.. Typologie-des-rhéogrammes-obtenus, 139 4.2.1 Identification des phases 139 4.2.2 Impact de la concentration et de la saturation sur les rhéogrammes, p.142

S. Thixotropie-des and .. De-la-contrainte, 155 4.5.1 Effet du temps d'établissement

C. Les, Toutefois, 8 des 12 bentonites ont des CEC comprises entre 66 et 76 meq/100g. Seules Ca-sm et Na-sm ont des CEC nettement supérieures (de l'ordre de 100 meq/100g, Ca 1 et Ca + 2 ont des CEC très faibles

C. Les and . Bentonites, tout comme leurs surfaces spécifiques, sont fonction de la quantité de smectite dans la bentonite. En effet, pour une même masse, une bentonite contenant de nombreux minéraux non argileux (à surface spécifique très faible) aura une surface active globale plus

. Ainsi, les échantillons de Ca-sm et Na-sm, enrichis en smectite, ont une forte CEC. A l'inverse Ca 1 et Ca + 2 ont une très faible CEC

. Ainsi, Ca-sm, associé en tactoïdes, a une forte CEC mais une faible surface spécifique (469 m 2 /g) tandis que la surface spécifique de Na-sm est très importante

D. La-partie and . De-la-courbe, Herschel Bulkley (Fig. 5.10) Na-sm forme les suspensions les plus visqueuses, les plus rhéofluidifiantes et avec les seuils les plus marqués. Seules les suspensions de Na 1 présentent également des seuils d'écoulement importants. Les aires de thixotropie, calculées par la méthode des trapèzes

. Fig, 23 ? Distribution granulométrique obtenue par granulométrie laser pour des bentonites calciques et sodiques naturelles après deux heures (2 h), une journée (1 j)

. Fig, 26 ? Rhéogrammes en contrainte imposée (essai 2) obtenus pour des suspensions de bentonites sodiques naturelles à diverses concentrations (60, 80 et 100 g/l)

]. S. Références, G. Abend, and . Lagaly, Sol?gel transitions of sodium montmorillonite dispersions, Applied Clay Science, vol.16, issue.1, pp.201-227, 2000.

C. Aguzzi, P. Cerezo, C. Viseras, and C. Caramella, Use of clays as drug delivery systems: Possibilities and limitations, Applied Clay Science, vol.36, issue.1-3, pp.22-36, 2007.
DOI : 10.1016/j.clay.2006.06.015

T. Allen, Particle Size Measurement. 5 e edition, 1990.

O. Altin, H. Ö. Özbelge, and T. Dogu, Effect of pH in an Aqueous Medium on the Surface Area, Pore Size Distribution, Density, and Porosity of Montmorillonite, Journal of Colloid and Interface Science, vol.217, issue.1, pp.19-27, 1999.
DOI : 10.1006/jcis.1999.6271

H. A. Barnes, Bubbles, Drops and Particles in Non?Newtoniun Fluids, R.P. Chhabra. Boca Raton FL, p.417, 1995.

H. A. Barnes, A review of the slip (wall depletion) of polymer solutions, emulsions and particle suspensions in viscometers: its cause, character, and cure, Journal of Non-Newtonian Fluid Mechanics, vol.56, issue.3, pp.221-244, 1995.
DOI : 10.1016/0377-0257(94)01282-M

H. A. Barnes, Thixotropy???a review, Journal of Non-Newtonian Fluid Mechanics, vol.70, issue.1-2, pp.1-33, 1997.
DOI : 10.1016/S0377-0257(97)00004-9

H. A. Barnes, The yield stress???a review or ????????????? ????????????everything flows?, Journal of Non-Newtonian Fluid Mechanics, vol.81, issue.1-2, pp.133-178, 1999.
DOI : 10.1016/S0377-0257(98)00094-9

H. A. Barnes and K. Walters, The yield stress myth?, Rheologica Acta, vol.4, issue.4, pp.323-326, 1995.
DOI : 10.1007/BF01333960

A. Bauer and G. Berger, Kaolinite and smectite dissolution rate in high molar KOH solutions at 35?? and 80??C, Applied Geochemistry, vol.13, issue.7, pp.905-916, 1998.
DOI : 10.1016/S0883-2927(98)00018-3

N. Benna, N. Kbir-ariguib, A. Magnin, and F. Bergaya, Effect of pH on Rheological Properties of Purified Sodium Bentonite Suspensions, Journal of Colloid and Interface Science, vol.218, issue.2, pp.442-455, 1999.
DOI : 10.1006/jcis.1999.6420

F. Bergaya and G. Lagaly, Surface modification of clay minerals, Applied Clay Science, vol.19, issue.1-6, pp.1-3, 2001.
DOI : 10.1016/S0169-1317(01)00063-1

A. Besq, Ecoulements laminaires de suspensions de bentonites industrielles. Caractérisation rhéométriques, Ecoulements en conduites axisymétriques. Application aux activités du Génie Civil, 2000.

