J. Nunzi, Organic photovoltaic materials and devices, Comptes Rendus Physique, vol.3, issue.4, pp.523-542, 2002.
DOI : 10.1016/S1631-0705(02)01335-X

S. Gunes, H. Neugebauer, and N. S. Sariciftci, Conjugated Polymer-Based Organic Solar Cells, Chemical Reviews, vol.107, issue.4, pp.1324-1338, 2007.
DOI : 10.1021/cr050149z

R. A. Janssen, J. C. Hummelen, and N. S. Sariciftci, Polymer???Fullerene Bulk Heterojunction Solar Cells, MRS Bulletin, vol.30, issue.01, pp.33-36, 2005.
DOI : 10.1002/anie.200351647

C. Brabec, V. Dyakonov, J. Parisi, and N. S. Sariciftci, Organic Photovoltaics -Concepts and Realization, Series in Materials Science, 2003.

F. Wudl, The chemical properties of buckminsterfullerene (C60) and the birth and infancy of fulleroids, Accounts of Chemical Research, vol.25, issue.3, pp.157-161, 1992.
DOI : 10.1021/ar00015a009

G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty et al., High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends, Nature Materials, vol.4, pp.864-868, 2005.
DOI : 10.1142/9789814317665_0012

W. Ma, C. Yang, X. Gong, K. Lee, and A. J. Heeger, Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology, Advanced Functional Materials, vol.75, issue.404, pp.15-1617, 2005.
DOI : 10.1002/adfm.200500211

M. Reyes-reyes, K. Kim, J. Dewald, R. Lopez-sandoval, A. Avadhanula et al., Meso-Structure Formation for Enhanced Organic Photovoltaic Cells, Organic Letters, vol.7, issue.26, pp.5749-5752, 2005.
DOI : 10.1021/ol051950y

C. W. Tang, Two???layer organic photovoltaic cell, Applied Physics Letters, vol.48, issue.2, pp.48-183, 1986.
DOI : 10.1063/1.96937

J. Rostalski and D. Meissner, Photocurrent spectroscopy for the investigation of charge carrier generation and transport mechanisms in organic p/n-junction solar cells, Solar Energy Materials and Solar Cells, vol.63, issue.1, pp.37-47, 2000.
DOI : 10.1016/S0927-0248(00)00018-0

P. Peumans and S. R. Forrest, Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells, Applied Physics Letters, vol.79, issue.1, pp.79-126, 2001.
DOI : 10.1063/1.1384001

A. K. Pandey, S. Dabos-seignon, and J. Nunzi, Pentacene: PTCDI-C13H27 molecular blends efficiently harvest light for solar cell applications Photoinduced Electron Transfer from a Conducting Polymer to Buckminsterfullerene, Appl. Phys. Lett. Science, vol.89, issue.258, pp.1474-1476, 1992.

C. J. Brabec, N. S. Sariciftci, and J. C. Hummelen, Plastic Solar Cells, Adv. Funct. Mater, issue.111, pp.15-26, 2001.

G. Yu, J. Gao, J. C. Hummelen, F. Wudl, and A. J. Heeger, polymer Photovoltaic Cells:Enhanced Efficiencies via a Network of internal Donor-Acceptor Heterojunctions, 5% efficient organic plastic solar cells, pp.1789-1791, 1995.

H. Hoppe and N. S. Sariciftci, Morphology of polymer/fullerene bulk heterojunction solar cells, J. Mater. Chem., vol.152, issue.404, pp.45-61, 2006.
DOI : 10.1039/b505361g

A. B. Holmes, Dye based donor/acceptor solar cells, Solar Energy Materials & Solar Cells, vol.61, pp.63-72, 2000.

L. Schmidt-mende, A. Fechtenkötter, K. Mullen, E. Moons, R. H. Friend et al., Self-Organized Discotic Liquid Crystals for High-Efficiency Organic Photovoltaics, Science, vol.293, issue.5532, pp.1119-1122, 2001.
DOI : 10.1126/science.293.5532.1119

G. Yu and A. J. Heeger, Charge separation and photovoltaic conversion in polymer composites with internal donor/acceptor heterojunctions, Journal of Applied Physics, vol.78, issue.7, pp.4510-4515, 1998.
DOI : 10.1063/1.359792

J. C. Hummelen, Origin of the Open Circuit Voltage of Plastic Solar Cells, Adv. Funct. Mater, issue.115, pp.374-380, 2001.

M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf et al., Design rules for donors in bulk-heterojunction solar cells -Towards 10% energy-conversion efficiency Built-in field electroabsorption spectroscopy of polymer light-emitting diodes incorporating a doped poly(3,4- ethylene dioxythiophene) hole injection layer, Adv. Mater. Appl. Phys. Lett, vol.18, issue.2312, pp.789-794, 1999.

C. J. Brabec, S. E. Shaheen, C. Winder, and N. S. Sariciftci, Effect of LiF/metal electrodes on the performance of plastic solar cells, Applied Physics Letters, vol.80, issue.7, pp.80-1288, 2002.
DOI : 10.1063/1.1446988

F. Padinger, R. S. Rittberger, and N. S. Sariciftci, Effects of Postproduction Treatment on Plastic Solar Cells, Advanced Functional Materials, vol.13, issue.1, pp.13-85, 2003.
DOI : 10.1002/adfm.200390011

W. Helfrich and W. G. Schneider, Recombination Radiation in Anthracene Crystals, Physical Review Letters, vol.14, issue.7, pp.14-229, 1965.
DOI : 10.1103/PhysRevLett.14.229

H. Shirakawa, E. J. Louis, A. G. Macdiarmid, C. H. Chiang, and A. J. Heeger, Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x, Journal of the Chemical Society, Chemical Communications, issue.16, pp.578-580, 1977.
DOI : 10.1039/c39770000578

V. Coropceanu, J. Cornil, D. A. Dasilvafilho, Y. Olivier, R. Silbey et al., Charge Transport in Organic Semiconductors, Chem. Rev, issue.4, pp.107-926, 2007.

