H. Ade, X. Zhang, S. Cameron, C. Costello, J. Kirz et al., Chemical contrast in X-ray microscopy and spatially resolved XANES spectroscopy of organic specimens, Science, vol.258, issue.5084, pp.972-975, 1992.
DOI : 10.1126/science.1439809

A. L. Ankudinov, B. Ravel, J. J. Rehr, and S. D. Conradson, Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure, Physical Review B, vol.58, issue.12, pp.7565-7576, 1998.
DOI : 10.1103/PhysRevB.58.7565

A. J. Berry, H. C. St, K. D. O-'neill, S. J. Jayasuriya, G. J. Campbell et al., XANES calibrations for the oxidation state of iron in a silicate glass, XANES calibrations for the oxidation state of iron in a silicate glass, pp.967-977, 2003.
DOI : 10.2138/am-2003-0704

R. Buschert, M. D. Giardina, A. Merlini, A. Balerna, and S. Mobilio, Laboratory EXAFS in a dispersive mode, Journal of Applied Crystallography, vol.21, issue.2, pp.79-85, 1988.
DOI : 10.1107/S0021889887008641

V. De-andrade, O. Vidal, E. Lewin, and P. O-'brien, Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples, Journal of Metamorphic Geology, vol.24, issue.7, pp.655-668, 2006.
DOI : 10.1111/j.1525-1314.2006.00660.x

URL : https://hal.archives-ouvertes.fr/hal-00139644

M. D. Dyar, M. E. Gunter, J. S. Delaney, A. Lanzirotti, and S. R. Sutton, Use of the spindle stage for orientation of single crystals for microXAS: Isotropy and anisotropy in Fe-XANES spectra, American Mineralogist, vol.87, issue.10, pp.1500-1504, 2002.
DOI : 10.2138/am-2002-1029

M. D. Dyar, E. W. Lowe, C. V. Guidotti, and J. S. Delaney, partitioning among silicates in metapelites: A synchrotron micro-XANES study, American Mineralogist, vol.87, issue.4, pp.514-522, 2002.
DOI : 10.2138/am-2002-0414

F. Farges, G. E. Brown-jr, P. Petit, and M. Muñoz, Transition elements in water-bearing silicate glasses/melts. part I. a high-resolution and anharmonic analysis of Ni coordination environments in crystals, glasses, and melts, Geochimica et Cosmochimica Acta, vol.65, issue.10, pp.1665-1678, 2001.
DOI : 10.1016/S0016-7037(00)00625-6

URL : https://hal.archives-ouvertes.fr/hal-00693735

F. W. Lytle, D. E. Sayers, and E. A. Stern, Extended x-ray-absorption fine-structure technique. II. Experimental practice and selected results, Physical Review B, vol.11, issue.12, pp.4825-4835, 1975.
DOI : 10.1103/PhysRevB.11.4825

. Munõzmunõz, redox and speciation micromapping 10, 1029.

T. Matsushita and R. P. Phizackerley, A Fast X-Ray Absorption Spectrometer for Use with Synchrotron Radiation, Japanese Journal of Applied Physics, vol.20, issue.11, pp.2223-2228, 1981.
DOI : 10.1143/JJAP.20.2223

M. Muñ-oz, P. Argoul, and F. Farges, Continuous Cauchy wavelet transform analyses of EXAFS spectra: A qualitative approach, American Mineralogist, vol.88, issue.4, pp.694-700, 2003.
DOI : 10.2138/am-2003-0423

M. Muñoz, H. Bureau, V. Malavergne, B. Ménez, M. Wilke et al., In situ speciation of nickel in hydrous melts exposed to extreme conditions, Phys. Scr. T, vol.115, pp.921-922, 2005.

S. Pascarelli, T. Neisius, and S. De-panfilis, Turbo-XAS: dispersive XAS using sequential acquisition, Journal of Synchrotron Radiation, vol.6, issue.5, pp.1044-1050, 1999.
DOI : 10.1107/S0909049599004513

S. Pascarelli, O. Mathon, M. Muñoz, T. Mairs, and J. Susini, Energy-dispersive absorption spectroscopy for hard-X-ray micro-XAS applications, Journal of Synchrotron Radiation, vol.13, issue.5, pp.351-358, 2006.
DOI : 10.1107/S0909049506026938

URL : https://hal.archives-ouvertes.fr/insu-00242564

P. Pfalzer, J. Urbach, M. Klemm, and S. Horn, Elimination of self-absorption in fluorescence hard-x-ray absorption spectra, Physical Review B, vol.60, issue.13, pp.9335-9339, 1999.
DOI : 10.1103/PhysRevB.60.9335

D. E. Sayers, F. W. Lytle, and E. A. Stern, Point Scattering Theory of X-Ray K-Absorption Fine Structure, Adv. X-ray Anal, vol.13, pp.248-271, 1970.
DOI : 10.1007/978-1-4613-9963-6_13

R. G. Shulman, Y. Yafet, P. Eisenberger, and W. E. Blumberg, Observations and interpretation of x-ray absorption edges in iron compounds and proteins., Proc. Natl. Acad, 1976.
DOI : 10.1073/pnas.73.5.1384

S. R. Sutton, S. Bajt, J. Delaney, D. Schuze, and T. Tokunaga, Synchrotron x???ray fluorescence microprobe: Quantification and mapping of mixed valence state samples using micro???XANES, Review of Scientific Instruments, vol.66, issue.2, pp.1464-1467, 1995.
DOI : 10.1063/1.1145942

B. K. Teo, EXAFS: Basic Principles and Data Analysis, Inorg. Chem. Concepts, vol.9, 1986.
DOI : 10.1007/978-3-642-50031-2