A. Besq, C. Malfoy, A. Pantet, P. Monnet, and D. Righi, Physicochemical characterisation and flow properties of some bentonite muds, Applied Clay Science, vol.23, issue.5-6, pp.275-286, 2003.
DOI : 10.1016/S0169-1317(03)00127-3

A. V. Blackmore and R. D. Miller, Tactoid size and osmotic swelling in calcium montmorillonite, pp.169-173, 1961.

A. Bogner, Le mode d'imagerie wet-STEM : développement, optimisation et compréhension . Application aux émulsions et latex, 2006.

A. Bogner, G. Thollet, D. Basset, P. Jouneau, and C. Gauthier, Wet STEM: A new development in environmental SEM for imaging nano-objects included in a liquid phase, Ultramicroscopy, vol.104, issue.3-4, pp.290-301, 2005.
DOI : 10.1016/j.ultramic.2005.05.005

URL : https://hal.archives-ouvertes.fr/hal-00436771

U. Brandenburg and G. Lagaly, Rheological properties of sodium montmorillonite dispersions, Applied Clay Science, vol.3, issue.3, pp.263-279, 1988.
DOI : 10.1016/0169-1317(88)90033-6

G. W. Brindley and G. Brown, Cristal structures of clay minerals and their X?Ray identification, 1980.

A. Cadene, S. Durand-vidal, P. Turqa, J. Brendle, and J. A. Chermak, Study of individual Na-montmorillonite particles size, morphology, and apparent charge, Journal of Colloid and Interface Science, vol.285, issue.2, pp.719-730, 2005.
DOI : 10.1016/j.jcis.2004.12.016

URL : https://hal.archives-ouvertes.fr/hal-00167105

L. Calarge, A. Pantet, and P. Monnet, R??ponses m??caniques d'une suspension de bentonite activ??e, Revue Europ??enne de G??nie Civil, vol.217, issue.1
DOI : 10.1346/CCMN.1994.0420211

I. C. Callaghan and R. H. Ottewill, Interparticle forces in montmorillonite gels, Faraday Discussions of the Chemical Society, vol.57, pp.110-118, 1974.
DOI : 10.1039/dc9745700110

H. Chamayou and J. P. Legros, Les bases physiques, chimiques et minéralogiques de la science du sol. 68-70, 1989.

P. R. Cheeke, Applied animal nutrition : feeds and feeding. Macmillan publishing, 1991.

J. S. Chen, J. H. Cushman, and P. F. Low, Rheological Behavior of Na-Montmorillonite Suspensions at Low Electrolyte Concentration, Clays and Clay Minerals, vol.38, issue.1, pp.57-62, 1990.
DOI : 10.1346/CCMN.1990.0380108

D. Cheng, Yield stress: A time-dependent property and how to measure it, Rheologica Acta, vol.14, issue.5, pp.542-554, 1986.
DOI : 10.1007/BF01774406

F. Claret, Caractérisation structurale des transitions minéralogiques dans les formations argileuses : Contrôles et implications géochimiques des processus d'illitisation, 2001.

J. E. Cook, J. M. Wilkinson, and M. K. Woolford, Effects of addition of sodium bentonite to unwilted grass on the flow of effluent from silo and on nutritive value of silage for sheep, Animal Production, vol.30, p.467, 1980.

P. Coussot, Rhéologie des boues et laves torrentielles Etude de dispersions et suspensions concentrées, Etudes du CEMAGREF

P. Coussot, Rheometry of pastes, suspensions, and granular mateerials. Applications in industry and environment, 2005.

P. Coussot, Q. D. Nguyen, H. T. Huynh, and D. Bonn, Viscosity bifurcation in thixotropic, yielding fluids, Journal of Rheology, vol.46, issue.3, pp.573-589, 2002.
DOI : 10.1122/1.1459447

M. Ddani, A. Meunier, M. Zahraoui, D. Beaufort, M. Wartiti et al., Clay mineralogy and chemical composition of bentonites from the Gourougou volcanic massif (northeast Morocco), clays and clay minerals, vol.53, issue.3, pp.7250-267, 2005.
DOI : 10.1346/CCMN.2005.0530305

R. G. De-kretser, P. J. Scales, and D. V. Boger, Surface chemistry-rheology inter-relationships in clay suspensions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.137, issue.1-3, pp.307-318, 1998.
DOI : 10.1016/S0927-7757(97)00372-5

F. and D. Larrard, Structures granulaires et formulation des bétons, Laboratoire central des ponts et chaussées, centre de Nantes, 2000.

