Methanol decomposition to synthesis gas at low temperature over palladium supported on ceria-zirconia solid solutions Oxidative Methanol Reforming Reactions on CuZnAl Catalysts Derived from Hydrotalcite-like Precursors Partial Oxidation of Methane to Synthesis Gas Using LnCoO 3 Partial oxidation of methane to synthesis gas. Bihaviour of different Ni supported catalysts Partial oxidation of methane to synthesis gas over unpromoted and (0.1-0.5 wt%) Ni-promoted cacium aluminate catalysts Partial oxidation of methane to syngas over Ni Syngas formation by direct oxidation of methane over Rh monoliths, A: Gen. -2001. -V. 210. -P. 301 -314. [4] Catal. Lett. ? 1993. ? V. 17. ? P. 223, pp.3-17, 1987. ,
Catalytic reaction of methane with carbon dioxide, Reaction Kinetics and Catalysis Letters, vol.18, issue.1, pp.12-107, 1979. ,
DOI : 10.1007/BF02071433
Synthesis and characterization of catalysts in the system Al 2 O 3 -MgO-NiO-Ni for methane reforming with CO 2, J. Am. Ceram. Soc, pp.1989-72 ,
Carbon dioxide reforming of methane on nickel catalysts, Chemical Engineering Science, vol.44, issue.12, pp.44-2825, 1989. ,
DOI : 10.1016/0009-2509(89)85092-4
Reduction of Carbon Dioxide by Methane with Ni-on-MgO-CaO Containing Catalysts, Chemistry Letters, vol.21, issue.10, pp.1992-2013, 1953. ,
DOI : 10.1246/cl.1992.1953
Partial oxidation of methane to synthesis gas, and carbon dioxide as an oxidising agent for methane conversion, Catalysis Today, vol.13, issue.2-3, pp.13-417, 1992. ,
DOI : 10.1016/0920-5861(92)80167-L
CO 2 -Reforming of methane over transition metals, J. Catal, pp.1993-144 ,
Carbon dioxide reforming of methane with supported rhodium, Applied Catalysis, vol.61, issue.1, pp.61-293, 1990. ,
DOI : 10.1016/S0166-9834(00)82152-1
The catalytic activity of Ru and Ir supported on Eu 2 O 3 for the reaction: a viable solarthermal energy system, Catal. Lett, pp.1991-2002 ,
Methane partial oxidation on Pt/CeO 2 and Pt/Al 2 O 3 catalysts, Appl. Catal, pp.223-253, 2002. ,
Production of Syngas by Direct Catalytic Oxidation of Methane, Science, vol.259, issue.5093, pp.259-343, 1993. ,
DOI : 10.1126/science.259.5093.343
Partial oxidation of methane to synthesis gas over rhodium catalysts, Catalysis Today, vol.40, issue.2-3, pp.40-157, 1998. ,
DOI : 10.1016/S0920-5861(98)00004-2
The Reaction Mechanism of the Partial Oxidation of Methane to Synthesis Gas: A Transient Kinetic Study over Rhodium and a Comparison with Platinum, Journal of Catalysis, vol.167, issue.1, pp.167-210, 1997. ,
DOI : 10.1006/jcat.1997.1533
Reactive Oxygen Species on Platinum Gauzes during Partial Oxidation of Methane into Synthesis Gas, Journal of Catalysis, vol.190, issue.2, pp.190-439, 2000. ,
DOI : 10.1006/jcat.1999.2770
URL : https://hal.archives-ouvertes.fr/hal-00006980
Partial oxidation of methane to synthesis gas:, Catalysis Today, vol.63, issue.2-4, pp.63-489, 2000. ,
DOI : 10.1016/S0920-5861(00)00495-8
Ceria in automotive exhaust catalysts I. Oxygen storage, Journal of Catalysis, vol.86, issue.2, pp.86-254, 1984. ,
DOI : 10.1016/0021-9517(84)90371-3
Oxygen storage dynamics in PtAl 2 O 3 catalysts, J. Catal. ?, issue.2, pp.178-192, 1998. ,
Direct Partial Oxidation of Methane to Synthesis Gas by Cerium Oxide, Journal of Catalysis, vol.175, issue.2, pp.175-152, 1998. ,
DOI : 10.1006/jcat.1998.1985
Pd-, Pt-, and Rh-loaded Ce 0 three-way catalysts: an investigation on performance and redox properties, J. Catal. ?, pp.206-207, 2002. ,
Direct conversion of methane to synthesis gas through gas-solid reaction using CeO 2 -ZrO 2 solid solution at moderate temperature, Appl. Catal. A: Gen. ?, pp.317-324, 1999. ,
Catalytic partial oxidation of methane over a 4% Rh/-Al 2 O 3 catalyst: Part I: Kinetic study in annular reactor, Catal. Today ?, pp.98-565, 2004. ,
Partial oxidation of light alkanes in short contact time microreactors, pp.15-98, 2000. ,
DOI : 10.1039/9781847553270-00098
Catalytic partial oxidation of natural gas at elevated pressure and low residence time, Catalysis Today, vol.64, issue.1-2 ,
DOI : 10.1016/S0920-5861(00)00504-6