O. Vidal, T. Parra, and P. Vieillard, Thermodynamic properties of the Tschermak solid solution in Fe-chlorite: Application to natural examples and possible role of oxidation, American Mineralogist, vol.90, issue.2-3, pp.347-358, 2005.
DOI : 10.2138/am.2005.1554

URL : https://hal.archives-ouvertes.fr/hal-00105068

O. Vidal, V. De-andrade, E. Lewin, M. Muñoz, T. Parra et al., P-T-deformation-Fe3+/Fe2+ mapping at the thin section scale and comparison with XANES mapping: application to a garnet-bearing metapelite from the Sambagawa metamorphic belt (Japan), Journal of Metamorphic Geology, vol.7, issue.7, pp.669-683, 2006.
DOI : 10.1111/j.1525-1314.2006.00661.x

URL : https://hal.archives-ouvertes.fr/insu-00242739

M. Wilke, F. Farges, P. Petit, G. E. Brown-jr, and F. Martin, XANES spectroscopic study, American Mineralogist, vol.86, issue.5-6, pp.714-730, 2001.
DOI : 10.2138/am-2001-5-612

. Munõzmunõz, redox and speciation micromapping 10, 1029.

P. Agard, O. Vidal, . Goffe´, and B. Goffe´, Interlayer and Si content of phengite in HP-LT carpholite-bearing metapelites, Journal of Metamorphic Geology, vol.19, issue.5, pp.479-495, 2001.
DOI : 10.1046/j.0263-4929.2001.00322.x

P. Arkai, S. W. Faryad, O. Vidal, and K. Balogh, Very lowgrade metamorphism of sedimentary rocks of the Meliata Unit, Western Carpathians, Slovakia; implications of phyllosilicate characteristics, International Journal of Earth Sciences, vol.92, pp.68-85, 2003.
URL : https://hal.archives-ouvertes.fr/hal-00105022

R. Augier, P. Agard, P. Monie, L. Jolivet, C. Robin et al., Exhumation, doming and slab retreat in the Betic Cordillera (SE Spain): in situ40Ar/39Ar ages and P-T-d-t paths for the Nevado-Filabride complex, Journal of Metamorphic Geology, vol.157, issue.5, pp.357-381, 2005.
DOI : 10.1016/S0024-4937(98)00047-4

URL : https://hal.archives-ouvertes.fr/hal-00083652

S. Banno and C. Sakai, Geology and metamorphic evolution of the Sambagawa metamorphic belt, Japan In: The Evolution of Metamorphic Belts, Special Publication, vol.43, pp.419-532, 1989.

S. Banno, C. Sakai, and T. Higashino, Pressure-temperature trajectory of the Sanbagawa metamorphism deduced from garnet zoning, Lithos, vol.19, issue.1, pp.51-63, 1986.
DOI : 10.1016/0024-4937(86)90015-0

R. G. Berman, Internally-Consistent Thermodynamic Data for Minerals in the System Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2, Journal of Petrology, vol.29, issue.2, pp.445-522, 1988.
DOI : 10.1093/petrology/29.2.445

R. G. Berman, Thermobarometry using multi-equilibrium calculations: a new technique, with petrological applications, Canadian Mineralogist, vol.29, pp.833-855, 1991.

A. J. Berry, H. Neill, . C. St, K. D. Jayasuriya, S. J. Campbell et al., XANES calibrations for the oxidation state of iron in a silicate glass, American Mineralogist, vol.88, issue.7, pp.967-977, 2003.
DOI : 10.2138/am-2003-0704

V. Bosse, M. Ballè-vre, and O. Vidal, Ductile Thrusting Recorded by the Garnet Isograd from Blueschist-Facies Metapelites of the Ile de Groix, Armorican Massif, France, Journal of Petrology, vol.43, issue.3, pp.485-510, 2002.
DOI : 10.1093/petrology/43.3.485

R. Bousquet, . Goffe´, B. Goffe´, O. Vidal, . Oberha¨nslioberha¨nsli et al., The tectono-metamorphic history of the Valaisan domain from the Western to the Central Alps: New constraints on the evolution of the Alps, Geological Society of America Bulletin, vol.114, issue.2, pp.207-225, 2002.
DOI : 10.1130/0016-7606(2002)114<0207:TTMHOT>2.0.CO;2

M. Cathelineau, Cation Site Occupancy in Chlorites and Illites as a Function of Temperature, Clay Minerals, vol.23, issue.4, pp.471-485, 1988.
DOI : 10.1180/claymin.1988.023.4.13

M. Cathelineau and D. Nieva, A chlorite solid solution geothermometer the Los Azufres (Mexico) geothermal system, Contributions to Mineralogy and Petrology, vol.76, issue.3, pp.235-244, 1985.
DOI : 10.1007/BF00413350

V. De-andrade, O. Vidal, and E. Lewin, Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples, Journal of Metamorphic Geology, vol.24, issue.7, 2006.
DOI : 10.1111/j.1525-1314.2006.00660.x

URL : https://hal.archives-ouvertes.fr/hal-00139644

M. Enami, Pressure-temperature path of Sanbagawa prograde metamorphism deduced from grossular zoning of garnet, Journal of Metamorphic Geology, vol.16, issue.1, pp.97-106, 1998.
DOI : 10.1111/j.1525-1314.1998.00058.x

M. Enami, S. R. Wallis, and . Banno, Paragenesis of sodic pyroxene-bearing quartz schists: implications for the P-T history of the Sanbagawa belt, Contributions to Mineralogy and Petrology, vol.2, issue.1-2, pp.182-198, 1994.
DOI : 10.1007/BF00310699

M. Faure, Microtectonic evidence for eastward ductile shear in the Jurassic orogen of SW Japan, Journal of Structural Geology, vol.7, issue.2, pp.175-186, 1985.
DOI : 10.1016/0191-8141(85)90130-0

