B. Scrosati, J. Electrochem, ]. Soc, J. M. Guyomard, . P. Tarascon-]-j et al., Lithium Rocking Chair Batteries: An Old Concept?, Inoue, International Meeting on Lithium Batteries, pp.2776-408, 1992.
DOI : 10.1149/1.2068978

I. Sandu, T. Brousse, D. M. Schleich, and M. Danot, SnO2 negative electrode for lithium ion cell: in situ M??ssbauer investigation of chemical changes upon discharge, Journal of Solid State Chemistry, vol.177, issue.11, p.4332, 2004.
DOI : 10.1016/j.jssc.2004.06.032

I. Sandu, T. Brousse, D. M. Schleich, and M. Danot, The chemical changes occurring upon cycling of a SnO2 negative electrode for lithium ion cell: In situ M??ssbauer investigation, Journal of Solid State Chemistry, vol.179, issue.2, p.476, 2006.
DOI : 10.1016/j.jssc.2005.10.042

S. C. Nam, Y. S. Yoon, W. I. Cho, B. W. Cho, H. S. Chun et al., Reduction of Irreversibility in the First Charge of Tin Oxide Thin Film Negative Electrodes, Journal of The Electrochemical Society, vol.148, issue.3, p.220, 2001.
DOI : 10.1149/1.1346603

W. H. Lee, H. C. Son, H. S. Moon, Y. I. Kim, S. H. Sung et al., Stoichiometry dependence of electrochemical performance of thin-film SnOx microbattery anodes deposited by radio frequency magnetron sputtering, Journal of Power Sources, vol.89, issue.1, p.102, 2000.
DOI : 10.1016/S0378-7753(00)00382-7

C. Branci, N. Benjelloun, J. Sarradin, and M. Ribes, Vitreous tin oxide-based thin film electrodes for Li-ion micro-batteries, Solid State Ionics, vol.135, issue.1-4, p.169, 2000.
DOI : 10.1016/S0167-2738(00)00297-6

K. S. Park, Y. J. Park, M. K. Kim, J. T. Son, H. G. Kim et al., Characteristics of tin nitride thin-film negative electrode for thin-film microbattery, Journal of Power Sources, vol.103, issue.1, p.67, 2001.
DOI : 10.1016/S0378-7753(01)00829-1

J. Graetz, C. Ahn, R. Yazami, and B. Fultz, The Electrochemical Society Extended abstracts, p.161, 2003.

G. Roberts, D. Ingersoll, S. Spangler, J. Wang, and K. Gross, The Electrochemical Society Extended abstracts, p.162, 2003.

H. Jung, M. Park, and S. K. Joo, The Electrochemical Society Extended abstracts, p.165, 2003.

S. J. Lee, H. K. Baik, and S. M. Lee, An all-solid-state thin film battery using LISIPON electrolyte and Si???V negative electrode films, Electrochemistry Communications, vol.5, issue.1, p.32, 2003.
DOI : 10.1016/S1388-2481(02)00528-3

R. Tillinski, C. Näther, B. Winkler, and W. Bensch, Synthesis and Crystal Structure of K6Ti6S18O: A New Coordination Compound Containing Discrete Ti6O Units in a Chalcogenide Environment, Zeitschrift f??r anorganische und allgemeine Chemie, vol.627, issue.12, p.2576, 2001.
DOI : 10.1002/1521-3749(200112)627:12<2576::AID-ZAAC2576>3.0.CO;2-A

J. A. Cody, C. Deudon, L. Cario, and A. Meerschaut, Synthesis and structure determination of a new cerium titanium oxysulfide [Ce20Ti11S44O6], Materials Research Bulletin, vol.32, issue.9, p.1181, 1997.
DOI : 10.1016/S0025-5408(97)00094-9

E. Schmidt, G. Meunier, and A. Levasseur, Electrochemical properties of new amorphous molybdenum oxysulfide thin films, Solid State Ionics, vol.76, issue.3-4, p.243, 1995.
DOI : 10.1016/0167-2738(94)00284-Y

J. B. Bates, D. Lubben, N. J. Dudney, and F. X. Hart, 5 Volt Plateau in LiMn[sub 2]O[sub 4] Thin Films, Journal of The Electrochemical Society, vol.142, issue.9, p.149, 1995.
DOI : 10.1149/1.2048729

J. B. Bates, N. J. Dudney, D. C. Lubben, G. R. Gruzalski, B. S. Kwak et al., Thin-film rechargeable lithium batteries, Journal of Power Sources, vol.54, issue.1, p.58, 1995.
DOI : 10.1016/0378-7753(94)02040-A

J. B. Bates, N. J. Dudney, B. J. Neudecker, A. Ueda, and C. D. Evans, Thin-film lithium and lithium-ion batteries, Solid State Ionics, vol.135, issue.1-4, p.33, 2000.
DOI : 10.1016/S0167-2738(00)00327-1

N. J. Dudney, Solid-state thin-film rechargeable batteries, Materials Science and Engineering: B, vol.116, issue.3, p.245, 2005.
DOI : 10.1016/j.mseb.2004.05.045

J. B. Bates, N. J. Dudney, B. J. Neudecker, F. X. Hart, H. P. Jun et al., Preferred Orientation of Polycrystalline LiCoO[sub 2] Films, Journal of The Electrochemical Society, vol.147, issue.1, p.59, 2000.
DOI : 10.1149/1.1393157

C. Navone, R. Baddour-hadjean, J. P. Pereira-ramos, and R. Salot, High-Performance Oriented V[sub 2]O[sub 5] Thin Films Prepared by DC Sputtering for Rechargeable Lithium Microbatteries, Journal of The Electrochemical Society, vol.152, issue.9, p.1790, 2005.
DOI : 10.1149/1.1990160

A. Benayad, H. Martinez, A. Gies, B. Pecquenard, A. Levasseur et al., XPS investigations achieved on the first cycle of V2O5 thin films used in lithium microbatteries, Journal of Electron Spectroscopy and Related Phenomena, vol.150, issue.1, p.1, 2006.
DOI : 10.1016/j.elspec.2005.09.001