A. R. Murphy and J. M. Frechet, Organic Semiconducting Oligomers for Use in Thin Film Transistors, Chemical Reviews, vol.107, issue.4, pp.1066-1096, 2007.
DOI : 10.1021/cr0501386

E. Bundgaard and F. C. Krebs, Low band gap polymers for organic photovoltaics, Solar Energy Materials and Solar Cells, vol.91, issue.11, pp.91-954, 2007.
DOI : 10.1016/j.solmat.2007.01.015

I. F. Perepichka, D. F. Perepichka, H. Meng, and F. Wudl, Light-Emitting Polythiophenes, Advanced Materials, vol.46, issue.112, pp.2281-2305, 2005.
DOI : 10.1002/adma.200500461

R. Demadrille, M. Firon, J. Leroy, P. Rannou, and A. Pron, Plastic Solar Cells Based on Fluorenone-Containing Oligomers and Regioregular Alternate Copolymers, Advanced Functional Materials, vol.119, issue.9, pp.1547-1552, 2005.
DOI : 10.1002/adfm.200500117

C. Shi, Y. Yao, Y. Yang, and Q. Pei, Regioregular Copolymers of 3-Alkoxythiophene and Their Photovoltaic Application, Journal of the American Chemical Society, vol.128, issue.27, pp.8990-8986, 2006.
DOI : 10.1021/ja061664x

J. Roncali, P. Blanchard, and P. Frère, (EDOT) as a versatile building block for advanced functional ?-conjugated systems, J. Mater. Chem, vol.3, issue.15, pp.4-1589, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00015751

G. Zotti, M. C. Gallazzi, G. Zerbi, and S. V. Meille, Conducting polymers from anodic coupling of some regiochemically defined dialkoxy-substituted thiophene oligomers, Synthetic Metals, vol.73, issue.3, pp.217-225, 1995.
DOI : 10.1016/0379-6779(95)80019-0

C. J. Brabec and N. S. Sariciftci, Low band-gap polymeric photovoltaic devices, Synth. Met, vol.121, pp.1583-1584, 2001.

M. M. Wienk, M. G. Turbiez, M. P. Strujik, M. Fonrodona, R. A. Janssen et al., Low-band gap poly(di-2-thienylthienopyrazine):fullerene solar cells, Applied Physics Letters, vol.88, issue.15, pp.153511-153549, 2006.
DOI : 10.1063/1.2195897

J. Hou, Z. T. Tan, Y. Yan, Y. He, C. Yang et al., Synthesis and Photovoltaic Properties of Two-Dimensional Conjugated Polythiophenes with Bi(thienylenevinylene) Side Chains, Journal of the American Chemical Society, vol.128, issue.14, pp.4911-4916, 2006.
DOI : 10.1021/ja060141m

M. Svensson, F. Zhang, S. C. Veenstra, W. J. Verhees, J. C. Hummelen et al., High-Performance Polymer Solar Cells of an Alternating Polyfluorene Copolymer and a Fullerene Derivative, Advanced Materials, vol.15, issue.12, pp.15-988, 2003.
DOI : 10.1002/adma.200304150

E. Bundgaard and F. C. Krebs, Low-Band-Gap Conjugated Polymers Based on Thiophene, Benzothiadiazole, and Benzobis(thiadiazole), Macromolecules, vol.39, issue.8, pp.39-2823, 2006.
DOI : 10.1021/ma052683e

D. Mühlbacher, M. Scharber, M. Morana, Z. Zhu, D. Waller et al., High Photovoltaic Performance of a Low-Bandgap Polymer, Advanced Materials, vol.201, issue.404, pp.2884-2889, 2006.
DOI : 10.1002/adma.200600160

J. Peet, J. Y. Kim, N. E. Coates, W. L. Ma, D. Moses et al., Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols, Nature Materials, vol.19, issue.7, pp.497-500, 2007.
DOI : 10.1038/nmat1928

Z. Zhu, D. Waller, R. Gaudiana, M. Morana, D. Mühlbacher et al., Panchromatic Conjugated Polymers Containing Alternating Donor/Acceptor Units for Photovoltaic Applications, Macromolecules, vol.40, issue.6, pp.40-1981, 2007.
DOI : 10.1021/ma062376o

K. Colladet, S. Fourier, T. Cleij, L. Lutsen, J. Gelan et al., Low Band Gap Donor???Acceptor Conjugated Polymers toward Organic Solar Cells Applications, Macromolecules, vol.40, issue.1, pp.65-72, 2007.
DOI : 10.1021/ma061760i

J. R. Reynolds, P. Taranekar, M. Abdulbaki, R. Krishnamoorti, S. Phanichphant et al., Optimization of narrow band-gap propylenedioxythiophene:cyanovinylene copolymers for optoelectronic applications Structure and band-gap design of a new series of light-emitting poly(cyanofluorene-alt-o/m/p-phenylenevinylene)-based copolymers for light-emitting diodes, Macromolecules Macromolecules, vol.39, issue.39, pp.9132-9142, 2006.

Y. Zou, J. Hou, C. Yang, and Y. Li, A Novel n-Type Conjugated Polymer DOCN-PPV:?? Synthesis, Optical, and Electrochemical Properties, Macromolecules, vol.39, issue.26, pp.8889-8891, 2006.
DOI : 10.1021/ma0626057

J. Cornil, D. A. Santos, D. Beljonne, and J. Brédas, Electronic Structure of Phenylene Vinylene Oligomers: Influence of Donor/Acceptor Substitutions, The Journal of Physical Chemistry, vol.99, issue.15, pp.5604-5611, 1995.
DOI : 10.1021/j100015a051

R. J. Kline, M. D. Mcgehee, and M. F. Toney, Highly oriented crystals at the buried interface in polythiophene thin-film transistors, Nature Materials, vol.49, issue.3, pp.222-228, 2006.
DOI : 10.1038/nmat1590

A. J. Spiering, R. A. Janssen, E. W. Meijer, P. Herwig, and D. M. De-leeuw, Two-dimensional charge transport in self-organized, high-mobility conjugated polymers, Nature, vol.401, issue.52, pp.685-688, 1999.