G. Français-de-rhéologie, Dictionnaire de rhéologie, volume 56 p. Groupe français de rhéologie edition, 1990.

B. Derjaguin and L. Landau, Theory of the stability of strongly charged lyophobic sols and of the adhesion of strongly charged particles in solutions of electrolytes, Progress in Surface Science, vol.43, issue.1-4, pp.633-62, 1941.
DOI : 10.1016/0079-6816(93)90013-L

C. Français and . Géosynthétiques, Recommandations générales pour la réalisation d'étanchéité par géosynthétiques bentonitiques, Comité Français des Géosynthétiques, vol.12, 1998.

G. Didier and L. Comeaga, Hydratation, gonflement, conductivité hydraulique Influence de produits chimiques, Actes du congrès Géo?Bento, étanchéité par géosynthétiques bentonitiques : état de l'art, pp.74-95, 1998.

R. Dohrmann, Cation exchange capacity methodology I: An efficient model for the detection of incorrect cation exchange capacity and exchangeable cation results, Applied Clay Science, vol.34, issue.1-4, pp.31-37, 2006.
DOI : 10.1016/j.clay.2005.12.006

J. Drappier, Plateaux de contrainte et bandes de cisaillement dans les fluides complexes, Ecole normale supérieure laboratoire de physique statistique, 2004.
URL : https://hal.archives-ouvertes.fr/tel-00005909

J. D. Duràn, M. M. Ramos-tejada, F. J. Arroyo, and F. Gonzàlez-caballero, Rheological and Electrokinetic Properties of Sodium Montmorillonite Suspensions, Journal of Colloid and Interface Science, vol.229, issue.1, pp.107-117, 2000.
DOI : 10.1006/jcis.2000.6956

J. Duval, Utilisation de la bentonite et autres argiles en alimentation animale, Projet pour une agriculture écologique, 1993.

D. G. Edwards, A. M. Posner, and J. P. Quirk, Repulsion of chloride ions by negatively charged clay surfaces. Part 2.???Monovalent cation montmorillonites, Trans. Faraday Soc., vol.61, issue.0, pp.2816-2819, 1965.
DOI : 10.1039/TF9656102816

A. Einstein, Investigations on Theory of Brownian Movement, 1926.

E. Eslinger and D. Peaver, Clay minerals for petroleum geologists and engineers, Society of Economic Paleontologists and Minerologists Short Course Notes, vol.22, 1988.
DOI : 10.2110/scn.88.22

R. A. Everson, N. A. Jorgensen, and G. P. Barrington, Effect of Bentonite, Nitrogen Source and Stage of Maturity on Nitrogen Redistribution in Corn Silage, Journal of Dairy Science, vol.54, issue.10, pp.1482-1490, 1971.
DOI : 10.3168/jds.S0022-0302(71)86051-4

D. Fauchadour, T. Pouget, J. Lechaire, L. Rouleau, and L. Normand, Evaluation of Cryotechniques for Tem Observation of Sols - Application to Boehmite Sols Used in Catalysts Forming, Oil & Gas Science and Technology, vol.54, issue.4, pp.513-524, 1999.
DOI : 10.2516/ogst:1999044

R. A. Fisher, Design of Experiments, BMJ, vol.1, issue.3923, 1935.
DOI : 10.1136/bmj.1.3923.554-a

H. Frenkel, J. O. Goertzen, and J. D. Rhoades, Effects of Clay Type and Content, Exchangeable Sodium Percentage, and Electrolyte Concentration on Clay Dispersion and Soil Hydraulic Conductivity1, Soil Science Society of America Journal, vol.42, issue.1, pp.32-38, 1978.
DOI : 10.2136/sssaj1978.03615995004200010008x

J. J. Fripiat, P. Cloos, and A. Poncelet, Comparaison entre les propriétés d'échange de la montmorillonite et d'une résine vis-à-vis des cations alcalins et alcalino-terreux