URL : https://hal.archives-ouvertes.fr/hal-00070928

F. Sauvage, E. Baudrin, M. Morcrette, and J. M. Tarascon, Pulsed Laser Deposition and Electrochemical Properties of LiFePO[sub 4] Thin Films, Electrochemical and Solid-State Letters, vol.7, issue.1, p.15, 2004.
DOI : 10.1149/1.1630411

W. C. West, J. F. Whitacre, and B. V. Ratnakumar, Radio Frequency Magnetron-Sputtered LiCoPO[sub 4] Cathodes for 4.8 V Thin-Film Batteries, Journal of The Electrochemical Society, vol.150, issue.12, p.1660, 2003.
DOI : 10.1149/1.1619987

M. Yamashita, H. Yamanaka, and H. Wakabayashi, Thin-film preparation of the Li2S_GeS2_Ga2S3 glass system by sputtering, Solid State Ionics, vol.89, issue.3-4, p.299, 1996.
DOI : 10.1016/0167-2738(96)00342-6

H. Wada, M. Ménétrier, A. Levasseur, and P. Hagenmuller, Preparation and ionic conductivity of new B2S3-Li2S-LiI glasses, Materials Research Bulletin, vol.18, issue.2, p.189, 1983.
DOI : 10.1016/0025-5408(83)90080-6

M. Ménétrier, A. Levasseur, and P. Hagenmuller, Electrochemical Properties of B[sub 2]S[sub 3]-Li[sub 2]S-LiI Vitreous Electrolytes, Journal of The Electrochemical Society, vol.131, issue.9, p.1971, 1984.
DOI : 10.1149/1.2116002

K. H. Joo, P. Vinatier, B. Pecquenard, A. Levasseur, and H. J. Sohn, Thin film lithium ion conducting LiBSO solid electrolyte, Solid State Ionics, vol.160, issue.1-2, p.51, 2003.
DOI : 10.1016/S0167-2738(03)00163-2

URL : https://hal.archives-ouvertes.fr/hal-00195921

K. H. Joo, H. J. Sohn, P. Vinatier, B. Pecquenard, and A. Levasseur, Lithium Ion Conducting Lithium Sulfur Oxynitride Thin Film, Electrochemical and Solid-State Letters, vol.7, issue.8, p.256, 2004.
DOI : 10.1149/1.1769317

URL : https://hal.archives-ouvertes.fr/hal-00150337

G. Meunier, R. Dormoy, and A. Levasseur, New positive-electrode materials for lithium thin film secondary batteries, Materials Science and Engineering: B, vol.3, issue.1-2, p.19, 1989.
DOI : 10.1016/0921-5107(89)90173-6

H. Benqlilou-moudden, G. Blondiaux, P. Vinatier, and A. Levasseur, Amorphous lithium cobalt and nickel oxides thin films: preparation and characterization by RBS and PIGE, Thin Solid Films, vol.333, issue.1-2, p.16, 1998.
DOI : 10.1016/S0040-6090(98)00572-0

K. J. Rao, H. Benqlilou-moudden, G. Couturier, P. Vinatier, and A. Levasseur, Structure and electrical properties of sputtered lithium cobaltite thin films, Materials Research Bulletin, vol.37, issue.7, p.1353, 2002.
DOI : 10.1016/S0025-5408(02)00756-0

URL : https://hal.archives-ouvertes.fr/hal-00728211

J. B. Bates, N. J. Dudney, G. R. Gruzalski, R. A. Zuhr, A. Choudhury et al., Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries, Journal of Power Sources, vol.43, issue.1-3, p.103, 1993.
DOI : 10.1016/0378-7753(93)80106-Y

B. Wang, J. B. Bates, F. X. Hart, B. C. Sales, R. A. Zuhr et al., Characterization of Thin-Film Rechargeable Lithium Batteries with Lithium Cobalt Oxide Cathodes, Journal of The Electrochemical Society, vol.143, issue.10, p.3203, 1996.
DOI : 10.1149/1.1837188

B. J. Neudecker, N. J. Dudney, and J. B. Bates, ???Lithium-Free??? Thin-Film Battery with In Situ Plated Li Anode, Journal of The Electrochemical Society, vol.147, issue.2, p.517, 2000.
DOI : 10.1149/1.1393226

J. W. Long, B. Dunn, D. R. Rolison, and H. S. White, Three-Dimensional Battery Architectures, Chemical Reviews, vol.104, issue.10, p.4463, 2004.
DOI : 10.1021/cr020740l

R. W. Hart, H. S. White, B. Dunn, and D. R. Rolison, 3-D Microbatteries, Electrochemistry Communications, vol.5, issue.2, p.120, 2003.
DOI : 10.1016/S1388-2481(02)00556-8

C. Wang, L. Taherabadi, J. Guangyao, M. Madou, Y. Yuting et al., C-MEMS for the Manufacture of 3D Microbatteries, Electrochemical and Solid-State Letters, vol.7, issue.11, p.435, 2004.
DOI : 10.1149/1.1798151

M. Nathan, D. Golodnitsky, V. Yufit, E. Strauss, T. Ripenbein et al., Three-dimensional thin-film Li-ion microbatteries for autonomous MEMS, Journal of Microelectromechanical Systems, vol.14, issue.5, p.879, 2005.
DOI : 10.1109/JMEMS.2005.851860

J. Y. Emery, Microionics, 1991.

M. Balkanski, C. Julien, and J. Y. Emery, Integrable lithium solid-state microbatteries, Journal of Power Sources, vol.26, issue.3-4, p.615, 1989.
DOI : 10.1016/0378-7753(89)80189-2

C. Julien, I. Samaras, M. Tsakiri, P. Dzwonkowski, and M. Balkanski, Lithium insertion in In???Se films and applications in microbatteries, Materials Science and Engineering: B, vol.3, issue.1-2, p.25, 1989.
DOI : 10.1016/0921-5107(89)90174-8

C. Julien and M. Balkanski, Thin-film microbatteries, 1991.

H. Ohtsuka and J. Yamaki, Electrical characteristics of Li2O_V2O5_SiO2 thin films, Solid State Ionics, vol.35, issue.3-4, p.201, 1989.
DOI : 10.1016/0167-2738(89)90296-8

