J. Cho, G. B. Kim, H. S. Lim, C. S. Kim, and S. I. Yoo, Improvement of Structural Stability of LiMn[sub 2]O[sub 4] Cathode Material on 55??C Cycling by Sol-Gel Coating of LiCoO[sub 2], Electrochemical and Solid-State Letters, vol.2, issue.12, pp.607-359, 1999.
DOI : 10.1149/1.1390922

Z. L. Liu, H. B. Wang, L. Fang, J. Y. Lee, and L. M. Gan, Improving the high-temperature performance of LiMn2O4 spinel by micro-emulsion coating of LiCoO2, Journal of Power Sources, vol.104, issue.1, p.101, 2002.
DOI : 10.1016/S0378-7753(01)00878-3

C. Delmas, C. Faure, and Y. Borthomieu, The effect of cobalt on the chemical and electrochemical behaviour of the nickel hydroxide electrode, Materials Science and Engineering: B, vol.13, issue.2, p.89, 1992.
DOI : 10.1016/0921-5107(92)90147-2

F. Pouillerie, P. Perton, J. Biensan, M. Pérès, C. Broussely et al., Effect of magnesium substitution on the cycling behavior of lithium nickel cobalt oxide, Journal of Power Sources, vol.96, issue.2, p.293, 2001.
DOI : 10.1016/S0378-7753(00)00653-4

Y. Nishida, K. Nakane, and T. Satoh, Synthesis and properties of gallium-doped LiNiO2 as the cathode material for lithium secondary batteries, Journal of Power Sources, vol.68, issue.2, p.561, 1997.
DOI : 10.1016/S0378-7753(97)02535-4

M. G. Kim, H. J. Shin, J. H. Kim, S. H. Park, and Y. K. Sun, XAS Investigation of Inhomogeneous Metal-Oxygen Bond Covalency in Bulk and Surface for Charge Compensation in Li-Ion Battery Cathode Li[Ni[sub 1???3]Co[sub 1???3]Mn[sub 1???3]]O[sub 2] Material, Journal of The Electrochemical Society, vol.152, issue.7, p.1320, 2005.
DOI : 10.1149/1.1926647

T. H. Cho, S. M. Park, M. Yoshio, T. Hirai, and Y. Hideshima, Effect of synthesis condition on the structural and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 prepared by carbonate co-precipitation method, Journal of Power Sources, vol.142, issue.1-2, p.306, 2005.
DOI : 10.1016/j.jpowsour.2004.10.016

Z. H. Lu, D. D. Macneil, and J. R. Dahn, Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3???2x/3)]Mn[sub (2/3???x/3)]]O[sub 2] for Lithium-Ion Batteries, Electrochemical and Solid-State Letters, vol.4, issue.11, pp.191-815, 2001.
DOI : 10.1149/1.1407994

Y. J. Park, X. L. Hong, K. S. Wu, S. H. Ryu, and . Chang, Structural investigation and electrochemical behaviour of Li[NixLi(1/3???2x/3)Mn(2/3???x/3)]O2 compounds by a simple combustion method, Journal of Power Sources, vol.129, issue.2, p.288, 2004.
DOI : 10.1016/j.jpowsour.2003.11.024

L. H. Yu, Y. L. Cao, H. X. Yang, X. P. Ai, and Y. Y. Ren, Preparation and electrochemical characterization of nanocrystalline Li[Li0.12Ni0.32Mn0.56]O2 pyrolyzed from polyacrylate salts, Materials Chemistry and Physics, vol.88, issue.2-3, p.353, 2004.
DOI : 10.1016/j.matchemphys.2004.07.023

Y. J. Park, Y. S. Hong, X. L. Wu, M. G. Kim, K. S. Ryu et al., Synthesis and Electrochemical Characteristics of Li[Co[sub x]Li[sub (1/3???x/3)]Mn[sub (2/3???2x/3)]]O[sub 2] Compounds, Journal of The Electrochemical Society, vol.151, issue.5, p.720, 2004.
DOI : 10.1149/1.1690781

R. D. Shannon and C. T. Prewitt, Effective ionic radii in oxides and fluorides, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.25, issue.5, p.925, 1969.
DOI : 10.1107/S0567740869003220

