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. Anal, Found: C, 56.08; H, 8.26; N, 16.59; Calc

J. Td, 76 (ddd, J 2.8, 6.2 and 13); d C (100 MHz, CDCl 3 ) 173, 1H), 2.46 (ddd, J 1.4, 9.6 and 13.4, 1H), 1.85 (hept, J 7.2, 1H), pp.4080-563, 2002.

J. Dd, 74 (ddd, J 2.2, 9.2 and 12.6, 1H), 1.82 (qq, J 6, 1H), 2.78 (s, 3H) 3H), 1.26 (t, J 6d, J 7.2, 3H); d C (100 MHz, pp.4-10

. Mg, 388 mmol) and trans-methyl crotonate (411 mL, 3.88 mmol) as a colourless oil

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M. Na and +. , 173 (M + H + , 37); HRMS: m/z 195, p.11024

. Moc-phe-oh, 41 g, 51.11. mmol, 87%) was prepared from L-phenylalanine (9.69 g, 58.66 mmol) according to ref

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=. ). @bullet and V. =. , M: 170.21 g mol -1 ; crystal system: triclinic; unit-cell dimensions and volume: a = 6 A ? , c = 11.610(3) A ? , a = 83 ? , b = 86 ? , g = 84 A ? 3 , temperature of measurement: 293.0 K; space group symbol: P ¯ 1; no. of formula units in the unit cell Z = 2; no. of measured and independent reflections: 9127 and 2392, R int : 0.09; refinement vs. F; final R values, 12 Crystal data for 1 (C 8 H 14 N 2 O 2

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