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Distribution d'estrogènes et de bêtabloquants dans les stations d'épuration des eaux résiduaires et dans l'eau de surface

Abstract : Estrogens and beta blockers are daily excreted by human beings and wastewater treatmentplants are recognised as the main pathway of these emerging micropollutants to the aquaticenvironment. This study aims at analyzing 5 estrogens (estrone, 17α- and 17β-estradiol, estriol, 17α-ethynylestradiol) and 10 beta blockers (acebutolol, atenolol, betaxolol, bisoprolol, metoprolol, nadolol, oxprenolol, propranolol, sotalol et timolol) in urban wastewater treatment plants and surface waters.First of all, methods were developed for the analysis of target molecules in sewage sludge and suspended particulate matters. Then, estrogens and beta blockers were studied in urban wastewater treatment plants. Generally, wastewater treatments are efficients to remove estrogens fromwastewater with mean removal rates above 90%. For beta blockers, acebutolol and nadolol areefficiently removed (mean removal rates of about 80%), while sotalol and propranolol are hardlyimpacted by wastewater treatment (mean removal rates below 20%). Other studied beta blockerspresent intermediate removal rates (between 40 and 70%). Except propranolol which is the lesshydrophilic molecule among the different studied beta blockers, target molecules are not adsorbed onsuspended particulate matters (mean proportion of 90% of the target molecules are present in the dissolved phase) and are not concentrated into sludge. So, calculated removal rates correspond,except for propranolol, to biodegradation and not to transfer into sludge. Residual molecules which are not removed by wastewater treatment reach the aquatic environment. The impact of wastewater treatment plants on the receiving rivers was studied showing a clear increase of target molecules concentrations near the wastewater treatment plants outfall. However, only propranolol presented an environmental risk ratio in the range or above 1 showing a possible environmental risk in 4 studied receiving waters out of 15. Never the less, even if no specific toxic effects are pointed out, each molecule contributes to the overall toxic potential of the substances present in the aquatic environment.
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Submitted on : Thursday, December 15, 2011 - 1:06:00 PM
Last modification on : Monday, May 18, 2020 - 2:35:32 PM
Long-term archiving on: : Friday, March 16, 2012 - 2:30:28 AM


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  • HAL Id : tel-00652345, version 1



Virginie Gabet-Giraud. Distribution d'estrogènes et de bêtabloquants dans les stations d'épuration des eaux résiduaires et dans l'eau de surface. Autre. Université Claude Bernard - Lyon I, 2009. Français. ⟨NNT : 2009LYO10275⟩. ⟨tel-00652345⟩



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