D. , I. À. La, . Il-est-Établi, and . Qu, aux q intermédiaires, celui-ci varie tel que : P (q) ? q ?1

N. Monomères-polymérisables-par and A. , 26 1.23 log(k app p ) vs E 1/2 pour le système OEGMA, O (trait plein) et pour système en masse ou dans du MeCN, p.27

C. Alcoxyamine-utilisée-par-laruelle, composées de 3 fonctions : fonction amorçante pour la NMP (I), fonction permettant le dégreffage (II), fonction permettant le greffage à la surface des particules (III), p.58

.. Ester-activé, Synthèse d'un précurseur silylé par amidification d'un, p.63

D. Du, Réaction de transestérification (ou hydrolyse)

.. Mn-théo-visé-temps, Evolution de la conversion et du ln, p.98

.. Mn-théo-visé-temps, Evolution de la conversion et du ln, p.98

R. De, Comparaison des énergies d'activation (kJ.mol -1 ) obtenues avec une simple et une double intégrale du signal, p.71

. Bibliographie, Nanoparticules Hybrides Silice/Polymère : Synthèses, Analyses DNPA, 2005.

J. Persello, Silica Sol, Composition containing the same, method for treating said silica sol and uses thereof, 2000.

T. Trindade, P. O-'brian, and N. L. Pickett, Nanocrystalline Semiconductors:?? Synthesis, Properties, and Perspectives, Chemistry of Materials, vol.13, issue.11, pp.3843-3858, 2001.
DOI : 10.1021/cm000843p

M. Daniel and D. Astruc, Gold Nanoparticles:?? Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology, Chemical Reviews, vol.104, issue.1, pp.293-346, 2004.
DOI : 10.1021/cr030698+

R. Shenhar, T. B. Norsten, and V. M. Rotello, Polymer-Mediated Nanoparticle Assembly: Structural Control and Applications, Advanced Materials, vol.11, issue.6, pp.657-669, 2005.
DOI : 10.1002/adma.200401291

J. E. Smith, L. Wang, W. Tan, and . @trac, Trends anal. chem, pp.848-855, 2006.

Q. Ma, E. E. Remsen, and T. Kowalewski, Two-Dimensional, Shell-Cross-linked Nanoparticle Arrays, Journal of the American Chemical Society, vol.123, issue.19, pp.4627-4628, 2001.
DOI : 10.1021/ja0156542

C. J. Mcdonald, K. J. Bouck, and A. B. Chaput, Emulsion Polymerization of Voided Particles by Encapsulation of a Nonsolvent, Macromolecules, vol.33, issue.5, pp.1593-1605, 2000.
DOI : 10.1021/ma991284e

M. Park, C. Xia, and R. Advincula, Cross-Linked, Luminescent Spherical Colloidal and Hollow-Shell Particles, Langmuir, vol.17, issue.24, pp.7670-7674, 2001.
DOI : 10.1021/la011006k

T. Morinaga, M. Ohkura, and K. Ohno, Monodisperse Silica Particles Grafted with Concentrated Oxetane-Carrying Polymer Brushes:?? Their Synthesis by Surface-Initiated Atom Transfer Radical Polymerization and Use for Fabrication of Hollow Spheres, Macromolecules, vol.40, issue.4, pp.1159-1164, 2006.
DOI : 10.1021/ma062230p

G. D. Fu, Z. Shang, and L. Hong, Preparation of Cross-Linked Polystyrene Hollow Nanospheres via Surface-Initiated Atom Transfer Radical Polymerizations, Macromolecules, vol.38, issue.18, pp.7867-7871, 2005.
DOI : 10.1021/ma0509098

C. R. Vestal and J. Zhang, /Polystyrene Core/Shell Nanoparticles, Journal of the American Chemical Society, vol.124, issue.48, pp.14312-14313, 2002.
DOI : 10.1021/ja0274709

D. Fournier, S. Pascual, and V. Montembault, Elaboration of well-defined Rasta resins and their use as supported catalytic systems for atom transfer radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.34, issue.18, pp.5316-5328, 2006.
DOI : 10.1002/pola.21644
URL : https://hal.archives-ouvertes.fr/hal-00119746

D. Fournier, S. Pascual, and V. Montembault, Well-Defined Azlactone-Functionalized (Co)polymers on a Solid Support:?? Synthesis via Supported Living Radical Polymerization and Application as Nucleophile Scavengers, Journal of Combinatorial Chemistry, vol.8, issue.4, pp.522-530, 2006.
DOI : 10.1021/cc0600122

B. R. Coad, J. N. Kizhakkedathu, and C. A. Haynes, Synthesis of Novel Size Exclusion Chromatography Support by Surface Initiated Aqueous Atom Transfer Radical Polymerization, Langmuir, vol.23, issue.23, pp.11791-11803, 2007.
DOI : 10.1021/la701703c

P. Hemström, M. Szumski, and K. Irgum, Atom-Transfer Radical Graft Polymerization Initiated Directly from Silica Applied to Functionalization of Stationary Phases for High-Performance Liquid Chromatography in the Hydrophilic Interaction Chromatography Mode, Analytical Chemistry, vol.78, issue.20, pp.7098-7103, 2006.
DOI : 10.1021/ac0602874

X. Huang and M. Wirth, Surface-Initiated Radical Polymerization on Porous Silica, Analytical Chemistry, vol.69, issue.22, pp.4577-4580, 1997.
DOI : 10.1021/ac9704523

S. K. Park, K. D. Kim, and H. T. Kim, Preparation of silica nanoparticles: determination of the optimal synthesis conditions for small and uniform particles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.197, issue.1-3, pp.7-17, 2002.
DOI : 10.1016/S0927-7757(01)00683-5