S. D. Jones, J. R. Akridge, S. G. Humphrey, C. C. Liu, and J. Sarradin, A Thin Film Solid State Nicrobattery for Use in Powering Nicrosensors, MRS Proceedings, vol.135, p.31, 1991.
DOI : 10.1557/PROC-210-31

S. D. Jones, J. R. Akridge, and F. K. Shokoohi, Thin film rechargeable Li batteries, Solid State Ionics, vol.69, issue.3-4, p.357, 1994.
DOI : 10.1016/0167-2738(94)90423-5

F. K. Shokoohi, J. M. Tarascon, B. J. Wilkens, D. Guyomard, and C. C. Chang, Low Temperature LiMn[sub 2]O[sub 4] Spinel Films for Secondary Lithium Batteries, Journal of The Electrochemical Society, vol.139, issue.7, p.1845, 1992.
DOI : 10.1149/1.2069509

E. J. Plichta, W. K. Behl, W. H. Chang, and D. M. Schleich, The Rechargeable LiAl/Li[sub 3.6]Ge[sub 0.6]V[sub 0.4]O[sub 4]/TiS[sub 2] High Temperature Solid-State Cell, Journal of The Electrochemical Society, vol.141, issue.6, p.1418, 1994.
DOI : 10.1149/1.2054940

P. Birke, W. F. Chu, and W. Weppner, Materials for lithium thin-film batteries for application in silicon technology, Solid State Ionics, vol.93, issue.1-2, p.1, 1997.
DOI : 10.1016/S0167-2738(96)00489-4

S. Lee, P. Liu, C. E. Tracy, and D. K. Benson, All-Solid-State Rocking Chair Lithium Battery on a Flexible Al Substrate, Electrochemical and Solid-State Letters, vol.2, issue.9, p.425, 1999.
DOI : 10.1149/1.1390859

K. Kushida, K. Kuriyama, and T. Nozaki, all-solid-state Li secondary battery arrays embedded in a Si substrate, Applied Physics Letters, vol.81, issue.26, p.5066, 2002.
DOI : 10.1063/1.1531220

M. Martin and F. Faverjon, Thin Solid Films Chapitre I : Généralités et contexte bibliographique, pp.398-399, 2001.

J. N. Harb, R. M. Lafollette, R. H. Selfridge, and L. L. Howell, Microbatteries for self-sustained hybrid micropower supplies, Journal of Power Sources, vol.104, issue.1, p.46, 2002.
DOI : 10.1016/S0378-7753(01)00904-1

R. A. Huggins, Supercapacitors and electrochemical pulse sources, Solid State Ionics, vol.134, issue.1-2, p.179, 2000.
DOI : 10.1016/S0167-2738(00)00725-6

F. R. Gamble, J. H. Osiecki, M. Cais, R. Pisharody, F. J. Disalvo et al., Intercalation Complexes of Lewis Bases and Layered Sulfides: A Large Class of New Superconductors, Science, vol.18, issue.5, p.493, 1971.
DOI : 10.1073/pnas.57.5.1131

M. S. Whittingham, Chemistry of intercalation compounds: Metal guests in chalcogenide hosts, Progress in Solid State Chemistry, vol.12, issue.1, p.41, 1978.
DOI : 10.1016/0079-6786(78)90003-1

M. S. Whittingham, The hydrated intercalation complexes of the layered disulfides, Materials Research Bulletin, vol.9, issue.12, p.1681, 1974.
DOI : 10.1016/0025-5408(74)90162-7

M. S. Whittingham and F. R. Gamble, The lithium intercalates of the transition metal dichalcogenides, Materials Research Bulletin, vol.10, issue.5, p.363, 1975.
DOI : 10.1016/0025-5408(75)90006-9

B. G. Silbernagel and M. S. Whittingham, The physical properties of the NaxTiS2 intercalation compounds: A synthetic and NMR study, Materials Research Bulletin, vol.11, issue.1, p.29, 1976.
DOI : 10.1016/0025-5408(76)90210-5

M. S. Whittingham, The Role of Ternary Phases in Cathode Reactions, Journal of The Electrochemical Society, vol.123, issue.3, p.315, 1976.
DOI : 10.1149/1.2132817

M. S. Whittingham, Electrical Energy Storage and Intercalation Chemistry, Science, vol.192, issue.4244, p.1126, 1976.
DOI : 10.1126/science.192.4244.1126

H. Imai, Y. Shimakawa, and Y. Kubo, crystal with nearly stoichiometric composition, Physical Review B, vol.64, issue.24, p.241104, 2001.
DOI : 10.1103/PhysRevB.64.241104

M. Anderman and J. T. Lundquist, Improved Li-TiS[sub 2] Cells of Spirally Wound Design, Journal of The Electrochemical Society, vol.135, issue.5, p.1167, 1988.
DOI : 10.1149/1.2095906

S. Surampudi, D. H. Shen, C. K. Huang, F. Deligiannis, A. Attia et al., Advances in Li???TiS2 cell technology, Journal of Power Sources, vol.36, issue.3, p.395, 1991.
DOI : 10.1016/0378-7753(91)87015-4

M. H. Lindic, B. Pecquenard, P. Vinatier, A. Levasseur, H. Martinez et al., Electrochemical Mechanisms during Lithium Insertion into TiO[sub 0.6]S[sub 2.8] Thin Film Positive Electrode in Lithium Microbatteries, Journal of The Electrochemical Society, vol.152, issue.1, p.141, 2005.
DOI : 10.1149/1.1834893

M. H. Klaproth, Analytical Essays Toward Promoting the Chemical Knowledge of Mineral Substances, 1801.

W. Biltz, P. Ehrlich, and K. Meisel, Beitr??ge zur systematischen Verwandtschaftslehre. 75. ??ber die Sulfide des Titans, Zeitschrift f??r anorganische und allgemeine Chemie, vol.228, issue.2, p.97, 1937.
DOI : 10.1002/zaac.19372340202