J. Ganne, F. Bussy, and O. Vidal, Multi-stage Garnet in the Internal Brianconnais Basement (Ambin Massif, Savoy): New Petrological Constraints on the Blueschist-facies Metamorphism in the Western Alps and Tectonic Implications, Journal of Petrology, vol.44, issue.7, pp.1281-1308, 2003.
DOI : 10.1093/petrology/44.7.1281

URL : https://hal.archives-ouvertes.fr/hal-00105028

A. Goto, S. Banno, T. Higashino, and S. Sakai, Occurrence of calcite in Sanbagawa pelitic schists: implications for the formation of garnet, rutile, oligoclase, biotite and hornblende, Journal of Metamorphic Geology, vol.92, issue.Suppl., pp.255-262, 2002.
DOI : 10.1046/j.0263-4929.2001.00365.x

C. &. Guidotti and F. P. Sassi, Su alcune sostituzioni isomorfe nelle miche Na-K: una rassegna, con particolare riguardo alle miche metamorfiche, Rendiconti Lincei, vol.81, issue.2, pp.57-78, 1998.
DOI : 10.1007/BF02904456

C. V. Guidotti and M. G. Yates, Petrogenetic implications of the Fe 3+ content of muscovite in pelitic schists, American Mineralogist, vol.79, pp.793-795, 1994.

H. Hara, K. Hide, K. Takuda, E. Tsukuda, M. Tokuda et al., Tectonic movement in the Sambagawa Belt, pp.307-330, 1977.

I. Hara, T. Shiota, and K. Hide, Nappe structure of the Sambagawa belt, Journal of Metamorphic Geology, vol.89, issue.5, pp.441-456, 1990.
DOI : 10.1016/0040-1951(79)90324-X

T. Higashino, The higher grade metamorphic zonation of the Sambagawa metamorphic belt in central Shikoku, Japan, Journal of Metamorphic Geology, vol.2, issue.4, pp.413-423, 1990.
DOI : 10.1016/0024-4937(82)90018-4

T. Higashino, Metamorphic zones of the Sambagawa metamorphic belt in central Shikoku, Japan., The Journal of the Geological Society of Japan, vol.96, issue.9, pp.703-708, 1990.
DOI : 10.5575/geosoc.96.703

S. Hillier and B. Velde, Octahedral Occupancy and the Chemical Composition of Diagenetic (Low-Temperature) Chlorites, Clay Minerals, vol.26, issue.2, pp.146-168, 1992.
DOI : 10.1180/claymin.1991.026.2.01

M. Inui and M. Toriumi, Prograde pressure-temperature paths in the pelitic schists of the Sambagawa metamorphic belt, SW Japan, Journal of Metamorphic Geology, vol.20, issue.6, pp.563-580, 2002.
DOI : 10.1046/j.1525-1314.2002.00389.x

M. Inui and M. Toriumi, A Theoretical Study on the Formation of Growth Zoning in Garnet Consuming Chlorite, Journal of Petrology, vol.45, issue.7, pp.1369-1392, 2004.
DOI : 10.1093/petrology/egh016

L. Leoni, F. Sartori, and M. Tamponi, Compositional variation in K-white micas and chlorites coexisting in Al-saturated metapelites under late diagenetic to low-grade metamorphic conditions (Internal Liguride Units, 1998.

E. Merino and B. Ransom, Free Energies of Formation of Illite Solid Solutions and their Compositional Dependence, Clays and Clay Minerals, vol.30, issue.1, pp.29-39, 1982.
DOI : 10.1346/CCMN.1982.0300104

M. Munoz, V. De-andrade, O. Vidal, E. Lewin, S. Pascarelli et al., X-ray absorption micro-mapping of iron redox and speciation in chlorite. G-cube, 2006.

T. Parra, O. Vidal, and P. Agard, A thermodynamic model for Fe???Mg dioctahedral K white micas using data from phase-equilibrium experiments and natural pelitic assemblages, Contributions to Mineralogy and Petrology, vol.143, issue.6, pp.706-732, 2002.
DOI : 10.1007/s00410-002-0373-6

T. Parra, O. Vidal, and L. Jolivet, Relation between the intensity of deformation and retrogression in blueschist metapelites of Tinos Island (Greece) evidenced by chlorite???mica local equilibria, Lithos, vol.63, issue.1-2, pp.41-66, 2002.
DOI : 10.1016/S0024-4937(02)00115-9

T. Parra, O. Vidal, and T. Theye, Experimental data on the Tschermak substitution in Fe-chlorite, American Mineralogist, vol.90, issue.2-3, pp.359-370, 2005.
DOI : 10.2138/am.2005.1556

URL : https://hal.archives-ouvertes.fr/hal-00105046

R. Rimmele´, G. Parra, T. Goffe´, B. Goffe´, R. Oberha¨nslioberha¨nsli et al., Exhumation Paths of High-Pressure-Low-Temperature Metamorphic Rocks from the Lycian Nappes and the Menderes Massif (SW Turkey): a Multi-Equilibrium Approach, Journal of Petrology, vol.46, issue.3, pp.641-669, 2004.
DOI : 10.1093/petrology/egh092

URL : https://hal.archives-ouvertes.fr/hal-00140284

R. G. Shulman, Y. Yafet, P. Eisenberger, and W. E. Blumberg, Observations and interpretation of x-ray absorption edges in iron compounds and proteins., Proceedings of the National Academy of Sciences of the United States of America, pp.1384-1388, 1976.
DOI : 10.1073/pnas.73.5.1384

M. Toriumi and M. Masui, Strain patterns in the Sanbagawa and Ryoke paired metamorphic belts, Japan, pp.387-394, 1986.
DOI : 10.1130/MEM164-p387

F. Trotet, O. Vidal, and L. Jolivet, Exhumation of Syros and Sifnos metamorphic rocks (Cyclades, Greece). New constraints on the P-T paths, European Journal of Mineralogy, vol.13, issue.5, pp.901-920, 2001.
DOI : 10.1127/0935-1221/2001/0013/0901

O. Vidal and T. Parra, Exhumation paths of high-pressure metapelites obtained from local equilibria for chlorite-phengite assemblages, Geological Journal, vol.36, issue.3-4, pp.139-161, 2000.
DOI : 10.1002/gj.856

O. Vidal, T. Parra, and F. Trotet, A thermodynamic model for Fe-Mg aluminous chlorite using data from phase equilibrium experiments and natural pelitic assemblages in the 100?600 °C, 1?25 kbar range, American Journal of Science, vol.6, pp.557-592, 2001.