M. Surin, P. Leclère, R. Lazzaroni, J. D. Yuen, G. Wang et al., Relationship between the microscopic morphology and the charge transport properties in poly(3-hexylthiophene) field-effect transistors, Journal of Applied Physics, vol.100, issue.3, p.33712, 2006.
DOI : 10.1063/1.2222065

J. Verilhac, G. Leblevennec, D. Djurado, F. Rieutord, M. Chouiki et al., Effect of macromolecular parameters and processing conditions on supramolecular organisation, morphology and electrical transport properties in thin layers of regioregular poly(3-hexylthiophene) Synthetic Metals, pp.15611-15624, 2006.

R. Zhang, B. Li, M. C. Lovu, M. Jeffries-el, G. Sauvé et al., Nanostructure Dependence of Field-Effect Mobility in Regioregular Poly(3-hexylthiophene) Thin Film Field Effect Transistors, Journal of the American Chemical Society, vol.128, issue.11, pp.3480-3480, 2006.
DOI : 10.1021/ja055192i

R. J. Kline, M. D. Mcgehee, E. N. Kadnikova, J. Liu, J. M. Frechet et al., Dependence of Regioregular Poly(3-hexylthiophene) Film Morphology and Field-Effect Mobility on Molecular Weight Macromolecules, pp.3312-3319, 2005.

T. Erb, U. Zhokhavets, G. Gobsch, S. Raleva, B. Stühn et al., Correlation Between Structural and Optical Properties of Composite Polymer/Fullerene Films for Organic Solar Cells, Advanced Functional Materials, vol.81, issue.7, pp.1193-1196, 2005.
DOI : 10.1002/adfm.200400521

I. Mcculloch, J. E. Northrup, C. Bailey, K. Genevicius, and D. Sparrowe, High carrier mobility polythiophene thin films:structure determination by experiment and theory, Adv. Mater, vol.19, pp.833-837, 2007.

S. Tierney, R. Wagner, W. Zhang, M. L. Chabinyc, R. J. Kline et al., Liquid-crystalline semiconducting polymers with high charge-carrier mobility, Nature Materials, vol.5, pp.328-333, 2006.

B. S. Ong, Y. Wu, P. Liu, and S. Gardner, High-Performance Semiconducting Polythiophenes for Organic Thin-Film Transistors, Journal of the American Chemical Society, vol.126, issue.11, pp.3378-3379, 2004.
DOI : 10.1021/ja039772w

Y. Wu, P. Liu, B. S. Ong, T. H. Srikumar, R. J. Wilson et al., Controlled orientation of liquid-crystalline polythiophene semiconductors for high-performance organic thin-film transistors Mobility enhancement in conjugated polymer field-effect transistors through chain alignment in a liquid-crystalline phase, Appl. Phys. Lett. E. P.; Grell, M Appl. Phys. Lett, vol.86, issue.3, pp.77-406, 2000.

D. Chirvase, J. Parisi, J. C. Hummelen, and V. Dyakonov, Influence of nanomorphology on the photovoltaic action of polymer???fullerene composites, Nanotechnology, vol.15, issue.9, pp.1317-1323, 2004.
DOI : 10.1088/0957-4484/15/9/035

X. Yang and J. Loos, Toward High-Performance Polymer Solar Cells:?? The Importance of Morphology Control, Macromolecules, vol.40, issue.5, pp.1353-1362, 2007.
DOI : 10.1021/ma0618732

R. A. Janssen, Nanoscale Morphology of High-Performance Polymer Solar Cells, Nano Letters, vol.5, pp.579-583, 2005.

M. T. Rispens, A. Meetsma, R. Rittberger, C. J. Brabec, N. S. Sariciftci et al., Influence of the sovent on the crystal structure of PCBM and the efficiency of MDMO-PPV:PCBM 'plastic' solar cells, Chem. Commun, pp.2116-2118, 2003.

G. Li, Y. Yao, H. Yang, V. Shrotriya, G. Yang et al., ???Solvent Annealing??? Effect in Polymer Solar Cells Based on Poly(3-hexylthiophene) and Methanofullerenes, Advanced Functional Materials, vol.16, issue.10, pp.1636-1644, 2006.
DOI : 10.1002/adfm.200600624

L. H. Nguyen, H. Hoppe, T. Erb, S. Günes, G. Gobsch et al., Effects of Annealing on the Nanomorphology and Performance of Poly(alkylthiophene):Fullerene Bulk-Heterojunction Solar Cells, Advanced Functional Materials, vol.11, issue.452, pp.1071-1078, 2007.
DOI : 10.1002/adfm.200601038

S. Chambon, A. Rivaton, J. Gardette, and M. Firon, Photo- and thermal degradation of MDMO-PPV:PCBM blends, Solar Energy Materials and Solar Cells, vol.91, issue.5, pp.394-398, 2007.
DOI : 10.1016/j.solmat.2006.10.015
URL : https://hal.archives-ouvertes.fr/hal-00398988

D. Bettignies, R. Leroy, J. Firon, M. Sentein, and C. , Accelerated lifetime measurements of P3HT:PCBM solar cells, Synthetic Metals, vol.156, issue.7-8, pp.510-513, 2006.
DOI : 10.1016/j.synthmet.2005.06.016

J. Manca, Tuning the Dimension of C 60 -Based Needlelike Crystals in Blended Thin Films, Adv. Funct. Mater, vol.16, pp.760-765, 2006.

A. Cravino, Conjugated polymers with tethered electron-accepting moieties as ambipolar materials for photovoltaics, Polymer International, vol.123, issue.404, pp.943-956, 2007.
DOI : 10.1002/pi.2244

A. Cravino and N. S. Sariciftci, Double-cable polymers for fullerene based organic optoelectronic applications, Journal of Materials Chemistry, vol.12, issue.7, pp.1931-1943, 2002.
DOI : 10.1039/b201558g

Z. T. Tan, J. Hou, Y. He, E. Zhou, C. Yang et al., Synthesis and photovoltaic properties of a donoracceptor double-cable polythiophene with high content of C 60 pendant, Macromolecules, issue.6, pp.40-1868, 2007.

F. S. Bates, G. H. Fredrickson, B. De-boer, U. Stalmach, P. F. Van-hutten et al., Block copolymers-designer soft materials Supramolecular self-assembly and opto-electronic properties of semi-conducting block copolymers, Physics Today Polymer, vol.76, issue.42, pp.32-38, 1999.

