X. Luo, Y. Chen, J. Huber, Y. Zhang, and P. Sinaÿ, Diisobutylaluminum hydride as a molecular scalpel: the regioselective stripping of four methyl groups from permethylated ??-cyclodextrin, Comptes Rendus Chimie, vol.7, issue.1, pp.25-28, 2004.
DOI : 10.1016/j.crci.2003.09.008

Y. Chen, J. Huber, Y. Zhang, and P. Sinaÿ, Regioselective one-step synthesis of hexahydroxy permethylated ??-cyclodextrin and unambiguous NMR analysis, Comptes Rendus Chimie, vol.8, issue.1, pp.27-30, 2005.
DOI : 10.1016/j.crci.2004.11.019

K. Wüthrich, NMR of proteins and nucleic acids, 1986.

L. Banci, I. Bertini, J. Huber, G. Spyroulias, and P. Et-turano, Solution structure of reduced horse heart cytochrome c, Journal of Biological Inorganic Chemistry, vol.4, issue.1, pp.21-31, 1999.
DOI : 10.1007/s007750050285

D. Wishart, B. Sykes, and F. Richards, Relationship between nuclear magnetic resonance chemical shift and protein secondary structure, Journal of Molecular Biology, vol.222, issue.2, pp.311-333, 1991.
DOI : 10.1016/0022-2836(91)90214-Q

J. Huber, J. Gaillard, and J. Moulis, NMR of Chromatium vinosum ferredoxin: evidence for structural inequivalence and impeded electron transfer between the two [4Fe-4S] clusters, Biochemistry, vol.34, issue.1, pp.194-205, 1995.
DOI : 10.1021/bi00001a024

J. Huber, J. Moulis, and J. Gaillard, H Longitudinal Relaxation Times in the Solution Structure of Paramagnetic Proteins. Application to [4Fe-4S] Proteins, Biochemistry, vol.35, issue.39, pp.12705-12711, 1996.
DOI : 10.1021/bi961354z

J. Mouesca, L. Noodleman, D. Case, and B. Lamotte, Spin Densities and Spin Coupling in Iron-Sulfur Clusters: A New Analysis of Hyperfine Coupling Constants, Inorganic Chemistry, vol.34, issue.17, pp.4347-4359, 1995.
DOI : 10.1021/ic00121a013

I. Bertini, F. Capozzi, L. Eltis, I. Felli, C. Luchinat et al., Sequence-Specific Assignment of Ligand Cysteine Protons of Oxidized, Recombinant HiPIP I from Ectothiorhodospira halophila, Inorganic Chemistry, vol.34, issue.10, pp.2516-2523, 1995.
DOI : 10.1021/ic00114a008

L. Banci, I. Bertini, J. Huber, C. Luchinat, A. Rosato et al., at High Magnetic Fields:?? Magnetic Susceptibility Anisotropy Contributions and Consequences for Protein Solution Structure Determination, Journal of the American Chemical Society, vol.120, issue.49, pp.12903-12909, 1998.
DOI : 10.1021/ja981791w

G. Bushnell, G. Louie, and G. Brayer, High-resolution three-dimensional structure of horse heart cytochrome c, Journal of Molecular Biology, vol.214, issue.2, pp.585-595, 1990.
DOI : 10.1016/0022-2836(90)90200-6

K. Modig, E. Liepinsh, G. Otting, B. Halle, and J. , Dynamics of Protein and Peptide Hydration, Journal of the American Chemical Society, vol.126, issue.1, pp.102-114, 2004.
DOI : 10.1021/ja038325d

I. Bertini, J. Huber, C. Luchinat, and M. Piccioli, Protein Hydration and Location of Water Molecules in Oxidized Horse Heart Cytochrome c by 1H NMR, Journal of Magnetic Resonance, vol.147, issue.1, pp.1-8, 2000.
DOI : 10.1006/jmre.2000.2131

