V. Figure, Extrudé sens travers (brut) Figure V, pp.8-1100

K. Albertsen and H. J. Schaller, Reactions of liquid titanium and hafnium with carbon 239:33, Nous chercherons dans le chapitre suivant à donner une interprétation de ces phénomènes en termes de processus physico-chimiques dd interface. REFERENCES BIBLIOGRAPHIQUES [Ade67] Adelsberg, L. and Cadoff Constitution and Thermodynamics of the System Ti-C, p.863199325, 1967.

K. Balasubramanian, A. Kroupa, and J. S. Kirkaldy, The Raman spectrum of Ti3SiC2 84:581775819 Experimental Investigation of the Thermodynamics of the C-Fe-Ti Austenite and the Solubility of Titanium Carbide, Journal of Applied Physics Metall. Trans. A, vol.23, issue.3, p.7099727, 1992.

. J. Mo-c-system, D. Phase-equilib-bandyopadhyay, R. C. Sharma, C. , and N. , 20:3322336 The Ti -N -C system (titanium -nitrogen -carbon), J. Phase Equilib, vol.21, 1991.

P. Booker, A. Kunrath, and M. Hepworth, Experimental determination of the ternary diagram of the Ti???Cr???C system, 45:162551632. [Bra05] Bratberg, J. Investigation and Modification of Carbide Sub-Systems in the, 1997.
DOI : 10.1016/S1359-6454(96)00266-2

M. Fe, -. Caglioti, G. Paoletti, A. Ricci, and F. P. , Choice of collimators for a crystal spectrometer for neutron diffraction Neutron diffraction investigation on single crystals of titanium carbide, titanium nitride, and zirconium nitride, Z. Metallkd. Nuclear Instruments Acta Chem. Scand, vol.96, issue.29, p.335534422332285633, 1958.

D. Barros, M. I. Rats, D. Vandenbulcke, L. Farges, and G. , Influence of internal diffusion barriers on carbon diffusion in pure titanium and Ti???6Al???4V during diamond deposition, Diamond and Related Materials, vol.8, issue.6, p.102221032, 1999.
DOI : 10.1016/S0925-9635(98)00439-7

M. S. Dre88-]-dresselhaus, G. Dresselhaus, K. Sugihara, I. L. Spain, and H. A. Goldberg, Graphite Fibers and Filaments, 1988.
DOI : 10.1007/978-3-642-83379-3

I. Dre09-]-dreiling, A. Haug, H. Holzschuh, C. , and T. , Raman spectroscopy as a tool to study cubic Ti???C???N CVD coatings, Surface and Coatings Technology, vol.204, issue.6-7, 2009.
DOI : 10.1016/j.surfcoat.2009.05.029

L. F. Dum99a-]-dumitrescu and M. Hillert, Reassessment of the Solubility of TiC and TiN in Fe., ISIJ International, vol.39, issue.1, p.84490, 1999.
DOI : 10.2355/isijinternational.39.84

L. F. Dum99b-]-dumitrescu, M. Hillert, and B. Sundman, A reassessment of Ti-C-N based on a critical review of available assessments of Ti-N and Ti-C, Z. Metallkd, vol.90, p.5344541, 1999.

R. Edwards and T. Raine, The Solid Solubilities of Some Stable Carbides

N. Cobalt, I. , 1. Pulvermetallurgie-eremenko, V. N. Bulanov, V. M. Gaevskaya et al., Investigation of the Polythermal Section of the Phase Diagram of the Ternary System Ti-Fe-C Carbon diffusion in vanadium and titanium carbides, Kyivskii Derzhavnyi Univ. im T.G. Shevchenka, Khim. Zbirnyk Poroshkovaya Metallurgiya, vol.7, issue.174, p.232224265569, 1952.

D. Martinez, F. A. Oliveira, and N. Shohoji, Characterisation of solar-synthesised TiCx (x=0) by X-ray diffraction, density and Vickers microhardness, Materials Chemistry and Physics, vol.50, issue.77, p.7111718, 2003.