J. A. Gratt and R. E. Cohen, The role of ordered block copolymer morphology in the performance of organic/inorganic photovoltaic devices, Journal of Applied Polymer Science, vol.83, issue.5, pp.3362-3368, 2004.
DOI : 10.1002/app.13526

N. Sary, R. Mezzenga, C. Brochon, G. Hadziioannou, and J. Ruokolainen, Weakly Segregated Smectic C Lamellar Clusters in Blends of Rods and Rod???Coil Block Copolymers, Macromolecules, vol.40, issue.9, pp.3277-3286, 2007.
DOI : 10.1021/ma062830o
URL : https://hal.archives-ouvertes.fr/hal-00383691

U. Stalmach, B. De-boer, C. Videlot, P. F. Van-hutten, G. Hadziioannou et al., Semiconducting Diblock Copolymers Synthesized by Means of Controlled Radical Polymerization Techniques, Journal of the American Chemical Society, vol.122, issue.23, pp.5464-5472, 2000.
DOI : 10.1021/ja000160a

R. D. Mccullough, Conducting regioregular polythiophene block copolymer nanofibrils synthesized by reversible addition fragmentation chain transfer polymerization (RAFT) and nitroxide mediated polymerization (NMP), Macromolecules, issue.14, pp.40-4733, 2007.

X. Yang, A. Alexeev, M. A. Michels, and J. Loos, -phenylenevinylene)/Methanofullerene Composite Films, Macromolecules, vol.38, issue.10, pp.4289-4295, 2005.
DOI : 10.1021/ma047589x
URL : https://hal.archives-ouvertes.fr/hal-01258459

X. Yang, K. J. Van-duren, R. A. Janssen, M. A. Michels, and J. Loos, -phenylenevinylene)/Methanofullerene Plastic Photovoltaic Devices, Macromolecules, vol.37, issue.6, pp.2151-2158, 2004.
DOI : 10.1021/ma035620+
URL : https://hal.archives-ouvertes.fr/hal-01258459

V. Causin, C. Marega, A. Marigo, L. Valentini, and J. M. Kenny, Crystallization and Melting Behavior of Poly(3-butylthiophene), Poly(3-octylthiophene), and Poly(3-dodecylthiophene), Macromolecules, vol.38, issue.2, pp.409-415, 2005.
DOI : 10.1021/ma048159+

S. Malik and A. K. Nandi, Crystallization mechanism of regioregular poly(3-alkyl thiophene)s, Journal of Polymer Science Part B: Polymer Physics, vol.39, issue.18, pp.2073-2085, 2002.
DOI : 10.1002/polb.10272

J. Liu, E. N. Kadnikova, Y. Liu, M. D. Mcgehee, and J. M. Fréchet, Polythiophene Containing Thermally Removable Solubilizing Groups Enhances the Interface and the Performance of Polymer???Titania Hybrid Solar Cells, Journal of the American Chemical Society, vol.126, issue.31, pp.9486-9487, 2004.
DOI : 10.1021/ja047452m

C. D. Müller, A. Falcou, N. Reckefuss, M. Rojahn, V. Wiederhirn et al., Multi-colour organic light-emitting displays by solution processing, Nature, vol.29, issue.6925, pp.829-833, 2003.
DOI : 10.1016/S0379-6779(99)00145-9

M. Drees, H. Hoppe, C. Winder, H. Neugebauer, N. S. Sariciftci et al., Stabilization of the nanomorphology of polymer???fullerene ???bulk heterojunction??? blends using a novel polymerizable fullerene derivative, Journal of Materials Chemistry, vol.117, issue.27, pp.5158-5163, 2005.
DOI : 10.1039/b505361g

J. Nierengarten and S. Setayesh, Towards polymerizable fullerene derivatives to stabilize the initially formed phases in bulk-heterojunction solar cells, New Journal of Chemistry, vol.14, issue.3, pp.313-316, 2006.
DOI : 10.1039/b517022m

E. Zhou, Z. T. Tan, Y. Yang, L. Huo, Y. Zou et al., Synthesis, Hole Mobility, and Photovoltaic Properties of Cross-Linked Polythiophenes with Vinylene???Terthiophene???Vinylene as Conjugated Bridge, Macromolecules, vol.40, issue.6, pp.1831-1837, 2007.
DOI : 10.1021/ma062633p

J. Raimundo, P. Blanchard, P. Frère, N. Mercier, I. Ledoux-rak et al., Push???pull chromophores based on 2,2???-bi(3,4-ethylenedioxythiophene) (BEDOT) ??-conjugating spacer, Tetrahedron Letters, vol.42, issue.8, pp.1507-1510, 2001.
DOI : 10.1016/S0040-4039(00)02317-0

K. J. Ihn, J. Moulton, and P. Smith, Whiskers of poly(3-alkylthiophene)s, Journal of Polymer Science Part B: Polymer Physics, vol.31, issue.6, pp.735-742, 1993.
DOI : 10.1002/polb.1993.090310614

J. A. Merlo and C. D. Frisbie, Field effect conductance of conducting polymer nanofibers, Journal of Polymer Science Part B: Polymer Physics, vol.80, issue.21, pp.2674-2680, 2003.
DOI : 10.1002/polb.10656

E. Kassmi, A. Héraud, G. Büchner, W. Fache, F. Lemaire et al., Aromatic nucleophilic substitution on thiophene rings, Journal of Molecular Catalysis, vol.72, issue.3, pp.299-305, 1992.
DOI : 10.1016/0304-5102(92)85007-3

S. Gronowitz, 3-substituted thiophenes, Arkiv. För Kemi, vol.12, issue.25, pp.239-246, 1957.

E. Schulz, K. Fahmi, and M. Lemaire, Synthetic methods for 3-substituted thiophenes, Acros Organics Acta, vol.1, pp.10-17, 1995.
URL : https://hal.archives-ouvertes.fr/hal-00005908

L. Robitaille and M. Leclerc, Synthesis, Characterization, and Langmuir-Blodgett Films of Fluorinated Polythiophenes, Macromolecules, vol.27, issue.7, pp.1847-1851, 1994.
DOI : 10.1021/ma00085a028

G. Daoust and M. Leclerc, Structure-property relationships in alkoxy-substituted polythiophenes, Macromolecules, vol.24, issue.2, pp.455-459, 1991.
DOI : 10.1021/ma00002a018