H. Gottlieb, V. Kotlyar, and A. Nudelman, NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities, The Journal of Organic Chemistry, vol.62, issue.21, pp.7512-7515, 1997.
DOI : 10.1021/jo971176v

P. Qi, D. Stefano, L. Wand, and A. , Solution Structure of Horse Heart Ferrocytochrome c Determined by High-Resolution NMR and Restrained Simulated Annealing, Biochemistry, vol.33, issue.21, pp.6408-6417, 1994.
DOI : 10.1021/bi00187a004

P. Kyritsis, J. Huber, I. Quinkal, J. Gaillard, and J. Moulis, Intramolecular Electron Transfer between [4Fe-4S] Clusters Studied by Proton Magnetic Resonance Spectroscopy, Biochemistry, vol.36, issue.25, pp.7839-7846, 1997.
DOI : 10.1021/bi970020m

C. Moser, J. Keske, K. Warncke, R. Farid, and P. Dutton, Nature of biological electron transfer, Nature, vol.355, issue.6363, pp.796-802, 1992.
DOI : 10.1038/355796a0

J. Winkler and H. Gray, Electron transfer in ruthenium-modified proteins, Chemical Reviews, vol.92, issue.3, pp.369-379, 1992.
DOI : 10.1021/cr00011a001

R. Kummerle, P. Kyritsis, J. Gaillard, J. Moulis, and J. , Electron transfer properties of iron???sulfur proteins, Journal of Inorganic Biochemistry, vol.79, issue.1-4, pp.83-91, 2000.
DOI : 10.1016/S0162-0134(99)00160-9

E. Wilhelm, R. Battino, and R. Wilcock, Low-pressure solubility of gases in liquid water, Chemical Reviews, vol.77, issue.2, pp.219-262, 1977.
DOI : 10.1021/cr60306a003

B. Goodson and J. , Nuclear Magnetic Resonance of Laser-Polarized Noble Gases in Molecules, Materials, and Organisms, Journal of Magnetic Resonance, vol.155, issue.2, pp.157-216, 2002.
DOI : 10.1006/jmre.2001.2341

G. Navon, Y. Song, T. Rõõm, S. Appelt, R. Taylor et al., Enhancement of Solution NMR and MRI with Laser-Polarized Xenon, Science, vol.271, issue.5257, pp.1848-1851, 1996.
DOI : 10.1126/science.271.5257.1848

P. Berthault, H. Desvaux, L. Goff, G. Pétro, and M. , A simple way to properly invert intense nuclear magnetization: application to laser-polarized xenon, Chemical Physics Letters, vol.314, issue.1-2, pp.52-56, 1999.
DOI : 10.1016/S0009-2614(99)01135-5

L. Dubois, D. Silva, P. Landon, C. Huber, J. Ponchet et al., through Xenon-Based NMR Spectroscopy, Journal of the American Chemical Society, vol.126, issue.48, pp.15738-15746, 2004.
DOI : 10.1021/ja046195i
URL : https://hal.archives-ouvertes.fr/hal-00088366

C. Landon, P. Berthault, F. Vovelle, and H. Desvaux, Magnetization transfer from laser-polarized xenon to protons located in the hydrophobic cavity of the wheat nonspecific lipid transfer protein, Protein Science, vol.265, issue.4, pp.762-770, 2001.
DOI : 10.1110/ps.47001

L. Dubois, S. Parrès, J. Huber, P. Berthault, H. Desvaux et al., Dynamics of Xenon inside Hydrophobic Cavities As Probed by NMR Relaxation of Dissolved Laser-Polarized Xenon, The Journal of Physical Chemistry B, vol.108, issue.2, pp.767-773, 2004.
DOI : 10.1021/jp0363242

H. Desvaux, L. Dubois, G. Huber, M. Quillin, P. Berthault et al., Dynamics of Xenon Binding Inside the Hydrophobic Cavity of Pseudo-Wild-type Bacteriophage T4 Lysozyme Explored through Xenon-Based NMR Spectroscopy, Journal of the American Chemical Society, vol.127, issue.33, pp.11676-11683, 2005.
DOI : 10.1021/ja053074p