R. J. Corriu, Ceramics and Nanostructures from Molecular Precursors, Angewandte Chemie International Edition, vol.39, issue.8, pp.1376-1398, 2000.
DOI : 10.1002/(SICI)1521-3773(20000417)39:8<1376::AID-ANIE1376>3.0.CO;2-S

R. K. Iler and . Ed, The Chemistry of Silica, 1955.

W. Stöber and A. Fink, Controlled growth of monodisperse silica spheres in the micron size range, Journal of Colloid and Interface Science, vol.26, issue.1, pp.62-69, 1968.
DOI : 10.1016/0021-9797(68)90272-5

C. G. Tan, B. D. Bowen, and N. Epstein, Production of monodisperse colloidal silica spheres: Effect of temperature, Journal of Colloid and Interface Science, vol.118, issue.1, pp.290-293, 1987.
DOI : 10.1016/0021-9797(87)90458-9

H. Giesche, Synthesis of monodispersed silica powders II. Controlled growth reaction and continuous production process, Journal of the European Ceramic Society, vol.14, issue.3, pp.205-214, 1994.
DOI : 10.1016/0955-2219(94)90088-4

A. Vioux, Nonhydrolytic Sol???Gel Routes to Oxides, Chemistry of Materials, vol.9, issue.11, pp.2292-2299, 1997.
DOI : 10.1021/cm970322a

A. L. Bug, M. E. Cates, and S. A. Safran, Theory of size distribution of associating polymer aggregates. I. Spherical aggregates, The Journal of Chemical Physics, vol.87, issue.3, pp.1824-1833, 1987.
DOI : 10.1063/1.453195

B. Zhao and W. J. Brittain, Polymer brushes: surface-immobilized macromolecules, Progress in Polymer Science, vol.25, issue.5, pp.677-710, 2000.
DOI : 10.1016/S0079-6700(00)00012-5

B. Ouada, H. Hommel, H. Legrand, and A. P. , Organization of the layers of polyethylene oxide grafted with different densities on silica, Journal of Colloid and Interface Science, vol.122, issue.2, pp.441-449, 1988.
DOI : 10.1016/0021-9797(88)90378-5

K. Bridger and B. Vincent, The terminal grafting of poly(ethylene oxide) chains to silica surfaces, European Polymer Journal, vol.16, issue.10, pp.1017-1021, 1980.
DOI : 10.1016/0014-3057(80)90185-8

N. Tsubokawa, A. Kuroda, and Y. Sone, Grafting onto carbon black by the reaction of reactive carbon black having epoxide groups with several polymers, Journal of Polymer Science Part A: Polymer Chemistry, vol.27, issue.5, pp.1701-1712, 1989.
DOI : 10.1002/pola.1989.080270521

V. Koutsos, E. W. Van-der-vegte, and E. Pelletier, Structure of Chemically End-Grafted Polymer Chains Studied by Scanning Force Microscopy in Bad-Solvent Conditions, Macromolecules, vol.30, issue.16, pp.4719-4726, 1997.
DOI : 10.1021/ma961625d

P. Mansky, Y. Liu, and E. Huang, Controlling Polymer-Surface Interactions with Random Copolymer Brushes, Science, vol.275, issue.5305, pp.1458-1460, 1997.
DOI : 10.1126/science.275.5305.1458

O. Prucker, C. A. Naumann, and J. Rühe, Photochemical Attachment of Polymer Films to Solid Surfaces via Monolayers of Benzophenone Derivatives, Journal of the American Chemical Society, vol.121, issue.38, pp.8766-8770, 1999.
DOI : 10.1021/ja990962+

K. P. Krenkler, R. Laible, and K. Hamann, Polyreaktionen an Pigmentoberfl??chen. VII. Mitteilung: Reaktionen von Polymeren mit endst??ndigen Chlorsilangruppen an Siliciumdioxidoberfl??chen, Angewandte Makromolekulare Chemie, vol.53, issue.1, pp.101-123, 1976.
DOI : 10.1002/apmc.1976.050530109

K. Ebata, K. Furukawa, and N. Matsumoto, Synthesis and Characterization of End-Grafted Polysilane on a Substrate Surface, Journal of the American Chemical Society, vol.120, issue.29, pp.7367-7368, 1998.
DOI : 10.1021/ja980802i

M. Swarc, ???Living??? Polymers, Nature, vol.78, issue.4543, pp.1168-1169, 1956.
DOI : 10.1038/1781168a0

T. R. Darling, T. P. Davis, and M. Fryd, Living polymerization: Rationale for uniform terminology, Journal of Polymer Science Part A: Polymer Chemistry, vol.10, issue.10, pp.1706-1708, 2000.
DOI : 10.1002/(SICI)1099-0518(20000515)38:10<1706::AID-POLA20>3.0.CO;2-5

K. Matyjaszewski and T. P. Davis, Handbook of Radical Polymerization, 2002.
DOI : 10.1002/0471220450

H. Fischer, The Persistent Radical Effect:?? A Principle for Selective Radical Reactions and Living Radical Polymerizations, Chemical Reviews, vol.101, issue.12, pp.3581-3610, 2001.
DOI : 10.1021/cr990124y

D. H. Solomon, E. Rizzardo, and P. Cacioli, Polymerization Process and Polymers Produced Thereby, 1986.

M. K. Georges, R. P. Veregin, and P. M. Kazmaier, Narrow molecular weight resins by a free-radical polymerization process, Macromolecules, vol.26, issue.11, pp.2987-2988, 1993.
DOI : 10.1021/ma00063a054

D. Benoit, V. Chaplinski, and R. Braslau, Development of a Universal Alkoxyamine for ???Living??? Free Radical Polymerizations, Journal of the American Chemical Society, vol.121, issue.16, pp.3904-3920, 1999.
DOI : 10.1021/ja984013c

