D. A. Kim and . Spivack, New Insight into Modeling Non-Covalently Imprinted Polymers, Journal of the American Chemical Society, vol.125, issue.37, p.11269, 2003.
DOI : 10.1021/ja0361502

S. Wulff and . Schauhoff, Enzyme-analog-built polymers. 27. Racemic resolution of free sugars with macroporous polymers prepared by molecular imprinting. Selectivity dependence on the arrangement of functional groups versus spatial requirements, The Journal of Organic Chemistry, vol.56, issue.1, p.395, 1991.
DOI : 10.1021/jo00001a071

K. Haupt and . Mosbach, Molecularly Imprinted Polymers and Their Use in Biomimetic Sensors, Chemical Reviews, vol.100, issue.7, p.2495, 2000.
DOI : 10.1021/cr990099w

L. I. Sellergren, Molecular recognition in macroporous polymers prepared by a substrate analog imprinting strategy, The Journal of Organic Chemistry, vol.55, issue.10, p.3381, 1990.
DOI : 10.1021/jo00297a074

J. Damen and D. C. Neckers, Stereoselective syntheses via a photochemical template effect, Journal of the American Chemical Society, vol.102, issue.9, p.3265, 1980.
DOI : 10.1021/ja00529a073

J. Whitcombe, M. E. Rodriguez, P. Villar, and E. N. Vulfson, A New Method for the Introduction of Recognition Site Functionality into Polymers Prepared by Molecular Imprinting: Synthesis and Characterization of Polymeric Receptors for Cholesterol, Journal of the American Chemical Society, vol.117, issue.27, p.7105, 1980.
DOI : 10.1021/ja00132a010

J. Shea and T. K. Dougherty, Molecular recognition on synthetic amorphous surfaces. The influence of functional group positioning on the effectiveness of molecular recognition, Journal of the American Chemical Society, vol.108, issue.5, p.1091, 1996.
DOI : 10.1021/ja00265a046

W. Wulff, A. Best, and . Akelah, Enzyme-analogue built polymers, 17 Investigations on the racemic resolution of amino acids, Reactive Polymers, Ion Exchangers, Sorbents, vol.2, issue.3, p.167, 1984.
DOI : 10.1016/0167-6989(84)90132-6

B. Wulff, G. Heide, and . Helfmeier, Enzyme-analog built polymers. 20. Molecular recognition through the exact placement of functional groups on rigid matrixes via a template approach, Journal of the American Chemical Society, vol.108, issue.5, p.1089, 1986.
DOI : 10.1021/ja00265a045

A. J. Rückert, B. Hall, and . Sellergren, Molecularly imprinted composite materials via iniferter-modified supports, J. Mater. Chem., vol.16, issue.8, p.2275, 2002.
DOI : 10.1039/B203115A

X. Wei and S. M. Li, Surface Molecular Imprinting by Atom Transfer Radical Polymerization, Biomacromolecules, vol.6, issue.2, p.1113, 2005.
DOI : 10.1021/bm049311i

G. Mayes and K. Mosbach, Molecularly Imprinted Polymer Beads:?? Suspension Polymerization Using a Liquid Perfluorocarbon as the Dispersing Phase, Analytical Chemistry, vol.68, issue.21, p.3769, 1996.
DOI : 10.1021/ac960363a

E. Cacho, A. Turiel, and . Martin-esteban, Characterisation and quality assessment of binding sites on a propazine-imprinted polymer prepared by precipitation polymerisation, Journal of Chromatography B, vol.802, issue.2, p.347, 2004.
DOI : 10.1016/j.jchromb.2003.12.018

K. Bruggemann, L. Haupt, E. Ye, K. Yilmaz, and . Mosbach, New configurations and applications of molecularly imprinted polymers, Journal of Chromatography A, vol.889, issue.1-2, p.15, 2000.
DOI : 10.1016/S0021-9673(00)00350-2

C. Sharma and A. S. Borovik, Design, Synthesis, and Characterization of Templated Metal Sites in Porous Organic Hosts:?? Application to Reversible Dioxygen Binding, Journal of the American Chemical Society, vol.122, issue.37, p.8946, 2000.
DOI : 10.1021/ja0014739

D. Spivak, M. A. Gilmore, and K. J. Shea, Evaluation of Binding and Origins of Specificity of 9-Ethyladenine Imprinted Polymers, Journal of the American Chemical Society, vol.119, issue.19, p.4388, 1997.
DOI : 10.1021/ja963510v

T. Muldoon and L. H. Stanker, Molecularly Imprinted Solid Phase Extraction of Atrazine from Beef Liver Extracts, Analytical Chemistry, vol.69, issue.5, p.803, 1997.
DOI : 10.1021/ac9604649

