C. J. Brinker and G. W. Scherer, Sol-Gel Science. The physics and chemistry of sol-gel processsing, 1990.

. Vergnès, Étude structurale et propriétés d'auto-organisation dans des gels hybrides organique-inorganique à base de silicium, 2002.

H. Schmidt and B. Seiferling, Chemistry And Applications Of Inorganic-Organic Polymers (Organically Modified Silicates), MRS Proceedings, vol.32, p.739, 1986.
DOI : 10.1016/0022-3093(85)90385-0

W. Geffcken and E. Berger, Deutsches Reichspatent 736411, Thin Solid Films, p.77129, 1939.

J. Livage, in Transformation of Organometallics into Common and Exotic Materials : Design and Activation, NATO ASI Series E, no, Martinus Nijhoff, issue.141, pp.250-255, 1988.

C. G. Pantano, R. K. Brow, and L. Carman, A. in Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics and Specialty Shapes, N.J, pp.110-128, 1988.
URL : https://hal.archives-ouvertes.fr/in2p3-00015198

E. Matijevic, Monodispersed metal (hydrous) oxides - a fascinating field of colloid science, Accounts of Chemical Research, vol.14, issue.1, pp.22-29, 1981.
DOI : 10.1021/ar00061a004

E. Matijevic, Monodispersed metal (hydrous) oxides - a fascinating field of colloid science, Accounts of Chemical Research, vol.14, issue.1, pp.22-29, 1981.
DOI : 10.1021/ar00061a004

R. Bauer, European Patent App, 1985.

E. R. Vance, Sol-gel production of titanosilicate glass-ceramics for nuclear waste immobilization, Journal of Materials Science, vol.67, issue.4, pp.1413-1416, 1986.
DOI : 10.1007/BF00553281

Y. Li and W. T. Yip, Liposomes as Protective Capsules for Active Silica Sol???Gel Biocomposite Synthesis, Journal of the American Chemical Society, vol.127, issue.37, pp.12756-12757, 2005.
DOI : 10.1021/ja0525354

R. J. Corriu, B. Boury, and R. J. Corriu, Ceramics and Nanostructures from Molecular Precursors, Angewandte Chemie International Edition, vol.39, issue.8, pp.1376-1398, 2000.
DOI : 10.1002/(SICI)1521-3773(20000417)39:8<1376::AID-ANIE1376>3.0.CO;2-S

K. J. Shea, D. A. Loy, and O. W. Webster, Arylsilsesquioxane gels and related materials. New hybrids of organic and inorganic networks, Journal of the American Chemical Society, vol.114, issue.17, pp.6700-6710, 1992.
DOI : 10.1021/ja00043a014

M. Trilla, G. Borja, R. Pleixats, M. Wong-chi-man, C. Bied et al., Recoverable Palladium Catalysts for Suzuki-Miyaura Cross- Coupling Reactions Based on Organic-Inorganic Hybrid Silica Materials Containing Imidazolium and Dihydroimidazolium Salts, Advanced Synthesis & Catalysis, vol.25, issue.16, pp.2566-2574, 2008.
DOI : 10.1002/adsc.200800455

URL : https://hal.archives-ouvertes.fr/hal-00340973

E. Lindner, T. Schneller, F. Auer, and H. A. Mayer, Chemistry in Interphases???A New Approach to Organometallic Syntheses and Catalysis, Angewandte Chemie International Edition, vol.38, issue.15, pp.2154-2174, 1999.
DOI : 10.1002/(SICI)1521-3773(19990802)38:15<2154::AID-ANIE2154>3.0.CO;2-T

B. Ameduri, B. Boutevin, J. J. Moreau, H. Moutaabbid, and M. Wong-chi-man, Hybrid organic???inorganic gels containing perfluoro-alkyl moieties, Journal of Fluorine Chemistry, vol.104, issue.2, pp.185-194, 2000.
DOI : 10.1016/S0022-1139(00)00211-6