O. Vidal, T. Parra, and P. Vieillard, Experimental data on the Tschermak solid solution in Fe-chlorites: application to natural examples and possible role of oxidation, American Mineralogist, vol.90, pp.359-370, 2005.

S. R. Wallis, THE TIMING OF FOLDING AND STRETCHING IN THE SAMBAGAWA BELT:THE ASEMIGAWA REGION, CENTRAL SHIKOKU, The Journal of the Geological Society of Japan, vol.96, issue.5, pp.345-352, 1990.
DOI : 10.5575/geosoc.96.345

S. R. Wallis, Exhuming the Sanbagawa metamorphic belt: the importance of tectonic discontinuities, Journal of Metamorphic Geology, vol.16, issue.1, pp.83-95, 1998.
DOI : 10.1111/j.1525-1314.1998.00072.x

S. R. Wallis, S. Banno, and M. Radvanec, Kinematics, structure and relationship to metamorphism of the east-west flow in the Sambagawa belt, southwest Japan. The Island Arc, pp.176-185, 1992.

G. F. Wang and S. Banno, Non-stoichiometry of interlayer cations in micas from low- to middle-grade metamorphic rocks in the Ryoke and the Sanbagawa belts, Japan, Contributions to Mineralogy and Petrology, vol.93, issue.3, pp.313-319, 1987.
DOI : 10.1007/BF00371995

M. Wilke, F. Farges, P. Petit, G. E. Brown, and F. Martin, XANES spectroscopic study, American Mineralogist, vol.86, issue.5-6, pp.714-730, 2001.
DOI : 10.2138/am-2001-5-612

A. P. Willner, Pressure-Temperature Evolution of a Late Palaeozoic Paired Metamorphic Belt in North-Central Chile (34??-35??30'S), Journal of Petrology, vol.46, issue.9, pp.1805-1833, 2005.
DOI : 10.1093/petrology/egi035

K. Yagi and T. Takeshita, Regional variation in exhumation and strain rate of the high-pressure Sambagawa metamorphic rocks in central Shikoku, southwest Japan, Journal of Metamorphic Geology, vol.7, pp.633-647, 2002.

H. Ade, X. Zhang, S. Cameron, C. Costello, J. Kirz et al., Chemical contrast in X-ray microscopy and spatially resolved XANES spectroscopy of organic specimens, Science, vol.258, issue.5084, pp.972-975, 1992.
DOI : 10.1126/science.1439809

P. Agard, O. Vidal, and B. Goffé, Interlayer and Si content of phengite in HP-LT carpholite-bearing metapelites, Journal of Metamorphic Geology, vol.19, issue.5, p.479, 2001.
DOI : 10.1046/j.0263-4929.2001.00322.x

P. Agard, L. Labrousse, S. Elvevold, and C. Lepvrier, Discovery of Paleozoic Fe-Mg carpholite in Motalafjella, Svalbard Caledonides: A milestone for subduction-zone gradients, Geology, vol.33, issue.10, pp.761-764, 2005.
DOI : 10.1130/G21693.1

A. L. Ankudinov, B. Ravel, J. J. Rehr, and S. D. Conradson, Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure, Physical Review B, vol.58, issue.12, pp.7565-7576, 1998.
DOI : 10.1103/PhysRevB.58.7565

P. Arkai, S. W. Faryad, O. Vidal, and K. Balogh, Very low-grade metamorphism of sedimentary rocks of the Meliata Unit, Western Carpathians, Slovakia; implications of phyllosilicate characteristics, International Journal of Earth Sciences, vol.92, issue.1, pp.68-85, 2003.
URL : https://hal.archives-ouvertes.fr/hal-00105022

R. Augier, P. Agard, P. Monie, L. Jolivet, C. Robin et al., Exhumation, doming and slab retreat in the Betic Cordillera (SE Spain): in situ40Ar/39Ar ages and P-T-d-t paths for the Nevado-Filabride complex, Journal of Metamorphic Geology, vol.157, issue.5, pp.23-27, 2005.
DOI : 10.1016/S0024-4937(98)00047-4

URL : https://hal.archives-ouvertes.fr/hal-00083652

S. Banno and C. Sakai, Geology and metamorphic evolution of the Sambagawa metamorphic belt, Japan The Evolution of metamorphic belts, pp.419-532, 1989.

S. Banno, T. Higashino, M. Otsuki, T. Itaya, and T. Nkajima, THERMAL STRUCTURE OF THE SANBAGAWA METAMORPHIC BELT IN CENTRAL SHIKOKU, Journal of Physics of the Earth, vol.26, issue.Supplement, pp.345-356, 1978.
DOI : 10.4294/jpe1952.26.Supplement_S345

S. Banno, C. Sakai, and T. Higashino, Pressure-temperature trajectory of the Sanbagawa metamorphism deduced from garnet zoning, Lithos, vol.19, issue.1, pp.51-63, 1986.
DOI : 10.1016/0024-4937(86)90015-0

A. E. Bence and A. L. Albee, Empirical Correction Factors for the Electron Microanalysis of Silicates and Oxides, The Journal of Geology, vol.76, issue.4, pp.382-403, 1968.
DOI : 10.1086/627339

R. Berman, Internally-Consistent Thermodynamic Data for Minerals in the System Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2, Journal of Petrology, vol.29, issue.2, pp.445-522, 1988.
DOI : 10.1093/petrology/29.2.445

R. Berman, Thermobarometry using multi-equilibrium calculations: a new technique, with petrological applications, Canadian Mineralogist, vol.29, pp.833-855, 1991.