A. Braunecker and K. Matyjaszewski, Controlled/living radical polymerization: Features, developments, and perspectives, Progress in Polymer Science, vol.32, issue.1, p.93, 2007.
DOI : 10.1016/j.progpolymsci.2006.11.002

J. Matyjaszewski and . Xia, Atom Transfer Radical Polymerization, Chemical Reviews, vol.101, issue.9, p.2921, 2001.
DOI : 10.1021/cr940534g

J. S. Wang and K. Matyjaszewski, Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes, Journal of the American Chemical Society, vol.117, issue.20, p.5614, 1995.
DOI : 10.1021/ja00125a035

A. Shipp and X. Yu, Kinetic analysis of styrene atom transfer radical polymerization: Extraction of radical-radical termination rate coefficients, Journal of Polymer Science Part A: Polymer Chemistry, vol.41, issue.21, p.5548, 2004.
DOI : 10.1002/pola.20396

J. M. Destarac, B. Bessière, and . Boutevin, Transition metal catalyzed atom Transfer Radical Polymerization (ATRP): from heterogeneous to homogeneous catalysis using 1,10-phenantroline and its derivatives as new copper(I) ligands, Macromolecular Rapid Communications, vol.18, issue.11, p.967, 1997.
DOI : 10.1002/marc.1997.030181103

. Fischer, The persistent radical effect in controlled radical polymerizations, Journal of Polymer Science Part A: Polymer Chemistry, vol.28, issue.13, p.1885, 1999.
DOI : 10.1002/(SICI)1099-0518(19990701)37:13<1885::AID-POLA1>3.0.CO;2-1

B. Matyjaszewski, H. Goebelt, C. Paik, and . Horwitz, Tridentate Nitrogen-Based Ligands in Cu-Based ATRP:?? A Structure???Activity Study, Macromolecules, vol.34, issue.3, p.430, 2001.
DOI : 10.1021/ma001181s

E. Patten and K. Matyjaszewski, Atom Transfer Radical Polymerization and the Synthesis of Polymeric Materials, Advanced Materials, vol.10, issue.12, p.901, 1998.
DOI : 10.1002/(SICI)1521-4095(199808)10:12<901::AID-ADMA901>3.0.CO;2-B

K. Matyjaszewski, Transition Metal Catalysis in Controlled Radical Polymerization: Atom Transfer Radical Polymerization, Chemistry - A European Journal, vol.5, issue.11, p.3095, 1999.
DOI : 10.1002/(SICI)1521-3765(19991105)5:11<3095::AID-CHEM3095>3.0.CO;2-#

P. Granel, R. Dubois, and . Jérôme, Controlled Radical Polymerization of Methacrylic Monomers in the Presence of a Bis(ortho-chelated) Arylnickel(II) Complex and Different Activated Alkyl Halides, Macromolecules, vol.29, issue.27, p.8576, 1996.
DOI : 10.1021/ma9608380

Y. Wu, Z. Shi, and . Fu, Synthesis of heteroarm star-shaped (polystyrene)n???[poly(ethyl acrylate)]m via atom transfer radical polymerization, Polymer, vol.46, issue.26, p.12722, 2005.
DOI : 10.1016/j.polymer.2005.08.099

H. Sagawa, Y. Abe, T. Hase, and . Inaba, Catalytic Asymmetric Aminolysis of 3,5,8-Trioxabicyclo[5.1.0]octane Providing an Optically Pure 2-Amino-1,3,4-butanetriol Equivalent, The Journal of Organic Chemistry, vol.64, issue.13, p.4962, 1999.
DOI : 10.1021/jo9900883

T. E. Von-werne and . Patten, Atom Transfer Radical Polymerization from Nanoparticles:?? A Tool for the Preparation of Well-Defined Hybrid Nanostructures and for Understanding the Chemistry of Controlled/???Living??? Radical Polymerizations from Surfaces, Journal of the American Chemical Society, vol.123, issue.31, p.7497, 2001.
DOI : 10.1021/ja010235q

E. Lindqvist and . Malmstroem, Surface modification of natural substrates by atom transfer radical polymerization, Journal of Applied Polymer Science, vol.5, issue.19, p.4155, 2006.
DOI : 10.1002/app.23457

R. Dayananda and . Dhamodharan, ATRP of methyl methacrylate using a novel binol ester-based bifunctional initiator, Journal of Polymer Science Part A: Polymer Chemistry, vol.38, issue.4, p.902, 2004.
DOI : 10.1002/pola.11036