G. Lagaly, Colloid Clay Science, Handbook of Clay Science, pp.141-246, 2006.
DOI : 10.1016/B978-0-08-098258-8.00010-9

C. S. Gomes and J. B. Silva, Minerals and clay minerals in medical geology, Applied Clay Science, vol.36, issue.1-3, pp.4-21, 2007.
DOI : 10.1016/j.clay.2006.08.006

R. Greenwood, Review of the measurement of zeta potentials in concentrated aqueous suspensions using electroacoustics, Advances in Colloid and Interface Science, vol.106, issue.1-3, pp.55-81, 2003.
DOI : 10.1016/S0001-8686(03)00105-2

R. Greenwood, P. F. Luckham, and G. T. , The Effect of Diameter Ratio and Volume Ratio on the Viscosity of Bimodal Suspensions of Polymer Latices, Journal of Colloid and Interface Science, vol.191, issue.1, pp.11-21, 1997.
DOI : 10.1006/jcis.1997.4915

P. Grondet and L. Petit, Dynamic viscosity of macroscopic suspensions of bimodal sized solid spheres, Journal of rheology, vol.41, pp.1261-1274, 1997.

N. Guven and R. M. Pollastro, Clay?water interface and its rheological implications. CMS workshop lectures. The Clay Mineral Society, 1992.

D. Guyonnet, E. Gaucher, H. Gaboriau, C. Pons, V. Norotte et al., Relationship between hydraulic performance, microstructure and surface chemistry in GCLs in contact with leachate, International Workshop "Hydro-Physico- Mechanics of Landfills, pp.137-141, 2005.

H. C. Hamaker, The London???van der Waals attraction between spherical particles, Physica, vol.4, issue.10, pp.1058-72, 1937.
DOI : 10.1016/S0031-8914(37)80203-7

J. Harding, uk/ jhh/clays/clays.html. site internet de UCL Physics and astronomy, Condensed matter and materials physics, 2007.

H. Heller and R. Keren, Rheology of Na-Rich Montmorillonite Suspension as Affected by Electrolyte Concentration and Shear Rate, Clays and Clay Minerals, vol.49, issue.4, pp.286-291, 2001.
DOI : 10.1346/CCMN.2001.0490402

A. K. Helmy, I. M. Natale, and M. E. Mandolesi, Negative Adsorption in Clay-Water Systems with Interacting Double Layers, Clays and Clay Minerals, vol.28, issue.4, pp.286-291, 1980.
DOI : 10.1346/CCMN.1980.0280403

U. Hofmann, Geheimnisse des tons. berichte der deutschen keramischen gesellschaft, Berichte der Deutschen Keramischen Gesellschaft, vol.38, pp.201-207, 1961.

M. Janek and G. Lagaly, Proton saturation and rheological properties of smectite dispersions, Applied Clay Science, vol.19, issue.1-6, pp.121-130, 2001.
DOI : 10.1016/S0169-1317(01)00051-5

S. Jarny, Caractérisation rhéologique de boues de forage industrielles Influence de diverses pollutions, 2001.

S. Jarny, P. Monnet, and L. David, Rhéométrie locale par vélocimétrie laser, Congrès Francophone de Techniques Laser (CFTL), pp.19-22

S. Jarny, N. Roussel, S. Rodts, R. L. Roy, and P. Coussot, Rheological behavior of cement pastes from MRI velocimetry, Cement and Concrete Research, vol.35, issue.10, pp.1873-1881, 2005.
DOI : 10.1016/j.cemconres.2005.03.009

K. Jasmund and G. Lagaly, Tonminerale und Tone. Struktur, Eigenschaften, Anwendung und Einsatz in Industrie und Umwelt, 1993.

N. Jozja, Etude de matériaux argileux albanais. Caractérisation « multi?échelle » d'une bentonite magnésienne. Impact de l'interaction avec le nitrate de plomb sur la perméabilité, 2003.

