A. E. Garcia-bennett, K. Miyasaka, O. Terasaki, and S. N. Che, Structural Solution of Mesocaged Material AMS-8, Chemistry of Materials, vol.16, issue.19, p.3597, 2004.
DOI : 10.1021/cm049398e

M. Kaneda, T. Tsubakiyama, A. Carlsson, Y. Sakamoto, T. Ohsuna et al., Structural Study of Mesoporous MCM-48 and Carbon Networks Synthesized in the Spaces of MCM-48 by Electron Crystallography, The Journal of Physical Chemistry B, vol.106, issue.6, p.1256, 2002.
DOI : 10.1021/jp0131875

T. Yu, H. Zhang, X. W. Yan, Z. X. Chen, X. D. Zou et al., Pore Structures of Ordered Large Cage-Type Mesoporous Silica FDU-12s, The Journal of Physical Chemistry B, vol.110, issue.43, p.21467, 2006.
DOI : 10.1021/jp064534j

F. Monnier, Q. Schüth, D. Huo, D. Kumar, R. S. Margolese et al., Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures, Science, vol.261, issue.5126, p.1299, 1993.
DOI : 10.1126/science.261.5126.1299

). A. Firouzi, D. Kumar, L. M. Bull, T. Besier, P. Sieger et al., Cooperative organization of inorganic-surfactant and biomimetic assemblies, Science, vol.267, issue.5201, p.1138, 1995.
DOI : 10.1126/science.7855591

). A. Firouzi, F. Atef, A. G. Oertli, G. D. Stucky, B. F. Chmelka et al., Alkaline Lyotropic Silicate???Surfactant Liquid Crystals, Journal of the American Chemical Society, vol.119, issue.15, pp.3596-3620, 1995.
DOI : 10.1021/ja963007i

Q. S. Huo, D. I. Margolese, and G. D. Stucky, Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials, Chemistry of Materials, vol.8, issue.5, p.1147, 1996.
DOI : 10.1021/cm960137h

). Q. Huo, D. I. Margolese, U. Ciesla, P. Feng, T. E. Gier et al., Generalized synthesis of periodic surfactant/inorganic composite materials, Nature, vol.368, issue.6469, p.317, 1994.
DOI : 10.1038/368317a0

K. J. Edler, P. A. Reynolds, J. W. White, D. Cookson, K. J. Edler et al., Faraday Trans, J. Chem. Soc. J. Phys. Chem. B Chem. Mater. J. Phys. Chem. C J. Am. Chem. Soc. J. Am. Chem. Soc, vol.102, issue.123, pp.3676-3710, 1021.

C. H. Ryoo, M. Ko, V. Kruk, M. Antochshuk, and . Jaroniec, Block-Copolymer-Templated Ordered Mesoporous Silica:?? Array of Uniform Mesopores or Mesopore???Micropore Network?, The Journal of Physical Chemistry B, vol.104, issue.48, p.11465, 2000.
DOI : 10.1021/jp002597a

A. Sayari, M. Kruk, M. Jaroniec, and I. L. Moudrakovski, New Approaches to Pore Size Engineering of Mesoporous Silicates, Advanced Materials, vol.10, issue.16, p.1376, 1998.
DOI : 10.1002/(SICI)1521-4095(199811)10:16<1376::AID-ADMA1376>3.0.CO;2-B

A. Sayari, P. Liu, M. Kruk, and M. Jaroniec, Characterization of Large-Pore MCM-41 Molecular Sieves Obtained via Hydrothermal Restructuring, Chemistry of Materials, vol.9, issue.11, p.2499, 1997.
DOI : 10.1021/cm970128o

A. Corma, Q. Kan, M. T. Navarro, J. Perez-pariente, F. Rey et al., Synthesis of MCM-41 with Different Pore Diameters without Addition of Auxiliary Organics, Chemistry of Materials, vol.9, issue.10, pp.2123-53, 1995.
DOI : 10.1021/cm970203v

S. G. Attard, J. C. Glyde, and C. G. Goltner, Liquid-crystalline phases as templates for the synthesis of mesoporous silica, Nature, vol.378, issue.6555, p.366, 1995.
DOI : 10.1038/378366a0

C. G. Goltner, S. Henke, M. C. Weissenberger, and M. Antonietti, Mesoporous Silica from Lyotropic Liquid Crystal Polymer Templates, Angewandte Chemie International Edition, vol.37, issue.5, p.613, 1998.
DOI : 10.1002/(SICI)1521-3773(19980316)37:5<613::AID-ANIE613>3.0.CO;2-G

D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson et al., Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science, vol.279, issue.5350, p.548, 1998.
DOI : 10.1126/science.279.5350.548

D. Zhao, Q. Huo, J. Feng, B. F. Chmelka, G. D. Stucky et al., Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures, Journal of the American Chemical Society, vol.120, issue.24, pp.6024-948, 1997.
DOI : 10.1021/ja974025i

J. J. Warner and J. C. , Feature article (61) Anastas In Green chemistry: Theory and Practice, Phys. Chem. A P. T, vol.104, issue.8328, p.116, 1998.