P. Lacroix-desmazes, J. Lutz, and F. Chauvin, Living Radical Polymerization: Use of an Excess of Nitroxide as a Rate Moderator, Macromolecules, vol.34, issue.26, pp.8866-8871, 2001.
DOI : 10.1021/ma010365j

D. Benoit, E. Harth, and P. Fox, Accurate Structural Control and Block Formation in the Living Polymerization of 1,3-Dienes by Nitroxide-Mediated Procedures, Macromolecules, vol.33, issue.2, pp.363-370, 2000.
DOI : 10.1021/ma991187l

L. Couvreur, C. Lefay, and J. Belleney, First Nitroxide-Mediated Controlled Free-Radical Polymerization of Acrylic Acid, Macromolecules, vol.36, issue.22, pp.8260-8267, 2003.
DOI : 10.1021/ma035043p

T. Diaz, A. Fischer, and A. Jonquières, Controlled Polymerization of Functional Monomers and Synthesis of Block Copolymers Using a ??-Phosphonylated Nitroxide, Macromolecules, vol.36, issue.7, pp.2235-2241, 2003.
DOI : 10.1021/ma0260086

D. Bertin, D. Gigmes, and C. Le-mercier, -oxyl)-Based Alkoxyamines, The Journal of Organic Chemistry, vol.69, issue.15, pp.4925-4930, 2004.
DOI : 10.1021/jo0495586
URL : https://hal.archives-ouvertes.fr/hal-00758371

F. Chauvin, P. Dufils, and D. Gigmes, Value of the Initiating Alkoxyamine and the Importance of the Experimental Conditions, Macromolecules, vol.39, issue.16, pp.5238-5250, 2006.
DOI : 10.1021/ma0527193
URL : https://hal.archives-ouvertes.fr/hal-00119089

J. Nicolas, C. Dire, and L. Mueller, Living Character of Polymer Chains Prepared via Nitroxide-Mediated Controlled Free-Radical Polymerization of Methyl Methacrylate in the Presence of a Small Amount of Styrene at Low Temperature, Macromolecules, vol.39, issue.24, pp.8274-8282, 2006.
DOI : 10.1021/ma061380x
URL : https://hal.archives-ouvertes.fr/hal-00119071

Y. Guillaneuf, D. Gigmes, and S. R. Marque, First Effective Nitroxide-Mediated Polymerization of Methyl Methacrylate, Macromolecules, vol.40, issue.9, pp.3108-3114, 2007.
DOI : 10.1021/ma062330v
URL : https://hal.archives-ouvertes.fr/hal-00145431

C. J. Hawker, Molecular Weight Control by a "Living" Free-Radical Polymerization Process, Journal of the American Chemical Society, vol.116, issue.24, pp.11185-11186, 1994.
DOI : 10.1021/ja00103a055

C. J. Hawker, G. C. Barclay, and A. Orellana, Initiating Systems for Nitroxide-Mediated ???Living??? Free Radical Polymerizations:?? Synthesis and Evaluation, Macromolecules, vol.29, issue.16, pp.5245-5254, 1996.
DOI : 10.1021/ma951905d

C. J. Hawker, A. W. Bosman, and E. Harth, New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations, Chemical Reviews, vol.101, issue.12, pp.3661-3688, 2001.
DOI : 10.1021/cr990119u

M. Kato, M. Kamigaito, and M. Sawamoto, Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization, Macromolecules, vol.28, issue.5, pp.1721-1723, 1995.
DOI : 10.1021/ma00109a056

J. Wang and K. Matyjaszewski, Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes, Journal of the American Chemical Society, vol.117, issue.20, pp.5614-5615, 1995.
DOI : 10.1021/ja00125a035

R. A. Gossage, L. A. Van-de-kul, and G. Van-koten, Diaminoarylnickel(II) ???Pincer??? Complexes:?? Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts, Accounts of Chemical Research, vol.31, issue.7, pp.423-431, 1998.
DOI : 10.1021/ar970221i

F. Minisci and . Rad, Add. Olefins, pp.165-171, 1975.

K. Matyjaszewski and J. Xia, Atom Transfer Radical Polymerization, Chemical Reviews, vol.101, issue.9, pp.2921-2990, 2001.
DOI : 10.1021/cr940534g

F. Simal, A. Demonceau, and A. Noels, Highly Efficient Ruthenium-Based Catalytic Systems for the Controlled Free-Radical Polymerization of Vinyl Monomers, Angewandte Chemie International Edition, vol.38, issue.4, p.538, 1999.
DOI : 10.1002/(SICI)1521-3773(19990215)38:4<538::AID-ANIE538>3.0.CO;2-W

W. A. Braunecker, Y. Itami, and K. Matyjaszewski, Osmium-Mediated Radical Polymerization, Macromolecules, vol.38, issue.23, pp.9402-9404, 2005.
DOI : 10.1021/ma051877r

V. Percec, B. Barboiu, and A. Neumann, Metal-Catalyzed ???Living??? Radical Polymerization of Styrene Initiated with Arenesulfonyl Chlorides. From Heterogeneous to Homogeneous Catalysis, Macromolecules, vol.29, issue.10, pp.3665-3668, 1996.
DOI : 10.1021/ma960061a

B. Wang, Y. Zhuang, and X. Luo, Controlled/???Living??? Radical Polymerization of MMA Catalyzed by Cobaltocene, Macromolecules, vol.36, issue.26, pp.9684-9686, 2003.
DOI : 10.1021/ma035334y

C. Granel, P. Dubois, and R. Jérome, Controlled Radical Polymerization of Methacrylic Monomers in the Presence of a Bis(ortho-chelated) Arylnickel(II) Complex and Different Activated Alkyl Halides, Macromolecules, vol.29, issue.27, p.8576, 1996.
DOI : 10.1021/ma9608380