R. R. Chianelli, J. C. Scanlon, and A. H. Thompson, Structure refinement of stoichiometric TiS2, Materials Research Bulletin, vol.10, issue.12, p.1379, 1975.
DOI : 10.1016/0025-5408(75)90100-2

J. Bénard and Y. Jeannin, Investigations of Nonstoichiometric Sulfides, Adv. Chem, vol.39, p.191, 1963.
DOI : 10.1021/ba-1964-0039.ch017

A. H. Thompson, F. R. Gamble, and C. R. Symon, The verification of the existence of TiS2, Materials Research Bulletin, vol.10, issue.9, p.915, 1975.
DOI : 10.1016/0025-5408(75)90071-9

D. A. Winn and B. C. Steele, Thermodynamic characterisation of non-stoichiometric titanium di-sulphide, Materials Research Bulletin, vol.11, issue.5, p.551, 1976.
DOI : 10.1016/0025-5408(76)90238-5

M. S. Whittingham and J. A. Panella, Formation of stoichiometric titanium disulfide, Materials Research Bulletin, vol.16, issue.1, p.37, 1981.
DOI : 10.1016/0025-5408(81)90175-6

M. J. Mckelvy and W. S. Glaunsinger, Compositional and structural investigations of highly stoichiometric titanium disulfide, Materials Research Bulletin, vol.21, issue.7, p.835, 1986.
DOI : 10.1016/0025-5408(86)90169-8

M. J. Mckelvy and W. S. Glaunsinger, Synthesis and characterization of nearly stoichiometric titanium disulfide, Journal of Solid State Chemistry, vol.66, issue.1, p.181, 1987.
DOI : 10.1016/0022-4596(87)90233-7

S. Kikkawa, R. Shimanouchi-futagami, and M. Koizumi, Plasma assisted CVD of TiS2, Applied Physics A Solids and Surfaces, vol.17, issue.19, p.105, 1989.
DOI : 10.1007/BF00615472

R. R. Chianelli and M. B. Dines, Low-temperature solution preparation of Group 4B, 5B and 6B transition-metal dichalcogenides, Inorganic Chemistry, vol.17, issue.10, p.2758, 1978.
DOI : 10.1021/ic50188a014

A. Bensalem and D. M. Schleich, Novel low temperature synthesis of titanium sulfide, Materials Research Bulletin, vol.23, issue.6, p.857, 1988.
DOI : 10.1016/0025-5408(88)90080-3

M. A. Sriram and P. N. Kumta, New molecular routes for synthesizing titanium disulfide, Materials Science and Engineering: B, vol.33, issue.2-3, p.140, 1995.
DOI : 10.1016/0921-5107(94)01180-X

M. A. Sriram, K. S. Weil, and P. N. Kumta, Low-Temperature Chemical Approaches for Synthesizing Sulfides and Nitrides of Reactive Transition Metals, Applied Organometallic Chemistry, vol.13, issue.2, p.163, 1997.
DOI : 10.1002/(SICI)1099-0739(199702)11:2<163::AID-AOC564>3.0.CO;2-S

K. Kanehori, F. Kirino, Y. Ito, K. Miyauchi, and T. Kudo, Kinetic Study on Chemical Vapor Deposition of Titanium Disulfide Thin Film, Journal of The Electrochemical Society, vol.136, issue.5, p.1265, 1989.
DOI : 10.1149/1.2096903

S. Kikkawa, M. Miyazaki, and M. Koizumi, Titanium disulfide thin film prepared by plasma CVD, Journal of Materials Research, vol.5, issue.12, p.2894, 1990.
DOI : 10.1016/0079-6786(78)90003-1

H. S. Chang and D. M. Schleich, TiS2 and TiS3 thin films prepared by MOCVD, Journal of Solid State Chemistry, vol.100, issue.1, p.62, 1992.
DOI : 10.1016/0022-4596(92)90156-P

C. H. Winter, T. S. Lewkebandara, and J. W. Proscia, Low-temperature atmospheric pressure chemical vapor deposition of titanium disulfide films, Chemistry of Materials, vol.4, issue.6, p.1144, 1992.
DOI : 10.1021/cm00024a007

C. H. Winter, T. S. Lewkebandara, J. W. Proscia, and A. R. Rheingold, A class of single-source precursors to titanium disulfide films. Synthesis, structure, and chemical vapor deposition studies of [TiCl4(HSR)2], Inorganic Chemistry, vol.32, issue.18, p.3807, 1993.
DOI : 10.1021/ic00070a007

J. Phalippou, Techniques de l'ingénieur Chapitre I : Généralités et contexte bibliographique, 2001.

J. Zarzycki, Les verres et l'état vitreux, 1982.

S. R. Elliott, Physics of amorphous materials-Second edition, Longman Scientific & Technical, United Kingdom, 1990.

W. H. Zachariasen, THE ATOMIC ARRANGEMENT IN GLASS, Journal of the American Chemical Society, vol.54, issue.10, p.3841, 1932.
DOI : 10.1021/ja01349a006

K. H. Sun and J. Am, FUNDAMENTAL CONDITION OF GLASS FORMATION, Journal of the American Ceramic Society, vol.25, issue.3, p.277, 1947.
DOI : 10.1021/ja01349a006

H. Rawson, IVème Congrès International du Verre, p.62, 1956.

D. Turnbull and M. Cohen, Concerning Reconstructive Transformation and Formation of Glass, The Journal of Chemical Physics, vol.29, issue.5, p.1049, 1958.
DOI : 10.1063/1.1744654

J. L. Souquet, A. Kone, and M. Levy, Theory and Applications of Amorphous Solid for Electrochemical Cells, Solid State Microbatteries
DOI : 10.1007/978-1-4899-2263-2_16

R. W. Cahn, Materials Science and Technology: A Comprehensive Treatment
DOI : 10.1002/9783527619306

A. Levasseur, J. C. Brethous, J. M. Reau, and P. Hagenmuller, Etude comparee de la conductivite ionique du lithium dans les halogenoborates vitreux, Materials Research Bulletin, vol.14, issue.7, p.921, 1979.
DOI : 10.1016/0025-5408(79)90158-2