C. Gerdemann, C. Eicken, and B. Krebs, The Crystal Structure of Catechol Oxidase:?? New Insight into the Function of Type-3 Copper Proteins, Accounts of Chemical Research, vol.35, issue.3, pp.183-2563, 1996.
DOI : 10.1021/ar990019a

A. Sanchez-ferrer, J. N. Rodriguez-lopez, F. Garc?a-canovas, and F. Garc?a-carmona, Tyrosinase: a comprehensive review of its mechanism, Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology, vol.1247, issue.1, pp.1-11, 1995.
DOI : 10.1016/0167-4838(94)00204-T

C. Eicken, B. Krebs, and J. C. Sacchettini, Catechol oxidase ??? structure and activity, Current Opinion in Structural Biology, vol.9, issue.6, p.677, 1999.
DOI : 10.1016/S0959-440X(99)00029-9

D. E. Wilcox, A. G. Porras, Y. T. Hwang, . Lerch-'k, M. E. Winkler et al., Substrate analog binding to the coupled binuclear copper active site in tyrosinase, Journal of the American Chemical Society, vol.107, issue.13, p.4015, 1985.
DOI : 10.1021/ja00299a043

L. M. Mirica, X. Ottenwaelder, D. P. Stack, D. P. Stack, P. Dalton-trans-comba et al., Structure and Spectroscopy of Copper???Dioxygen Complexes, Chemical Reviews, vol.104, issue.2, pp.1013-73, 1881.
DOI : 10.1021/cr020632z

M. W. Mckittrick and C. Jones, Toward Single-Site Functional MaterialsPreparation of Amine-Functionalized Surfaces Exhibiting Site-Isolated Behavior, Chemistry of Materials, vol.15, issue.5, pp.1132-2676, 2003.
DOI : 10.1021/cm020952z

M. W. Pantoliano, J. S. Valentine, and L. A. Nafie, Spectroscopic studies of copper(II) bound at the native copper site or substituted at the native zinc site of bovine erythrocuprein (superoxide dismutase), Journal of the American Chemical Society, vol.104, issue.23, pp.6310-775, 1982.
DOI : 10.1021/ja00387a027

M. Kodera, K. Katayama, Y. Tachi, K. Kano, S. Hirota et al., -Peroxodicopper(II) Complex of a Sterically Hindered Hexapyridine Dinucleating Ligand, Journal of the American Chemical Society, vol.121, issue.47, p.11006, 1999.
DOI : 10.1021/ja992295q
URL : https://hal.archives-ouvertes.fr/insu-01183192

E. Monzani, G. Battaini, A. Perotti, L. Casella, M. Gullotti et al., Mechanistic, Structural, and Spectroscopic Studies on the Catecholase Activity of a Dinuclear Copper Complex by Dioxygen, Inorganic Chemistry, vol.38, issue.23, p.5359, 1999.
DOI : 10.1021/ic990397b

A. Corma, From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis, Chemical Reviews, vol.97, issue.6, p.2373, 1997.
DOI : 10.1021/cr960406n

D. Y. Zhao, J. L. Feng, Q. S. Huo, N. Melosh, G. H. Fredrickson et al., Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science, vol.279, issue.5350, p.548, 1998.
DOI : 10.1126/science.279.5350.548

D. Y. Zhao, Q. S. Huo, J. L. Feng, B. F. Chmelka, and G. D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures, Journal of the American Chemical Society, vol.120, issue.24, p.6024, 1998.
DOI : 10.1021/ja974025i

K. J. Edler, P. A. Reynolds, and J. W. White, Small-Angle Neutron Scattering Studies on the Mesoporous Molecular Sieve MCM-41, The Journal of Physical Chemistry B, vol.102, issue.19, p.3676, 1998.
DOI : 10.1021/jp971694+

S. H. Han, J. Xu, W. G. Hou, X. M. Yu, Y. S. Wang et al., Synthesis of High-Quality MCM-48 Mesoporous Silica Using Gemini Surfactant Dimethylene-1,2-bis(dodecyldimethylammonium bromide), The Journal of Physical Chemistry B, vol.108, issue.39, pp.15043-15075, 1967.
DOI : 10.1021/jp0477093