. I. Carbon-system, Equilibrium between titanium carbide (TiCx) of various stoichiometries and iron-carbon alloys):7911797. [Fra99] Frage, N. Interaction between nonstoichiometric titanium carbide and Fe-C alloys, Scr. Mater. Metallurgical and Materials Transactions B, vol.35, issue.75, p.308577863, 1996.

K. Frisk, A revised thermodynamic description of the Ti???C system, Calphad, vol.27, issue.4, 2003.
DOI : 10.1016/j.calphad.2004.01.004

D. Girodin and J. Moraux, L acier 32CrMoV13 nitruré profond pour applications aéronautiques, Recueil des conférences, pp.Journées franco-allemandes

A. Grigorr-eva, V. V. Klimenko, and V. N. , Properties of chromium carbides and powder metallurgy alloys based on chromium carbides, p.2955306, 2002.

E. L. Haase, Y. Hashimoto, S. Ohmori, K. Kohyama, and Y. Arami, Preparation and characterization of MoCx thin films 69(3-4):2455255 Partial phase diagram of the Ti-C-O system in the high carbon and high oxygen region, Journal of Low Temperature Physics Koon Gakkaishi, vol.7, issue.5, p.209916, 1981.

. Hua08, J. Huang, J. Spowart, and J. Jones, The role of microstructural variability on the very high-cycle fatigue behavior of discontinuously-reinforced aluminum metal matrix composites using ultrasonic fatigue, International Journal of Fatigue, 2008.

H. W. Hug99-]-hugosson, O. Eriksson, L. Nordstrom, U. Jansson, L. Fast et al., Theory of phase stabilities and bonding mechanisms in stoichiometric and substoichiometric molybdenum carbide, Journal of Applied Physics, vol.86, issue.7, p.37588, 1999.
DOI : 10.1063/1.371284

H. W. Hug01b-]-hugosson, U. Jansson, B. Johansson, and O. Eriksson, 63:165116 Phase stability diagrams of transition metal carbides, a theoretical study, Phase stabilities and structural relaxations in substoichiometric TiC1-x, p.4444450, 2001.

P. Jame, Techniques des analyses élémentaires du Service Central dd Analyse, 2007.

[. Jonsson and S. , Assessment of the Ti-C System, Z. Metallkd, vol.87, issue.9, p.7033, 1996.

[. Jonsson and S. , Assessment of the Fe-Ti-C system, calculation of the Fe-TiN system, and prediction of the solubility limit of Ti(C,N) in liquid Fe, Metallurgical and Materials Transactions B, vol.9, issue.2, pp.29-3711384, 1998.
DOI : 10.1007/s11663-998-0114-y

S. Kacim, L. Binst, F. Reniers, and F. Bouillon, Composition and structure of reactively sputter-deposited molybdenum-carbon films, Dependence of the properties of titanium carbide-steel materials upon the composition of the titanium carbide, 1996.
DOI : 10.1016/S0040-6090(95)08230-1

M. V. Klein, A. John, W. , and W. S. , Raman scattering induced by carbon vacancies in titanium carbide, Soviet Powder Metallurgy and Metal Ceramics, p.5499551154661556, 1975.

D. Kohlstedt, W. Williams, J. Woodhouse, A. E. Korneev, I. A. Stepanova et al., Chemical Diffusion in Titanium Carbide Crystals Analysis of the phase composition of steels Phase formation and microstructure in sputter-deposited Ti-Mo-C and Ti-W-C thin films 33A, Journal of Applied Physics Metal Science and Heat Treatment Metall. Mater. Trans. A, vol.48, issue.11, p.414476157991588, 1970.

