. Jahn-teller, Esta distorção pode, por conseqüência, levar a formação de fases HDL com maior desordem estrutural RAMAN, WAXS et la spectrométrie de masse, toutes dédiées au contrôle in situ des réactions chimiques au cours de la dégradation thermiques des nanocomposites

. Enfin, une question annexe de ce travail mérite également d'être étudiée : la raison de la formation des nanoparticules de Cu métallique ans la phase HDL primitive, en l'absence de matière organique. La détermination de la paire redox, qui conduit à la formation de Cu métallique, est encore en discussion. De quelque manière, ce résultat prouve que les phases HDL peuvent être vues en tant que précurseurs à l

P. Papaspyrides and C. D. , en tant qu'outils dans les études fondamentales sur les atomes individuels qui s'agrègent en clusters ou bulks Polymer/layered silicate (clay) nanocomposites: an overview of flame retardancy, Par dessus tout, les phases HDL peuvent être utiles, pp.35-902, 2010.

T. , S. Zaikov, and G. , Polymer nanocomposite research advances, 2008.

T. , I. S. Drits, and V. A. , The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction, Clays Clay Miner., v, vol.19, p.19, 1984.

J. J. Bravo-suarez, E. A. Paez-mozo, and S. T. Oyama, Review of the synthesis of layered double hydroxides: a thermodynamic approach, Qu??mica Nova, vol.27, issue.4, pp.601-614, 2004.
DOI : 10.1590/S0100-40422004000400015

R. , S. Prasanna, S. V. Kamath, and P. , Polytype selection by intercalated anions: design and synthesis of the 3R(2) polytype of the layered double hydroxide of Zn and Al 15 LEROUX, F.; TAVIOT-GUÉHO, C. Fine tuning between organic and inorganic host structure: new trends in layered double hydroxide hybrid assemblies, Cryst. Growth Des. J. Mater. Chem, issue.11 61, pp.2287-2293, 2005.

R. , B. Newville, M. A. Artemis, L. , and A. , HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT Polymer/montmorillonite nanocomposites with improved thermal properties. Part I. Factors influencing thermal stability and mechanisms of thermal stability improvement, J. of Synchrotron Radiat. Thermochim. Acta, vol.12, issue.2, pp.537-541, 2005.

H. , A. R. Grand, A. F. Wilkie, and C. A. , Developments in flame retardants for heat and fire resistant textiles the role of char formation and intumescence Fire retardancy of polymeric materials, Polym. Degrad. Stab, vol.54, pp.2-3, 1996.

A. Fek, M. , and A. , Oxidation-reduction mechanism of iron in dioctahedral smectites: I. Crystal chemistry of oxidized reference nontronites Montmorillonite cracking catalyst X-ray diffraction Effect of surface modification on the interlayer chemistry of iron in a smectite clay Thermal dehydration and X-ray studies on montmorillonite, Am. Mineral. Indus. Eng. Chem., v. Chem. Mater. Am. Mineral, vol.85, issue.65 10 2, pp.44-53, 1948.

H. , C. M. Charnock, J. M. Plant, and D. A. , Cation occupancies in Mg, Co, Ni, Zn, Al ferrite spinels: a multi-element EXAFS study, Disponível em, pp.953-8984, 2007.

S. 68, J. A. Chagas, A. P. Mar-apr, V. R. Constantino, and T. J. Pinnavaia, Diagramas de ellingham e de van't hoff: algumas considerações. Quim. Nova, v. 30 Basic properties of Mg 1-X (2+) Al X (3+) layered double hydroxides intercalated by carbonate, hydroxide chloride and sulfate anions, Inorg. Chem, vol.69, issue.2 3 4, pp.34-883, 1995.

Z. , H. T. Nagy, and K. L. , Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water, J. Colloid Interface Sci, vol.274, issue.2, pp.613-624, 2004.

I. C. Mcneill, R. C. Mcguiness, J. A. Chandrasiri, D. E. Roberts, C. A. Wilkie et al., 2. reaction products, structural changes and degradation mechanism The effect of some transition metal chlorides on the thermal degradation of poly(methyl methacrylate) -a study using TGA-FTIR spectrometry Impact of the chemical composition of nanofillers on the flammability of polymer nanocomposites Thermal stability and degradation kinetics of poly(methyl methacrylate)/layered copper hydroxy methacrylate composites Polyurethanes crosslinked by metals and their complexes with crown ether, CREPALDI, E. L.; VALIM, J. B. Layered double hydroxides: structure, synthesis, properties and applications. Quim. Nova, v. 21, pp.209-224, 1984.
URL : https://hal.archives-ouvertes.fr/hal-01431307

L. 81 and J. P. , Structural electrical and optical properties of undoped and indium doped ZnO thin films prepared by the pyrosol process at different temperatures Thin Solid Films, v. 416, n. 1-2 Chemical kinetics of copper oxide reduction with carbon monoxide Time-resolved studies for the mechanism of reduction of copper oxides with carbon monoxide: complex behavior of lattice oxygen and the formation of suboxides Synthesis and thermal evolution of hydrotalcite-type compounds containing noble metals, 86 IVANOVA, O. S.; ZAMBORINI, F. P. Size-dependent electrochemical oxidation of silver nanoparticles. J. Amer. Chem. Soc., v. 132, pp.1448-1458, 2000.

N. , K. H. Liu, H. Penner, R. M. Vulcelic, M. Jones et al., Subnanometer silver clusters exhibiting unexpected electrochemical metastability on graphite Cation ordering in synthetic LDH. Clays Clay Miner., v. 45 Anion exchange reactions of hydroxy double salts Catalysis and temperature dependence on the formation of ZnO nanoparticles and of zinc acetate derivatives prepared by the sol-gel route, 90 GHOSE, S. The crystal structure of hydrozincite, Zn 5 (OH) 6 (CO 3 ) 2 . Acta Cryst. Remeasurement of the structure of hexagonal ZnO. Acta Cryst. B, v. 25, pp.4016-4023, 1209.