The Reaction Mechanism of the Partial Oxidation of Methane to Synthesis Gas: A Transient Kinetic Study over Rhodium and a Comparison with Platinum, Journal of Catalysis, vol.167, issue.1, pp.167-210, 1997. ,
DOI : 10.1006/jcat.1997.1533
Development of a molecular kinetic scheme for methane partial oxidation over a Rh/??-Al2O3 catalyst, Journal of Catalysis, vol.241, issue.1, pp.1-13, 2006. ,
DOI : 10.1016/j.jcat.2006.03.018
Reaction Mechanism and Role of the Support in the Partial Oxidation of Methane on Rh/Al2O3, Journal of Catalysis, vol.159, issue.2, pp.1996-159 ,
DOI : 10.1006/jcat.1996.0105
Experimental and numerical study on the transient behavior of partial oxidation of methane in a catalytic monolith, Chemical Engineering Science, vol.58, issue.3-6, pp.2003-58 ,
DOI : 10.1016/S0009-2509(02)00589-4
Rhodium-catalyzed partial oxidation of methane to CO and H2. Transient studies on its mechanism, Catalysis Letters, vol.29, issue.1-2, pp.29-249, 1994. ,
DOI : 10.1007/BF00814271
The state of Rh during the partial oxidation of methane into synthesis gas, Catalysis Letters, vol.57, issue.1/2, pp.9-17, 1999. ,
DOI : 10.1023/A:1019058507319
Effect of Support on Partial Oxidation of Methane to Synthesis Gas over Supported Rhodium Catalysts, Journal of Catalysis, vol.187, issue.1, pp.151-159, 1999. ,
DOI : 10.1006/jcat.1999.2593
Analysis of a catalytic annular reactor for very short contact times, Chemical Engineering Science, vol.54, issue.6, pp.1999-54 ,
DOI : 10.1016/S0009-2509(98)00261-9
An experimental reactor to study the intrinsic kinetics of catalytic partial oxidation of methane in the presence of heat-transport limitations, Applied Catalysis A: General, vol.187, issue.1, pp.187-220, 1999. ,
DOI : 10.1016/S0926-860X(99)00181-7
Kinetics for the partial oxidation of methane on a Pt gauze at low conversions, AIChE Journal, vol.30, issue.9, pp.2000-2046 ,
DOI : 10.1002/aic.690460912
Comparison among structured and packed-bed reactors for the catalytic partial oxidation of CH4 at short contact times, Catalysis Today, vol.105, issue.3-4, pp.709-717, 2005. ,
DOI : 10.1016/j.cattod.2005.06.045
Partial oxidation of methane to syngas at high space velocities over Rh-coated spheres, Applied Catalysis A: General, vol.211, issue.1, pp.53-68, 2001. ,
DOI : 10.1016/S0926-860X(00)00835-8
Brief overview of the partial oxidation of methane to synthesis gas, Top. Catal, pp.2003-2025 ,
Utilization of natural gases for the ammonia process, Trans. Faraday Soc. ?, pp.25-462, 1929. ,
The catalytic oxidation of methane to carbon monoxide and hydrogen, Transactions of the Faraday Society, vol.42, pp.335-340, 1946. ,
DOI : 10.1039/tf946420335b
Low-temperature selective oxidation of methane to carbon monoxide and hydrogen over cobalt-MgO catalysts, Appl. Catal. A: Gen. ?, pp.90-91, 1992. ,
Low temperature oxidative conversion of methane to syngas over NiO-CaO catalyst, Catalysis Letters, vol.43, issue.4, pp.1992-2007 ,
DOI : 10.1007/BF00769159
Low temperature oxidative conversion of methane to synthesis gas over Co/rare earth oxide catalysts, Catalysis Letters, vol.132, issue.3, p.16, 1992. ,
DOI : 10.1007/BF00764339
Selective oxidation of methane to CO and H2 over unreduced NiO-rare earth oxide catalysts, Catalysis Letters, vol.59, issue.4, pp.1993-2015 ,
DOI : 10.1007/BF00807236
Catalytic and thermodynamic approach of the oxyreforming reaction of methane, Catalysis Today, vol.13, issue.2-3, pp.1992-2005 ,
DOI : 10.1016/0920-5861(92)80168-M
Catalytic partial oxidation of methane to synthesis gas over Ni???CeO2, Applied Catalysis A: General, vol.208, issue.1-2, pp.403-417, 2001. ,
DOI : 10.1016/S0926-860X(00)00728-6
Rare earth promoted nickel catalysts for the selective oxidation of natural gas to syngas, Surf. Sci. Catal, pp.1998-119 ,
Kinetic study of the catalytic partial oxidation of methane to synthesis gas over Ni/La 2 O 3 catalyst, Surf. Sci. Catal, pp.1998-119 ,
Design of stable Ni catalysts for partial oxidation of methane to synthesis gas, Journal of Catalysis, vol.177, issue.2, pp.177-386, 1998. ,
DOI : 10.1006/jcat.1998.2051
Low-cost Oxygen Electrode Material, Nature, vol.6, issue.5248, 1970. ,
DOI : 10.1038/226847a0