R. Keren, Rheology of Aqueous Suspension of Sodium/Calcium Montmorillonite, Soil Science Society of America Journal, vol.52, issue.4, pp.924-928, 1988.
DOI : 10.2136/sssaj1988.03615995005200040004x

R. Keren, Effect of Clay Charge Density and Adsorbed Ions on the Rheology of Montmorillonite Suspension, Soil Science Society of America Journal, vol.53, issue.1, pp.25-29, 1989.
DOI : 10.2136/sssaj1989.03615995005300010005x

R. Keren and D. L. Sparks, The Role of Edge Surfaces in Flocculation of 2:1 Clay Minerals, Soil Science Society of America Journal, vol.59, issue.2, pp.430-435, 1995.
DOI : 10.2136/sssaj1995.03615995005900020023x

R. K. Khandal and T. F. Tadros, Application of viscoelastic measurements to the investigation of the swelling of sodium montmorillonite suspensions, Journal of Colloid and Interface Science, vol.125, issue.1, pp.122-128, 1988.
DOI : 10.1016/0021-9797(88)90060-4

N. Kherfellah, S. Bekkour, and K. Benhadid, Utilisation de systèmes argileux pour le colmatage des pertes de boues de forage en circulation, Rhéologie, vol.7, pp.48-54, 2005.

W. Kuhn and H. Kuhn, Die Abh??ngigkeit der Viskosit??t vom Str??mungsgef??lle bei hochverd??nnten Suspensionen und L??sungen, Helvetica Chimica Acta, vol.102, issue.1, pp.97-127, 1945.
DOI : 10.1002/hlca.19450280111

G. Lagaly, Principles of flow of kaolin and bentonite dispersions, Applied Clay Science, vol.4, issue.2, pp.105-123, 1989.
DOI : 10.1016/0169-1317(89)90003-3

G. Lagaly, M. Reese, and S. Abend, Smectites as colloidal stabilizers of emulsions, Applied Clay Science, vol.14, issue.1-3, pp.83-103, 1999.
DOI : 10.1016/S0169-1317(98)00051-9

G. Lagaly and S. Ziesmer, Colloid chemistry of clay minerals : the coagulation of montmorillonite dispersions. Colloid and Interface Science, pp.100-102, 2003.

D. Lautrin, Utilisation pratique des paramètres dérivés de l'essai au bleu de méthylène dans les projets de génie civil, 1989.

L. and L. Pluart, Nanocomposites epoxyde/amine/montmorillonite : rôle des interactions sur la formation, la morphologie aux différents niveaux d'échelle et les propriétés mécaniques des réseaux, 2002.

M. Lenoble, P. Snabre, and B. Pouligny, Resuspension visqueuse d'une boue modèle : figures de localisation de l'écoulement, 41 e colloque annuel du groupe français de rhéologie, pp.95-98, 2006.

Y. Li, J. Argillier, E. Rosenberg, and J. Durrieu, Static and dynamic filtration properties of aqueous suspensions of clays and electrolytes. Revue de l'institut français du pétrôle, pp.207-218, 1997.

R. A. Lionberger, Viscosity of bimodal and polydisperse colloidal suspensions, Physical Review E, vol.65, issue.6, p.61408, 2002.
DOI : 10.1103/PhysRevE.65.061408

P. F. Luckham and M. A. Ukeje, Effect of Particle Size Distribution on the Rheology of Dispersed Systems, Journal of Colloid and Interface Science, vol.220, issue.2, pp.347-356, 1999.
DOI : 10.1006/jcis.1999.6515

R. C. Mackenzie, A micromethod for determination of cation?exchange capacity of clay, Journal of Colloid and Interface Science, vol.6, pp.219-222, 1951.

R. C. Mackenzie, Differential thermal analysis, 1970.

C. Malfoy, Rhéophysique des suspensions colloïdales : application au mélange eauargile (smectites) Rapport de master recherche, 2000.

C. Malfoy, Influence du cation échangeable et des hétérogénéités minérales sur le comportement rhéologique de suspensions de smectite, 2003.

C. Malfoy, M. Ddani, A. Pantet, and P. Monnet, Les bentonites : transfert et échanges. Un matériau aux propriétés évolutives et variables, Actes du Colloque National sur les propriétés de transfert dans les matériaux, p.15, 2006.

L. P. Meier and R. Nüesch, The Lower Cation Exchange Capacity Limit of Montmorillonite, Journal of Colloid and Interface Science, vol.217, issue.1, pp.77-85, 1999.
DOI : 10.1006/jcis.1999.6254

J. P. Melcion, La granulométrie de l'aliment : principe, mesure et obtention, pp.81-97, 2000.

M. B. M-'ewen and M. I. Pratt, The gelation of montmorillonite. Part 1.???The formation of a structural framework in sols of Wyoming bentonite, Trans. Faraday Soc., vol.53, issue.0, pp.535-547, 1957.
DOI : 10.1039/TF9575300535

J. Mewis, Thixotropy - a general review, Journal of Non-Newtonian Fluid Mechanics, vol.6, issue.1, pp.1-20, 1979.
DOI : 10.1016/0377-0257(79)87001-9

F. Mollet, Contribution à l'étude de l'écoulement d'un fluide thixotrope (Contribution to the study of a thixotropic fluid flow), 1996.