A. Levasseur, M. Kbala, J. C. Brethous, J. M. Réau, and P. Hagenmuller, Etudes electrique et Raman des verres du systeme B2O3 - Li2O - Li2SO4, Solid State Communications, vol.32, issue.10, p.839, 1979.
DOI : 10.1016/0038-1098(79)90482-4

K. Nassau, R. J. Cava, and A. M. Glass, The ionic conductivity variation in rapidly quenched lithium-containing glasses, Solid State Ionics, vol.2, issue.3, p.163, 1981.
DOI : 10.1016/0167-2738(81)90174-0

K. Hirai, M. Tatsumisago, and T. Minami, Thermal and electrical properties of rapidly quenched glasses in the systems Li2S_SiS2_LixMOy (LixMOy = Li4SiO4, Li2SO4), Solid State Ionics, vol.78, issue.3-4, p.269, 1995.
DOI : 10.1016/0167-2738(95)00094-M

B. Wang, B. S. Kwak, B. C. Sales, and J. B. Bates, Ionic conductivities and structure of lithium phosphorus oxynitride glasses, Journal of Non-Crystalline Solids, vol.183, issue.3, p.297, 1995.
DOI : 10.1016/0022-3093(94)00665-2

R. Sakamoto, M. Tatsumisago, and T. Minami, N, The Journal of Physical Chemistry B, vol.103, issue.20, p.4029, 1999.
DOI : 10.1021/jp983755p

URL : https://hal.archives-ouvertes.fr/jpa-00213821

F. Mizuno, A. Hayashi, K. Tadanaga, T. Minami, and M. Tatsumisago, All-solid-state lithium secondary batteries using Li2S?SiS2?Li4SiO4 glasses and Li2S?P2S5 glass ceramics as solid electrolytes, Solid State Ionics, vol.175, issue.1-4, p.699, 2004.
DOI : 10.1016/j.ssi.2004.08.027

A. Hayashi, S. Hama, F. Mizuno, K. Tadanaga, T. Minami et al., Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries, Solid State Ionics, vol.175, issue.1-4, p.683, 2004.
DOI : 10.1016/j.ssi.2004.08.036

F. Mizuno, A. Hayashi, K. Tadanaga, and M. Tatsumisago, New, Highly Ion-Conductive Crystals Precipitated from Li2S-P2S5 Glasses, Advanced Materials, vol.5, issue.19, p.918, 2005.
DOI : 10.1002/adma.200401286

M. Tatsumisago, Glassy materials based on Li2S for all-solid-state lithium secondary batteries, Solid State Ionics, vol.175, issue.1-4, p.13, 2004.
DOI : 10.1016/j.ssi.2004.09.012

Y. I. Lee, J. H. Lee, S. H. Hong, and Y. S. Park, Li-ion conductivity in Li2O?B2O3?V2O5 glass system, Solid State Ionics, vol.175, issue.1-4, p.687, 2004.
DOI : 10.1016/j.ssi.2004.08.024

N. J. Dudney, Addition of a thin-film inorganic solid electrolyte (Lipon) as a protective film in lithium batteries with a liquid electrolyte, Journal of Power Sources, vol.89, issue.2, p.176, 2000.
DOI : 10.1016/S0378-7753(00)00427-4

K. Chung, W. S. Kim, and Y. K. Choi, Lithium phosphorous oxynitride as a passive layer for anodes in lithium secondary batteries, Journal of Electroanalytical Chemistry, vol.566, issue.2, p.263, 2004.
DOI : 10.1016/j.jelechem.2003.11.035

S. Zhao, Z. Fu, and Q. Qin, A solid-state electrolyte lithium phosphorus oxynitride film prepared by pulsed laser deposition, Thin Solid Films, vol.415, issue.1-2, p.108, 2002.
DOI : 10.1016/S0040-6090(02)00543-6

S. J. Lee, J. H. Bae, H. W. Lee, H. K. Baik, and S. M. Lee, Electrical conductivity in Li???Si???P???O???N oxynitride thin-films, Journal of Power Sources, vol.123, issue.1, p.61, 2003.
DOI : 10.1016/S0378-7753(03)00457-9

J. K. Ahn and S. G. Yoon, Characteristics of perovskite (Li0.5La0.5)TiO3 solid electrolyte thin films grown by pulsed laser deposition for rechargeable lithium microbattery, Electrochimica Acta, vol.50, issue.2-3, p.371, 2004.
DOI : 10.1016/j.electacta.2004.02.065

A. Richardt and A. M. Durand, Généralités sur les technologies de dépôt sous videDépôts de couches minces par pulvérisation (sputtering), Le vide-Les couches minces-Les couches dures Fine, p.1, 1985.

M. Martin, F. K. Faverjon-]-w, J. W. Chu, M. A. Mayer, and . Nicolet, Thin Solid FilmsBackscattering spectrometry, Nucl. Instrum. Methods Phys. Res. B, vol.572, issue.15, pp.398-399, 1978.

D. Aurbach, E. Zinigrad, Y. Cohen, and H. Teller, A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions, Solid State Ionics, vol.148, issue.3-4, p.405, 2002.
DOI : 10.1016/S0167-2738(02)00080-2

M. H. Lindic, H. Martinez, A. Benayad, B. Pecquenard, P. Vinatier et al., XPS investigations of TiOySz amorphous thin films used as positive electrode in lithium microbatteries, Solid State Ionics, vol.176, issue.17-18, p.1529, 2005.
DOI : 10.1016/j.ssi.2005.04.007

URL : https://hal.archives-ouvertes.fr/hal-00096015

H. L. Tuller, D. P. Button, and D. R. Uhlmann, Fast ion transport in oxide glasses, Journal of Non-Crystalline Solids, vol.40, issue.1-3, p.93, 1980.
DOI : 10.1016/0022-3093(80)90096-4

C. Gabrielli, Techniques de l'ingénieur, PE, vol.2, issue.210, p.1, 1994.

C. Gabrielli, Solartron Instruments Farnborough Références bibliographiques du chapitre III [1] P. Zeman and S. Takabayashi, Surf. Coat. Technol, vol.153, p.93, 1990.