Total Oxidation of Hydrocarbons on Perovskite Oxides, Catalysis Reviews, vol.1461, issue.4, pp.1992-2026 ,
DOI : 10.1246/cl.1981.1767
Methane dry reforming over welldispersed Ni catalyst prepared from perovskite-type mixed oxides, Surf. Sci. Catal. ?, pp.119-843, 1998. ,
A sustainable catalyst for the partial oxidation of methane to syngas: Ni/Ca 1-x Sr x TiO 3 , prepared in situ from perovskite precursors, Chem. Int. Ed. Eng, pp.1996-2031 ,
Rare earth promoted nickel catalysts for the selective oxidation of natural gas to syngas, Surf. Sci. Catal. ?, pp.119-849, 1998. ,
Carbon dioxide reforming of methane to synthesis gas over Ni/La 2 O 3 catalysts, Appl. Catal, pp.138-109, 1996. ,
Development of coking-resistant Ni-based catalyst for partial oxidation and CO 2 -reforming of methane to syngas, Appl. Catal. A: Gen. ?, pp.166-343, 1998. ,
Selective oxidation of methane to synthesis gas using transition metal catalysts, Nature, vol.344, issue.6264, pp.1990-344 ,
DOI : 10.1038/344319a0
Partial oxidation of methane to synthesis gas, Catalysis Letters, vol.344, issue.2, pp.1990-1996 ,
DOI : 10.1007/BF00774718
Partial oxidation of methane to synthesis gas, and carbon dioxide as an oxidising agent for methane conversion, Catalysis Today, vol.13, issue.2-3, pp.13-417, 1992. ,
DOI : 10.1016/0920-5861(92)80167-L
Recent advances in the conversion of methane to synthesis gas, Catalysis Today, vol.23, issue.1, pp.23-26, 1995. ,
DOI : 10.1016/0920-5861(94)00080-L
A study of carbon deposition on catalysts during the partial oxidation of methane to synthesis gas, Catalysis Letters, vol.46, issue.4, pp.1993-2015 ,
DOI : 10.1007/BF00807237
Syngas Formation by Direct Catalytic Oxidation of Methane, J. Catal, pp.1992-138 ,
Catalytic partial oxidation of methane to synthesis gas using monolithic reactors, Catalysis Today, vol.21, issue.2-3, pp.21-471, 1994. ,
DOI : 10.1016/0920-5861(94)80169-X
Catalytic partial oxidation of methane to synthesis gas, Catalysis Today, vol.24, issue.3, pp.24-211, 1995. ,
DOI : 10.1016/0920-5861(95)00027-D
Effect of pressure on three catalytic partial oxidation reactions at millisecond contact times, Catalysis Letters, vol.259, issue.1-2, pp.1995-2028 ,
DOI : 10.1007/BF00817042
Partial oxidation of methane to synthesis gas over a Pt/10% Rh gauze, Catal. Lett, pp.1997-2042 ,
High yields of synthesis gas by millisecond partial oxidation of higher hydrocarbons, Catal. Lett. ?, pp.70-99, 2000. ,
Autothermal reforming of aliphatic and aromatic hydrocarbon liquids, Int. J. Hydrogen Energy, pp.1983-1991 ,
Systemanalytischer Vergleich inovativer Kraftstoffe und Antriebssysteme, pp.493-528 ,
Use of CeO 2 -based oxides in the three-way catalysis, Catal. Today ?, pp.50-285, 1999. ,
Fuel-rich methane combustion: Role of the Pt dispersion and oxygen mobility in a fluorite-like complex oxide support, Catalysis Today, vol.117, issue.4, pp.117-475, 2006. ,
DOI : 10.1016/j.cattod.2006.06.017
URL : https://hal.archives-ouvertes.fr/hal-00102520
Physical, chemical and electrochemical properties of pure and doped ceria, Solid State Ionics. -2000. ? V. 129. ? P, pp.63-94 ,
DOI : 10.1016/S0167-2738(99)00318-5
Sustainable hydrogen from bio-oil???Steam reforming of acetic acid as a model oxygenate, Journal of Catalysis, vol.227, issue.1, pp.2004-227 ,
DOI : 10.1016/j.jcat.2004.07.002
The application of Ce---Zr oxide solid solution to oxygen storage promoters in automotive catalysts, pp.73-75, 0193. ,
Production method of cerium oxide with high storage capacity of oxygen and its mechanism, Journal of Alloys and Compounds, vol.193, issue.1-2, pp.298-299, 0193. ,
DOI : 10.1016/0925-8388(93)90377-Y
Structural changes of ZrO 2 -CeO 2 solid solutions around the monoclinic-tetragonal phase boundary, Phys. Rev. B, pp.1995-51 ,
Diffusionless Tetragonal-Cubic Transformation Temperature in Zirconia-Ceria Solid Solutions, Journal of the American Ceramic Society, vol.31, issue.11, 1993. ,
DOI : 10.1111/j.1151-2916.1993.tb04028.x
Zirconia-Ceria Solid Solution Synthesis and the Temperature-Time-Transformation Diagram for the 1:1 Composition, Journal of the American Ceramic Society, vol.31, issue.11, pp.76-1745, 1993. ,