M. A. Keegstra, T. H. Peters, and L. Brandsma, Copper(I) halide catalysed synthesis of alkyl aryl and alkyl heteroaryl ethers, Tetrahedron, vol.48, issue.17, pp.48-3633, 1992.
DOI : 10.1016/S0040-4020(01)88501-X

R. K. Arvela and N. E. Leadbeater, Rapid, Easy Cyanation of Aryl Bromides and Chlorides Using Nickel Salts in Conjunction with Microwave Promotion, The Journal of Organic Chemistry, vol.68, issue.23, pp.9122-9125, 2003.
DOI : 10.1021/jo0350561

G. P. Ellis, T. M. Romney-alexander, H. M. Torenius, and H. Tye, Cyanation of aromatic halides Ionic liquids as reagents and solvents in conjunction with microwave heating: rapid synthesis of alkylhalides from alcohols and nitriless from aryl halides, Chem. Rev. Leadbeater, N. E. Tetrahedron, vol.87, issue.59, pp.779-794, 1987.

E. E. Sheina, S. M. Khersonsky, E. G. Jones, and R. D. Mccullough, Highly conductive, regioregular alkoxy-functionalized polythiophenes:a new class of stable, low band gap materials, Chem. Mater, issue.13, pp.17-3317, 2005.

Y. Li, G. Vamvounis, and S. Holdcroft, Tuning Optical Properties and Enhancing Solid-State Emission of Poly(thiophene)s by Molecular Control:?? A Postfunctionalization Approach, Macromolecules, vol.35, issue.18, pp.6900-6906, 2002.
DOI : 10.1021/ma020140o

A. J. Spiering, R. A. Janssen, E. W. Meijer, P. Herwig, D. M. De-leeuw et al., Two-dimensional charge transport in self-organized, high-mobility conjugated polymers Handbook of Oligo-and Polythiophenes Selective carbon-carbon bond formation by cross-coupling of grignard reagents with organic halides. Catalysis by nickel-phosphine complexes, Nature Stille, J. K., Angew. Chem. Int. Ed. J. Am. Chem. Soc, vol.401, issue.2612, pp.685-688, 1972.

E. Negishi, A. O. King, and N. Okukado, Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides, The Journal of Organic Chemistry, vol.42, issue.10, pp.42-1821, 1977.
DOI : 10.1021/jo00430a041

K. Tamao, S. Kodama, I. Nakajima, and M. Kumada, Nickel-phosphine complex-catalyzed Grignard coupling???II, Tetrahedron, vol.38, issue.22, pp.38-3347, 1982.
DOI : 10.1016/0040-4020(82)80117-8

F. Demanze, A. Yassar, and F. Garnier, Alternating Donor???Acceptor Substitutions in Conjugated Polythiophenes, Macromolecules, vol.29, issue.12, pp.4267-4273, 1996.
DOI : 10.1021/ma9514737

F. Demanze, A. Yassar, and F. Garnier, Push-pull substituted polythiophene, Synthetic Metals, vol.76, issue.1-3, pp.269-272, 1996.
DOI : 10.1016/0379-6779(95)03468-Y

D. L. Ladd, P. B. Harrsch, and L. I. Kruse, Synthesis and tubulin binding of 4'-(1-azi-2,2,2-trifluoroethyl)oncodazole, a photolabile analog of oncodazole, The Journal of Organic Chemistry, vol.53, issue.2, pp.417-420, 1988.
DOI : 10.1021/jo00237a035

J. Roncali, Conjugated poly(thiophenes): synthesis, functionalization, and applications, Chemical Reviews, vol.92, issue.4, pp.711-738, 1992.
DOI : 10.1021/cr00012a009

R. D. Mccullough, R. D. Lowe, M. Jayaraman, and D. L. Anderson, Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes), The Journal of Organic Chemistry, vol.58, issue.4, pp.904-912, 1993.
DOI : 10.1021/jo00056a024

T. Chen and R. D. Rieke, The first regioregular head-to-tail poly(3-hexylthiophene-2,5-diyl) and a regiorandom isopolymer: nickel versus palladium catalysis of 2(5)-bromo-5(2)-(bromozincio)-3-hexylthiophene polymerization, Journal of the American Chemical Society, vol.114, issue.25, pp.10087-10088, 1992.
DOI : 10.1021/ja00051a066

S. Guillerez and G. Bidan, New convenient synthesis of highly regioregular poly(3-octylthiophene) based on the Suzuki coupling reaction, Synthetic Metals, vol.93, issue.2, pp.123-126, 1998.
DOI : 10.1016/S0379-6779(97)04102-7

V. M. Niemi, P. Knuuttila, J. Osterholm, and J. Korvola, Polymerization of 3-alkylthiophenes with FeCl3, Polymer, vol.33, issue.7, pp.1559-1562, 1992.
DOI : 10.1016/0032-3861(92)90138-M

T. Yamamoto, Y. Hayashi, and A. Yamamoto, A Novel Type of Polycondensation Utilizing Transition Metal-Catalyzed C???C Coupling. I. Preparation of Thermostable Polyphenylene Type Polymers, Bulletin of the Chemical Society of Japan, vol.51, issue.7, pp.51-2091, 1978.
DOI : 10.1246/bcsj.51.2091

T. Chen, X. Wu, and R. D. Rieke, Regiocontrolled Synthesis of Poly(3-alkylthiophenes) Mediated by Rieke Zinc: Their Characterization and Solid-State Properties, Journal of the American Chemical Society, vol.117, issue.1, pp.233-244, 1995.
DOI : 10.1021/ja00106a027

M. R. Andersson, D. Selse, M. Berggren, H. Järvinen, T. Hjertberg et al., Regioselective polymerization of 3-(4-octylphenyl)thiophene with FeCl3, Macromolecules, vol.27, issue.22, pp.6503-6506, 1994.
DOI : 10.1021/ma00100a039

S. Amou, O. Haba, K. Shirato, T. Hayakawa, M. Ueda et al., Head-to-tail regioregularity of poly(3-hexylthiophene) in oxidative coupling polymerization with FeCl3, Journal of Polymer Science Part A: Polymer Chemistry, vol.131, issue.13, pp.1943-1948, 1999.
DOI : 10.1002/(SICI)1099-0518(19990701)37:13<1943::AID-POLA7>3.0.CO;2-X

I. Polec, A. Henckens, L. Goris, M. Nicolas, M. A. Loi et al., Convenient synthesis and polymerization of 5,6-disubstituted dithiophthalides toward soluble poly(isothianaphthene): An initial spectroscopic characterization of the resulting low-band-gap polymers, Journal of Polymer Science Part A: Polymer Chemistry, vol.7, issue.7, pp.1034-1045, 2003.
DOI : 10.1002/pola.10646

J. Manca, Tuning the Dimension of C 60 -Based Needlelike Crystals in Blended Thin Films, Adv. Funct. Mater, vol.16, pp.760-765, 2006.