I. Martin-litas, P. Vinatier, A. Levasseur, J. C. Dupin, D. Gonbeau et al., Characterisation of r.f. sputtered tungsten disulfide and oxysulfide thin films, Thin Solid Films, vol.416, issue.1-2, p.1, 2002.
DOI : 10.1016/S0040-6090(02)00717-4

URL : https://hal.archives-ouvertes.fr/hal-00817518

J. A. Thornton, High Rate Thick Film Growth, Annual Review of Materials Science, vol.7, issue.1, pp.239-246, 1977.
DOI : 10.1146/annurev.ms.07.080177.001323

M. H. Lindic, H. Martinez, A. Benayad, B. Pecquenard, P. Vinatier et al., Solid State Ionics, Thin Solid Films, vol.176, issue.106, p.1529, 1998.

K. Dokko, N. Anzue, M. Mohamedi, T. Itoh, and I. Uchida, Raman spectro-electrochemistry of LiCoxMn2???xO4 thin film electrodes for 5 V lithium batteries, Electrochemistry Communications, vol.6, issue.4, p.384, 2004.
DOI : 10.1016/j.elecom.2004.02.005

V. V. Yakovlev, G. Scarel, C. R. Aita, and S. Mochizuki, Short-range order in ultrathin film titanium dioxide studied by Raman spectroscopy, Applied Physics Letters, vol.76, issue.9, p.1107, 2000.
DOI : 10.1063/1.125953

S. Kitazawa, C. Yeongsoo, and S. Yamamoto, In situ optical spectroscopy of PLD of nano-structured TiO2, Vacuum, vol.74, issue.3-4, p.637, 2004.
DOI : 10.1016/j.vacuum.2004.01.048

L. V. Hong, N. T. Le, N. C. Thuan, N. D. Thanh, N. X. Nghia et al., Observation of the phase formation in TiO2 nano thin film by Raman scattering, Journal of Raman Spectroscopy, vol.37, issue.10, p.946, 2005.
DOI : 10.1002/jrs.1388

B. Wang, J. B. Bates, F. X. Hart, B. C. Sales, R. A. Zuhr et al., Characterization of Thin-Film Rechargeable Lithium Batteries with Lithium Cobalt Oxide Cathodes, Journal of The Electrochemical Society, vol.143, issue.10, p.3203, 1996.
DOI : 10.1149/1.1837188

A. Kuhn, R. Amandi, and F. Garcia-alvarado, Electrochemical lithium insertion in TiO2 with the ramsdellite structure, Journal of Power Sources, vol.92, issue.1-2, p.221, 2001.
DOI : 10.1016/S0378-7753(00)00530-9

G. Armstrong, A. R. Armstrong, J. Canales, and P. G. Bruce, TiO[sub 2](B) Nanotubes as Negative Electrodes for Rechargeable Lithium Batteries, Electrochemical and Solid-State Letters, vol.9, issue.3, p.139, 2006.
DOI : 10.1149/1.2162327

A. R. Armstrong, G. Armstrong, J. Canales, and P. G. Bruce, TiO2???B nanowires as negative electrodes for rechargeable lithium batteries, Journal of Power Sources, vol.146, issue.1-2, p.501, 2005.
DOI : 10.1016/j.jpowsour.2005.03.057

T. Brousse, R. Marchand, P. L. Taberna, and P. Simon, TiO2 (B)/activated carbon non-aqueous hybrid system for energy storage, Journal of Power Sources, vol.158, issue.1, p.571, 2006.
DOI : 10.1016/j.jpowsour.2005.09.020

URL : https://hal.archives-ouvertes.fr/hal-00474875

M. Poulain, Glass formation in ionic systems, Nature, vol.32, issue.5830, p.279, 1981.
DOI : 10.1038/293279a0

L. Zhenhua, Chemical bond approach to the chalcogenide glass forming tendency, Journal of Non-Crystalline Solids, vol.127, issue.3, p.298, 1991.
DOI : 10.1016/0022-3093(91)90482-L

I. A. Courtney and J. R. Dahn, Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites, Journal of The Electrochemical Society, vol.144, issue.6, p.2045, 1997.
DOI : 10.1149/1.1837740

I. Sandu, T. Brousse, D. M. Schleich, and M. Danot, SnO2 negative electrode for lithium ion cell: in situ M??ssbauer investigation of chemical changes upon discharge, Journal of Solid State Chemistry, vol.177, issue.11, p.4332, 2004.
DOI : 10.1016/j.jssc.2004.06.032

I. Sandu, T. Brousse, D. M. Schleich, and M. Danot, The chemical changes occurring upon cycling of a SnO2 negative electrode for lithium ion cell: In situ M??ssbauer investigation, Journal of Solid State Chemistry, vol.179, issue.2, p.476, 2006.
DOI : 10.1016/j.jssc.2005.10.042

C. Rossignol, G. Ouvrard, and E. Baudrin, X-Ray Absorption Spectroscopy Study of the Structural and Electronic Changes upon Cycling of LiNiVO[sub 4] as a Battery Electrode, Journal of The Electrochemical Society, vol.148, issue.8, p.869, 2001.
DOI : 10.1149/1.1382590

R. T. Sanderson, Polar covalence, 1983.

G. Adam and J. H. Gibbs, On the Temperature Dependence of Cooperative Relaxation Properties in Glass???Forming Liquids, The Journal of Chemical Physics, vol.43, issue.1, p.139, 1965.
DOI : 10.1063/1.1696442

R. W. Cahn, Materials Science and Technology: A Comprehensive Treatment
DOI : 10.1002/9783527619306

K. J. Rao, Structural Chemistry of Glasses, 2002.

C. A. Angell, Solid State Ionics, pp.18-19, 1986.

S. Sakka, K. Kamiya, and T. Yoko, Preparation and properties of Ca???Al???Si???O???N oxynitride glasses, Journal of Non-Crystalline Solids, vol.56, issue.1-3, p.147, 1983.
DOI : 10.1016/0022-3093(83)90460-X