DOI : 10.1111/j.1151-2916.1993.tb06643.x
Metastable tetragonal CeO 2 -ZrO 2 solid solution, pp.485-486 ,
URL : https://hal.archives-ouvertes.fr/jpa-00225604
Phase diagram calculation and fabrication of multi-component zirconia-based ceramics, Shanghai University. ? 2005. ? V. 9. ? P, pp.358-360 ,
Revised phase diagram of the system ZrO 2 -CeO 2 below 1400°C, J. Am. Ceram. Soc. ?, pp.66-506, 1983. ,
Raman scattering study of cubictetragonal phase transition in Zr 1-x Ce x O 2 solid solution, J. Am. Ceram. Soc. ?, pp.77-1067, 1994. ,
Modification of the redox behaviour of CeO 2 induced by structural doping with ZrO 2, J. Catal, pp.1996-164 ,
Solid solutions of metastable tetragonal ZrO 2 and Ce 3 ZrO 8 in the system ZrO 2 -CeO 2, J. Mater. Sci, pp.1996-2027 ,
Influence of the gas atmosphere on the reaction of zirconium dioxide with oxides of cerium, Izv. Akad. Nauk SSSR, Neorg. Mater, pp.1966-1968 ,
Thermal stability of doped ceria: experiment and modelling, Journal of the Chemical Society, Faraday Transactions, vol.91, issue.21, pp.91-3941, 1995. ,
DOI : 10.1039/ft9959103941
URL : https://hal.archives-ouvertes.fr/emse-00610336
Rh-loaded CeO 2 -ZrO 2 solid solutions as highly efficient oxygen exchangers: dependence of the reduction behavior and the oxygen storage capacity on the structural properties, J. Catal. ?, pp.151-168, 1995. ,
Thermal stability of oxygen storage properties in a mixed CeO 2 -ZrO 2 system, Appl. Catal. B: Environ, pp.1998-2014 ,
Nanophase fluorite-structured CeO 2 -ZrO 2 catalysts prepared by high-energy mechanical milling, J. Catal, pp.1997-169 ,
Solution processing approaches for solid electrolytes and electrode materials, Journal of Materials Research, vol.6, issue.04, pp.13-17, 1998. ,
DOI : 10.1016/S0167-2738(96)00418-3
Preparation of La 1-z Sr z Co 1-y Fe y O 3-x thin films, membranes and coatings on dense and porous substrates, J. Mater. Res. ?, pp.10-12, 1995. ,
Mixed-cation oxide powders via polymeric precursors, pp.1002-1007 ,
Synthesis of ZrO 2 -Y 6 WO 12 solid solution powders by a polymerized complex method, J. Mater. Res. ?, pp.13-17, 1998. ,
Thermal stability of a high surface area ceria under reducing atmosphere, Applied Catalysis A: General, vol.129, issue.1, pp.1995-129 ,
DOI : 10.1016/0926-860X(95)00089-5
A novel and simple route to catalysts with high oxygen storage capacity: the direct room-temperature synthesis of CeO 2 -ZrO 2 solid solutions, J. Chem. Soc., Chem. Commun, pp.1995-2016 ,
Measurement of the ceria surface area of a three-way commercial catalyst after laboratory and engine bench aging., Surf. Sci. Catal. ?, vol.116, pp.137-146, 1998. ,
DOI : 10.1016/S0167-2991(98)80871-9
An unusual promotion of the redox behaviour of CeO2-ZrO2 solid solutions upon sintering at high temperatures, Catalysis Letters, vol.77, issue.1-2, pp.1995-2028 ,
DOI : 10.1007/BF00817058
Design better cerium-based oxidation catalyst, pp.27-32, 1997. ,
Effect of ZrO 2 content on textural and structural properties of CeO 2 -ZrO 2 solid solutions made by citrate complexation route, Inorganica Chimica Acta ?, pp.349-217, 2003. ,
Dependency of the Oxygen Storage Capacity in Zirconia-Ceria Solid Solutions upon Textural Properties, Top.Catal. ?, issue.16, pp.17-83, 2001. ,
Nanostructured CeO 2 -ZrO 2 mixed oxide, 2005. ? V. 15. ? P, pp.633-648 ,
From Zr-Rich to Ce-Rich: Thermal Stability of OSC Materials on the Whole Range of Composition, Topics in Catalysis, vol.30, issue.31, pp.30-31, 2004. ,
DOI : 10.1023/B:TOCA.0000029784.75813.81
Effect of the preparation method on the properties of zirconia-ceria materials, Journal of Materials Chemistry, vol.9, issue.7, pp.9-1615, 1999. ,
DOI : 10.1039/a900536f
Effect of ceria content on the sintering of ZrO 2 based ceramics synthesized from a polymeric precursor, J. Mater. Sci. ?, pp.36-3825, 2001. ,
Effect of coprecipitation conditions on the surface area, phase composition, and reducibility of CeO 2 -ZrO 2 -Y 2 O 3 materials for automotive three-way catalysts, Surf. Sci. Catal, pp.1998-118 ,
Sintering, Microstructure, Hardness and Fracture Toughness Behaviour of Y 2 O 3 -CeO 2 -ZrO 2, J. Am. Ceram. Soc. ?, pp.71-813, 1988. ,