A. J. Berry, H. O-'neill, . C. St, K. D. Jayasuriya, S. J. Campbell et al., XANES calibrations for the oxidation state of iron in a silicate glass, American Mineralogist, vol.88, issue.7, pp.967-977, 2003.
DOI : 10.2138/am-2003-0704

O. Beyssac, B. Goffé, C. Chopin, and J. N. Rouzaud, Raman spectra of carbonaceous material in metasediments: a new geothermometer, Journal of Metamorphic Geology, vol.30, issue.9, pp.859-871, 2002.
DOI : 10.1046/j.1525-1314.2002.00408.x

H. E. Bishop, Optics and Microanalysis eds R, pp.153-161, 1966.

H. E. Bishop, The prospects for an improved absorption correction in electron probe microanalysis, Journal of Physics D: Applied Physics, vol.7, issue.14, pp.2009-2029, 1974.
DOI : 10.1088/0022-3727/7/14/320

V. Bosse, M. Ballèvre, and O. Vidal, Ductile Thrusting Recorded by the Garnet Isograd from Blueschist-Facies Metapelites of the Ile de Groix, Armorican Massif, France, Journal of Petrology, vol.43, issue.3, pp.485-510, 2002.
DOI : 10.1093/petrology/43.3.485

R. Bousquet, B. Goffé, O. Vidal, R. Oberhänsli, and M. Patriat, The tectonometamorphic history of the Valaisan domain from the Western to the Central Alps: New constraints for the evolution of the Alps, GSA Bulletin, pp.114-116, 2002.

J. B. Brady, Diffusion data for silicate minerals, glasses, and liquids, AGU Reference Shelf, vol.103, pp.269-290, 1995.
DOI : 10.1029/RF002p0269

D. S. Bright, J. Bailey, J. A. Bentley, and . Small, Visibility of two intermixed phases as a function of grain size and signal to noise: a computer simulation, Proc. 50 th ann. Meeting Electron Microsc. Soc. Amer, pp.1610-1621, 1992.

R. Buschert, M. D. Giardina, A. Merlini, A. Balerna, and S. Mobilio, Laboratory EXAFS in a dispersive mode, Journal of Applied Crystallography, vol.21, issue.2, pp.79-85, 1988.
DOI : 10.1107/S0021889887008641

R. Castaing, Application des sondes electronique à une methode d'analyse ponctuelle chimique et cristallographique, p.55, 1951.

M. Cathelineau and D. Nieva, A chlorite solid solution geothermometer. The Los Azufres (Mexico) geothermal system. Contribution to Mineralogy and Petrology, pp.235-244, 1985.
DOI : 10.1007/bf00413350

M. Cathelineau, The chlorite and illite geothermometers, International congress of geochemistry and cosmochemistr, p.182, 1988.
DOI : 10.1016/0009-2541(88)90734-6

G. L. Clarke, N. R. Daczko, and C. Nockolds, A method for applying matrix corrections to X-ray intensity maps using the Bence-Albee algorithm and Matlab, Journal of Metamorphic Geology, vol.129, issue.6, pp.635-644, 2001.
DOI : 10.1046/j.0263-4929.2001.00336.x

H. Coulon, Etude minéralogique et chimique de l'argile de Fourges-Cahaignes (FoCa 7 " Alt " ). Synthèse des résultats CEA-SESD Fontenay au Roses, pp.89-129, 1989.

R. D. Dallmeyer, J. J. Peucat, T. Hirajima, and Y. Otha, Tectonothermal chronology within a blueschist-eclogite complex, west-central Spitsbergen, Svalbard: Evidence from 40Ar39Ar and RbSr mineral ages, Lithos, vol.24, issue.4, pp.291-304, 1990.
DOI : 10.1016/0024-4937(89)90049-2

D. Andrade, O. Vidal, V. Lewin, E. Brien, and O. , Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples, Journal of Metamorphic Geology, vol.24, issue.7, 2006.
DOI : 10.1111/j.1525-1314.2006.00660.x

URL : https://hal.archives-ouvertes.fr/hal-00139644

D. Capitani and C. , Gleichgewichtsphasendiagramme: Therorie und software, European Journal of Mineralogy, vol.6, p.48, 1994.

M. H. Dodson, Closure temperature in cooling geochronological and petrological systems. Contribution to mineralogy and petrology, pp.259-274, 1973.

H. Drescher, L. Reimer, and H. Seidel, Backscattering and secondary electron emission of 10?100 kev electrons and correlations to scanning electron microscopy, Z Angew Phys, vol.29, pp.331-336, 1970.

P. Duncumb and S. J. Reed, The calculation of stopping power and backscattering effects in electron probe microanalysis, Quantitative Electron Probe Microanalysis, 1968.