C. F. Cheng, W. Zhou, and . Klinowski, Directing the pore dimensions in the mesoporous molecular sieve MCM-41, Chemical Physics Letters, vol.263, issue.1-2, p.247, 1996.
DOI : 10.1016/S0009-2614(96)01159-1

J. Liu, Y. S. Shin, Z. M. Nie, J. H. Chang, L. Q. Wang et al., Molecular Assembly in Ordered Mesoporosity:?? A New Class of Highly Functional Nanoscale Materials, The Journal of Physical Chemistry A, vol.104, issue.36, p.8328, 2000.
DOI : 10.1021/jp0009812

W. Z. Zhou, A. Klinowski-corma, Q. Kan, M. T. Navarro, J. Perez-pariente et al., The mechanism of channel formation in the mesoporous molecular sieve MCM-41, Moudrakovski, I. L. Adv. Mater, pp.207-251, 1997.
DOI : 10.1016/S0009-2614(98)00606-X

A. Galarneau, D. Desplantier, R. Dutartre, and F. Di-renzo, Micelle-templated silicates as a test bed for methods of mesopore size evaluation, Microporous and Mesoporous Materials, vol.27, issue.2-3, p.297, 1999.
DOI : 10.1016/S1387-1811(98)00263-7
URL : https://hal.archives-ouvertes.fr/hal-00172394

B. Lefèvre, A. Galarneau, J. Iapichella, C. Petitto, F. Di-renzo et al., Synthesis of Large-Pore Mesostructured Micelle-Templated Silicas as Discrete Spheres, Chemistry of Materials, vol.17, issue.3, p.601, 2005.
DOI : 10.1021/cm048481z

X. S. Zhao, G. Q. Lu, A. K. Whittaker, G. J. Millar, H. Y. Zhu et al., Faraday Trans, J. Phys. Chem. B J. Chem. Soc, vol.101, issue.652550, p.92, 1985.

F. Rouquerol, J. Rouquerol, and K. Sing, Adsorption by powders &porous solids: principles, methodology and applications, 1999.

Q. S. Zheng, Y. Yu, and . Zhao, Effects of Hydraulic Pressure on the Stability and Transition of Wetting Modes of Superhydrophobic Surfaces, Langmuir, vol.21, issue.26, p.12207, 2005.
DOI : 10.1021/la052054y

M. Ogura, H. Miyoshi, S. P. Naik, and T. Okubo, Investigation on the Drying Induced Phase Transformation of Mesoporous Silica; A Comprehensive Understanding toward Mesophase Determination, Journal of the American Chemical Society, vol.126, issue.35, p.10937, 2004.
DOI : 10.1021/ja047785j

Z. Zhang, Y. Han, F. Xiao, and D. Zhao, Mesoporous Aluminosilicates with Ordered Hexagonal Structure, Strong Acidity, and Extraordinary Hydrothermal Stability at High Temperatures, Journal of the American Chemical Society, vol.123, issue.21, p.5014, 2001.
DOI : 10.1021/ja004138t

Y. Liu, W. Z. Zhang, and T. J. Pinnavaia, Steam-Stable Aluminosilicate Mesostructures Assembled from Zeolite Type Y Seeds, Journal of the American Chemical Society, vol.122, issue.36, p.8791, 2000.
DOI : 10.1021/ja001615z

C. S. Cundy and P. A. Cox, The Hydrothermal Synthesis of Zeolites:?? History and Development from the Earliest Days to the Present Time, Chemical Reviews, vol.103, issue.3, p.663, 2003.
DOI : 10.1021/cr020060i

M. Choi, H. S. Cho, R. Srivastava, C. Venkatesan, D. H. Choi et al., Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity, Nature Materials, vol.73, issue.9, p.718, 2006.
DOI : 10.1038/nmat1705

S. C. Christiansen, D. Y. Zhao, M. T. Janicke, C. C. Landry, G. D. Stucky et al., Molecularly Ordered Inorganic Frameworks in Layered Silicate Surfactant Mesophases, Journal of the American Chemical Society, vol.123, issue.19, p.4519, 2001.
DOI : 10.1021/ja004310t

V. P. Naik, A. S. Chiang, R. W. Thompson, and F. C. Huang, Formation of Silicalite-1 Hollow Spheres by the Self-assembly of Nanocrystals, Chemistry of Materials, vol.15, issue.3, p.787, 2003.
DOI : 10.1021/cm020786v