T. Grande, J. R. Holloway, P. F. Mcmillan, and C. A. Angell, Nitride glasses obtained by high-pressure synthesis, Nature, vol.369, issue.6475, p.43, 1994.
DOI : 10.1038/369043a0

M. M. Thackeray, W. I. David, and J. B. Goodenough, High-temperature lithiation of ??-Fe2O3: A mechanistic study, Journal of Solid State Chemistry, vol.55, issue.3, p.280, 1984.
DOI : 10.1016/0022-4596(84)90278-0

L. M. Fransson, J. T. Vaughey, R. Benedek, K. Edstrom, J. O. Thomas et al., Phase transitions in lithiated Cu2Sb anodes for lithium batteries: an in situ X-ray diffraction study, Electrochemistry Communications, vol.3, issue.7, p.317, 2001.
DOI : 10.1016/S1388-2481(01)00140-0

I. Chapitre, Utilisation d'un indice de formation d'une phase amorphe pour prédire le comportement d'un matériau d'électrode

K. D. Kepler, J. T. Vaughey, and M. M. Thackeray, Li[sub x]Cu[sub 6]Sn[sub 5]???(0<x<13): An Intermetallic Insertion Electrode for Rechargeable Lithium Batteries, Electrochemical and Solid-State Letters, vol.2, issue.7, p.307, 1999.
DOI : 10.1149/1.1390819

J. T. Vaughey, J. O. Hara, and M. M. Thackeray, Intermetallic Insertion Electrodes with a Zinc Blende-Type Structure for Li Batteries: A Study of Li[sub x]InSb???(0???x???3), Electrochemical and Solid-State Letters, vol.3, issue.1, p.13, 2000.
DOI : 10.1149/1.1390944

R. Alcantara, J. Fernandez-madrigal, P. Lavela, J. L. Tirado, J. C. Jumas et al., Electrochemical reaction of lithium with the CoSb3 skutterudite, Journal of Materials Chemistry, vol.9, issue.10, p.2517, 1999.
DOI : 10.1039/a902060h

K. West and A. M. Crespi, Lithium insertion into silver vanadium oxide, Ag2V4O11, Journal of Power Sources, vol.54, issue.2, p.334, 1995.
DOI : 10.1016/0378-7753(94)02095-K

M. M. Thackeray, S. D. Baker, K. T. Adendorff, and J. B. Goodenough, Lithium insertion into Co3O4: A preliminary investigation, Solid State Ionics, vol.17, issue.2, p.175, 1985.
DOI : 10.1016/0167-2738(85)90069-4

D. Larcher, G. Sudant, J. B. Leriche, Y. Chabre, and J. M. Tarascon, The Electrochemical Reduction of Co[sub 3]O[sub 4] in a Lithium Cell, Journal of The Electrochemical Society, vol.149, issue.3, p.234, 2002.
DOI : 10.1149/1.1435358

F. Leroux, G. R. Goward, W. P. Power, and L. F. Nazar, Understanding the Nature of Low-Potential Li Uptake into High Volumetric Capacity Molybdenum Oxides, Electrochemical and Solid-State Letters, vol.1, issue.6, p.255, 1998.
DOI : 10.1149/1.1390704

T. Tsumura and M. Inagaki, Lithium insertion/extraction reaction on crystalline MoO3, Solid State Ionics, vol.104, issue.3-4, p.183, 1997.
DOI : 10.1016/S0167-2738(97)00418-9

I. Martin-litas, P. Vinatier, A. Levasseur, J. C. Dupin, and D. Gonbeau, Electrochemical properties of tungsten oxysulphide thin films as positive electrodes for lithium microbatteries, Bulletin of Materials Science, vol.77, issue.82, p.673, 2003.
DOI : 10.1007/BF02706762

URL : https://hal.archives-ouvertes.fr/hal-00169102

M. S. Whittingham, Lithium Batteries and Cathode Materials, Chemical Reviews, vol.104, issue.10, p.4271, 2004.
DOI : 10.1021/cr020731c

L. Hernan, M. Macias, J. Morales, L. Sanchez, and J. L. Tirado, Lithium insertion into pyrochlore WO3, Solid State Ionics, vol.48, issue.3-4, p.231, 1991.
DOI : 10.1016/0167-2738(91)90037-C

D. C. Silva, O. Crosnier, G. Ouvrard, J. Greedan, A. Sefat et al., Reversible Lithium Uptake by FeP[sub 2], Electrochemical and Solid-State Letters, vol.6, issue.8, p.162, 2003.
DOI : 10.1149/1.1588112

W. Liu, X. Huang, Z. Wang, H. Li, and L. Chen, Studies of Stannic Oxide as an Anode Material for Lithium-Ion Batteries, Journal of The Electrochemical Society, vol.145, issue.1, p.59, 1998.
DOI : 10.1149/1.1838211

M. S. Whittingham, The Role of Ternary Phases in Cathode Reactions, Journal of The Electrochemical Society, vol.123, issue.3, p.315, 1976.
DOI : 10.1149/1.2132817

D. W. Murphy and F. A. Trumbore, The Chemistry of TiS[sub 3] and NbSe[sub 3] Cathodes, Journal of The Electrochemical Society, vol.123, issue.7, p.960, 1976.
DOI : 10.1149/1.2133012

V. Pralong, D. C. Souza, K. T. Leung, and L. F. Nazar, Reversible lithium uptake by CoP3 at low potential: role of the anion, Electrochemistry Communications, vol.4, issue.6, p.516, 2002.
DOI : 10.1016/S1388-2481(02)00363-6

R. Alcantara, J. L. Tirado, J. C. Jumas, L. Monconduit, and J. Olivier-fourcade, Electrochemical reaction of lithium with CoP3, Journal of Power Sources, vol.109, issue.2, p.308, 2002.
DOI : 10.1016/S0378-7753(02)00081-2

I. Chapitre, Utilisation d'un indice de formation d'une phase amorphe pour prédire le comportement d'un matériau d'électrode

T. Moriga, K. Watanabe, D. Tsuji, S. Massaki, and I. Nakabayashi, Reaction Mechanism of Metal Silicide Mg2Si for Li Insertion, Journal of Solid State Chemistry, vol.153, issue.2, p.386, 2000.
DOI : 10.1006/jssc.2000.8787

G. A. Roberts, E. J. Cairns, J. A. Reimer, J. J. Power-sources, J. H. Lee et al., Chapitre V : Etude de nouveaux matériaux pour une utilisation en tant qu'électrolyte solide Références bibliographiques du chapitre V [1] S, Phalippou, Techniques de l'ingénieur, pp.424-61, 1919.

