1-bromododecane : 8.64 mL (8.97g, 36 mmol), carbonate de potassium : 19.9g (144 mmol) Le produit brut filtré après quenchagè a l'eau est chromatographié sur colonne de silice, ´ eluant : 95/5 (Ether de pétrole / Acétate d'´ ethyle) On récupère deux produits, pp.3-5 ,
ADN sous leur forme libre ontétéontété déposées sur des surfaces de HOPG [125] [126], sur l'or [127], et sur le cuivre [128] [129] [130] [131] [132]. CesétudesCesétudes soulignent notamment l'effet prédominant des associations par liaisons H sur la structure des monocouches formées, et permettent d'´ etablir unparalì ele avec la formation de ces liaisons en 3D dans des systèmes comme l'ADN. D'autres systèmessystèmesélémentaires des systèmes vivants ,
la recherche au niveau nanométrique promet des solutionsàsolutionsà de nombreuxprobì emes, notamment celui de la libération de principes actifs ,
24 résume les résultats obtenus par STM sur les deux substrats. L'image de la Figure 5.24a est obtenue sur un substrat de graphite, tandis que l'image de la Figure 5 On constate que les structures sont quasiment identiques et indépendantes du substrat. Des doubles rangées de spots brillants (noyaux aromatiques) sont observées, séparées par les cha??nescha??nes alkoxy-. La distance inter-lamellaire vaut 3 ,
Les cha??nescha??nes forment un angle de 30åvec l'axe des rangées. On constate de plus que ces cha??nescha??nes ne sont pas entremêlées (l'´ ecartement entre chaque cha??necha??ne vaut 5 ? A) ,
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