A. Braunecker and K. Matijaszewski, Controlled/living radical polymerization: Features, developments, and perspectives, Progress in Polymer Science, vol.32, issue.1, p.93, 2007.
DOI : 10.1016/j.progpolymsci.2006.11.002

K. Matijaszewski and J. Xia, Atom Transfer Radical Polymerization, Chemical Reviews, vol.101, issue.9, p.2921, 2001.
DOI : 10.1021/cr940534g

A. Dayananda, R. Ramakrishnan, and J. Dhamodharan, ???MMA) via Ambient Temperature ATRP of MMA, Journal of Macromolecular Science, Part A, vol.36, issue.4, p.471, 2005.
DOI : 10.1016/S0032-3861(01)00514-6

H. Gong, C. Tang, B. Liu, Q. Jiang, Y. Ren et al., Preparation of hyperbranched polymers through ATRP of in situ formed AB* monomer, Journal of Applied Polymer Science, vol.101, issue.2, p.850, 2006.
DOI : 10.1002/app.23751

Y. Wang, E. Zheng, C. J. Roberys, L. Duxbury, D. J. Ding et al., Controlling Chain Growth:?? A New Strategy to Hyperbranched Materials, Macromolecules, vol.40, issue.20, p.7184, 2007.
DOI : 10.1021/ma0707133

M. Chang, J. W. Vanderhoff, and M. S. El-aasser, Monodisperse porous polymer particles: Formation of the porous structure, Journal of Polymer Science Part A: Polymer Chemistry, vol.30, issue.2, p.245, 1992.
DOI : 10.1002/pola.1992.080300209

B. Matijaszewski, H. J. Göbelt, C. P. Paij, and . Horwitz, Tridentate Nitrogen-Based Ligands in Cu-Based ATRP:?? A Structure???Activity Study, Macromolecules, vol.34, issue.3, p.430, 2001.
DOI : 10.1021/ma001181s

H. D. Li and . Stöver, Synthesis of monodisperse poly(divinylbenzene) microspheres, Journal of Polymer Science Part A: Polymer Chemistry, vol.31, issue.13, p.3257, 1993.
DOI : 10.1002/pola.1993.080311313

E. Shim, S. Yang, M. J. Jin, Y. H. Chang, and S. Choe, Effect of the polymerization parameters on the morphology and spherical particle size of poly(styrene-co-divinylbenzene) prepared by precipitation polymerization, Colloid and Polymer Science, vol.32, issue.1, p.41, 2004.
DOI : 10.1007/s00396-004-1086-3

M. Jin, Y. Jiang, Y. Shi, Y. Lin, K. Peng et al., Narrowly dispersed molecularly imprinted microspheres prepared by a modified precipitation polymerization method, Analytica Chimica Acta, vol.612, issue.1, p.105, 2008.
DOI : 10.1016/j.aca.2008.02.011

B. Bai, X. Huang, W. Yang, and . Huang, Synthesis of monodisperse poly(methacrylic acid) microspheres by distillation???precipitation polymerization, European Polymer Journal, vol.43, issue.9, p.3923, 2007.
DOI : 10.1016/j.eurpolymj.2007.06.024

X. Liu, Y. Yang, and . Wang, Preparation of monodisperse hydrophilic polymer microspheres withN,N???-methylenediacrylamide as crosslinker by distillation precipitation polymerization, Polymer International, vol.25, issue.7, p.905, 2007.
DOI : 10.1002/pi.2223

E. H. Joso, M. H. Pan, T. P. Stenzel, C. Davis, L. Barner-kowollik et al., Ambient temperature synthesis of well-defined microspheres via precipitation polymerization initiated by UV-irradiation, Journal of Polymer Science Part A: Polymer Chemistry, vol.196, issue.15, p.3482, 2007.
DOI : 10.1002/pola.22132

E. Shim, S. Yang, M. J. Jin, Y. H. Chang, and S. Choe, Effect of the polymerization parameters on the morphology and spherical particle size of poly(styrene-co-divinylbenzene) prepared by precipitation polymerization, Colloid and Polymer Science, vol.32, issue.1, p.41, 2004.
DOI : 10.1007/s00396-004-1086-3

E. H. Brandrup, E. A. Immergut, A. Grulke, D. R. Abe, and . Bloch, Polymer Handbook 4th Ed, p.688, 1999.

. Odian, Principles of polymerization, 1970.
DOI : 10.1002/047147875X

Y. Wang, E. Zheng, C. J. Roberts, L. Duxbury, D. J. Ding et al., Controlling Chain Growth:?? A New Strategy to Hyperbranched Materials, Macromolecules, vol.40, issue.20, p.7184, 2007.
DOI : 10.1021/ma0707133