M. Enami, Petrology of pelitic schists in the oligoclase-biotite zone of the Sanbagawa metamorphic terrain, Japan: phase equilibria in the highest grade zone of a high-pressure intermediate type of metamorphic belt, Journal of Metamorphic Geology, vol.70, issue.2, pp.141-161, 1983.
DOI : 10.1007/BF00376256

M. Enami, W. S. Banno, and S. , Paragenesis of sodic pyroxene-bearing quartz schists: implications for the P-T history of the Sanbagawa belt, Contributions to Mineralogy and Petrology, vol.2, issue.1-2, pp.182-198, 1994.
DOI : 10.1007/BF00310699

M. Enami, Pressure-temperature path of Sanbagawa prograde metamorphism deduced from grossular zoning of garnet, Journal of Metamorphic Geology, vol.16, issue.1, pp.97-106, 1998.
DOI : 10.1111/j.1525-1314.1998.00058.x

F. Farges, G. E. Brown, . Jr, P. E. Petit, and M. Muñoz, Transition elements in water-bearing silicate glasses/melts. part I. a high-resolution and anharmonic analysis of Ni coordination environments in crystals, glasses, and melts, Geochimica et Cosmochimica Acta, vol.65, issue.10, pp.1665-1678, 2001.
DOI : 10.1016/S0016-7037(00)00625-6

URL : https://hal.archives-ouvertes.fr/hal-00693735

M. Faure, EASTWARD DUCTILE SHEAR DURING THE EARLY TECTONIC PHASE IN THE SANBAGAWA BELT, The Journal of the Geological Society of Japan, vol.89, issue.6, pp.319-329, 1983.
DOI : 10.5575/geosoc.89.319

M. Faure, Microtectonic evidence for eastward ductile shear in the Jurassic orogen of SW Japan, Journal of Structural Geology, vol.7, issue.2, pp.175-186, 1985.
DOI : 10.1016/0191-8141(85)90130-0

J. Ganne, F. Bussy, and O. Vidal, Multi-stage Garnet in the Internal Brianconnais Basement (Ambin Massif, Savoy): New Petrological Constraints on the Blueschist-facies Metamorphism in the Western Alps and Tectonic Implications, Journal of Petrology, vol.44, issue.7, pp.1281-1308, 2003.
DOI : 10.1093/petrology/44.7.1281

URL : https://hal.archives-ouvertes.fr/hal-00105028

S. Gin, P. Jollivet, J. Mestre, M. Jullien, and C. Pozo, French SON 68 nuclear glass alteration mechanisms on contact with clay media, Applied Geochemistry, vol.16, issue.7-8, pp.861-881, 2001.
DOI : 10.1016/S0883-2927(00)00068-8

B. Goffé, Définition du faciès à Fe-Mg-carpholite-chloritoïde, un marqueur du métamorphisme de HP-BT dans les métasédiments alumineux, Thèse Doct. Sci. Paris, p.212, 1982.

B. Goffé and R. Bousquet, Ferrocarpholite, chloritoïde et lawsonite dans les métapélites des unités du Versoyen et, 1997.

C. V. Guidotti and F. P. Sassi, Su alcune sostituzioni isomorfe nelle miche Na-K: una rassegna, con particolare riguardo alle miche metamorfiche, Rendiconti Lincei, vol.81, issue.2, pp.57-78, 1998.
DOI : 10.1007/BF02904456

C. V. Guidotti and M. G. Yates, Petrogenetic implications of the Fe 3+ content of muscovite in pelitic schists, American Mineralogist, vol.79, pp.793-795, 1994.

J. I. Goldstein, D. E. Newbury, P. Echlin, D. C. Joy, C. Fiori et al., Scanning Electron Microscopy and X-ray Microanalysis, 1992.

A. Goto, S. Banno, T. Higashino, and S. Sakai, Occurrence of calcite in Sanbagawa pelitic schists: implications for the formation of garnet, rutile, oligoclase, biotite and hornblende, Journal of Metamorphic Geology, vol.92, issue.Suppl., pp.255-262, 2002.
DOI : 10.1046/j.0263-4929.2001.00365.x

I. Hara, K. Hide, K. Takuda, E. Tsukuda, M. Tokuda et al., Tectonic movement in the Sambagawa Belt The Sambagawa belt, pp.307-330, 1977.

I. Hara, T. Shiota, K. Hide, K. Okamoto, K. Takeda et al., Nappe structure of the Sambagawa belt, Journal of Metamorphic Geology, vol.89, issue.5, pp.441-456, 1990.
DOI : 10.1016/0040-1951(79)90324-X

K. F. Heinrich, X-ray Optics and Microanalysis, pp.159-67, 1966.

K. F. Heinrich, Mass absorption coefficients for electron probe analysis Congr. on X-ray Oprics and microanalysis, Proc. 11 th Int, pp.67-119, 1987.

K. F. Heinrich and D. E. Newbury, Electron probe quantitation, 1991.
DOI : 10.1007/978-1-4899-2617-3

T. Higashino, Biotite zone of Sanbagawa metamorphic terrain in the Siragayama area, central Shikoku, Japan, The Journal of the Geological Society of Japan, vol.81, issue.11, pp.653-670, 1975.
DOI : 10.5575/geosoc.81.653

T. Higashino, The higher grade metamorphic zonation of the Sambagawa metamorphic belt in central Shikoku, Japan, Journal of Metamorphic Geology, vol.2, issue.4, pp.413-423, 1990.
DOI : 10.1016/0024-4937(82)90018-4

T. Higashino, Metamorphic zones of the Sambagawa metamorphic belt in central Shikoku, Japan. Journal of the Geological Society of Japan, vol.9, pp.703-708, 1990.

S. Hillier and B. Velde, Octahedral Occupancy and the Chemical Composition of Diagenetic (Low-Temperature) Chlorites, Clay Minerals, vol.26, issue.2, pp.146-168, 1991.
DOI : 10.1180/claymin.1991.026.2.01

T. Hirajima, Y. Hiroi, and Y. Ohta, Lawsonite and pumpellyite in spitsbergen, Norsk Geologisk Tidsskrift, vol.4, pp.267-273, 1984.