J. Inst, . Metalslan78, J. I. Langford, and A. J. Wilson, 16:211, Scherrer after Sixty Years: A Survey, 1975.

D. Lee, S. Alexandrovskii, K. , B. W. Binder, S. Aigner et al., Novel synthesis of substoichiometric ultrafine titanium carbide Solid state properties of group IVb carbonitrides, Mater. Lett. Journal of Alloys and Compounds, vol.217, p.1377147, 1995.

G. Levi, Structure refinement of titanium carbonitride (TiCN), Materials Letters, vol.35, issue.5-6, pp.5-63444350, 1998.
DOI : 10.1016/S0167-577X(97)00276-0

I. M. Lif61-]-lifshitz and V. Slyozov, The kinetics of precipitation from supersaturated solid solutions, [Lip05] Lipatnikov, V. Phase equilibria, phases and compounds in the V-C system, p.35550, 1961.
DOI : 10.1016/0022-3697(61)90054-3

B. Loh07-]-lohse, A. Calka, and D. Wexler, Raman spectroscopy sheds new light on TiC formation during the controlled milling of titanium and carbon, Journal of Alloys and Compounds, pp.434-4354055409, 2007.

J. Lu and U. Jansson, Chemical vapor deposition of molybdenum carbides: aspects of nanocrystallinityMaterial Analysis Using Diffraction): a user friendly Java program for Rietveld Texture Analysis and more, Thin Solid Films, vol.396, 2001.

T. Mas90-]-massalski, H. Okamoto, P. Subramanian, and L. Kacprzak, Binary Alloy Phase Diagrams, 1990.

S. Maz85-]-mazumdar, V. Ramaswamy, . Msit, N. Lebrun, and P. Perrot, The Carbon-Iron-Titanium System 1:27738. [Mir01] Miracle The Landolt-Börnstein Database, Carbon Iron Titanium, Alloys Phase Diagrams Aeronautical Applications of Metal-Matrix Composite. ASM Handbook, vol.11, issue.2, 1985.

J. L. Murray, The Fe???Ti (Iron-Titanium) system, Bulletin of Alloy Phase Diagrams, vol.22, issue.5, p.3200334, 1981.
DOI : 10.1007/BF02868286

H. Okamoto, Carbon-Titanium) Journal of Phase Equilibria and Diffusion, 3066307. [Phi85] Philibert, J. Diffusion et transport de matière dans les solides. Ed. de Physique, 1985.

C. Pig06-]-pighini, Synthèses de nanocristaux de TiO2 anatase à distribution de taille contrôlée Influence de la taille des cristallites sur le spectre Raman et étude des propriétés de surface, 2006.

. Piv69, J. Pivot, A. Vancraeynest, C. , and D. , Diffusion chimique dans le systeme fer-molybdene 31:3422344. [Rag03] Raghavan, V. C-Fe-Ti (carbon-iron-titanium), Journal of Nuclear Materials J. Phase Equilib, 1969.

V. Raghavan, P. P. C-cr-fe-mo, F. J. Van-loo, and G. Bastin, 28:2700273. [Ram68] Ramqvist, L. Variation of lattice parameter and hardness with carbon content of Group IVb metal carbides, Phase Relations, Diffusion Paths and Kinetics in the System C-Fe-Ti at 1273 K, 1968.

P. Rogl, S. K. Naik, and R. , In Abstracts of the Satellite Meeting on Powder Diffraction of the XV Congress of the IUCr, Pattern Matching Analysis, 1990.

H. Moc, T. Monatshefte-für-chemieroi01-]-roisnel, and J. Rodriquez-carvajal, WinPLOTR: A Windows Tool for Powder Diffraction Pattern Analysis, Materials Science Forum, vol.108, issue.2, pp.132551337-378, 1977.

E. Rudy, The phase diagrams of the systems Ti-Nb-C

S. Sarian, Diffusion of Carbon in TiC, Journal of Applied Physics, vol.39, issue.7, 1968.
DOI : 10.1063/1.1656774

. Kolloidteilchen-mittels-röntgenstrahlen, Oxygen diffusion in titanium carbide, Nachr. Ges. Wiss. Göttingen, vol.26, p.988100, 1918.