R. Marchand, Nitrogen-containing phosphate glasses, Journal of Non-Crystalline Solids, vol.56, issue.1-3, p.173, 1983.
DOI : 10.1016/0022-3093(83)90464-7

R. Abramovici and M. Ish-shalom, Nitrogen-containing glasses and glass ceramics in some Me-Si-Al-O-N systems, Industrial & Engineering Chemistry Product Research and Development, vol.24, issue.4, p.586, 1985.
DOI : 10.1021/i300020a018

J. B. Bates, N. J. Dudney, G. R. Gruzalski, R. A. Zuhr, A. Choudhury et al., Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries, Journal of Power Sources, vol.43, issue.1-3, p.103, 1993.
DOI : 10.1016/0378-7753(93)80106-Y

N. J. Dudney and M. L. Jenson, Properties of vacuum deposited thin films of lithium phosphorous oxynitride (Lipon) with an expanded composition range, CRADA Final Report, 2003.

U. V. Alpen, Li3N: A promising Li ionic conductor, Journal of Solid State Chemistry, vol.29, issue.3, p.379, 1979.
DOI : 10.1016/0022-4596(79)90195-6

B. A. Boukamp and R. A. Huggins, Fast ionic conductivity in lithium nitride, Materials Research Bulletin, vol.13, issue.1, p.23, 1978.
DOI : 10.1016/0025-5408(78)90023-5

A. Rabenau, Lithium nitride and related materials case study of the use of modern solid state research techniques???, Solid State Ionics, vol.6, issue.4, p.277, 1982.
DOI : 10.1016/0167-2738(82)90012-1

A. Levasseur, M. Kbala, J. C. Brethous, J. M. Réau, and P. Hagenmuller, Etudes electrique et Raman des verres du systeme B2O3 - Li2O - Li2SO4, Solid State Communications, vol.32, issue.10, p.839, 1979.
DOI : 10.1016/0038-1098(79)90482-4

P. W. Mcmillan, Glass-Ceramics, 1979.

M. J. Fairweather, J. A. Topping, M. K. Murthy, and J. Am, Effect of Al2O3 on a Complex Li2O-ZnO-SiO2 Glass-Ceramic, Journal of the American Ceramic Society, vol.56, issue.5, p.260, 1975.
DOI : 10.1007/BF00554364

A. A. Omar, A. A. El-shennawi, and A. R. , Thermal expansion of Li2O-ZnO-Al2O3-SiO2 glasses and corresponding glass-ceramics, Journal of Materials Science, vol.35, issue.22, p.6049, 1991.
DOI : 10.1007/BF01113882

E. Demirkesen and E. Maytalman, Effect of Al2O3 additions on the crystallization behaviour and bending strength of a Li2O???ZnO???SiO2 glass-ceramic, Ceramics International, vol.27, issue.1, p.99, 2001.
DOI : 10.1016/S0272-8842(00)00048-1

W. Paszkowicz, M. Knapp, J. Z. Domagala, G. Kamler, and S. Podsiadlo, Low-temperature thermal expansion of Mg3N2, Journal of Alloys and Compounds, vol.328, issue.1-2, p.272, 2001.
DOI : 10.1016/S0925-8388(01)01310-X

M. Rajaram, D. E. Day, and J. Am, Cation Effects in NaPO3 Glasses Doped with Metal Nitrides and Oxides, Journal of the American Ceramic Society, vol.72, issue.2, p.400, 1986.
DOI : 10.1111/j.1151-2916.1986.tb04768.x

K. H. Joo, P. Vinatier, B. Pecquenard, A. Levasseur, and H. J. Sohn, Thin film lithium ion conducting LiBSO solid electrolyte, Solid State Ionics, vol.160, issue.1-2, p.51, 2003.
DOI : 10.1016/S0167-2738(03)00163-2

URL : https://hal.archives-ouvertes.fr/hal-00195921

K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 1979.

M. Irion, M. Couzi, A. Levasseur, J. M. Reau, and J. C. Brethous, An infrared and Raman study of new lonic-conductor lithium glasses, Journal of Solid State Chemistry, vol.31, issue.3, p.285, 1980.
DOI : 10.1016/0022-4596(80)90090-0

M. Tatsumisago, Glassy materials based on Li2S for all-solid-state lithium secondary batteries, Solid State Ionics, vol.175, issue.1-4, p.13, 2004.
DOI : 10.1016/j.ssi.2004.09.012

N. Machida, H. Yamamoto, S. Asano, and T. Shigematsu, Preparation of amorphous 75LS???PS???(25?)PS (mol%) solid electrolytes by a high-energy ball-milling process and their application for an all-solid-state lithium battery, Solid State Ionics, vol.176, issue.5-6, p.473, 2005.
DOI : 10.1016/j.ssi.2004.08.019

K. Chung, W. S. Kim, and Y. K. Choi, Lithium phosphorous oxynitride as a passive layer for anodes in lithium secondary batteries, Journal of Electroanalytical Chemistry, vol.566, issue.2, p.263, 2004.
DOI : 10.1016/j.jelechem.2003.11.035

S. Zhao, Z. Fu, and Q. Qin, A solid-state electrolyte lithium phosphorus oxynitride film prepared by pulsed laser deposition, Thin Solid Films, vol.415, issue.1-2, p.108, 2002.
DOI : 10.1016/S0040-6090(02)00543-6

M. H. Lindic, B. Pecquenard, P. Vinatier, A. Levasseur, H. Martinez et al., Characterization of rf sputtered TiOySz thin films, Thin Solid Films, vol.484, issue.1-2, p.113, 2005.
DOI : 10.1016/j.tsf.2005.02.014

URL : https://hal.archives-ouvertes.fr/hal-00083724