new high level glasses with an increased waste loading charge, 2007.

E. Gürmen and E. Daniels, by Neutron Diffraction, The Journal of Chemical Physics, vol.55, issue.3, 1093.
DOI : 10.1063/1.1676191

N. Henry and P. Deniard, Heat treatments versus microstructure in a molybdenum-rich borosilicate, Journal of Non-Crystalline Solids, vol.333, issue.2, pp.199-205, 2004.
DOI : 10.1016/j.jnoncrysol.2003.09.055

D. R. Olander, Fundamental aspects of nuclear reactor fuel elements Etude de la stabilité thermique du verre nucléaire. Modélisation de son évolution à long terme, 1976.

X. Orlhac and C. Fillet, Determination of the crystallized fractions of a largely amorphous multiphase material by the Rietveld method, Journal of Applied Crystallography, vol.34, issue.2, pp.114-118, 2001.
DOI : 10.1107/S0021889800017908

V. Picot and X. Deschanels, Ion beam radiation effects in monazite, Journal of Nuclear Materials, vol.381, issue.3, pp.290-296, 2008.
DOI : 10.1016/j.jnucmat.2008.09.001

URL : https://hal.archives-ouvertes.fr/hal-00606691

F. Ziegler and J. P. Biersack, The Stopping and Range of Ions in Matter, 1985.
DOI : 10.1007/978-1-4615-8103-1_3