P. Silva, C. Landon, B. Industri, A. Marais, M. Ponchet et al., Solution structure of a tobacco lipid transfer protein exhibiting new biophysical and biological features, Proteins: Structure, Function, and Bioinformatics, vol.419, issue.6905, pp.356-67, 2005.
DOI : 10.1002/prot.20405
URL : https://hal.archives-ouvertes.fr/hal-00088539

N. Farrow, R. Muhandiram, A. Singer, S. Pascal, C. Kay et al., Backbone Dynamics of a Free and a Phosphopeptide-Complexed Src Homology 2 Domain Studied by 15N NMR Relaxation, Biochemistry, vol.33, issue.19, pp.5984-6003, 1994.
DOI : 10.1021/bi00185a040

J. Canceill, L. Lacombe, A. Collet, and J. , Analytical optical resolution of bromochlorofluoromethane by enantioselective inclusion into a tailor-made cryptophane and determination of its maximum rotation, Journal of the American Chemical Society, vol.107, issue.24, pp.6993-6996, 1985.
DOI : 10.1021/ja00310a041

A. Collet, J. Dutasta, B. Lozach, J. Canceill, and . Top, Cyclotriveratrylenes and cryptophanes: Their synthesis and applications to host-guest chemistry and to the design of new materials, Curr. Chem, vol.165, pp.103-129, 1993.
DOI : 10.1007/BFb0111282

K. Bartik, M. Luhmer, J. Dutasta, A. Collet, J. Reisse et al., H NMR Study of the Reversible Trapping of Xenon by Cryptophane-A in Organic Solution, Journal of the American Chemical Society, vol.120, issue.4, pp.784-791, 1998.
DOI : 10.1021/ja972377j

T. Brotin, T. Devic, A. Lesage, L. Emsley, and A. Collet, Synthesis of Deuterium-Labeled Cryptophane-A and Investigation of Xe@Cryptophane Complexation Dynamics by 1D-EXSY NMR Experiments, Chemistry, vol.106, issue.7, pp.1561-1573, 2001.
DOI : 10.1002/1521-3765(20010401)7:7<1561::AID-CHEM1561>3.0.CO;2-9

M. Darzac, T. Brotin, L. Rousset, D. Bouchu, and J. Dutasta, Synthesis and application of cryptophanol hosts: 129Xe NMR spectroscopy of a deuterium-labeled (Xe)2@bis-cryptophane complex, New Journal of Chemistry, vol.28, issue.4, pp.502-512, 2004.
DOI : 10.1039/b312979a

J. Huber, L. Dubois, H. Desvaux, T. Brotin, J. Dutasta et al., NMR Study of Optically Active Monosubstituted Cryptophanes and Their Interaction with Xenon, The Journal of Physical Chemistry A, vol.108, issue.44, pp.9608-9615, 2004.
DOI : 10.1021/jp0472055

M. Luhmer, B. Goodson, Y. Song, D. Laws, L. Kaiser et al., Study of Xenon Binding in Cryptophane-A Using Laser-Induced NMR Polarization Enhancement, Journal of the American Chemical Society, vol.121, issue.14, pp.3502-3512, 1999.
DOI : 10.1021/ja9841916

M. Spence, S. Rubin, I. Dimitrov, E. Ruiz, D. Wemmer et al., Functionalized xenon as a biosensor, Proceedings of the National Academy of Sciences, vol.98, issue.19, pp.10654-10657, 2001.
DOI : 10.1073/pnas.191368398

M. Pons, O. Millet, and . Prog, Dynamic NMR studies of supramolecular complexes, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.38, issue.4, pp.267-324, 2001.
DOI : 10.1016/S0079-6565(00)00029-7