S. Arai, H. Okada, M. Ohtsuka, J. Ichimura, and . Yamaki, Characterization and cathode performance of Li1 ??? xNi1 + xO2 prepared with the excess lithium method, Solid State Ionics, vol.80, issue.3-4, p.261, 1995.
DOI : 10.1016/0167-2738(95)00144-U

E. Pouillerie, C. Suard, and . Delmas, Structural Characterization of Li1???z???xNi1+zO2 by Neutron Diffraction, Journal of Solid State Chemistry, vol.158, issue.2, p.187, 2001.
DOI : 10.1006/jssc.2001.9092

P. Strobel and B. Lambertandron, Crystallographic and magnetic structure of Li2MnO3, Journal of Solid State Chemistry, vol.75, issue.1, p.90, 1988.
DOI : 10.1016/0022-4596(88)90305-2

K. Numata, C. Sakaki, and S. Yamanaka, Synthesis and characterization of layer structured solid solutions in the system of LiCoO2???Li2MnO3, Solid State Ionics, vol.117, issue.3-4, p.257, 1999.
DOI : 10.1016/S0167-2738(98)00417-2

G. S. Meng, C. P. Ceder, W. S. Grey, Y. Yoon, and . Shao-horn, Understanding the Crystal Structure of Layered LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] by Electron Diffraction and Powder Diffraction Simulation, Electrochemical and Solid-State Letters, vol.7, issue.6, p.155, 2004.
DOI : 10.1149/1.1718211

Y. Koyama, Y. Makimura, I. Tanaka, H. Adachi, and T. Ohzuku, Systematic Research on Insertion Materials Based on Superlattice Models in a Phase Triangle of LiCoO[sub 2]-LiNiO[sub 2]-LiMnO[sub 2], Journal of The Electrochemical Society, vol.151, issue.9, p.1499, 2004.
DOI : 10.1149/1.1783908

P. G. Bruce, A. R. Armstrong, R. L. Gitzendanner, L. Croguennec, P. Deniard et al., New intercalation compounds for lithium batteries: layered LiMnO2, Journal of Materials Chemistry, vol.9, issue.1, pp.193-3323, 1997.
DOI : 10.1039/a803938k

K. Y. Gopukumar, K. B. Chung, and . Kim, Novel synthesis of layered LiNi1/2Mn1/2O2 as cathode material for lithium rechargeable cells, Electrochimica Acta, vol.49, issue.5, p.803, 2004.
DOI : 10.1016/j.electacta.2003.09.034

H. Kobayashi, H. Sakaebe, K. Kageyama, Y. Tatsumi, T. Arachi et al., Changes in the structure and physical properties of the solid solution LiNi1???xMnxO2 with variation in its composition, 11 A. Rougier, I. Saadoune, P. Gravereau, P. Willmann and C. Delmas, Solid State Ionics, pp.590-83, 1996.
DOI : 10.1039/b211558a

C. Delmas, I. Saadoune, and A. Rougier, 13 I. Saadoune and C. Delmas, J. Power Sources J. Mater. Chem, vol.595, issue.6, pp.43-44, 1993.

K. W. Jouanneau, L. J. Eberman, J. R. Krause, and . Dahn, Synthesis, Characterization, and Electrochemical Behavior of Improved Li[Ni[sub x]Co[sub 1???2x]Mn[sub x]]O[sub 2] (0.1???x???0.5), Journal of The Electrochemical Society, vol.150, issue.12, p.1637, 2003.
DOI : 10.1149/1.1622956

D. C. Li, T. Muta, L. Q. Zhang, M. Yoshio, and H. Noguchi, Effect of synthesis method on the electrochemical performance of LiNi1/3Mn1/3Co1/3O2, Journal of Power Sources, vol.132, issue.1-2, p.150, 2004.
DOI : 10.1016/j.jpowsour.2004.01.016

Y. Koyama, N. Yabuuchi, I. Tanaka, H. Adachi, and T. Ohzuku, Solid-State Chemistry and Electrochemistry of LiCo[sub 1/3]Ni[sub 1/3]Mn[sub 1/3]O[sub 2] for Advanced Lithium-Ion Batteries, Journal of The Electrochemical Society, vol.151, issue.10, p.1545, 2004.
DOI : 10.1149/1.1784823