P. Lecomte, P. Drapier, and P. Dubois, Controlled Radical Polymerization of Methyl Methacrylate in the Presence of Palladium Acetate, Triphenylphosphine, and Carbon Tetrachloride, Macromolecules, vol.30, issue.24, p.7631, 1997.
DOI : 10.1021/ma970890b

W. Tang and K. Matyjaszewski, Effect of Ligand Structure on Activation Rate Constants in ATRP, Macromolecules, vol.39, issue.15, pp.4953-4959, 2006.
DOI : 10.1021/ma0609634

M. B. Gillies, K. Matyjaszewski, and P. Norrby, A DFT Study of R???X Bond Dissociation Enthalpies of Relevance to the Initiation Process of Atom Transfer Radical Polymerization, Macromolecules, vol.36, issue.22, pp.8551-8559, 2003.
DOI : 10.1021/ma0351672

J. Gromada and K. Matyjaszewski, Measurement of Initial Degree of Polymerization without Reactivation as a New Method To Estimate Rate Constants of Deactivation in ATRP, Macromolecules, vol.35, issue.16, pp.6167-6173, 2002.
DOI : 10.1021/ma020279z

Y. Shen, H. Tang, and S. Ding, Catalyst separation in atom transfer radical polymerization, Progress in Polymer Science, vol.29, issue.10, pp.1053-1078, 2004.
DOI : 10.1016/j.progpolymsci.2004.08.002

A. M. Kasko, A. M. Heintz, and C. Pugh, The Effect of Molecular Architecture on the Thermotropic Behavior of Poly[11-(4???-cyanophenyl-4??????-phenoxy)undecyl acrylate] and Its Relation to Polydispersity, Macromolecules, vol.31, issue.2, pp.256-271, 1998.
DOI : 10.1021/ma971279f

G. Kickelbick, H. Paik, and K. Matyjaszewski, Immobilization of the Copper Catalyst in Atom Transfer Radical Polymerization, Macromolecules, vol.32, issue.9, pp.2941-2947, 1999.
DOI : 10.1021/ma9818432

W. Jakubowski, K. Min, and K. Matyjaszewski, Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization of Styrene, Macromolecules, vol.39, issue.1, pp.39-45, 2006.
DOI : 10.1021/ma0522716

T. P. Le, G. Moad, and E. Rizzardo, Polymerization with living characteristics, 1998.

P. Corpart, D. Charmot, and S. Zard, Method for block polymer synthesis by controlled radical polymerization from dithiocarbamate compounds, 1999.

M. Nowakowska, S. Zapotoczny, and A. Karewicz, vinylnaphthalene) by Nitroxide-Mediated Free Radical Polymerization, Macromolecules, vol.33, issue.20, pp.7345-7348, 2000.
DOI : 10.1021/ma991817j

B. Keoshkerian, M. K. Georges, and D. Boils-boissier, Living Free-Radical Aqueous Polymerization, Macromolecules, vol.28, issue.18, pp.6381-6382, 1995.
DOI : 10.1021/ma00122a058

K. Bian and M. F. Cunningham, Nitroxide-Mediated Living Radical Polymerization of 2-Hydroxyethyl Acrylate and the Synthesis of Amphiphilic Block Copolymers, Macromolecules, vol.38, issue.3, pp.695-701, 2005.
DOI : 10.1021/ma0485383

X. Zhang, J. Xia, and K. Matyjaszewski, Controlled/???Living??? Radical Polymerization of 2-(Dimethylamino)ethyl Methacrylate, Macromolecules, vol.31, issue.15, pp.5167-5169, 1998.
DOI : 10.1021/ma980477j

F. Zeng, Y. Shen, and S. Zhu, Atom transfer radical polymerization of 2-(dimethylamino)ethyl methacrylate in aqueous media, Journal of Polymer Science Part A: Polymer Chemistry, vol.33, issue.20, pp.3821-3827, 2000.
DOI : 10.1002/1099-0518(20001015)38:20<3821::AID-POLA130>3.0.CO;2-G

G. Coullerez, E. Malmstrom, and M. Jonsson, Solvent Effects on the Redox Properties of Cu Complexes Used as Mediators in Atom Transfer Radical Polymerization, The Journal of Physical Chemistry A, vol.110, issue.34, pp.10355-10360, 2006.
DOI : 10.1021/jp057191i

G. Coullerez, A. Carlmark, and E. E. Malmstrom, Understanding Copper-Based Atom-Transfer Radical Polymerization in Aqueous Media, The Journal of Physical Chemistry A, vol.108, issue.35, pp.7129-7131, 2004.
DOI : 10.1021/jp048996d

Y. Tsujii, M. Ejaz, and K. Sato, Mechanism and Kinetics of RAFT-Mediated Graft Polymerization of Styrene on a Solid Surface. 1. Experimental Evidence of Surface Radical Migration, Macromolecules, vol.34, issue.26, pp.8872-8878, 2001.
DOI : 10.1021/ma010733j

G. Michael and H. Ferch, Schriftenreihe Pigmente : Grundlagen von AEROSIL c (Technical Bulletin 11), 1998.

C. Li and B. C. Benicewicz, Synthesis of Well-Defined Polymer Brushes Grafted onto Silica Nanoparticles via Surface Reversible Addition???Fragmentation Chain Transfer Polymerization, Macromolecules, vol.38, issue.14, pp.5929-5936, 2005.
DOI : 10.1021/ma050216r

M. Husseman, E. E. Malmström, and M. Mcnamara, Controlled Synthesis of Polymer Brushes by ???Living??? Free Radical Polymerization Techniques, Macromolecules, vol.32, issue.5, pp.1424-1431, 1999.
DOI : 10.1021/ma981290v

R. Matsuno, K. Yamamoto, and H. Otsuka, Polystyrene-Grafted Magnetite Nanoparticles Prepared through Surface-Initiated Nitroxyl-Mediated Radical Polymerization, Chemistry of Materials, vol.15, issue.1, pp.3-5, 2003.
DOI : 10.1021/cm020766t