H. G. Montes, J. Duplay, L. Martinez, Y. Gerauld, and B. Rousset-tournier, Influence of interlayer cations on the water sorption and swelling???shrinkage of MX80 bentonite, Applied Clay Science, vol.23, issue.5-6, pp.309-321, 2003.
DOI : 10.1016/S0169-1317(03)00130-3

H. G. Montes, B. Fritz, A. Clement, and N. Michau, A simplified method to evaluate the swelling capacity evolution of a bentonite barrier related to geochemical transformations, Applied Geochemistry, vol.20, issue.2, pp.409-422, 2005.
DOI : 10.1016/j.apgeochem.2004.08.009

S. and M. Mouanga, Diversité des bentonites, implication des hétérogénéités dans les argiles, 2006.

A. Mujumbar, A. Beris, and A. Metzner, Transient phenomena in thixotropic systems, Journal of Non?Newtonian Fluids Mechanics, vol.2072, pp.1-22, 2001.

F. Muller, Mémoire présenté en vue de l'obtention de L'Habilitation à Diriger des Recherches. Habilitation à diriger des recherches, 2004.

H. Murray, Clays in industry A Clay Odyssey ? 12 th International Clay Conference, 2001.

N. , N. Touze-foltz, C. Duquennoi, and E. Gaget, Hydraulic and mechanical behavior of GCLs in contact with leachate as part of a composite liner, Geotextiles and Geomembranes, vol.24, pp.188-197, 2006.

K. Norrish, The swelling of montmorillonite, Discussions of the Faraday Society, vol.18, pp.120-134, 1954.
DOI : 10.1039/df9541800120

J. D. Oster, I. Shainberg, and J. D. Wood, Flocculation Value and Gel Structure of Sodium/Calcium Montmorillonite and Illite Suspensions1, Soil Science Society of America Journal, vol.44, issue.5, pp.955-959, 1980.
DOI : 10.2136/sssaj1980.03615995004400050016x

N. Ouchiyama and T. Tanaka, Porosity of a mass of solid particles having a range of sizes, Industrial & Engineering Chemistry Fundamentals, vol.20, issue.1, pp.66-71, 1981.
DOI : 10.1021/i100001a013

T. Paillat, Contribution à l'étude des phénomènes electrocinétiques dans les milieux poreux Application au stockage géologique de déchets et à la prévention contre l'électrisation dans les transformateurs, 1998.

S. Paumier, A. Pantet, and P. Monnet, Homoionic smectite (N a + or Ca 2+ ) unit size evaluation in diluted dispersions using method crosschecking, Clays and Clay Minerals

M. Pawlick, J. S. Laskowski, and A. Ansari, Effect of carboxymethyl cellulose and ionic strength on stability of??mineral suspensions in potash ore flotation systems, Journal of Colloid and Interface Science, vol.260, issue.2, pp.251-258, 2003.
DOI : 10.1016/S0021-9797(02)00225-4

D. Penner and G. Lagaly, Influence of Organic and Inorganic Salts on the Coagulation of Montmorillonite Dispersions, Clays and Clay Minerals, vol.48, issue.2, pp.131-142, 2001.
DOI : 10.1346/CCMN.2000.0480211

T. Permien and G. Lagaly, The rheological and colloidal properties of bentonite dispersions in the presence of organic compounds IV. Sodium montmorillonite and acids, Applied Clay Science, vol.9, issue.4, pp.251-263, 1994.
DOI : 10.1016/0169-1317(94)90003-5

T. Permien and G. Lagaly, The Rheological and Colloidal Properties of Bentonite Dispersions in the Presence of Organic Compounds V. Bentonite and Sodium Montmorillonite and Surfactants, Clays and Clay Minerals, vol.43, issue.2, pp.229-236, 1995.
DOI : 10.1346/CCMN.1995.0430210

J. Perrin, Brownian movement and molecular reality, translated by F. Soddy FRS, 1910.

Y. Peysson, Solid/liquid dispersions in drilling and production. Oil and Gas Science and technology, Revue IFP, vol.59, pp.11-21, 2004.

G. Picard, Hétérogénéité de l'écoulement de fluides à seuil : approche phénoménologique et modélisation élasto?plastique, 2004.