M. Shaju, G. V. Rao, and B. V. Chowdari, Influence of Li-Ion Kinetics in the Cathodic Performance of Layered Li(Ni[sub 1/3]Co[sub 1/3]Mn[sub 1/3])O[sub 2], Journal of The Electrochemical Society, vol.151, issue.9, p.1324, 2004.
DOI : 10.1149/1.1775218

J. K. Ngala, N. A. Chernova, M. M. Ma, M. Mamak, P. Y. Zavalij et al., The synthesis, characterization and electrochemical behavior of the layered LiNi0.4Mn0.4Co0.2O2 compound, Journal of Materials Chemistry, vol.14, issue.2, p.214, 2004.
DOI : 10.1039/b309834f

Z. X. Wang, Y. C. Sun, L. Q. Chen, and X. J. Huang, Electrochemical Characterization of Positive Electrode Material LiNi[sub 1/3]Co[sub 1/3]Mn[sub 1/3]O[sub 2] and Compatibility with Electrolyte for Lithium-Ion Batteries, Journal of The Electrochemical Society, vol.151, issue.6, p.914, 2004.
DOI : 10.1149/1.1740781

W. S. Yoon, C. P. Grey, M. Balasubramanian, X. Q. Yang, D. A. Fischer et al., Combined NMR and XAS Study on Local Environments and Electronic Structures of Electrochemically Li-Ion Deintercalated Li[sub 1???x]Co[sub 1/3]Ni[sub 1/3]Mn[sub 1/3]O[sub 2] Electrode System, Electrochemical and Solid-State Letters, vol.7, issue.3, p.53, 2004.
DOI : 10.1149/1.1643592

Y. K. Sun, S. H. Kang, and K. Amine, Synthesis and electrochemical behavior of layered Li(Ni0.5???xCo2xMn0.5???x)O2 (x = 0 and 0.025) materials prepared by solid-state reaction method, Materials Research Bulletin, vol.39, issue.6, p.819, 2004.
DOI : 10.1016/j.materresbull.2004.02.007

Y. C. Sun, C. Ouyang, Z. X. Wang, X. J. Huang, and L. Q. Chen, Effect of Co Content on Rate Performance of LiMn[sub 0.5???x]Co[sub 2x]Ni[sub 0.5???x]O[sub 2] Cathode Materials for Lithium-Ion Batteries, Journal of The Electrochemical Society, vol.151, issue.4, p.504, 2004.
DOI : 10.1149/1.1647574

S. Jouanneau, D. D. Macneil, Z. Lu, S. D. Beattie, G. Murphy et al., Morphology and Safety of Li[Ni[sub x]Co[sub 1???2x]Mn[sub x]]O[sub 2] (0???x???1/2), Journal of The Electrochemical Society, vol.150, issue.10, p.1299, 2003.
DOI : 10.1149/1.1602077

D. D. Macneil, Z. Lu, J. R. Dahn, and J. , Structure and Electrochemistry of Li[Ni[sub x]Co[sub 1???2x]Mn[sub x]]O[sub 2] (0???x???1/2), Journal of The Electrochemical Society, vol.149, issue.10, pp.1332-71, 2002.
DOI : 10.1149/1.1505633

S. Venkatraman and A. Manthiram, ) ??? 1) Oxides, Chemistry of Materials, vol.15, issue.26, p.5003, 2003.
DOI : 10.1021/cm034757b

J. F. Berar, J. Lelann, A. Rougier, C. Delmas, and G. Chouteau, Applied Cryst, J. Phys. Chem. Solids European Physical Journal B, vol.24, issue.7, pp.1101-551, 1991.

M. Guilmard, C. Pouillerie, L. Croguennec, and C. Delmas, Structural and electrochemical properties of LiNi0.70Co0.15Al0.15O2, Solid State Ionics, vol.160, issue.1-2, p.39, 2003.
DOI : 10.1016/S0167-2738(03)00106-1
URL : https://hal.archives-ouvertes.fr/hal-00207941

J. P. Pérès, F. Weill, and C. Delmas, Lithium/vacancy ordering in the monoclinic LixNiO2 (0.50??????x??????0.75) solid solution, Solid State Ionics, vol.116, issue.1-2, p.19, 1999.
DOI : 10.1016/S0167-2738(98)00239-2