URL : https://hal.archives-ouvertes.fr/hal-00164014

J. H. Jung, H. Kobayashi, K. J. Van-bommel, S. Shinkai, and T. Shimizu, Structures Using an Organogel Template, Chemistry of Materials, vol.14, issue.4, pp.1445-1447, 2002.
DOI : 10.1021/cm011625e

B. J. Melde, B. T. Holland, C. F. Blanford, and A. Stein, Mesoporous Sieves with Unified Hybrid Inorganic/Organic Frameworks, Chemistry of Materials, vol.11, issue.11, pp.3302-3308, 1999.
DOI : 10.1021/cm9903935

W. Wang, W. Zhou, and A. Sayari, Synthesis of Periodic Mesoporous Phenylenesilica under Acidic Conditions with Novel Molecular Order in the Pore Walls, Chemistry of Materials, vol.15, issue.26, pp.4886-4889, 2003.
DOI : 10.1021/cm034809x

B. Boury, F. Ben, and R. J. Corriu, Hydrolysis/Polycondensation in the Solid State: Access to Crystalline Silica-Based Hybrid Materials, Angewandte Chemie International Edition, vol.5, issue.15, pp.2853-2856, 2001.
DOI : 10.1002/1521-3773(20010803)40:15<2853::AID-ANIE2853>3.0.CO;2-J

G. Cerveau, S. Chappellet, and R. J. Corriu, Long-range ordered lamellar silicon based hybrid materials, Journal of Materials Chemistry, vol.13, issue.8, pp.1905-1909, 2003.
DOI : 10.1039/b303672n

J. J. Moreau, L. Vellutini, M. Wong-chi-man, C. Bied, J. Bantignies et al., Self-Organized Hybrid Silica with Long-Range Ordered Lamellar Structure, Journal of the American Chemical Society, vol.123, issue.32, pp.7957-7958, 2001.
DOI : 10.1021/ja016053d

URL : https://hal.archives-ouvertes.fr/hal-00163106

J. J. Moreau, L. Vellutini, M. Wong-chi-man, and C. Bied, )-Diureidocyclohexane, Journal of the American Chemical Society, vol.123, issue.7, pp.1509-1510, 2001.
DOI : 10.1021/ja003843z

J. J. Moreau, L. Vellutini, M. Wong-chi-man, and C. Bied, Shape-Controlled Bridged Silsesquioxanes: Hollow Tubes and Spheres, Chemistry - A European Journal, vol.9, issue.7, pp.1594-1599, 2003.
DOI : 10.1002/chem.200390183

URL : https://hal.archives-ouvertes.fr/hal-00163500

J. J. Moreau, B. P. Pichon, C. Bied, and M. Wong-chi-man, Structuring of bridged silsesquioxanes via cooperative weak interactions: H-bonding of urea groups and hydrophobic interactions of long alkylene chains, Journal of Materials Chemistry, vol.125, issue.180, pp.3929-3936, 2005.
DOI : 10.1039/b504635a

URL : https://hal.archives-ouvertes.fr/hal-00163465

J. J. Moreau, B. P. Pichon, G. Arrachart, M. Wong-chi-man, and C. Bied, Nanostructuring organo-silicas: combination of intermolecular interactions and molecular recognition properties to generate self-assembled hybrids with phenylene or adenine???thymine bridging units, New Journal of Chemistry, vol.42, issue.5, pp.653-658, 2005.
DOI : 10.1039/b419376h

A. N. Parikh, M. A. Schivley, E. Koo, K. Seshadri, D. Aurentz et al., -Octadecyltrichlorosilane, Journal of the American Chemical Society, vol.119, issue.13, p.3135, 1997.
DOI : 10.1021/ja963284p

URL : https://hal.archives-ouvertes.fr/hal-00314659

A. Shimojima, D. Muchizuki, K. Kuroda, A. Shimojima, N. Umeda et al., 13, 3603; b), Chem. Mater. Chem. Mater. Chem. Mater. J. Sol-Gel Sci. & Technol, vol.13, issue.32, pp.4768-63, 1144.