K. F. Abbett, A. S. Teja, J. Kowalik, and L. Tolbert, Polymerization of 3-Undecylbithiophene and Preparation of Poly(3-undecylbithiophene)/Polystyrene Composites in Supercritical Carbon Dioxide, Macromolecules, vol.36, issue.9, pp.3015-3019, 2003.
DOI : 10.1021/ma021115l

H. S. Ganapathy, H. Yuvaraj, H. S. Hwang, J. S. Kim, B. Choi et al., CO 2 soluble semiconducting polymers synthesized in supercritical carbon dioxide, Synth. Met, pp.1567-1575, 2006.

M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf et al., Design Rules for Donors in Bulk-Heterojunction Solar Cells???Towards 10???% Energy-Conversion Efficiency, Advanced Materials, vol.215, issue.6, pp.789-794, 2006.
DOI : 10.1002/adma.200501717

R. A. Janssen, Nanoscale Morphology of High-Performance Polymer Solar Cells, Nano Letters, vol.5, pp.579-583, 2005.

T. J. Savenije, J. E. Kroeze, X. Yang, and J. Loos, The formation of crystalline P3HT fibrils upon annealing of a PCBM:P3HT bulk heterojunction, Thin Solid Films, vol.511, issue.512, pp.511-512, 2006.
DOI : 10.1016/j.tsf.2005.12.123

X. Yang and J. Loos, Toward High-Performance Polymer Solar Cells:?? The Importance of Morphology Control, Macromolecules, vol.40, issue.5, pp.1353-1362, 2007.
DOI : 10.1021/ma0618732

U. Zhokhavets, T. Erb, H. Hoppe, G. Gobsch, and N. S. Sariciftci, Effect of annealing of poly(3-hexylthiophene)/fullerene bulk heterojunction composites on structural and optical properties, Thin Solid Films, vol.496, issue.2, pp.679-682, 2006.
DOI : 10.1016/j.tsf.2005.09.093

P. Leclère, M. Surin, P. Brocorens, M. Cavallini, F. Biscarini et al., Supramolecular assembly of conjugated polymers: From molecular engineering to solid-state properties, Materials Science and Engineering: R: Reports, vol.55, issue.1-2, pp.1-56, 2006.
DOI : 10.1016/j.mser.2006.12.001

X. Zhang, X. Zhang, K. Zou, C. Lee, and S. Lee, Single-Crystal Nanoribbons, Nanotubes, and Nanowires from Intramolecular Charge-Transfer Organic Molecules, Journal of the American Chemical Society, vol.129, issue.12, pp.3527-3532, 2007.
DOI : 10.1021/ja0642109

A. C. Grimsdale and K. Müllen, The Chemistry of Organic Nanomaterials, Angewandte Chemie International Edition, vol.102, issue.452, pp.5592-5629, 2005.
DOI : 10.1002/anie.200500805

S. Yagai, Y. Monma, N. Kawauchi, T. Karatsu, and A. Kitamura, Supramolecular Nanoribbons and Nanoropes Generated from Hydrogen-Bonded Supramolecular Polymers Containing Perylene Bisimide Chromophores, Organic Letters, vol.9, issue.6, pp.1137-1140, 2007.
DOI : 10.1021/ol070139f

H. Goto, Cholesteric Liquid Crystal Inductive Asymmetric Polymerization:?? Synthesis of Chiral Polythiophene Derivatives from Achiral Monomers in a Cholesteric Liquid Crystal, Macromolecules, vol.40, issue.5, pp.1377-1385, 2007.
DOI : 10.1021/ma062296k

O. J. Dautel, M. Robitzer, J. Lère-porte, F. Serein-spirau, and J. J. Moreau, Self-Organized Ureido Substituted Diacetylenic Organogel. Photopolymerization of One-Dimensional Supramolecular Assemblies to Give Conjugated Nanofibers, Journal of the American Chemical Society, vol.128, issue.50, pp.16213-16223, 2006.
DOI : 10.1021/ja065434u
URL : https://hal.archives-ouvertes.fr/hal-00162768

P. Leclère, M. Surin, P. Viville, R. Lazzaroni, A. F. Kilbinger et al., About Oligothiophene Self-Assembly:?? From Aggregation in Solution to Solid-State Nanostructures, Chemistry of Materials, vol.16, issue.23, pp.4452-4466, 2004.
DOI : 10.1021/cm049673x

M. Brinkmann and J. Wittmann, Orientation of Regioregular Poly(3-hexylthiophene) by Directional Solidification: A Simple Method to Reveal the Semicrystalline Structure of a Conjugated Polymer, Advanced Materials, vol.14, issue.7, pp.860-863, 2006.
DOI : 10.1002/adma.200501838

R. C. Hiorns, R. De-bettignies, J. Leroy, S. Bailly, M. Firon et al., High Molecular Weights, Polydispersities, and Annealing Temperatures in the Optimization of Bulk-Heterojunction Photovoltaic Cells Based on Poly(3-hexylthiophene) or Poly(3-butylthiophene), Advanced Functional Materials, vol.62, issue.134, pp.2263-2273, 2006.
DOI : 10.1002/adfm.200600005

K. J. Ihn, J. Moulton, and P. Smith, Whiskers of poly(3-alkylthiophene)s, Journal of Polymer Science Part B: Polymer Physics, vol.31, issue.6, pp.735-742, 1993.
DOI : 10.1002/polb.1993.090310614