Surface characterization of alumina-supported ceria, The Journal of Physical Chemistry, vol.92, issue.17, pp.1988-92 ,
DOI : 10.1021/j100328a029
Pd/Ce 0.6 Zr 0.4 O 2 /Al 2 O 3 as advanced materials for three-way catalysts -Part 1. Catalyst characterisation, thermal stability and catalytic activity in the reduction of NO by CO, Appl. Catal. B: Environ. ?, pp.24-157, 2000. ,
Stabilisation of nanostructured Ce 0.2 Zr 0.8 O 2 solid solution by impregnation on Al 2 O 3 : a suitable method for the production of thermally stable oxygen storage/release promoters for three-way catalysts, Chem. Commun, vol.21, pp.2167-2168, 2000. ,
Thermal stabilization of Ce x Zr 1-x O 2 oxygen storage promoters by addition of Al 2 O 3 : effect of thermal aging on textural, structural, and morphological properties, Chem. Mater, pp.2004-2020 ,
New Pd/Ce x Zr 1x O 2 /Al 2 O 3 three-way catalysts prepared by microemulsion Part 1. Characterization and catalytic behavior for CO oxidation, Appl. Catal. B: Environ. ?, pp.31-39, 2001. ,
Effect of Preparation Method and Redox Treatment on the Reducibility and Structure of Supported Ceria???Zirconia Mixed Oxide, Journal of Catalysis, vol.209, issue.2, pp.2002-209 ,
DOI : 10.1006/jcat.2002.3644
Nanostructured materials for advanced automotive depollution catalysts, J. Solid State Chem, pp.2003-171 ,
Structural properties and thermal stability of ceria-zirconia and related materialsCatalysis by Ceria and Related Materials, pp.217-241, 2002. ,
Thermal stability of Ce 1-x Zr x O 2 solid solution powders, pp.1998-2016 ,
Surface and catalytic properties of Al 2 O 3 ?ZrO 2 solid solutions prepared by sol?gel methods, Appl. Catal. A: Gen, pp.2000-197 ,
Improvement of thermal stability of alumina by addition of zirconia, Catal. Lett, pp.1999-62 ,
Spectroscopic study of oxygen adsorption on CeO 2 /-Al 2 O 3 catalyst supports, J. Chem. Soc. -Faraday Trans, pp.1996-92 ,
Stabilisation of nanostructured CeO 2 ZrO 2 solid solutions by addition of Al 2 O 3 : a suitable way for production of thermally stable oxygen storage/release promoters for three, Appl. Catal. B: Environ, pp.2001-140 ,
Remarkable stabilization of transition alumina operated by ceria under reducing and redox conditions, Applied Catalysis B: Environmental, vol.28, issue.2, 2000. ,
DOI : 10.1016/S0926-3373(00)00226-5
NO Decomposition over Partially Reduced Metallized CeO 2 -ZrO 2 Solid Solution, Catal. Lett, pp.1994-2018 ,
Redox behavior of CeO 2 ?ZrO 2 mixed oxides I. Influence of redox treatments on high surface area catalysts, Appl. Catal. B: Environ, pp.2000-2027 ,
URL : https://hal.archives-ouvertes.fr/emse-00609905
Redox behavior of CeO 2 ?ZrO 2 mixed oxides II. Influence of redox treatments on high surface area catalysts, Appl. Catal. B: Environ. ?, pp.30-75, 2001. ,
URL : https://hal.archives-ouvertes.fr/emse-00610076
Reversible changes in the redox behaviour of a Ce 0.68 Zr 0.32 O 2 mixed oxide: effect of alternating the re-oxidation temperature after reduction at 1223 K, Chem. Commun. ?, pp.149-150, 1999. ,
Oxygen release behaviour of Ce (1-x) Zr x O 2 powders and appearance of Ce (8-4y) Zr 4y O (14-) solid solution in the ZrO 2 ?CeO 2 ?CeO 1.5 system, pp.107-114 ,
Oxygen evolution properties of CeO 2 -ZrO 2 powders as automotive exhaust sub-catalysts and the phase diagrams, Nippon Kinzoku Gakkaishi, pp.1995-59 ,
Crystal structure of metastable k-CeZrO phase possessing an ordered arrangement of Ce and Zr ions, Alloys Comp. ? 2000. ? V. 312, pp.94-103 ,
X-ray absorption fine structure analysis of local structure of CeO 2 -ZrO 2 mixed oxides with the same composition ratio (Ce, Catal. Today ?, issue.1, pp.74-225, 2002. ,
Improvement of oxygen storage capacity of CeO 2 ?ZrO 2 solid solution by heat treatment in reducing atmosphere, J. Ceram. Soc. of Japan ?, pp.110-126, 2002. ,
Computer Modeling of Local Level Structures in (Ce, Zr) Mixed Oxide, The Journal of Physical Chemistry B, vol.107, issue.34, pp.8840-8853, 2003. ,
DOI : 10.1021/jp0340156