F. Pignon, A. Magnin, and J. M. Piau, Thixotropic colloidal suspensions and flow curves with minimum: Identification of flow regimes and rheometric consequences, Journal of Rheology, vol.40, issue.4, pp.573-587, 1996.
DOI : 10.1122/1.550759

J. R. Pils, D. A. Laird, and V. P. Evangelou, Role of cation demixing and quasicrystal formation and breakup on the stability of smectitic colloids, Applied Clay Science, vol.35, issue.3-4, pp.201-211, 2007.
DOI : 10.1016/j.clay.2006.09.014

D. Quemada, Modélisation rhéologique structurelle. Dispersions concentrées et fluides complexes, 2006.

J. P. Quirk and S. Marcelja, Application of Double-Layer Theories to the Extensive Crystalline Swelling of Li-Montmorillonite, Langmuir, vol.13, issue.23, pp.6241-6248, 1997.
DOI : 10.1021/la970484l

M. Ramirez-gilly, L. P. Martinez-padilla, and O. Manero, Particle image velocimetry applied to suspensions of millimetric-size particles using a vane-in-a-large-baffled-cup rheometer, Journal of Food Engineering, vol.78, issue.4, pp.1117-1126, 2007.
DOI : 10.1016/j.jfoodeng.2005.12.046

B. Rand, E. Pekenae, J. W. Goodwin, and R. W. Smith, Investigation into the existence of edge???face coagulated structures in Na-montmorillonite suspensions, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol.76, issue.0, pp.225-235, 1980.
DOI : 10.1039/f19807600225

D. Robbe and B. Roger, Granulométrie des éléments fins par diffraction laser. présentation de la méthode, pp.13-24, 1987.

G. Roy, M. Pelletier, F. Thomas, C. Despas, and J. Bessière, Aggregation in Na-, K-, and Ca-montmorillonite dispersions, characterized by impedance spectroscopy, Clay Minerals, vol.35, issue.2, pp.335-343, 2000.
DOI : 10.1180/000985500546800

L. L. Schramm and J. C. Kwak, Influence of Exchangeable Cation Composition on the Size and Shape of Montmorillonite Particles in Dilute Suspension, Clays and Clay Minerals, vol.30, issue.1, pp.40-48, 1982.
DOI : 10.1346/CCMN.1982.0300105

C. Schultz and T. Grundl, pH Dependence of ferrous sorption onto two smectite clays, Chemosphere, vol.57, issue.10, pp.1301-1306, 2004.
DOI : 10.1016/j.chemosphere.2004.09.023

J. Schurz, The yield stress ? An empirical reality, Rheologica Acta, vol.28, issue.2, pp.170-171, 1990.
DOI : 10.1007/BF01332384

I. Shainberg and H. Otoh, Size and Shape of Montmorillonite Particles Saturated with Na/Ca Ions (Inferred from Viscosity and Optical Measurements), Israel Journal of Chemistry, vol.74, issue.3, pp.251-259, 1968.
DOI : 10.1002/ijch.196800035

R. T. Shanmuganathan and J. M. Oades, Influence of anions on dispersion and physical properties of the A horizon of a Red-brown earth, Geoderma, vol.29, issue.3, pp.257-277, 1983.
DOI : 10.1016/0016-7061(83)90091-5

J. Stawinski, J. Wierzchos, and M. T. Garcia-gonzales, Influence of Calcium and Sodium Concentration on the Microstructure of Bentonite and Kaolin, Clays and Clay Minerals, vol.38, issue.6, pp.617-622, 1990.
DOI : 10.1346/CCMN.1990.0380607

C. Su and Y. Shen, Preparation and dispersive behaviors of reduced charge smectite, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.259, issue.1-3, pp.173-177, 2005.
DOI : 10.1016/j.colsurfa.2005.02.010

. F. Th and . Tadros, Correlation of viscoelastic properties of stable and flocculated suspensions with their interparticle interactions, Advances in Colloid and Interface Science, vol.68, pp.97-200, 1996.