Z. H. Lu and J. R. Dahn, Structure and Electrochemistry of Layered Li[Cr[sub x]Li[sub (1/3???x/3)]Mn[sub (2/3???2x/3)]]O[sub 2], Journal of The Electrochemical Society, vol.149, issue.11, p.1454, 2002.
DOI : 10.1149/1.1513557

Z. H. Lu and J. R. Dahn, Understanding the Anomalous Capacity of Li/Li[Ni[sub x]Li[sub (1/3???2x/3)]Mn[sub (2/3???x/3)]]O[sub 2] Cells Using In Situ X-Ray Diffraction and Electrochemical Studies, Journal of The Electrochemical Society, vol.149, issue.7, p.815, 2002.
DOI : 10.1149/1.1480014

W. Lee, Y. K. Sun, and J. Prakash, A novel layered Li [Li0.12NizMg0.32???zMn0.56]O2 cathode material for lithium-ion batteries, Electrochimica Acta, vol.49, issue.25, p.4425, 2004.
DOI : 10.1016/j.electacta.2004.04.033

R. Stoyanova, E. Zhecheva, R. Alcantara, J. L. Tirado, G. Bromiley et al., Lithium/nickel mixing in the transition metal layers of lithium nickelate: high-pressure synthesis of layered Li[LixNi1???x]O2 oxides as cathode materials for lithium-ion batteries, Solid State Ionics, vol.161, issue.3-4, p.197, 2003.
DOI : 10.1016/S0167-2738(03)00280-7

S. Venkatraman and A. Manthiram, ) ??? 1) Oxides, Chemistry of Materials, vol.15, issue.26, p.5003, 2003.
DOI : 10.1021/cm034757b

L. Tournadre, I. Croguennec, F. Saadoune, Y. Weill, P. Shao-horn et al., System. 1. Its Structural Characterization, Chemistry of Materials, vol.16, issue.8, p.1411, 2004.
DOI : 10.1021/cm035176p
URL : https://hal.archives-ouvertes.fr/hal-00138567

K. M. Shaju, G. V. Rao, and B. V. Chowdari, X-ray photoelectron spectroscopy and electrochemical behaviour of 4 V cathode, Li(Ni1/2Mn1/2)O2, Electrochimica Acta, vol.48, issue.11, p.1505, 2003.
DOI : 10.1016/S0013-4686(03)00088-4

W. Yoon, Y. Paik, X. Yang, M. Balasubramanian, J. Mcbreen et al., Investigation of the Local Structure of the LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] Cathode Material during Electrochemical Cycling by X-Ray Absorption and NMR Spectroscopy, Electrochemical and Solid-State Letters, vol.5, issue.11, p.263, 2002.
DOI : 10.1149/1.1513001

J. F. Berar, J. Lelann, R. Kanno, H. Kubo, Y. Kawamoto et al., Applied Cryst, 19 D. Briggs and M. P. Seah, Auger and X-ray Photoelectron Spectroscopy, pp.216-1168, 1990.

J. C. Dupin, D. Gonbeau, I. Martin-litas, P. Vinatier, A. Levasseur et al., Lithium intercalation/deintercalation in transition metal oxides investigated by X-ray photoelectron spectroscopy, Journal of Electron Spectroscopy and Related Phenomena, vol.120, issue.1-3, pp.55-251, 1973.
DOI : 10.1016/S0368-2048(01)00284-5

H. Kobayashi, H. Sakaebe, K. Kageyama, Y. Tatsumi, T. Arachi et al., Changes in the structure and physical properties of the solid solution LiNi1???xMnxO2 with variation in its composition, Journal of Materials Chemistry, vol.13, issue.3, p.590, 2003.
DOI : 10.1039/b211558a

D. Carlier, I. Saadoune, M. Menetrier, and C. Delmas, Lithium Electrochemical Deintercalation from O2-LiCoO[sub 2], Journal of The Electrochemical Society, vol.149, issue.10, p.1310, 2002.
DOI : 10.1149/1.1503075

M. Guilmard, L. Croguennec, D. Denux, and C. Delmas, = 0.50 and 0.30), Chemistry of Materials, vol.15, issue.23, p.4476, 2003.
DOI : 10.1021/cm030059f