C. E. Kirschhock, R. Ravishankar, F. Verspeurt, P. J. Grobet, P. A. Jacobs et al., O System???, The Journal of Physical Chemistry B, vol.106, issue.12, p.3333, 2002.
DOI : 10.1021/jp0146521

A. Corma, Q. Kan, M. T. Navarro, J. Perez-pariente, and F. Rey, Synthesis of MCM-41 with Different Pore Diameters without Addition of Auxiliary Organics, Chemistry of Materials, vol.9, issue.10, pp.2123-1147, 1996.
DOI : 10.1021/cm970203v

S. Li and Y. Yan, -Oriented Pure Silica Zeolite MFI Film, Journal of the American Chemical Society, vol.126, issue.34, pp.10732-234, 2004.
DOI : 10.1021/ja0478429
URL : https://hal.archives-ouvertes.fr/tel-00807841

T. P. Mabande, S. Ghosh, and . Lai, -Oriented MFI Films on Porous Stainless Steel Substrates, Industrial & Engineering Chemistry Research, vol.44, issue.24, p.9086, 2005.
DOI : 10.1021/ie050668s

P. Phiriyawirut, R. Magaraphan, A. M. Jamieson, S. Wongkasemjit, and . Micropor, Morphology study of MFI zeolite synthesized directly from silatrane and alumatrane via the sol???gel process and microwave heating, Microporous and Mesoporous Materials, vol.64, issue.1-3, p.83, 2003.
DOI : 10.1016/S1387-1811(03)00502-X

L. M. Mirica, X. Ottenwaelder, and D. P. Stack, Structure and Spectroscopy of Copper???Dioxygen Complexes, 16) Solomon, pp.1013-96, 1996.
DOI : 10.1021/cr020632z

S. Pandiarajan, M. Umadevi, R. K. Rajaram, and V. Ramakrishnan, Infrared and Raman spectroscopic studies of l-valine l-valinium perchlorate monohydrate, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol.62, issue.1-3, p.630, 2005.
DOI : 10.1016/j.saa.2005.02.008

J. A. Welleman, F. B. Hulsbergen, J. Verbiest, J. J. Reedijk, and . Inorg, (27) Reedijk, Nucl. Chem. J. Transition Met. Chem, vol.40, issue.26, p.143, 1978.

J. Gouteron, S. Jeannin, Y. Jeannin, J. Livage, and C. Sanchez, X-ray, ESR and optical absorption studies of tetrakis(cyclohexylamine)copper(II) nitrate: an example of a flattened-tetrahedral copper(II) complex, Inorganic Chemistry, vol.23, issue.21, p.3387, 1984.
DOI : 10.1021/ic00189a024

A. W. Addison, M. Carpenter, L. K. Lau, ?. M. Wicholas, and M. , Coordination sphere flexibility at copper: chemistry of a unipositive copper(II) macrocycle, [Cu(cyclops)]+, Inorganic Chemistry, vol.17, issue.6, pp.1545-775, 1978.
DOI : 10.1021/ic50184a032

G. S. Eaton, S. S. Eaton, L. J. Berliner, and J. Reuben, In biological Magnetic Resonance, Eds, vol.8, p.339, 1987.

G. A. Van-albada, M. G. Van-der-horst, I. Mutikainen, U. Turpeinen, and J. Reedijk, An alternating chain consisting of dinuclear Cu(II) ions bridged by end-on bis(??-dicyanamido-??N1,N5) ligands and hydrogen-bonded pairs of bis(pyrimidin-2-yl)amines, with unusually long Cu???Cu distances of 7.20 and 9.99??: Synthesis, structure and magnetic properties of [Cu(dipm)(??-dca)(H2O)(ClO4)]2??2EtOH, Inorganic Chemistry Communications, vol.10, issue.9, p.1014, 2007.
DOI : 10.1016/j.inoche.2007.05.018

T. Hermann, P. Augffinger, W. G. Scott, and E. Westhof, Evidence for a hydroxide ion bridging two magnesium ions at the active site of the hammerhead ribozyme, Nucleic Acids Research, vol.25, issue.17, p.3421, 1997.
DOI : 10.1093/nar/25.17.3421

P. Comba, L. R. Gahan, G. Haberhauer, G. R. Hanson, C. J. Noble et al., Copper(II) Coordination Chemistry of Westiellamide and Its Imidazole, Oxazole, and Thiazole Analogues, Chemistry - A European Journal, vol.56, issue.14, p.4393, 2008.
DOI : 10.1002/chem.200701778