E. J. Corey, F. E. Mcdonald, X. Wei, and . Org, La première est basée sur une transposition sigmatropique [1,5] rendue possible par 124 (a) Xiong, Z J. Am. Chem. Soc, vol.122, issue.4831, 2000.

L. F. Silva and . Jr, Construction of cyclopentyl units by ring contraction reactions, Tetrahedron, vol.58, issue.45, p.9137, 2002.
DOI : 10.1016/S0040-4020(02)00990-0

R. Britton, O. Delgado, A. Meyer, and K. G. Poullennec, Information sur la numérotation des atomes du motif thiazole (14) Paterson, I, Angew. Chem., Int. Ed, issue.13, pp.43-4629, 2004.

I. Ohtani, T. Kusumi, Y. Kashman, and H. Kakisawa, High-field FT NMR application of Mosher's method. The absolute configurations of marine terpenoids, Journal of the American Chemical Society, vol.113, issue.11, p.4092, 1991.
DOI : 10.1021/ja00011a006

H. Azizian, C. Eaborn, A. Pidcock, X. Han, B. M. Stoltz et al., Synthesis of organotrialkylstannanes. The reaction between organic halides and hexaalkyldistannanes in the presence of palladium complexes, Journal of Organometallic Chemistry, vol.215, issue.1, pp.49-7600, 1981.
DOI : 10.1016/S0022-328X(00)84615-X

M. Rega, P. Candal, C. Jiménez, J. Rodríguez, B. S. Pedersen et al., (42) (a) Pérez, I.; Pérez Sestelo, Eur. J. Org. Chem. Tetrahedron Organic Syntheses J.; Sarandeses, J. J. Am. Chem. Soc. J. Org. Chem, vol.35, issue.123, pp.934-2433, 1955.

G. Mahler, G. Serra, S. Dematteis, J. Saldaña, L. Domínguez et al., Synthesis and biological evaluation of simplified mycothiazole analogues, Bioorganic & Medicinal Chemistry Letters, vol.16, issue.5, p.1309, 2006.
DOI : 10.1016/j.bmcl.2005.11.072

S. C. Finch, A. L. Wilkins, A. D. Hawkes, D. J. Jensen, A. L. Mackenzie et al., Isolation and identification of (44-R,S)-44,55-dihydroxyyessotoxin from Protoceratium reticulatum, and its occurrence in extracts of shellfish from New Zealand, Norway and Canada, Toxicon, vol.46, issue.2, p.160, 2005.
DOI : 10.1016/j.toxicon.2005.03.007

E. M. Carreira, J. Du-bois, V. Rodeschini, P. Van-de-weghe, C. Tarnus et al., (+)-Zaragozic Acid C: Synthesis and Related Studies, Journal of the American Chemical Society, vol.117, issue.31, pp.8106-62, 1995.
DOI : 10.1021/ja00136a008

B. Jung, M. S. Hong, S. H. Kang, H. C. Kim, S. H. Kang et al., Enantioselective Synthesis of Tertiary Alcohols by the Desymmetrizing Benzoylation of 2-Substituted Glycerols, Angewandte Chemie International Edition, vol.37, issue.15, pp.2616-67, 1308.
DOI : 10.1002/anie.200604977

F. Calo, A. Bondke, J. Richardson, A. J. White, and A. G. Barrett, Total synthesis and determination of the absolute stereochemistry of the squalene synthase inhibitors CJ-13,981 and CJ-13,982, Tetrahedron Letters, vol.50, issue.26, p.3388, 2009.
DOI : 10.1016/j.tetlet.2009.02.121

B. M. Trost, E. J. Mceachern, F. D. Toste, and K. Nomura, A Two-Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles, Journal of the American Chemical Society, vol.120, issue.48, p.12702, 1998.
DOI : 10.1021/ja983238k

P. Patrkja-ferraboschi, P. Grisenti, A. Manzocchi, and E. Santanieffo, Regio- and enantioselectivity of Pseudomonas cepacia lipase in the transesterification of 2-substituted-1,4-butanediols, Tetrahedron: Asymmetry, vol.5, issue.4, p.691, 1994.
DOI : 10.1016/0957-4166(94)80031-6

T. W. Greene and P. G. Wuts, Protecting Groups in Organic Synthesis, 1999.

S. D. Burke, D. N. Deaton, N. Machinaga, and C. Kibayashi, Synthesis of (+)-dihydrocompactin and (+)-compactin via vinylsilane terminated cationic cyclization, Tetrahedron Letters, vol.32, issue.36, pp.4651-4165, 1989.
DOI : 10.1016/S0040-4039(00)92272-X

D. R. Williams, P. D. Lowder, Y. D. Gu, and D. A. Brooks, Studies of mild dehydrogenations in heterocyclic systems, Tetrahedron Letters, vol.38, issue.3, p.331, 1997.
DOI : 10.1016/S0040-4039(96)02344-1

R. R. Schrock, J. S. Murdzek, G. C. Bazan, J. Robbins, M. Dimare et al., Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins, Journal of the American Chemical Society, vol.112, issue.10, p.3875, 1990.
DOI : 10.1021/ja00166a023