Effects of Trivalent Dopants on the Redox Properties of Ce0.6Zr0.4O2Mixed Oxide, Journal of Catalysis, vol.171, issue.1, pp.160-168, 1997. ,
DOI : 10.1006/jcat.1997.1784
Redox behavior of surface-modified CeO 2 -ZrO 2 catalysts by chemical filing process, Chem. Mater. ?, 2000. ,
Studies of the oxygen release reaction in the platinum???ceria???zirconia system, Catalysis Today, vol.50, issue.2, pp.1999-50 ,
DOI : 10.1016/S0920-5861(98)00511-2
The Dynamics of Oxygen Storage in Ceria???Zirconia Model Catalysts Measured by CO Oxidation under Stationary and Cycling Feedstream Compositions, Journal of Catalysis, vol.193, issue.2, pp.2000-193 ,
DOI : 10.1006/jcat.2000.2887
Effects of thermal pretreatment on the redox behaviour of Ce0.5Zr0.5O2: isotopic and spectroscopic studies, Physical Chemistry Chemical Physics, vol.4, issue.1, pp.2002-2006 ,
DOI : 10.1039/b106765f
Oxygen storage capacity on cerium oxide ? preciouse metal system ,
Chemical modification of catalyst support for enhancement of transient catalytic activity: nitric oxide reduction by carbon monoxide over rhodium, Journal of Catalysis, vol.131, issue.1, pp.1991-131 ,
DOI : 10.1016/0021-9517(91)90324-W
Hydrothermal synthesis and properties of mixed conducting Ce 1-x Tb x O 2-solid solutions, Chem. Mater. ?, issue.11, pp.473-479, 1999. ,
Materials, The Journal of Physical Chemistry B, vol.103, issue.18, pp.3634-3639, 1999. ,
DOI : 10.1021/jp984383n
Effective ionic radii in oxides and fluorides, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.25, issue.5, pp.925-946, 1969. ,
DOI : 10.1107/S0567740869003220
Nanophase catalytic oxides: I. Synthesis of doped cerium oxides as oxygen storage promoters, Applied Catalysis B: Environmental, vol.6, issue.4, pp.325-337, 1995. ,
DOI : 10.1016/0926-3373(95)00041-0
Evidence for different copper species in precursors of copper???cerium oxide catalysts for hydrogenation reactions. An X-ray diffraction, EPR and X-ray photoelectron spectroscopy study, J. Chem. Soc., Faraday Trans., vol.19, issue.1, pp.92-131, 1996. ,
DOI : 10.1039/FT9969200131
Effect of cerium on the mobility of oxygen on manganese oxides, Applied Catalysis A: General, vol.142, issue.2, pp.142-279, 1996. ,
DOI : 10.1016/0926-860X(96)00095-6
Catalytic properties of ceria and CeO 2 -containing materials, Catal. Rev. Sci. Eng. ?, pp.38-439, 1996. ,
Some contributions of electron microscopy to the characterization of the strong metal?support interaction effect, Catal. Today, pp.2003-77 ,
Catalysis by Ceria and Related Materials, pp.1-500, 2002. ,
DOI : 10.1142/p249
On the role of oxygen storage in three-way catalysis, Top. Catal, pp.2004-2032 ,
Rh- CeO 2 interaction induced by high-temperature reduction -characterization and catalytic behavior in transient and continuous conditions, J. Chem. Soc. Faraday Trans. ?, pp.88-1311, 1992. ,
Metal-support interactions in Rh ,
Nb 2 O 5 Catalysts as inferred from CO 2 methanation activity, J. Catal. ?, vol.156, pp.171-174, 1995. ,
Reduction of NO over partially reduced metal-loaded CeO 2 ?ZrO 2 solid solutions, J. Catal, pp.1996-162 ,
A temperature-programmed and transient kinetic study of CO 2 activation and methanation over CeO 2 supported noble metals, J. Catal, pp.1997-166 ,
A novel dynamic kinetic model of oxygen isotopic exchange on a supported metal catalyst, Appl. Surf. Sci. ?, pp.236-342, 2004. ,
URL : https://hal.archives-ouvertes.fr/hal-00007463
Influence of Ceria on Pd Activity for the CO+O2 Reaction, Journal of Catalysis, vol.187, issue.2, pp.474-485, 1999. ,
DOI : 10.1006/jcat.1999.2624
Low-temperature redox activity in co-precipitated catalysts: a comparison between gold and platinum-group metals, Catalysis Today, vol.72, issue.1-2, pp.72-107, 2002. ,
DOI : 10.1016/S0920-5861(01)00484-9
Nanocrystalline catalysts based on CeO 2 -ZrO 2 doped by praseodymium or gadolinium: synthesis and properties, Proc. ?, 2006. ,
Preparation of Ce-Zr-O composites by a polymerized complex method, Surf. Sci. Catal, pp.2002-143 ,
Adsorption of Gases in Multimolecular Layers, Journal of the American Chemical Society, vol.60, issue.2, pp.60-309, 1938. ,
DOI : 10.1021/ja01269a023
Microscopy and imaging in " Spectroscopy in catalysis, pp.167-200, 2000. ,