S. Hotta, S. D. Rughooputh, A. J. Heeger, and F. Wudl, Spectroscopic studies of soluble poly(3-alkylthienylenes), Macromolecules, vol.20, issue.1, pp.212-215, 1987.
DOI : 10.1021/ma00167a038

K. Faïd, M. Fréchette, M. Ranger, L. Mazerolle, I. Lévesque et al., Chromic Phenomena in Regioregular and Nonregioregular Polythiophene Derivatives, Chemistry of Materials, vol.7, issue.7, pp.1390-1396, 1995.
DOI : 10.1021/cm00055a018

S. Garreau, M. Leclerc, N. Errien, and G. Louarn, Planar-to-Nonplanar Conformational Transition in Thermochromic Polythiophenes:?? A Spectroscopic Study, Macromolecules, vol.36, issue.3, pp.692-697, 2003.
DOI : 10.1021/ma021358d

T. Yamamoto, D. Komarudin, M. Ara, B. Lee, H. Suganuma et al., Extensive Studies on ??-Stacking of Poly(3-alkylthiophene-2,5-diyl)s and Poly(4-alkylthiazole-2,5-diyl)s by Optical Spectroscopy, NMR Analysis, Light Scattering Analysis, and X-ray Crystallography, Journal of the American Chemical Society, vol.120, issue.9, pp.2047-2058, 1998.
DOI : 10.1021/ja973873a

J. A. Merlo and C. D. Frisbie, Field Effect Transport and Trapping in Regioregular Polythiophene Nanofibers, The Journal of Physical Chemistry B, vol.108, issue.50, pp.19169-19179, 2004.
DOI : 10.1021/jp047023a

J. Verilhac, Transistors organiques à base de dérivés du polythiophène. Effets de la structure moléculaire et supramoléculaire, Thèse de Doctorat, p.27, 2006.

N. Kiriy, E. Jähne, H. Adler, M. Schneider, A. Kiriy et al., One-Dimensional Aggregation of Regioregular Polyalkylthiophenes, Nano Letters, vol.3, issue.6, pp.707-712, 2003.
DOI : 10.1021/nl0341032

F. Banishoeib1, S. F. , T. J. Cleij1, and L. , The synthesis of poly(thienylene vinylene) derivatives via the dithiocarbamate route: low band gap p-type conjugated polymers for photovoltaics, The European Physical Journal Applied Physics, vol.37, issue.3, pp.237-240, 2007.
DOI : 10.1051/epjap:2007003

L. H. Nguyen, S. Günes, H. Neugebauer, N. S. Sariciftci, F. Banishoeib et al., Precursor route poly(thienylene vinylene) for organic solar cells: Photophysics and photovoltaic performance, Solar Energy Materials & Solar Cells, issue.17, pp.90-2815, 2006.

M. Zdrojek, T. Mélin, H. Diesinger, D. Stiévenard, W. Gebicki et al., Charging and discharging processes of carbon nanotubes probed by electrostatic force microscopy, Journal of Applied Physics, vol.100, issue.11, p.114326, 2006.
DOI : 10.1063/1.2392674
URL : https://hal.archives-ouvertes.fr/hal-00127829

T. Heim, K. Lmimouni, and D. Vuillaume, Ambipolar charge injection and transport in a single pentacene monolayer island. Nanno Letters, pp.2145-2150, 2004.
URL : https://hal.archives-ouvertes.fr/hal-00002914

Z. Hu, M. D. Fischein, C. Querner, and M. Drndic, Electric-Field-Driven Accumulation and Alignment of CdSe and CdTe Nanorods in Nanoscale Devices, Nano Letters, vol.6, issue.11, pp.2585-2591, 2006.
DOI : 10.1021/nl0620379

R. Krupke, F. Hennrich, H. Löhneysen, and M. M. Kappes, Separation of Metallic from Semiconducting Single-Walled Carbon Nanotubes, Science, vol.301, issue.5631, pp.344-347, 2003.
DOI : 10.1126/science.1086534

X. Liu, J. L. Spencer, A. B. Kaiser, and W. M. Arnold, Electric-field oriented carbon nanotubes in different dielectric solvents, Current Applied Physics, vol.4, issue.2-4, pp.125-128, 2004.
DOI : 10.1016/j.cap.2003.10.012

M. V. Kakade, S. Givens, K. Gardner, K. H. Lee, D. B. Chase et al., Electric Field Induced Orientation of Polymer Chains in Macroscopically Aligned Electrospun Polymer Nanofibers, Journal of the American Chemical Society, vol.129, issue.10, pp.2777-2782, 2007.
DOI : 10.1021/ja065043f

T. Kim, M. Kao, E. F. Hasselbrink, and E. Meyhöfer, Active Alignment of Microtubules with Electric Fields, Nano Letters, vol.7, issue.1, pp.211-217, 2007.
DOI : 10.1021/nl061474k

L. Sardone, V. Palermo, E. Devaux, D. Credgington, M. De-loos et al., Electric-Field-Assisted Alignment of Supramolecular Fibers, Advanced Materials, vol.49, issue.10, pp.1276-1280, 2006.
DOI : 10.1002/adma.200600269

M. Mas-torrent, D. Den-boer, M. Durkut, P. Hadley, and A. P. Schenning, Field effect transistors based on poly(3-hexylthiophene) at different length scales, Nanotechnology, vol.15, issue.4, pp.265-269, 2004.
DOI : 10.1088/0957-4484/15/4/028

G. Derue, S. Coppée, S. Gabriele, M. Surin, V. Geskin et al., Nanorubbing of Polythiophene Surfaces, Journal of the American Chemical Society, vol.127, issue.22, pp.8018-8019, 2005.
DOI : 10.1021/ja0505806

F. Monestier, J. Simon, P. Torchio, L. Escoubas, F. Flory et al., Modeling the short-circuit current density of polymer solar cells based on P3HT:PCBM blend, Solar Energy Materials and Solar Cells, vol.91, issue.5, pp.405-410, 2007.
DOI : 10.1016/j.solmat.2006.10.019

C. Brabec, V. Dyakonov, J. Parisi, and N. S. Sariciftci, Organic Photovoltaics -Concepts and Realization, Series in Materials Science, 2003.