G. Tagushi, System of experimental design, 1987.

J. Tarchitzky and Y. Chen, Rheology of Sodium-montmorillonite suspensions, Soil Science Society of America Journal, vol.66, issue.2, pp.406-412, 2002.
DOI : 10.2136/sssaj2002.4060

F. Thomas, L. J. Michot, D. Vantelon, E. Montargès, B. Prélot et al., Layer charge and electrophoretic mobility of smectites, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.159, issue.2-3, pp.351-358, 1999.
DOI : 10.1016/S0927-7757(99)00291-5

URL : https://hal.archives-ouvertes.fr/hal-00345882

E. Tombàcz, Z. Libor, E. Illés, A. Majzik, and E. Klumpp, The role of reactive surface sites and complexation by humic acids in the interaction of clay mineral and iron oxide particles, Organic Geochemistry, vol.35, issue.3, pp.257-267, 2004.
DOI : 10.1016/j.orggeochem.2003.11.002

E. Tombàcz and M. Szekeres, Colloidal behavior of aqueous montmorillonite suspensions: the specific role of pH in the presence of indifferent electrolytes, Applied Clay Science, vol.27, issue.1-2, pp.75-94, 2004.
DOI : 10.1016/j.clay.2004.01.001

O. Touret, C. H. Pons, D. Tessier, and Y. Tardy, Etude de la Repartition de L'eau dans des Argiles Saturees Mg2+ Aux Fortes Teneurs En Eau, Clay Minerals, vol.25, issue.2, pp.217-233, 1990.
DOI : 10.1180/claymin.1990.025.2.07

P. H. Uhlherr, J. Guo, C. Tiu, X. M. Zhang, J. Z. Zhou et al., The shear-induced solid???liquid transition in yield stress materials with chemically different structures, Journal of Non-Newtonian Fluid Mechanics, vol.125, issue.2-3, pp.101-119, 2005.
DOI : 10.1016/j.jnnfm.2004.09.009

H. Vali and L. Bachmann, Ultrastructure and flow behavior of colloidal smectite dispersions, Journal of Colloid and Interface Science, vol.126, issue.1, pp.278-291, 1988.
DOI : 10.1016/0021-9797(88)90122-1

H. Van-olphen, An Introduction to Clay Colloid Chemistry, Soil Science, vol.126, issue.1, 1977.
DOI : 10.1097/00010694-197807000-00013

D. Vantelon, Répartition des cations dans la couche octaédrique des montmorillonites : Répercussions sur les propriétés colloidales, 2001.

H. A. Velasco-molina, A. R. Swoboda, and C. L. Godfrey, DISPERSION OF SOILS OF DIFFERENT MINERALOGY IN RELATION TO SODIUM ADSORPTION RATIO AND ELECTROLYTIC CONCENTRATION, Soil Science, vol.111, issue.5, pp.282-287, 1971.
DOI : 10.1097/00010694-197105000-00003

K. Verburg and P. Baveye, Hysteresis in the Binary Exchange of Cations on 2:1 Clay Minerals: A Critical Review, Clays and Clay Minerals, vol.42, issue.2, pp.207-220, 1994.
DOI : 10.1346/CCMN.1994.0420211

E. J. Verwey, J. G. Th, and . Overbeek, Theory of the Stability of Lyophobic Colloids, 1948.

H. Viallis-terrisse, Interaction des silicates de calcium hydratés, principaux constituants du ciment, avec les chlorures d'alcalins. Analogie avec les argiles, 2000.

A. Weiss and R. Franck, Über den bau des gerüst en thixotropen gelen, Naturforsch, vol.10, pp.141-143, 1961.

G. Wiegner, Ionenumtausch und struktur, Trans. 3 r d Int, pp.5-28, 1935.

M. K. Woolford, J. M. Wilkinson, and J. E. Cook, Investigations on the effect of sodium bentonite and other moisture absorbents on the production of effluent from grass silage, Animal Feed Science and Technology, vol.8, issue.2, pp.107-118, 1983.
DOI : 10.1016/0377-8401(83)90092-5

Y. Xiang, G. Villemure, and C. Detellier, Observation by scanning electron microscopy of globular particles of Ca?montmorillonite and of montmorillonite exchanged with methyl viologen or tris (bipyridyl) ruthenium (II), Clays and Clay Minerals, vol.40, pp.362-364, 1992.

N. Yildiz, Y. Sarikaya, and A. C. Alimli, The effect of the electrolyte concentration and pH on the rheological properties of the original and the Na2CO3-activated K??tahya bentonite, Applied Clay Science, vol.14, issue.5-6, pp.319-327, 1999.
DOI : 10.1016/S0169-1317(99)00006-X

H. Zhao, P. F. Low, and J. M. Bradford, EFFECTS OF pH and ELECTROLYTE CONCENTRATION ON PARTICLE INTERACTION IN THREE HOMOIONIC SODIUM SOIL CLAY SUSPENSIONS, Soil Science, vol.151, issue.3, pp.196-207, 1991.
DOI : 10.1097/00010694-199103000-00002