Wall coating optimization for microchannel reactors, Catalysis Today, vol.125, issue.1-2, pp.16-23, 2007. ,
DOI : 10.1016/j.cattod.2007.01.074
URL : https://hal.archives-ouvertes.fr/hal-00160814
The Vibrational Spectroscopies In Spectroscopy in Catalysis, pp.201-229, 2000. ,
Practical surface analysis by auger and X-ray photoelectron spectroscopy, 1983. ,
Handbook of X-ray photoelectron spectroscopy, 1992. ,
Tansient response method in heterogeneous catalysis, pp.139-176 ,
The Transient Method and Elementary Steps in Heterogeneous Catalysis, Catalysis Reviews, vol.1, issue.1, pp.1976-1989 ,
DOI : 10.1080/00087647608069936
Temporal Analysis of Products (TAP)???A Unique Catalyst Evaluation System with Submillisecond Time Resolution, Catalysis Reviews, vol.5, issue.1, pp.30-49, 1988. ,
DOI : 10.1080/01614948808078616
TAP reactor studies in in-situ spectroscopy in heterogeneous catalysis, pp.237-269, 2002. ,
Studies of binary oxide catalysts for the ammoxidation of methanol to hydrogen cyanide, Symposium on Chemicals from Syngas and Methanol Presented before the Division of Petroleum Chemistry, 1986. ,
TAP-2: An interrogative kinetics approach, Applied Catalysis A: General, vol.160, issue.1, pp.160-55, 1997. ,
DOI : 10.1016/S0926-860X(97)00124-5
Specific features concerning the mechanism of methane reforming by carbon dioxide over Ni/La 2 O 3 catalyst, J. Catal, pp.1997-172 ,
URL : https://hal.archives-ouvertes.fr/hal-00006607
A C1 mechanism for methane oxidation on platinum, Journal of Catalysis, vol.213, issue.1, pp.213-236, 2003. ,
DOI : 10.1016/S0021-9517(02)00045-3
Partial oxidation of methane to synthesis gas over corundum supported mixed oxides: One channel studies, Catal. Tod. -2005. ? V. 105, pp.367-371 ,
DOI : 10.1016/j.cattod.2005.06.030
Selective oxidation of hydrocarbons into synthesis gas at short contact times: Design of monolith catalysts and main process parameters, Kinetics and Catalysis, vol.91, issue.2, pp.2005-2051 ,
DOI : 10.1007/s10975-005-0070-3
Selective catalytic oxidation of methane to syngas over supported mixed oxides comprising Ni and Pt, Kinetics and Catalysis, pp.2004-2049 ,
Partial oxidation of methane to synthesis gas over Pt/MgO Kinetics of surface processes, pp.1996-2028 ,
Thermal behavior of (Ce,Zr)O x / Al 2 O 3 complex oxides prepared by a microemulsion method, Phys. Chem. Chem. Phys, pp.2002-2006 ,
Vibrational and electronic spectroscopic properties of zirconia powders, J. Mater. Chem. ?, pp.11-1891, 2001. ,
Study of the Raman spectrum of CeO 2 nanometer thin films, Mater. Chem. Phys. ?, pp.68-246, 2001. ,
Raman Spectroscopy of Tetragonal Zirconia Solid Solutions, Journal of the American Ceramic Society, vol.19, issue.5, pp.1993-76 ,
DOI : 10.1111/j.1151-2916.1992.tb04222.x
Transport property and Raman spectra of nanocrystalline solid solutions Ce 0.8 Nd 0.2 O 2 with different particle size, Mater. Chem. Phys, pp.2001-69 ,
An XPS study of interactions in thin films containing a noble metal with valence-invariant and reducible oxides, Journal of Catalysis, vol.137, issue.1, pp.1992-137 ,
DOI : 10.1016/0021-9517(92)90143-6
Partial oxidation of methane over platinum metal gauze, Catalysis Letters, vol.29, issue.1-2, pp.1996-2032 ,
DOI : 10.1007/BF00807201
Analysis of a catalytic annular reactor for very short contact times, Chemical Engineering Science, vol.54, issue.6, pp.1999-54 ,
DOI : 10.1016/S0009-2509(98)00261-9
Chemical reactor analysis and design ,
Miniaturization of hydroprocessing catalyst testing systems: Theory and practice, AIChE Journal, vol.42, issue.12, pp.2004-2046 ,
DOI : 10.1002/aic.690421219
A comparison of lumped and distributed models of monolith catalytic combustors, Chemical Engineering Science, vol.50, issue.17, pp.50-2705, 1995. ,
DOI : 10.1016/0009-2509(95)00099-Q
Introduction to catalytic combustion // Gordon and Breach Science Publishers ? 1997. ? Ps, p.681 ,
Stofftransport bei Wandreaktion im Einlaufgebiet eines Str??mungsrohres, Chemie Ingenieur Technik, vol.38, issue.1, pp.30-35 ,
DOI : 10.1002/cite.330380107
ODEPACK, A systematized collection of ODE solvers, pp.55-64, 1983. ,