L. Luo, Q. Liu, and . Deng, Chromatographic Separation of the Enantiomers of a Series of C2-Asymmetric Bi-Naphthyl Compounds by Molecularly Imprinted Polymers, Chromatographia, vol.11, issue.7-8, p.393, 2006.
DOI : 10.1365/s10337-006-0017-5

S. Ou, H. Tang, and . Zou, Chiral separation of 1,1???-bi-2-naphthol and its analogue on molecular imprinting monolithic columns by HPLC, Journal of Separation Science, vol.984, issue.17, p.2282, 2005.
DOI : 10.1002/jssc.200500165

X. Wei, S. M. Li, and . Husson, Surface Molecular Imprinting by Atom Transfer Radical Polymerization, Biomacromolecules, vol.6, issue.2, p.1113, 2005.
DOI : 10.1021/bm049311i

M. J. Boonpangrak, V. Whitcombe, K. Prachayasittikul, L. Mosbach, and . Ye, Preparation of molecularly imprinted polymers using nitroxide-mediated living radical polymerization, Biosensors and Bioelectronics, vol.22, issue.3, p.349, 2006.
DOI : 10.1016/j.bios.2006.04.014

G. Tamayo, M. M. Titirici, A. Martin-esteban, and B. Sellergren, Synthesis and evaluation of new propazine-imprinted polymer formats for use as stationary phases in liquid chromatography, Analytica Chimica Acta, vol.542, issue.1, p.38, 2005.
DOI : 10.1016/j.aca.2004.12.063

S. Boonpangrak, V. Prachayasittikul, L. Bülow, L. Ye, and J. , Molecularly imprinted polymer microspheres prepared by precipitation polymerization using a sacrificial covalent bond, Journal of Applied Polymer Science, vol.804, issue.4, p.1390, 2005.
DOI : 10.1002/app.22519

E. H. Brandrup, E. A. Immergut, A. Grulke, D. R. Abe, and . Bloch, Polymer Handbook 4th Ed, p.688, 1999.

Q. Kan, Z. Zhao, Z. Zhang, J. J. Wang, and . Zhu, Molecularly imprinted polymers microsphere prepared by precipitation polymerization for hydroquinone recognition, Talanta, vol.75, issue.1, p.22, 2008.
DOI : 10.1016/j.talanta.2007.08.038

M. A. Spivak, K. J. Gilmore, and . Shea, Evaluation of Binding and Origins of Specificity of 9-Ethyladenine Imprinted Polymers, Journal of the American Chemical Society, vol.119, issue.19, p.4388, 1997.
DOI : 10.1021/ja963510v

T. Muldoon and L. H. Stanker, Molecularly Imprinted Solid Phase Extraction of Atrazine from Beef Liver Extracts, Analytical Chemistry, vol.69, issue.5, p.803, 1997.
DOI : 10.1021/ac9604649

C. Sharma and A. S. Borovik, Design, Synthesis, and Characterization of Templated Metal Sites in Porous Organic Hosts:?? Application to Reversible Dioxygen Binding, Journal of the American Chemical Society, vol.122, issue.37, p.8946, 2000.
DOI : 10.1021/ja0014739

T. Nomachi, K. Kubo, K. Hosoya, and . Kaya, Solvent effects in the preparation of molecularly imprinted polymers for melatonin using N-propionyl-5-methoxytryptamine as the pseudo template, Analytical and Bioanalytical Chemistry, vol.22, issue.6, p.1291, 2006.
DOI : 10.1007/s00216-006-0310-z

S. Liu, Y. L. Xi, H. Wang, C. Yan, and R. Y. Gao, Chiral Separation of Binaphthol Enantiomers on Molecularly Imprinted Polymer Monolith by Capillary Electrochromatography, Analytical Sciences, vol.20, issue.4, p.673, 2004.
DOI : 10.2116/analsci.20.673

T. Ikegami, H. Mukawa, T. Nariai, and . Takeuchi, Bisphenol A-recognition polymers prepared by covalent molecular imprinting, Analytica Chimica Acta, vol.504, issue.1, p.131, 2004.
DOI : 10.1016/j.aca.2003.08.032

H. Schmidt, A. S. Belmont, and K. Haupt, Porogen formulations for obtaining molecularly imprinted polymers with optimized binding properties, Analytica Chimica Acta, vol.542, issue.1, p.118, 2005.
DOI : 10.1016/j.aca.2005.03.064

L. and F. Leo, Le canon à électrons est de type FEG, c'est-à-dire que l'émission se fait par effet de champ