D. Kaschiev, Nucleation : Basic theory with applications, 2001.

O. Heinemann and A. Mersmann, Crystallization Technology Handbook, New York; c) Mullin J.W.; Crystallization, 2001.

A. Mersmann, Crystallization Technology Handbook, p.75, 2001.

N. Jongen, P. Bowen, J. Lemaître, J. C. Valmalette, and H. Hofmann, Precipitation of Self-Organized Copper Oxalate Polycrystalline Particles in the Presence of Hydroxypropylmethylcellulose (HPMC): Control of Morphology, Journal of Colloid and Interface Science, vol.226, issue.2, pp.189-198, 2000.
DOI : 10.1006/jcis.2000.6747

E. Matijevic and P. Sheiner, Ferric hydrous oxide sols, Journal of Colloid and Interface Science, vol.63, issue.3, pp.509-524, 1978.
DOI : 10.1016/S0021-9797(78)80011-3

R. L. Penn and J. F. Banfield, Morphology development and crystal growth in nanocrystalline aggregates under hydrothermal conditions: insights from titania, Geochimica et Cosmochimica Acta, vol.63, issue.10, pp.1549-1557, 1045.
DOI : 10.1016/S0016-7037(99)00037-X

W. J. Hehre, L. Radom, P. V. Schleyer, and J. A. Pople, Ab initio molecular orbital theory, Accounts of Chemical Research, vol.9, issue.11, 1986.
DOI : 10.1021/ar50107a003

G. Cerveau, S. Chappellet, and R. J. Corriu, Structure of organic???inorganic hybrid solids: influence of the hydrophilicity and hydrophobicity of precursors, J. Mater. Chem., vol.3, issue.12, pp.2885-2889, 2003.
DOI : 10.1039/B307470F

G. Cerveau, R. J. Corriu, E. Framery, and F. Lerouge, Auto-organization of Nanostructured Organic???Inorganic Hybrid Xerogels Prepared by Sol???Gel Processing: The Case of a ???Twisted??? Allenic Precursor, Chemistry of Materials, vol.16, issue.20, pp.3794-3799, 2004.
DOI : 10.1021/cm049061c

J. J. Moreau, B. P. Pichon, M. Wong-chi-man, C. Bied, H. Pritzkow et al., A Better Understanding of the Self-Structuration of Bridged Silsesquioxanes, Angewandte Chemie International Edition, vol.43, issue.2, pp.203-206, 2004.
DOI : 10.1002/anie.200352485

URL : https://hal.archives-ouvertes.fr/hal-00163494

C. J. Brinker and G. W. Scherer, Sol-Gel Science. The physics and chemistry of sol-gel processsing, p.140, 1990.

P. N. Pusey, Dynamic Light Scattering in Scattering Methods Applied to Soft Condensed Matter, p.207, 2002.

J. S. Pederson, Modelling of Small-Angle Scattering Data in Scattering Methods Applied to Soft Condensed Matter, p.398, 2002.

N. J. Harrick, Internal Reflection Spectroscopy, 1967.

. Arrachart, Auto-assemblage d'organosilices par reconnaissance moléculaire, 2005.

B. V. Pichon and M. Zaharescu, Étude approfondie de l'auto-organisation de silices hybrides comportant des groupes urées et aromatiques, J. Non-Cryst. Solids, vol.319, issue.11, pp.263-279, 2003.

J. Van-esch, R. M. Keloggg, and B. L. Feringa, Di-urea compounds as gelators for organic solvents, Tetrahedron Letters, vol.38, issue.2, pp.281-284, 1997.
DOI : 10.1016/S0040-4039(96)02292-7

J. Van-esch, S. De-feyter, R. M. Kelogg, F. De-schryver, and B. L. Feringa, Self-Assembly of Bisurea Compounds in Organic Solvents and on Solid Substrates, Chemistry - A European Journal, vol.95, issue.44, pp.1238-1243, 1997.
DOI : 10.1002/chem.19970030811