Steps in the reaction H 2 +O 2 H 2 O on Pt: OH desorption at high temperatures, J. Phys. Chem, pp.1992-96 ,
Step in CH 4 oxidation on the Pt and Rh surface: hightemperature reactor simulations, AIChE J, pp.1993-2032 ,
Methane dissociation and syngas formation on Ru and Au : a theoretical study, J. Catal, pp.1999-185 ,
ChemInform Abstract: The Bond-Order Conservation Approach to Chemisorption and Heterogeneous Catalysis: Applications and Implications, ChemInform, vol.37, issue.41, pp.37-101, 1990. ,
DOI : 10.1002/chin.199141310
Activation of methane on iron, nickel, and platinum surfaces: a molecular orbital study, The Journal of Physical Chemistry, vol.92, issue.3, pp.1988-92 ,
DOI : 10.1021/j100314a043
Sazonova // (in Russian, reading to " Influence of the oxygen mobility in complex oxide supports on the mechanism of the partial oxidation of methane, Chem. J, pp.52-73, 2008. ,
Development of a transient kinetic model for the CO oxidation by O 2 over a Pt, Appl. Catal. B: Environ, issue.2, pp.1998-2017 ,
Silicon nitride supported platinum catalysts for the partial oxidation of methane at high temperatures, Catalysis Today, vol.64, issue.1-2, pp.64-51, 2001. ,
DOI : 10.1016/S0920-5861(00)00508-3
Surface Areas of Pt???Rh Catalyst Gauzes Used for Ammonia Oxidation, Journal of Catalysis, vol.160, issue.2, pp.1994-146 ,
DOI : 10.1006/jcat.1996.0133
The adsorption and dissociation of CO 2 on Rh, Appl. Surf. Sci, pp.1993-67 ,
The Netherlands, 1995. ,
Transient studies of carbon dioxide reforming of methane over Pt/ZrO 2 and Pt, Catal. Today ?, issue.2 3, pp.115-191, 2006. ,
URL : https://hal.archives-ouvertes.fr/hal-00093513
Future Directions and Industrial Perspectives Micro- and macro-kinetics: Their relationship in heterogeneous catalysis, Topics in Catalysis, vol.14, issue.270, pp.1994-1995 ,
DOI : 10.1007/BF01492288
Étude expérimentale et modélisation de l'oxydation partielle du méthane en gaz de synthèse sur réacteur catalytique monolithique à temps court __________________________________________________________________________ RESUME en français ,
Experimental study and mathematical modeling of catalytic partial oxidation of methane to synthesis gas over monolith catalyst at short contact times ____________________________________________________________________________ RESUME en anglais : Main objective of the thesis was to develop a structured reactor for the efficient catalytic partial oxidation of methane (CPOM) to synthesis gas. The investigated catalysts comprised Pt as noble or Ni as base metal supported on CeO 2 -ZrO 2 mixed oxides introduced as wall coatings of corundum monolith substrates. It was possible to elucidate the effect of different dopants modifying the mixed oxide and to establish the impact of process parameters on the CPOM performance of single monolith channels at short contact times. A mechanistic study revealed important factors, e.g. surface (species) or bulk (storage) effects, in the interaction between the CeO 2 -ZrO 2 mixed oxide and Pt, playing a key role as the most active sites. Kinetic experiments lead to the insight that Pt is required for reforming reactions and showed a significant reactivity of the doped CeO 2 -ZrO 2 support in the oxidative methane activation. A mathematical description of the experimental data was achieved with a model accounting mainly for the activity of Pt. The activity of Pt sites was found significantly higher than that of the support although TAP investigations indicated that a more oxidized catalyst shows lower methane activation rates. ____________________________________________________________________________ DISCIPLINE : Chimie ? Génie des procédés ____________________________________________________________________________ MOTS-CLES : Catalytic partial oxidation of methane, synthesis gas, CeZrO x support, structured catalyst, short contact times, reaction mechanism, kinetic study ____________________________________________________________________________ INTITULE ET ADRESSE DE L'U.F.R. OU DU LABORATOIRE : Institut de Recherche sur la Catalyse et l'Environnement de Lyon ,