A. K. Chatterjee, T. Choi, D. P. Sanders, and R. H. Grubbs, A General Model for Selectivity in Olefin Cross Metathesis, Journal of the American Chemical Society, vol.125, issue.37, p.11360, 2003.
DOI : 10.1021/ja0214882

H. E. Blackwell, D. J. Leary, A. K. Chatterjee, R. A. Washenfelder, D. A. Bussmann et al., New Approaches to Olefin Cross-Metathesis, Journal of the American Chemical Society, vol.122, issue.1, p.58, 2000.
DOI : 10.1021/ja993063u

T. Katsuki, K. B. Sharpless, A. L. Gemal, J. Luche, Z. Xiong et al., The first practical method for asymmetric epoxidation, Journal of the American Chemical Society, vol.102, issue.18, pp.5974-5454, 1980.
DOI : 10.1021/ja00538a077

R. M. Garbaccio, S. J. Stachel, D. K. Baeschlin, and S. J. Danishefsky, Concise Asymmetric Syntheses of Radicicol and Monocillin I, Journal of the American Chemical Society, vol.123, issue.44, p.10903, 2001.
DOI : 10.1021/ja011364+

M. E. Jung and D. C. Amico, Stereospecific Rearrangement of Optically Active Tertiary Allylic Epoxides To Give Optically Active Quaternary Aldehydes: Synthesis of .alpha.-Alkyl Amino Aldehydes and Acids, Journal of the American Chemical Society, vol.117, issue.28, p.7379, 1995.
DOI : 10.1021/ja00133a011

E. J. Corey, M. Chaykovsky, C. J. Kowalski, M. S. Haque, and K. W. Fields, ). Formation and Application to Organic Synthesis, Journal of the American Chemical Society, vol.87, issue.6, pp.1353-1429, 1965.
DOI : 10.1021/ja01084a034

T. W. Greene and P. G. Wuts, Protective Groups in Organic Synthesis, p.86, 1999.
DOI : 10.1002/0471220574

Y. Oikawa, T. Yoshioka, and O. Yonemitsu, Protection of hydroxy groups by intramolecular oxidative formation of methoxybenzylidene acetals with DDQ, 208) Huang, pp.889-3675, 1982.
DOI : 10.1016/S0040-4039(00)86975-0

L. C. Hirayama, K. K. Dunham, B. Singaram, N. Toda, M. Ori et al., Asymmetric indium-mediated synthesis of homopropargylic alcohols, Tetrahedron Letters, vol.47, issue.29, pp.5173-269, 2003.
DOI : 10.1016/j.tetlet.2006.05.049

S. E. Martin, D. F. Suárez, N. Wang, R. Liu, and J. Chen, Catalytic aerobic oxidation of alcohols by Fe(NO3)3???FeBr3, Tetrahedron Letters, vol.43, issue.25, pp.4475-5322, 2002.
DOI : 10.1016/S0040-4039(02)00829-8

B. Guan, D. Xing, G. Cai, X. Wan, N. Yu et al., Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic Ligand, Journal of the American Chemical Society, vol.127, issue.51, p.18004, 2005.
DOI : 10.1021/ja055398j

Y. Maeda, N. Kakiuchi, S. Matsumura, T. Nishimura, T. Kawamura et al., Oxovanadium Complex-Catalyzed Aerobic Oxidation of Propargylic Alcohols, The Journal of Organic Chemistry, vol.67, issue.19, p.6718, 2002.
DOI : 10.1021/jo025918i

A. T. Radosevich, C. Musich, F. D. Toste, I. E. Mark?, P. R. Giles et al., Perkin Trans, J. Am. Chem. Soc. J. Am. Chem. Soc. J. Chem. Soc, vol.127, issue.119 1, p.3291, 1090.

H. Egami, H. Shimizu, and T. Katsuki, Aerobic oxidation of primary alcohols in the presence of activated secondary alcohols, Tetrahedron Letters, vol.46, issue.5, p.783, 2005.
DOI : 10.1016/j.tetlet.2004.12.010

J. Louie, C. W. Bielawski, R. H. Grubbs, L. Kersten, R. H. Taylor et al., Tandem Catalysis:?? The Sequential Mediation of Olefin Metathesis, Hydrogenation, and Hydrogen Transfer with Single-Component Ru Complexes, Journal of the American Chemical Society, vol.123, issue.45, p.11312, 2001.
DOI : 10.1021/ja016431e

Q. Yao, E. P. Kinney, and Z. Yang, as an Active Catalyst Revisited, The Journal of Organic Chemistry, vol.68, issue.19, pp.7528-5830, 2003.
DOI : 10.1021/jo034646w

P. J. Harrington, L. S. Hegedus, and K. F. Mcdaniel, Palladium-catalyzed reactions in the synthesis of 3- and 4-substituted indoles. 2. Total synthesis of the N-acetyl methyl ester of (.+-.)-clavicipitic acids, Journal of the American Chemical Society, vol.109, issue.14, p.4335, 1987.
DOI : 10.1021/ja00248a032