H. Seifert, H. Lukas, and G. Petzow, Thermodynamic optimization of the Ti-C system, Journal of Phase Equilibria, vol.220, issue.5, p.24435, 1996.
DOI : 10.1007/BF02648366

A. V. Shcherbedinskaya, A. N. Minkevich, . She02, G. Shen, K. Tang et al., Diffusion of carbon in niobium and titanium carbides A simple route to prepare nanocrystalline titanium carbonitride Interdiffusion in the beta phases of the Ti-Ni and Ti-Fe systems 40:3766379. [Shi01] Shimada, S. Interfacial reaction on oxidation of carbides with formation of carbon 141-142:999104 The oxidation of TiC in dry oxygen, wet oxygen, and water vapor, [Smi67] Smithells, C. J. and Totemeier, T. C. Smithells metals reference book, p.12331255811586, 1965.

T. S. Sri05-]-srivatsan, A. H. Meslet, and V. K. Vasudevan, Cyclic plastic strain response and fracture behavior of 2009 aluminum alloy metal-matrix composite, International Journal of Fatigue, vol.27, issue.4, p.3577371, 2005.
DOI : 10.1016/j.ijfatigue.2004.08.009

C. G. Ste08-]-stefanita, From Bulk to Nano The Many Sides of Magnetism, chapter Barkhausen Noise as a Magnetic Nondestructive Testing Technique, Series in Materials Science, 2008.

. Sto62, E. K. Storms, and R. J. Mcneal, Vanadium-vanadium carbide system, Journal of Physical Chemistry, vol.66, p.140118, 1962.

. Sto67 and E. K. Storms, The refractory carbides, 1967.

. Sur01, C. H. Suresh, N. Koga, . Swi67, J. H. Swisher et al., A Consistent Approach toward Atomic Radii 105(24):594005944 Solubility Permeability and Diffusivity of Oxygen in Solid Iron, The Journal of Physical Chemistry A Trans. AIME J, 1967.

A. Valeeva, A. Rempel, and A. Gusev, Structure and some properties of alloys on TiC-VC0.90, TiC-V2C, and TiC-V sections and in the TiC-VC0.90-C region of the Ti-V-C ternary system Structure and Specific Heat of Disordered and Ordered Titanium Monoxide TiOy Carbide formation from beta-titanium and graphite, Carbon System. Arch. Eisenhuettenwes, p.33337844823552421055112, 1938.

. Vel01, T. Velikanova, A. Bondar, A. Grytsiv, O. Dovbenko et al., Metallochemistry of chromium in ternary systems formed by chromium with d-metals and carbon 320:3411352. [vL89a] van Loo Diffusion of carbon in TiC1-y and ZrC1-y On the diffusion of carbon in titanium carbide Theory of precipitate change by redissolution, ):4033411. [Vog17] Vogel, R. About the Influence of the Titanium on the Perlit Creation in Carbon Steel. Ferrum, pp.32-3317771955811591, 1917.

P. Waldner and G. Eriksson, Thermodynamic modelling of the system titanium-oxygen, Calphad, vol.23, issue.2, 1999.
DOI : 10.1016/S0364-5916(99)00025-5

R. Willens, E. Buehler, M. , and B. , 103:1122117 Superconductivity of the transitionmetal carbides, Carbon Systems. Journal of The Electrochemical Society Phys. Rev, vol.159, p.327730, 1956.

A. Compd, S. Zhang, C. Qin, and L. Lim, 264:2233227 Solid solution extent of WC and TaC in Ti(C,N) as revealed by lattice parameter increase, Int. J. Refract. Met. Hard Mater, vol.12, p.3299, 1994.

D. L. Zhang, Processing of advanced materials using high-energy mechanical milling, Progress in Materials Science, vol.49, issue.3-4, p.5377560, 2004.
DOI : 10.1016/S0079-6425(03)00034-3