C. Devaux, F. Cousin, and E. Beyou, Low Swelling Capacity of Highly Stretched Polystyrene Brushes, Macromolecules, vol.38, issue.10, pp.4296-4300, 2005.
DOI : 10.1021/ma047478y

C. Devaux, J. P. Chapel, and P. Chaumont, Controlled structure and density of ???living??? polystyrene brushes on flat silica surfaces, The European Physical Journal E, vol.7, issue.4, pp.345-352, 2002.
DOI : 10.1140/epje/i2001-10098-2

J. Bonilla-cruz, T. Lara-ceniceros, and E. Saldivar-guerra, Towards Controlled Graft Polymerization of Poly[styrene-co-(maleic anhydride)] on Functionalized Silica Mediated by Oxoaminium Bromide Salt. Facile Synthetic Pathway Using Nitroxide Chemistry, Macromolecular Rapid Communications, vol.34, issue.13, pp.1397-1403, 2007.
DOI : 10.1002/marc.200700182

Z. Chen, J. Cai, and L. Zhang, End-grafting copolymers of styrene and 4-vinylpyridine on an interacting solid surface, Journal of Polymer Science Part B: Polymer Physics, vol.56, issue.11, pp.1332-1343, 2004.
DOI : 10.1002/polb.20406

S. Blomberg, S. Ostberg, and E. Harth, Production of crosslinked, hollow nanoparticles by surface-initiated living free-radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.33, issue.9, pp.1309-1320, 2002.
DOI : 10.1002/pola.10210

J. Parvole, L. Billon, and J. Montfort, Formation of polyacrylate brushes on silica surfaces, Polymer International, vol.24, issue.10, pp.1111-1116, 2002.
DOI : 10.1002/pi.1045

J. Parvole, G. Laruelle, and C. Guimon, Initiator-Grafted Silica Particles for Controlled Free Radical Polymerization: Influence of the Initiator Structure on the Grafting Density, Macromolecular Rapid Communications, vol.24, issue.18, pp.1074-1078, 2003.
DOI : 10.1002/marc.200300035

A. Kasseh, A. Ait-kadi, and J. Pierson, Organic/inorganic hybrid composites prepared by polymerization compounding and controlled free radical polymerization, Polymer, vol.44, issue.5, pp.1367-1375, 2003.
DOI : 10.1016/S0032-3861(02)00905-9

J. Parvole, G. Laruelle, and L. Billon, Surface Initiated Polymerization of Poly(butyl acrylate) by Nitroxide Mediated Polymerization: First Comparative Polymerization of a Bimolecular and a Unimolecular Initiator-Grafted Silica Particles, Macromolecular Chemistry and Physics, vol.18, issue.3, pp.372-382, 2005.
DOI : 10.1002/macp.200400372

C. Bartholome, E. Beyou, and E. Bourgeat-lami, Nitroxide-Mediated Polymerization of Styrene Initiated from the Surface of Silica Nanoparticles. In Situ Generation and Grafting of Alkoxyamine Initiators, Macromolecules, vol.38, issue.4, pp.1099-1106, 2005.
DOI : 10.1021/ma048501i

R. Inoubli, S. Dagreou, and M. Delville, In situ thermo-dependant trapping of carbon radicals: a versatile route to well-defined polymer-grafted silica nanoparticles, Soft Matter, vol.28, issue.14, pp.1014-1024, 2007.
DOI : 10.1039/B705249A
URL : https://hal.archives-ouvertes.fr/hal-00164460

F. Chauvin, J. Couturier, and P. Dufils, Crowded Phosphonylated Alkoxyamines with Low Dissociation Temperatures: A Milestone in Nitroxide-Mediated Polymerization
DOI : 10.1021/bk-2006-0944.ch023

M. Ejaz, S. Yamago, and K. Ohno, Controlled Graft Polymerization of Methyl Methacrylate on Silicon Substrate by the Combined Use of the Langmuir???Blodgett and Atom Transfer Radical Polymerization Techniques, Macromolecules, vol.31, issue.17, pp.5934-5936, 1998.
DOI : 10.1021/ma980240n

K. Ohno, K. Koh, and Y. Tsujii, Synthesis of Gold Nanoparticles Coated with Well-Defined, High-Density Polymer Brushes by Surface-Initiated Living Radical Polymerization, Macromolecules, vol.35, issue.24, pp.8989-8993, 2002.
DOI : 10.1021/ma0209491

C. R. Vestal and Z. J. Zhang, /Polystyrene Core/Shell Nanoparticles, Journal of the American Chemical Society, vol.124, issue.48, pp.14312-14313, 2002.
DOI : 10.1021/ja0274709

Q. Yang, L. Wang, and W. Xiang, Preparation of polymer-grafted carbon black nanoparticles by surface-initiated atom transfer radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.125, issue.15, pp.3451-3459, 2007.
DOI : 10.1002/pola.22077

G. Kickelbick, D. Holzinger, and C. Brick, Hybrid Inorganic???Organic Core???Shell Nanoparticles from Surface-Functionalized Titanium, Zirconium, and Vanadium Oxo Clusters, Chemistry of Materials, vol.14, issue.10, pp.4382-4389, 2002.
DOI : 10.1021/cm021216y

V. Werne, T. Patten, and T. E. , Atom Transfer Radical Polymerization from Nanoparticles:?? A Tool for the Preparation of Well-Defined Hybrid Nanostructures and for Understanding the Chemistry of Controlled/???Living??? Radical Polymerizations from Surfaces, Journal of the American Chemical Society, vol.123, issue.31, pp.7497-7505, 2001.
DOI : 10.1021/ja010235q

