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tétrakis (trifluorophosphine) diiridium (I)) a été synthétisé pour la première fois par Ce complexe de couleur bleu foncé est volatil et très sensible à l'air. L'analyse de la structure moléculaire du complexe a montré qu'il est dimèrique avec des ponts chlorure (figure 4.1) [32] . Les deux plans IrCl 2 font un angle dièdre de 107° dont résulte une interaction intramoléculaire Ir?Ir importante (la distance Ir-Ir est de 2.941 Å) La minimisation des contacts F?Cl intramoléculaires force l'ion Ir à sortir de son plan de coordination de 0.20 Å. De plus, les atomes d'iridium sont positionnés en zig-zag et la distance Ir-Ir intermoléculaire est de 3, 3.1 Introduction [IrCl(PF 3 ) 2 ] 2) Å. La structure dinucléaire est similaire à celle observée pour deux produits à base de rhodium : [RhCl(PF 3 ) 2 ] 2 [33] et [RhCl(CO) 2 ] 2 [34] . Toutefois, les interactions Rh?Rh intra-et intermoléculaires, dans ces produits ,
PF 3 ) 2 ] 2 par exemple, les distances Rh-Rh intra-et intermoléculaire sont respectivement de 2.9709(5)Å et 3.37Å. La plus faible interaction intermoléculaire explique l'apparence physique très différente du complexe par rapport au voisin d'iridium : le complexe de rhodium est en couleur rouge tandis que, RhClIrCl ,
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