J. J. Moreau, B. P. Pichon, C. Bied, M. Wong-chi-man, J. J. Moreau et al., Structuring of bridged silsesquioxanes via cooperative weak interactions: H-bonding of urea groups and hydrophobic interactions of long alkylene chains, Journal of Materials Chemistry, vol.125, issue.180, pp.3929-3936, 2005.
DOI : 10.1039/b504635a

URL : https://hal.archives-ouvertes.fr/hal-00163465

J. Roisnel, WinPLOTR: A Windows Tool for Powder Diffraction Pattern Analysis, Proceedings of the Seventh European Powder Diffraction Conference, pp.118-123, 2000.
DOI : 10.4028/www.scientific.net/MSF.378-381.118

D. Klug and E. , Nitrite and nitrate ions as infrared pressure gauges for diamond anvils, Review of Scientific Instruments, vol.54, issue.9, pp.1205-1208, 1983.
DOI : 10.1063/1.1137551

B. Orel, R. Je?e, A. Vil?nik, and U. L. ?tangar, Hydrolysis and Solvolysis of Methyltriethoxysilane Catalyzed with HCl or Trifluoroacetic Acid: IR Spectroscopic and Surface Energy Studies, Journal of Sol-Gel Science and Technology, vol.38, issue.3, pp.251-265, 1963.
DOI : 10.1007/s10971-005-2522-7

J. F. Brown, H. Lester, and L. H. Vogt, The Polycondensation of Cyclohexylsilanetriol, Journal of the American Chemical Society, vol.87, issue.19, pp.4313-4317, 1965.
DOI : 10.1021/ja00947a016

W. Hohenberg and . Kohn, Inhomogeneous Electron Gas, Physical Review, vol.136, issue.3B, p.864, 1964.
DOI : 10.1103/PhysRev.136.B864

L. Kohn and . Sham, Self-Consistent Equations Including Exchange and Correlation Effects, Physical Review, vol.140, issue.4A, p.1133, 1965.
DOI : 10.1103/PhysRev.140.A1133

C. Garcia, S. Elsässer, M. Louie, and . Cohen, Use of gradient-corrected functionals in total-energy calculations for solids, Physical Review B, vol.46, issue.15, p.9829, 1992.
DOI : 10.1103/PhysRevB.46.9829

P. Zupan, K. Blaha, J. P. Schwartz, and . Perdew, and Fe: Performance of local-spin-density and generalized-gradient-approximation density functionals, Physical Review B, vol.58, issue.17, p.11266, 1998.
DOI : 10.1103/PhysRevB.58.11266

C. Payne, M. P. Teter, D. C. Allan, T. A. Arias, and J. D. , total-energy calculations: molecular dynamics and conjugate gradients, Reviews of Modern Physics, vol.64, issue.4, p.1045, 1992.
DOI : 10.1103/RevModPhys.64.1045

A. Maradudin, E. W. Montroll, G. H. Weiss, and I. P. Ipatova, Theory of lattice dynamics in the harmonic approximation, 1971.

S. Baroni, A. De-gironcoli, P. Dal-corso, and . Giannozzi, Phonons and related crystal properties from density-functional perturbation theory, Reviews of Modern Physics, vol.73, issue.2, p.515, 2001.
DOI : 10.1103/RevModPhys.73.515

J. Pérez, Optique : Fondements et Applications, 2000.

J. Pérez, Electromagnétisme : Fondements et Applications, 1990.

A. Maradudin and R. F. Wallis, Lattice Anharmonicity and Optical Absorption in Polar Crystals. II. Classical Treatment in the Linear Approximation, Physical Review, vol.123, issue.3, p.777, 1961.
DOI : 10.1103/PhysRev.123.777

K. Born and . Hang, Dynamical Theory of Crystal Lattices, American Journal of Physics, vol.23, issue.7, 1954.
DOI : 10.1119/1.1934059

C. Gonze and . Lee, Dynamical matrices, Born effective charges, dielectric permittivity tensors, and interatomic force constants from density-functional perturbation theory, Physical Review B, vol.55, issue.16, p.10355, 1997.
DOI : 10.1103/PhysRevB.55.10355