T. Hirajima, S. Banno, Y. Hiroi, and Y. Ohta, Phase petrology of eclogites and related rocks from the Motalafjella high-pressure metamorphic complex in Spitsbergen (Arctic Ocean) and its significance, Lithos, vol.22, issue.2, pp.75-97, 1988.
DOI : 10.1016/0024-4937(88)90018-7

W. T. Horsfield, Glaucophane Schists of Caledonian age from Spitsbergen, Geological Magazine, vol.137, issue.01, pp.29-36, 1972.
DOI : 10.1130/0016-7606(1968)79[1727:OROCMI]2.0.CO;2

M. Inui and M. Toriumi, Prograde pressure-temperature paths in the pelitic schists of the Sambagawa metamorphic belt, SW Japan, Journal of Metamorphic Geology, vol.20, issue.6, pp.563-580, 2002.
DOI : 10.1046/j.1525-1314.2002.00389.x

M. Inui and M. Toriumi, A Theoretical Study on the Formation of Growth Zoning in Garnet Consuming Chlorite, Journal of Petrology, vol.45, issue.7, pp.1369-1392, 2004.
DOI : 10.1093/petrology/egh016

L. Leoni, F. Sartori, and M. Tamponi, Compositional variation in K-white micas and chlorites coexisting in Al-saturated metapelites under late diagenetic to low-grade metamorphic conditions (Internal Liguride Units, Nortern Apennines, Italy), European Journal of Mineralogy, vol.10, pp.1321-1339, 1998.

J. Lieberman and K. Petrakakis, TWEEQU thermobarometry: Analysis of uncertainties and application to granulites from Western Alaska and Austria, Canadian Mineralogist, vol.29, pp.857-887, 1991.

G. Love and V. D. Scott, Evaluation of a new correction procedure for quantitative electron probe microanalysis, Journal of Physics D: Applied Physics, vol.11, issue.10, pp.1369-1376, 1978.
DOI : 10.1088/0022-3727/11/10/002

F. W. Lytle, D. E. Sayers, and E. A. Stern, Extended x-ray-absorption fine-structure technique. II. Experimental practice and selected results, Physical Review B, vol.11, issue.12, pp.4825-4835, 1975.
DOI : 10.1103/PhysRevB.11.4825

M. Kerrow, W. S. Dewey, J. F. Scotese, and C. R. , The Ordovician and Silurian development of the Iapetus Ocean, Paleontology, vol.44, pp.165-178, 1991.

S. Marayuma, J. G. Liou, and M. Terabayashi, Blueschist and eclogites of the world and their exhumation. International geology review, pp.485-594, 1996.

B. A. Marmo, G. L. Clarke, and R. Powell, Fractionation of bulk rock composition due to porphyroblast growth: effects on eclogite facies mineral equilibria, Pam Peninsula, New Caledonia, Journal of Metamorphic Geology, vol.62, issue.1, pp.151-165, 2002.
DOI : 10.1046/j.0263-4929.2001.00346.x

H. J. Massonne and W. Schreyer, Phengite geobarometry based on the limiting assemblage with K-feldspar, phlogopite, and quartz. Contribution to Mineralogy and Petrology, pp.212-224, 1987.

E. Merino and B. Ransom, Free Energies of Formation of Illite Solid Solutions and their Compositional Dependence, Clays and Clay Minerals, vol.30, issue.1, pp.29-39, 1982.
DOI : 10.1346/CCMN.1982.0300104

J. Mosar, E. A. Eide, P. T. Osmundsen, A. Sommaruga, and T. H. Torsvik, Greenland- Norway separation: a geodynamic model for the North Atlantic, Norwegian Journal of Geology, vol.82, pp.281-298, 2002.

M. Muñoz, Behavior of network formers and modifiers in hydrated magmas, 2003.

M. Muñoz, H. Bureau, V. Malavergne, B. Ménez, M. Wilke et al., In situ speciation of nickel in hydrous melts exposed to extreme conditions, Physica Scripta, pp.115-921, 2005.

Y. Otha, T. Hirajima, and Y. Hiroi, Caledonian high-pressure metamorphism in central western Spitsbergen, pp.205-214, 1986.

F. Papillon, M. Jullien, and C. Bataillon, Carbon steel behaviour in compacted clay : two long term tests for corrosion prediction. In Prediction of the long term corrosion behaviour in nuclear waste systems. Féron and MacDonald Eds, pp.439-454, 2003.

T. Parra, O. Vidal, and P. Agard, A thermodynamic model for Fe-Mg dioctahedral Kwhite micas using data from phase equilibrium experiments and natural pelitic assemblages. Contribution to Mineralogy and Petrology, pp.706-732, 2002.

T. Parra, O. Vidal, and T. Theye, Experimental data on the Tschermak substitution in Fe-chlorite, American Mineralogist, vol.90, issue.2-3, pp.359-370, 2005.
DOI : 10.2138/am.2005.1556

URL : https://hal.archives-ouvertes.fr/hal-00105046

S. Pascarelli, T. Neisius, D. Panfilis, and S. , Turbo-XAS: dispersive XAS using sequential acquisition, Journal of Synchrotron Radiation, vol.6, issue.5, pp.1044-1050, 1999.
DOI : 10.1107/S0909049599004513

P. Pfalzer, J. Urbach, M. Klemm, and S. Horn, Elimination of self-absorption in fluorescence hard-x-ray absorption spectra, Physical Review B, vol.60, issue.13, pp.9335-9339, 1999.
DOI : 10.1103/PhysRevB.60.9335

J. Philibert and R. Tixier, Physical aspects of electron microscopy and microbeam analysis, 1975.

J. Pouchou and F. Pichoir, PAP" ?(??) procedure for improved quantitative microanalysis: In: Microbeam Analysis, pp.104-106, 1985.