K. Matyjaszewski, P. J. Miller, and N. Shukla, Polymers at Interfaces:?? Using Atom Transfer Radical Polymerization in the Controlled Growth of Homopolymers and Block Copolymers from Silicon Surfaces in the Absence of Untethered Sacrificial Initiator, Macromolecules, vol.32, issue.26, pp.8716-8724, 1999.
DOI : 10.1021/ma991146p

E. Harrak, A. Carrot, G. Oberdisse, and J. , Surface???Atom Transfer Radical Polymerization from Silica Nanoparticles with Controlled Colloidal Stability, Macromolecules, vol.37, issue.17, pp.6376-6384, 2004.
DOI : 10.1021/ma035959w

S. G. Boyes, A. M. Granville, and M. Baum, Polymer brushes??????surface immobilized polymers, Surface Science, vol.570, issue.1-2, pp.1-12, 2004.
DOI : 10.1016/j.susc.2004.06.193

A. M. Granville, S. G. Boyes, and B. Akgun, Synthesis and Characterization of Stimuli-Responsive Semifluorinated Polymer Brushes Prepared by Atom Transfer Radical Polymerization, Macromolecules, vol.37, issue.8, pp.2790-2796, 2004.
DOI : 10.1021/ma035915n

Z. Bao, M. L. Bruening, and G. L. Baker, Rapid Growth of Polymer Brushes from Immobilized Initiators, Journal of the American Chemical Society, vol.128, issue.28, pp.9056-9060, 2006.
DOI : 10.1021/ja058743d

Z. Lei and S. Bi, Preparation of polymer nanocomposites of core???shell structure via surface-initiated atom transfer radical polymerizations, Materials Letters, vol.61, issue.16, pp.3531-3534, 2007.
DOI : 10.1016/j.matlet.2006.11.120

C. Chen, B. Ko, and S. Lin, Hydrophilic polymer supports grafted by poly(ethylene glycol) derivatives via atom transfer radical polymerization, Polymer, vol.47, issue.19, pp.6630-6635, 2006.
DOI : 10.1016/j.polymer.2006.07.012

W. Feng, J. Brash, and S. Zhu, Atom-transfer radical grafting polymerization of 2-methacryloyloxyethyl phosphorylcholine from silicon wafer surfaces, Journal of Polymer Science Part A: Polymer Chemistry, vol.42, issue.12, pp.2931-2942, 2004.
DOI : 10.1002/pola.20095

P. Liu, Y. Liu, and . Su, Modification of Poly(hydroethyl acrylate)-Grafted Cross-linked Poly(vinyl chloride) Particles via Surface-Initiated Atom-Transfer Radical Polymerization (SI-ATRP). Competitive Adsorption of Some Heavy Metal Ions on Modified Polymers, Industrial & Engineering Chemistry Research, vol.45, issue.7, pp.2255-2260, 2006.
DOI : 10.1021/ie051247d

C. Xu, T. Wu, and Y. Mei, Synthesis and Characterization of Tapered Copolymer Brushes via Surface-Initiated Atom Transfer Radical Copolymerization, Langmuir, vol.21, issue.24, pp.11136-11140, 2005.
DOI : 10.1021/la051853d

S. Yamamoto, M. Ejaz, and Y. Tsujii, Surface Interaction Forces of Well-Defined, High-Density Polymer Brushes Studied by Atomic Force Microscopy. 2. Effect of Graft Density, Macromolecules, vol.33, issue.15, pp.5608-5612, 2000.
DOI : 10.1021/ma991988o

F. J. Xu, Q. J. Cai, and E. T. Kang, ???Cl) Moieties of Glass and Oriented Single Crystal Silicon Surfaces, Macromolecules, vol.38, issue.4, pp.1051-1054, 2005.
DOI : 10.1021/ma0477605

K. Ohno, T. Morinaga, and K. Koh, Synthesis of Monodisperse Silica Particles Coated with Well-Defined, High-Density Polymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization, Macromolecules, vol.38, issue.6, pp.2137-3142, 2005.
DOI : 10.1021/ma048011q

M. Zhang, L. Liu, and H. Zhao, Double-responsive polymer brushes on the surface of colloid particles, Journal of Colloid and Interface Science, vol.301, issue.1, pp.85-91, 2006.
DOI : 10.1016/j.jcis.2006.05.004

X. Chen and S. P. Armes, Surface Polymerization of Hydrophilic Methacrylates from Ultrafine Silica Sols in Protic Media at Ambient Temperature: A Novel Approach to Surface Functionalization Using a Polyelectrolytic Macroinitiator, Advanced Materials, vol.15, issue.18, pp.1558-1562, 2003.
DOI : 10.1002/adma.200305067

X. P. Chen, R. D. Perruchot, and C. , Synthesis and aqueous solution properties of polyelectrolyte-grafted silica particles prepared by surface-initiated atom transfer radical polymerization, Journal of Colloid and Interface Science, vol.257, issue.1, pp.56-64, 2003.
DOI : 10.1016/S0021-9797(02)00014-0

C. Perruchot, A. Khan, and A. Kamitsi, Synthesis of Well-Defined, Polymer-Grafted Silica Particles by Aqueous ATRP, Langmuir, vol.17, issue.15, pp.4479-4481, 2001.
DOI : 10.1021/la0102758

Y. Wang, X. Pei, and X. He, Synthesis of well-defined, polymer-grafted silica nanoparticles via reverse ATRP, European Polymer Journal, vol.41, issue.6, pp.1326-1332, 2005.
DOI : 10.1016/j.eurpolymj.2004.12.010

Y. Wang, X. Pei, and K. Yuan, Reverse ATRP grafting from silica surface to prepare well-defined organic/inorganic hybrid nanocomposite, Materials Letters, vol.59, issue.4, pp.520-523, 2005.
DOI : 10.1016/j.matlet.2004.10.040