A. Cherubini, A. Bifone, and . Prog, Hyperpolarised xenon in biology, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.42, issue.1-2, pp.1-30, 2003.
DOI : 10.1016/S0079-6565(02)00052-3

D. Rudkevich and A. Leontiev, Molecular Encapsulation of Gases, Australian Journal of Chemistry, vol.57, issue.8, pp.713-722, 2004.
DOI : 10.1071/CH04102

H. Desvaux, J. Huber, T. Brotin, J. Dutasta, and P. Berthault, Magnetization Transfer from Laser-Polarized Xenon to Protons with Spin-Diffusion Quenching, ChemPhysChem, vol.113, issue.4, pp.384-387, 2003.
DOI : 10.1002/cphc.200390067

. Thème, Etude des interactions eau-cytochrome c de coeur de cheval et de l'orientation partielle de cytochromes dans le champ magnétique par RMN homo et hétéronucléaire

C. Bourse, 1992-1993 DEA d'analyses physico-chimiques et chimie analytique Université Lyon I

J. Huber, J. Gaillard, J. Moulis, and . Nmr, NMR of Chromatium vinosum ferredoxin: evidence for structural inequivalence and impeded electron transfer between the two [4Fe-4S] clusters, Biochemistry, vol.34, issue.1, pp.194-205, 1995.
DOI : 10.1021/bi00001a024

C. Guillard, P. Pichat, G. Huber, and C. Hoang-van, The GC-MS analysis of organic intermediates from the TiO 2 photocatalytic treatment of water contaminated by lindane (1?, 2?, 3?, 4?, 5?, 6?-hexachlorocyclohexane), J. of Adv. Oxidation technologies, vol.1, pp.53-60, 1996.

L. Banci, I. Bertini, J. Huber, C. Luchinat, and A. Rosato, at High Magnetic Fields:?? Magnetic Susceptibility Anisotropy Contributions and Consequences for Protein Solution Structure Determination, Journal of the American Chemical Society, vol.120, issue.49, pp.12903-12909, 1998.
DOI : 10.1021/ja981791w

L. Banci, I. Bertini, J. Huber, G. Spyroulias, and P. Turano, Solution structure of reduced horse heart cytochrome c, Journal of Biological Inorganic Chemistry, vol.4, issue.1, pp.21-31, 1999.
DOI : 10.1007/s007750050285

L. Dubois, S. Parrès, J. Huber, P. Berthault, and H. Desvaux, Dynamics of Xenon inside Hydrophobic Cavities As Probed by NMR Relaxation of Dissolved Laser-Polarized Xenon, The Journal of Physical Chemistry B, vol.108, issue.2, pp.767-773, 2004.
DOI : 10.1021/jp0363242

L. Dubois, P. Berthault, J. Huber, and H. Desvaux, Mapping hydrophobic molecular regions using dissolved laser-polarized xenon NMR, Comptes Rendus Physique, vol.5, issue.3, pp.305-313, 2004.
DOI : 10.1016/j.crhy.2004.02.003

P. Berthault, G. Huber, P. Ha, L. Dubois, H. Desvaux et al., Study of the Hydrophobic Cavity of ??-Cryptogein through Laser-Polarized Xenon NMR Spectroscopy, ChemBioChem, vol.193, issue.1, pp.59-64, 2006.
DOI : 10.1002/cbic.200500140
URL : https://hal.archives-ouvertes.fr/hal-00018878

G. Huber, T. Brotin, L. Dubois, H. Desvaux, J. Dutasta et al., Water Soluble Cryptophanes Showing Unprecedented Affinity for Xenon:?? Candidates as NMR-Based Biosensors, Journal of the American Chemical Society, vol.128, issue.18, 2006.
DOI : 10.1021/ja060266r

B. Gonzalez, J. Huber, L. Auriol, . Propriétaires-metabolic-explorer, and S. Bruker, Dispositif pour l'analyse spectroscopique RMN in vivo des métabolites d'un milieu de culture, p.241021, 2000.