S. J. Reed, Electron microprobe analysis and scanning electron microscopy in geology, p.196, 1996.
DOI : 10.1017/CBO9780511610561

G. Rimmelé, T. Parra, B. Goffé, R. Oberhänsli, L. Jolivet et al., Exhumation Paths of High-Pressure-Low-Temperature Metamorphic Rocks from the Lycian Nappes and the Menderes Massif (SW Turkey): a Multi-Equilibrium Approach, Journal of Petrology, vol.46, issue.3, 2004.
DOI : 10.1093/petrology/egh092

D. E. Sayers, F. W. Lytle, and E. A. Stern, Point scattering theory of X-ray K-absorption fine structure Advances in X-ray Analysis, pp.248-271, 1970.

R. G. Shulman, Y. Yafet, P. Eisenberger, and W. E. Blumberg, Observations and interpretation of x-ray absorption edges in iron compounds and proteins., Proceedings of the National Academy of Science, pp.1384-1388, 1976.
DOI : 10.1073/pnas.73.5.1384

S. R. Sutton, S. Bajt, J. Delaney, D. Schuze, and T. Tokunaga, Synchrotron x???ray fluorescence microprobe: Quantification and mapping of mixed valence state samples using micro???XANES, Review of Scientific Instruments, vol.66, issue.2, pp.1464-1467, 1995.
DOI : 10.1063/1.1145942

B. K. Teo, EXAFS: Basic Principles and Data Analysis, Inorganic Chemistry Concepts, p.349, 1986.
DOI : 10.1007/978-3-642-50031-2

D. K. Tinkham and E. D. Ghent, XRMapAnal: A program for analysis of quantitative X-ray maps, American Mineralogist, vol.90, issue.4, pp.737-744, 2005.
DOI : 10.2138/am.2005.1483

M. Toriumi and M. Masui, Strain patterns in the Sanbagawa and Ryoke paired metamorphic belts, Japan, pp.387-394, 1986.
DOI : 10.1130/MEM164-p387

T. H. Torsvik, R. Van-der-voo, J. G. Meert, J. Mosar, and H. J. Walderhaug, Reconstructions of the continents around the North Atlantic at about the 60th parallel, Earth and Planetary Science Letters, vol.187, issue.1-2, pp.55-69, 2001.
DOI : 10.1016/S0012-821X(01)00284-9

F. Trotet, O. Vidal, and L. Jolivet, Exhumation of Syros and Sifnos metamorphic rocks (Cyclades, Greece). New constraints on the P-T paths, European Journal of Mineralogy, vol.13, issue.5, pp.901-920, 2001.
DOI : 10.1127/0935-1221/2001/0013/0901

O. Vidal, B. Goffé, and T. Theye, Experimental study of the stability of sudoite and magnesiocarpholite and calculation of a new petrogenetic grid for the system, 1992.

O. Vidal, B. Goffé, R. Bousquet, and T. Parra, Calibration and testing of an empirical chloritoid-chlorite Mg-Fe exchange thermometer and thermodynamic data for daphnite, Journal of Metamorphic Geology, vol.116, issue.1, pp.25-39, 1999.
DOI : 10.1046/j.1525-1314.1999.00174.x

O. Vidal and T. Parra, Exhumation paths of high-pressure metapelites obtained from local equilibria for chlorite-phengite assemblages, Geological Journal, vol.36, issue.3-4, pp.139-161, 2000.
DOI : 10.1002/gj.856

O. Vidal, T. Parra, and F. Trotet, A thermodynamic model for Fe-Mg aluminous chlorite using data from phase equilibrium experiments and natural pelitic assemblages in the 100- 600°C, 1-25 kbar range, American Journal of Science, vol.6, pp.557-592, 2001.

O. Vidal, T. Parra, and P. Vieillard, Experimental data on the Tschermak solid solution in Fe-chlorites: Application to natural examples and possible role of oxidation, American Mineralogist, vol.90, pp.359-370, 2005.

O. Vidal, V. De-andrade, E. Lewin, M. Munoz, T. Parra et al., P-Tdeformation-Fe 3+ /Fe 2+ mapping at the thin section scale and comparison with XANES mapping. Application to a garnet-bearing metapelite from the Sambagawa metamorphic belt, Journal of Metamorphic Geology, 2006.

S. R. Wallis, THE TIMING OF FOLDING AND STRETCHING IN THE SAMBAGAWA BELT:THE ASEMIGAWA REGION, CENTRAL SHIKOKU, The Journal of the Geological Society of Japan, vol.96, issue.5, pp.345-352, 1990.
DOI : 10.5575/geosoc.96.345

S. R. Wallis, S. Banno, and M. Radvanec, Kinematics, structure and relationship to metamorphism of the east-west flow in the Sambagawa belt, southwest Japan. The Island Arc, Thematic articles, pp.176-185, 1992.

S. R. Wallis, Exhuming the Sanbagawa metamorphic belt: the importance of tectonic discontinuities, Journal of Metamorphic Geology, vol.16, issue.1, pp.83-95, 1998.
DOI : 10.1111/j.1525-1314.1998.00072.x

G. F. Wang and S. Banno, Non-stoichiometry of interlayer cations in micas from low- to middle-grade metamorphic rocks in the Ryoke and the Sanbagawa belts, Japan, Contributions to Mineralogy and Petrology, vol.93, issue.3, pp.313-319, 1987.
DOI : 10.1007/BF00371995

M. Wilke, F. Farges, P. Petit, G. E. Brown, . Jr et al., XANES spectroscopic study, American Mineralogist, vol.86, issue.5-6, pp.714-730, 2001.
DOI : 10.2138/am-2001-5-612

K. Yagi and T. Takeshita, Regional variation in exhumation and strain rate of the highpressure Sambagawa metamorphic rocks in central Shikoku, southwest Japan, Journal of Metamorphic Geology, vol.7, pp.633-647, 2002.