K. R. Yoon, Y. S. Chi, and K. Lee, Surface-initiated, ring-opening polymerization of p-dioxanone from gold and silicon oxide surfaces, Journal of Materials Chemistry, vol.13, issue.12, pp.2910-2914, 2003.
DOI : 10.1039/b305903k

K. R. Yoon, K. Lee, and Y. S. Chi, Surface-Initiated, Enzymatic Polymerization of Biodegradable Polyesters, Advanced Materials, vol.15, issue.24, pp.2063-2066, 2003.
DOI : 10.1002/adma.200305562

R. Zirbs, W. Binder, and M. Gahleitner, ???Grafting From??? -Living Cationic Polymerization of Poly(isobutylene) from Silica-Nanoparticle Surfaces, Macromolecular Symposia, vol.28, issue.1, pp.93-96, 2007.
DOI : 10.1002/masy.200750814

Q. Zhou, S. Wang, and X. Fan, Living Anionic Surface-Initiated Polymerization (LASIP) of a Polymer on Silica Nanoparticles, Langmuir, vol.18, issue.8, pp.3324-3331, 2002.
DOI : 10.1021/la015670c

K. V. Bernaerts and F. Du-prez, Dual/heterofunctional initiators for the combination of mechanistically distinct polymerization techniques, Progress in Polymer Science, vol.31, issue.8, pp.671-722, 2006.
DOI : 10.1016/j.progpolymsci.2006.08.007

D. Li, X. Sheng, and B. Zhao, Environmentally Responsive ???Hairy??? Nanoparticles:?? Mixed Homopolymer Brushes on Silica Nanoparticles Synthesized by Living Radical Polymerization Techniques, Journal of the American Chemical Society, vol.127, issue.17, pp.6248-6256, 2005.
DOI : 10.1021/ja0422561

J. Di and D. Y. Sogah, Exfoliated Block Copolymer/Silicate Nanocomposites by One-Pot, One-Step in-Situ Living Polymerization from Silicate-Anchored Multifunctional Initiator, Macromolecules, vol.39, issue.15, pp.5052-5057, 2006.
DOI : 10.1021/ma060543e

B. S. Lee, J. K. Lee, and W. Kim, Surface-Initiated, Atom Transfer Radical Polymerization of Oligo(ethylene glycol) Methyl Ether Methacrylate and Subsequent Click Chemistry for Bioconjugation, Biomacromolecules, vol.8, issue.2, pp.744-749, 2007.
DOI : 10.1021/bm060782+

R. Ranjan and W. Brittain, Tandem RAFT Polymerization and Click Chemistry: An Efficient Approach to Surface Modification, Macromolecular Rapid Communications, vol.44, issue.21, pp.2084-2089, 2007.
DOI : 10.1002/marc.200700428

J. Huang, H. Murata, and R. R. Koepsel, Antibacterial Polypropylene via Surface-Initiated Atom Transfer Radical Polymerization, Biomacromolecules, vol.8, issue.5, pp.1396-1399, 2007.
DOI : 10.1021/bm061236j

B. Zhao, W. J. Brittain, and W. Zhou, -PMMA Brushes upon Treatment with Selective Solvents, Journal of the American Chemical Society, vol.122, issue.10, pp.2407-2408, 2000.
DOI : 10.1021/ja992465z
URL : https://hal.archives-ouvertes.fr/hal-00807197

B. Zhao and J. Brittain, -Poly(methyl methacrylate) Monolayer on a Silicate Substrate by Sequential Carbocationic Polymerization and Atom Transfer Radical Polymerization, Journal of the American Chemical Society, vol.121, issue.14, pp.3557-3558, 1999.
DOI : 10.1021/ja984428y
URL : https://hal.archives-ouvertes.fr/hal-00807197

J. Di and D. Y. Sogah, Intergallery Living Polymerization Using Silicate-Anchored Photoiniferter. A Versatile Preparatory Method for Exfoliated Silicate Nanocomposites, Macromolecules, vol.39, issue.3, pp.1020-1028, 2006.
DOI : 10.1021/ma049794i

H. Mori, D. Chan-seng, and M. Zhang, Hybrid Nanoparticles with Hyperbranched Polymer Shells via Self-Condensing Atom Transfer Radical Polymerization from Silica Surfaces, Langmuir, vol.18, issue.9, pp.3682-3693, 2002.
DOI : 10.1021/la011630x

G. Carrot, A. Harrak, and J. Jestin, Polymer grafting from 10-nm individual particles: proving control by neutron scattering, Soft Matter, vol.35, issue.12, pp.1043-1047, 2006.
DOI : 10.1039/b600749j

J. Pyun, S. Jia, and T. Kowalewski, Synthesis and Characterization of Organic/Inorganic Hybrid Nanoparticles:?? Kinetics of Surface-Initiated Atom Transfer Radical Polymerization and Morphology of Hybrid Nanoparticle Ultrathin Films, Macromolecules, vol.36, issue.14, pp.5094-5104, 2003.
DOI : 10.1021/ma034188t

E. Unsal, B. Elmas, and B. Caglayan, Preparation of an Ion-Exchange Chromatographic Support by A ???Grafting From??? Strategy Based on Atom Transfer Radical Polymerization, Analytical Chemistry, vol.78, issue.16, pp.5868-5875, 2006.
DOI : 10.1021/ac060506l

Y. Sun, X. Ding, and Z. Zheng, Surface initiated ATRP in the synthesis of iron oxide/polystyrene core/shell nanoparticles, European Polymer Journal, vol.43, issue.3, pp.762-772, 2007.
DOI : 10.1016/j.eurpolymj.2006.10.021

M. J. Mulvihill, B. J. Rupert, and A. Hochbaum, Synthesis of Bifunctional Polymer Nanotubes from Silicon Nanowire Templates via Atom Transfer Radical Polymerization, Journal of the American Chemical Society, vol.127, issue.46, pp.16040-16041, 2005.
DOI : 10.1021/ja056242m