Y. S. Meng, G. Ceder, C. P. Grey, W. S. Yoon, and Y. Shao-horn, Understanding the Crystal Structure of Layered LiNi[sub 0.5]Mn[sub 0.5]O[sub 2] by Electron Diffraction and Powder Diffraction Simulation, Electrochemical and Solid-State Letters, vol.7, issue.6, p.155, 2004.
DOI : 10.1149/1.1718211

P. Strobel and L. , Crystallographic and magnetic structure of Li2MnO3, Journal of Solid State Chemistry, vol.75, issue.1, p.90, 1988.
DOI : 10.1016/0022-4596(88)90305-2

J. S. Kim, C. S. Johnson, J. T. Vaughey, M. M. Thackeray, and S. A. Hackney, ??? 0.3), Chemistry of Materials, vol.16, issue.10, p.1996, 2004.
DOI : 10.1021/cm0306461

A. D. Robertson and P. G. Bruce, Overcapacity of Li[Ni[sub x]Li[sub 1/3???2x/3]Mn[sub 2/3???x/3]]O[sub 2] Electrodes, Electrochemical and Solid-State Letters, vol.7, issue.9, pp.294-720, 2004.
DOI : 10.1149/1.1783114

J. Ammundsen, I. Paulsen, R. S. Davidson, C. H. Liu, J. M. Shen et al., Local Structure and First Cycle Redox Mechanism of Layered Li[sub 1.2]Cr[sub 0.4]Mn[sub 0.4]O[sub 2] Cathode Material, Journal of The Electrochemical Society, vol.149, issue.4, pp.431-432, 2002.
DOI : 10.1149/1.1456535

M. S. Park, S. J. Cho, K. S. Jin, Y. S. Nahm, and . Hong, Effect of Li ion in transition metal sites on electrochemical behavior of layered lithium manganese oxides solid solutions, Solid State Ionics, vol.171, issue.1-2, p.141, 2004.
DOI : 10.1016/j.ssi.2004.04.016

C. P. Grey and N. Dupre, NMR Studies of Cathode Materials for Lithium-Ion Rechargeable Batteries, Chemical Reviews, vol.104, issue.10, p.4493, 2004.
DOI : 10.1021/cr020734p

M. Broussely, F. Perton, P. Biensan, J. M. Bodet, J. Labat et al., LixNiO2, a promising cathode for rechargeable lithium batteries, Journal of Power Sources, vol.54, issue.1, p.109, 1995.
DOI : 10.1016/0378-7753(94)02049-9

J. Choi, A. Manthiram, J. R. Armstrong, and P. G. Bruce, 14 A, Electrochem. Soc. Journal of Materials Chemistry Solid State Ionics, vol.152, issue.176, pp.1714-1035, 2005.

M. Guilmard, A. Rougier, M. Grüne, L. Croguennec, and C. Delmas, Effects of aluminum on the structural and electrochemical properties of LiNiO2, Journal of Power Sources, vol.115, issue.2, p.305, 2003.
DOI : 10.1016/S0378-7753(03)00012-0
URL : https://hal.archives-ouvertes.fr/hal-00242745

M. Guilmard, L. Croguennec, and C. Delmas, Effects of Manganese Substitution for Nickel on the Structural and Electrochemical Properties of LiNiO[sub 2], Journal of The Electrochemical Society, vol.150, issue.10, p.1287, 2003.
DOI : 10.1149/1.1601227

H. Kobayashi, H. Sakaebe, K. Kageyama, Y. Tatsumi, T. Arachi et al., Changes in the structure and physical properties of the solid solution LiNi1???xMnxO2 with variation in its composition, Journal of Materials Chemistry, vol.13, issue.3, p.590, 2003.
DOI : 10.1039/b211558a

L. Q. Zhang, X. Q. Wang, H. Noguchi, M. Yoshio, K. Takada et al., Electrochemical and ex situ XRD investigations on (1???x)LiNiO2??xLi2TiO3 (0.05???x???0.5), Electrochimica Acta, vol.49, issue.20, p.3305, 2004.
DOI : 10.1016/j.electacta.2004.03.002

J. S. Kim, C. S. Johnson, J. T. Vaughey, M. M. Thackeray, and S. A. Hackney, ??? 0.3), Chemistry of Materials, vol.16, issue.10, p.1996, 2004.
DOI : 10.1021/cm0306461