G. Gruner, Carbon nanotube films for transparent and plastic electronics, Journal of Materials Chemistry, vol.127, issue.4, pp.16-3533, 2006.
DOI : 10.1039/b603821m

H. Ago, K. Petritsch, M. S. Shaffer, A. H. Windle, and R. H. Friend, Composites of Carbon Nanotubes and Conjugated Polymers for Photovoltaic Devices, Advanced Materials, vol.11, issue.15, pp.1281-1285, 1999.
DOI : 10.1002/(SICI)1521-4095(199910)11:15<1281::AID-ADMA1281>3.0.CO;2-6

D. Pasquier, A. Unalan, H. E. Kanwal, A. Miller, S. Chhowalla et al., Conducting and transparent single-wall carbon nanotube electrodes for polymer-fullerene solar cells, Organic solar cells with carbon nanotubes replacing In2O3:Sn as the transparent electrode, p.233503, 2005.
DOI : 10.1063/1.2132065

Z. Wu, Z. Chen, X. Du, J. M. Logan, J. Sippel et al., Conductive Carbon Nanotube Films Photovoltaic Properties of Dye Functionalized Single-Wall Carbon Nanotube, ScienceConjugated Polymer Devices Chem. Mater. Kymakis, E. Appl. Phys. Lett, vol.16, issue.241, pp.80-112, 1273.

E. Kymakis and G. A. Amaratunga, Carbon nanotubes as electron acceptors in polymeric photovoltaics, Rev. Adv. Mater. Sci, vol.10, pp.300-305, 2005.

E. Kymakis, E. Koudoumas, I. Franghiadakis, and G. A. Amaratunga, Post-fabrication annealing effects in polymer-nanotube photovoltaic cells, Journal of Physics D: Applied Physics, vol.39, issue.6, pp.39-1058, 2006.
DOI : 10.1088/0022-3727/39/6/010

X. Xie, Y. Mai, and X. Zhou, Dispersion and alignment of carbon nanotubes in polymer matrix: A review, Materials Science and Engineering: R: Reports, vol.49, issue.4, pp.89-112, 2005.
DOI : 10.1016/j.mser.2005.04.002

J. Geng and T. Zeng, Influence of Single-Walled Carbon Nanotubes Induced Crystallinity Enhancement and Morphology Change on Polymer Photovoltaic Devices, Journal of the American Chemical Society, vol.128, issue.51, pp.16827-16833, 2006.
DOI : 10.1021/ja065035z

A. Ikeda, K. Nobusawa, T. Hamano, and J. Kikuchi, Single-Walled Carbon Nanotubes Template the One-Dimensional Ordering of a Polythiophene Derivative Org, Lett, vol.8, issue.24, pp.5489-5492, 2006.

A. J. Miller, R. A. Hatton, G. Y. Chen, S. R. Silva, S. K. Batabyal et al., Carbon nanotubes grown on In2O3:Sn glass as large area electrodes for organic photovoltaics Functionalized carbon nanotubes in donor/acceptor-type photovoltaic devices, 90, 023105. 31. Pradhan, p.93106, 2006.

C. Li, Y. Chen, Y. Wang, Z. Iqbal, M. Chhowalla et al., A fullerene???single wall carbon nanotube complex for polymer bulk heterojunction photovoltaic cells, J. Mater. Chem., vol.14, issue.452, pp.2406-2411, 2007.
DOI : 10.1039/B618518E

G. Les, MS ont été effectuées sur un appareil HP équipé d'une colonne capillaire Chrompack (Cpsil525, 25 m x 0,32 mm, df = 0,11 µm)

L. Analyses, Chemstation équipée d'une colonne 300 mm x 7,5 mm PLgel Mixed-D 5 µm/10 4 Å, d'un détecteur UV-Visible à barette de diode calée à 420 nm et d'un détecteur d'indice de réfraction. La température de la colonne est maintenue à 40 °C et le débit à 1 mL.min -1 . La calibration de la colonne est obtenue à partir d'échantillons de polystyrène (PS) monodisperse (PS) (S-M2-10*, polymer Laboratories), 1100.

. Dans-un-bicol-muni-d-'un-réfrigérant, 21 mol) sont introduits en solution dans 120 mL d'acide acétique et 100 mL d'eau. 5,7 équivalents de zinc (78 g, 1,19 mol) sont ajoutés petit à petit sous forme de poudre dans le milieu. La température est portée à 120 °C pour activer la réaction. Le milieu est laissé 24 heures à 120 °C puis filtré sur celite et extrait à l'hexane, Les phases organiques sont lavées au NaHCO 3 , avec de l'eau et une solution saturée de NaCl puis séchées sur Na 2 SO 4 . Le produit brut est composé à 98, pp.5-8

1. Qd, 1. , J. Hzd, 3. , and J. Hz, RMN 13 C (CDCl 3 ) : 142,6, EIMS m/z (intensité relative) : 178 (M ·+, pp.9522-71

. Dans-un-bicol-muni-d-'un-réfrigérant, 9 mmol) sont introduits en solution dans 8 mL d'acide acétique et 5 mL d'eau. 10 équivalents de zinc (11,45 g, 0,17 mol) sont ajoutés petit à petit sous forme de poudre dans le milieu. La température est portée à 120 °C pour activer la réaction. Le milieu est laissé pendant 24 heures à 120 °C puis filtré sur celite et extrait à l'hexane, Les phases organiques sont lavées au NaHCO 3 , avec de l'eau et une solution saturée de NaCl puis séchées sur Na 2 SO 4 . Le produit brut est purifié sur HPLC (éluant : acétonitrile). 2,7 g de produit sont obtenus, pp.5-8

. Dans, mmol) sont introduits en solution dans 20 mL d'éther diéthylique anhydre à -78 °C, pp.5-8

2. Hzt, 3. , and J. =. , RMN 13 C (CDCl 3 ) : ? = 147,3, pp.616127-616158

. La-température-du-milieu-remonte-alors-lentement-jusqu, ambiante (~1h30) puis le milieu est mis au reflux du THF toute la nuit. Le milieu est hydrolysé. Le précipité marron, très difficile à filtrer, peut être solubilisé par légère acidification du milieu avec de l'acide chlorhydrique 1,5 M

1. Hzd, 2. , 3. , and J. =. , 7 Hz) RMN 13 C (CDCl 3 ): 155,8, pp.88158453-188, 2009.