L. Crops, travaux non publiés, 2007.

S. Marque, C. Le-mercier, and P. Tordo, Factors Influencing the C???O???Bond Homolysis of Trialkylhydroxylamines, Macromolecules, vol.33, issue.12, pp.4403-4410, 2000.
DOI : 10.1021/ma9918452

F. Ziarelli and S. Caldarelli, Solid-state NMR as an analytical tool: Quantitative aspects, Solid State Nuclear Magnetic Resonance, vol.29, issue.1-3, pp.214-218, 2006.
DOI : 10.1016/j.ssnmr.2005.08.013

S. H. Cho, M. S. Jhon, and S. H. Yuk, Temperature-induced phase transition of poly(N,N-dimethylaminoethyl methacrylate-co-acrylamide), Journal of Polymer Science Part B: Polymer Physics, vol.35, issue.4, pp.595-598, 1996.
DOI : 10.1002/(SICI)1099-0488(199703)35:4<595::AID-POLB7>3.0.CO;2-P

J. Huang, H. Murata, and R. R. Koepsel, Antibacterial Polypropylene via Surface-Initiated Atom Transfer Radical Polymerization, Biomacromolecules, vol.8, issue.5, pp.1396-1399, 2007.
DOI : 10.1021/bm061236j

M. Ma and S. Zhu, Grafting polyelectrolytes onto polyacrylamide for flocculation 1. Polymer synthesis and characterization, Colloid & Polymer Science, vol.277, issue.2-3, pp.115-122, 1999.
DOI : 10.1007/s003960050375

M. Ma and S. Zhu, Grafting polyelectrolytes onto polyacrylamide for flocculation 2. Model suspension flocculation and sludge dewatering, Colloid & Polymer Science, vol.277, issue.2-3, pp.123-129, 1999.
DOI : 10.1007/s003960050376

S. B. Lee, A. J. Russel, and K. Matyjaszewski, -Butyl Methacrylate in Aqueous Media, Biomacromolecules, vol.4, issue.5, pp.1386-1393, 2003.
DOI : 10.1021/bm034126a
URL : https://hal.archives-ouvertes.fr/hal-00857436

K. Bian and M. Cunningham, Nitroxide-mediated radical polymerization of 2-(dimethylamino)ethyl acrylate and its sequential block copolymerization with styrene andN-butyl acrylate, Journal of Polymer Science Part A: Polymer Chemistry, vol.35, issue.1, pp.414-426, 2005.
DOI : 10.1002/pola.21147

P. Van-de-weterring, N. J. Zuidam, and M. J. Van-steenbergen, A Mechanistic Study of the Hydrolytic Stability of Poly(2-(dimethylamino)ethyl methacrylate), Macromolecules, vol.31, issue.23, pp.8063-8068, 1998.
DOI : 10.1021/ma980689g

A. Kajiwara and K. Matyjaszewski, EPR study of the atom transfer radical polymerization (ATRP) of (meth)acrylates, Macromolecular Rapid Communications, vol.19, issue.6, pp.319-321, 1998.
DOI : 10.1002/(SICI)1521-3927(19980601)19:6<319::AID-MARC319>3.0.CO;2-C

B. Charleux, J. Nicolas, and O. Guerret, Theoretical Expression of the Average Activation???Deactivation Equilibrium Constant in Controlled/Living Free-Radical Copolymerization Operating via Reversible Termination. Application to a Strongly Improved Control in Nitroxide-Mediated Polymerization of Methyl Methacrylate, Macromolecules, vol.38, issue.13, pp.5485-5492, 2005.
DOI : 10.1021/ma050087e

D. Bertin, D. Gigmes, and S. R. Marque, Polar, Steric, and Stabilization Effects in Alkoxyamines C???ON Bond Homolysis:?? A Multiparameter Analysis, Macromolecules, vol.38, issue.7, pp.2638-2650, 2005.
DOI : 10.1021/ma050004u

H. Fischer, A. Kramer, and S. R. Marque, Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C???ON Bond Homolysis Rate Constant, Macromolecules, vol.38, issue.24, pp.9974-9984, 2005.
DOI : 10.1021/ma0512612

W. A. Braunecker and K. Matyjaszewski, Controlled/living radical polymerization: Features, developments, and perspectives, Progress in Polymer Science, vol.32, issue.1, pp.93-146, 2007.
DOI : 10.1016/j.progpolymsci.2006.11.002

M. Sahnoun, M. Charreyre, and L. Veron, Synthetic and characterization aspects of dimethylaminoethyl methacrylate reversible addition fragmentation chain transfer (RAFT) polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.150, issue.16, pp.3551-3565, 2005.
DOI : 10.1002/pola.20813

R. Nicolay, L. Marx, and P. Hémery, Synthesis and Evaluation of a Functional, Water- and Organo-Soluble Nitroxide for ???Living??? Free Radical Polymerization, Macromolecules, vol.40, issue.17, pp.6067-6075, 2007.
DOI : 10.1021/ma071282r

P. Debye, Molecular-weight Determination by Light Scattering., The Journal of Physical and Colloid Chemistry, vol.51, issue.1, pp.18-32, 1947.
DOI : 10.1021/j150451a002

P. T. Lindner and Z. , Neutrons, X-Ray and Light Scattering Methods Applied to Soft Condensed Matter, 2002.

B. H. Zimm and W. H. Stockmayer, The Dimensions of Chain Molecules Containing Branches and Rings, The Journal of Chemical Physics, vol.17, issue.12, pp.1301-1314, 1949.
DOI : 10.1063/1.1747157

H. Benoit, On the effect of branching and polydispersity on the angular distribution of the light scattered by gaussian coils, Journal of Polymer Science, vol.11, issue.5, pp.507-510, 1953.
DOI : 10.1002/pol.1953.120110512