M. Sliwa, I. Malfant, T. Asahi, H. Masuhara, and K. , Nakatani Dynamics of photochromism and thermochromism for salicylidene-aminopyridine Phys

M. Sliwa, T. Asahi, H. Masuhara, and K. , Nakatani Photochromic dynamics of salicylidene aniline in solid state by using femtosecond transient absorption spectroscopy Molecular Crystals and Liquid Crystals, pp.541-548, 2005.

P. Feneyrou, F. Soyer, P. L. Barny, E. Ishow, M. Sliwa et al., Delaire Photochromic compounds as optical limiters in the nanosecond time range: the example of mercury dithizonate complex Photochemistry Photobiologie Science, pp.195-202, 2003.

S. Au-groupe-d-'optique-non-linéaire-et-d-'optoélectronique, Photo-commutation à l'état solide de la Génération de Second Harmonique de salicylidène-anilines, 2005.

G. Réunion-annuelle-du and . Pom3, Photochromes organiques : Molecules Photo-commutation à l'état solide de la Génération de Seconde Harmonique (GSH) de salicylidèneanilines (anils) : propriétés photochromes, investigations fondamentales M, Lille, pp.14-15, 2004.

. Séminaire-interne-au-laboratoire-de-photophysique and . De, Cachan, 10 Décembre 2004 : Eléments de réponse sur l'origine de la photo-modulation de la Génération de Second Harmonique pour les salicylidène-anilines M, Photochimie Supramoléculaires et Macromoléculaires (PPSM)

Y. R. Shen, The Principles of Nonlinear Optics, 2002.

D. M. Burland, Special Issue on Optical Nonlinearities in Chemistry, Chemical Reviews, issue.1, p.94, 1994.

P. A. Franken, G. Weinreich, C. W. Peters, and A. E. Hill, Generation of Optical Harmonics, Physical Review Letters, vol.7, issue.4, p.118, 1961.
DOI : 10.1103/PhysRevLett.7.118

J. Zyss and I. Ledoux, Molécules organiques et traitement optiques. L'écho des recherches, pp.19-30, 1987.

I. Ledoux, R. Pinsard-levenson, and J. Zyss, Matériaux organiques pour les réseaux de communications optiques : de la molécule aux composants. L'écho des recherches, pp.35-48, 1995.

H. S. Nalwa and S. Miyata, Nonlinear Optics of Organic Molecules and Polymers, Optical Engineering, vol.36, issue.9, 1997.
DOI : 10.1117/1.601490

S. L. Gilat, S. H. Kawai, and J. M. And-lehn, Light-Triggered Molecular Devices: Photochemical Switching Of optical and Electrochemical Properties in Molecular Wire Type Diarylethene Species, Chemistry - A European Journal, vol.173, issue.1, pp.275-284, 1995.
DOI : 10.1002/chem.19950010504

S. Houbrechts, K. Clays, A. Persoons, Z. Pikramenou, and J. M. And-lehn, Hyper-Rayleigh scattering investigation of nitrobenzyl pyridine model compounds for optical modulation of the hyperpolarisability, Chemical Physics Letters, vol.258, issue.3-4, pp.3-4, 1996.
DOI : 10.1016/0009-2614(96)00676-8

D. Majumdar, H. M. Lee, J. Kim, K. S. Kim, and B. J. Mhin, -(3-thienyl)-ethene derivatives, The Journal of Chemical Physics, vol.111, issue.13, pp.111-5866, 1999.
DOI : 10.1063/1.479881

J. A. Delaire, I. Fanton-maltey, J. Chauvin, K. Nakatani, and M. Irie, Nonlinear Optical Properties of Diarylethenes, Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, vol.15, issue.1, pp.557-562, 2000.
DOI : 10.1021/cm970369w

B. J. Coe, Molecular Materials Possessing Switchable Quadratic Nonlinear Optical Properties, Chemistry - A European Journal, vol.5, issue.9, pp.2464-2471, 1999.
DOI : 10.1002/(SICI)1521-3765(19990903)5:9<2464::AID-CHEM2464>3.0.CO;2-L

I. Asselberghs, K. Clays, A. Persoons, M. D. Ward, and J. Mccleverty, Switching of molecular second-order polarisability in solution, Journal of Materials Chemistry, vol.14, issue.19, pp.14-2831, 2004.
DOI : 10.1039/b401434k

T. Weyland, I. Ledoux, S. Brasselet, J. Zyss, and C. Lapinte, Nonlinear optical properties of redox-active mono-, bi-, and trimetallic sigma-acetylide complexes connected through a phenyl ring in the Cp*(dppe)Fe series. An example of electro-switchable NLO response, Organometallics, issue.24, pp.19-5235, 2000.

F. Paul, K. Costuas, I. Ledoux, S. Deveau, J. Zyss et al., Redox-switchable second-order molecular polarizabilities with electron-rich iron sigma-aryl acetylides, Organometallics, issue.24, pp.21-5229, 2002.
DOI : 10.1021/om020303x

I. Asselberghs, K. Clays, A. Persoons, A. M. Mcdonagh, M. D. Ward et al., In situ reversible electrochemical switching of the molecular first hyperpolarizability, Chemical Physics Letters, vol.368, issue.3-4, pp.3-4, 2003.
DOI : 10.1016/S0009-2614(02)01890-0

S. K. Hurst, M. P. Cifuentes, J. P. Morrall, N. T. Lucas, I. R. Whittall et al., Organometallic complexes for nonlinear optics. 22. Quadratic and cubic hyperpolarizabilities of trans-bis(bidentate phosphine)ruthenium sigma-arylvinylidene and sigma-arylalkynyl complexes, Organometallics, issue.22, pp.20-4664, 2001.

I. Asselberghs, Y. Zhao, K. Clays, A. Persoons, A. Comito et al., Reversible switching of molecular second-order nonlinear optical polarizability through proton-transfer Characterization of Quasi- Crystal Structure by Optical Frequency Doubling, Chemical Physics Letters Chemical Physics Letters, vol.364, issue.873, pp.3-4, 1982.

H. Sakaguchi, L. A. Gomezjahn, M. Prichard, T. L. Penner, D. G. Whitten et al., Subpicosecond Photoinduced Switching of 2nd-Harmonic Generation from a Ruthenium Complex in Supported Langmuir-Blodgett-Films, Journal of Physical Chemistry, issue.8, pp.97-1474, 1993.

O. Sato, R. Baba, K. Hashimoto, and A. Fujishima, Observation of the Trans- Cis Photoisomerization of Azobenzene Derivative in Langmuir-Blodgett-Film by the Optical 2nd-Harmonic Generation, Denki Kagaku, issue.6, pp.62-530, 1994.

K. Yamada, H. Otsubo, H. Yonemura, S. Yamada, and T. Matsuo, Nonlinear Optical Responses of Dialkoxyazobenzene Isomers Adsorbed to Interface between Heptane and Viologen-Modified Quartz Plates, Chemistry Letters, vol.26, issue.5, pp.451-452, 1997.
DOI : 10.1246/cl.1997.451

J. Abe, M. Hasegawa, H. Matsushima, Y. Shirai, N. Nemoto et al., Investigation of Dipolar Alignment of Mesogenic Chromophores in Side-Chain Liquid-Crystalline Polysiloxane Using Electric-Field-Induced 2nd- Harmonic Generation, Macromolecules, issue.8, pp.28-2938, 1995.

R. Loucif-saibi, K. Nakatani, J. A. Delaire, M. Dumont, and Z. Sekkat, Photoisomerization and second harmonic generation in disperse red one-doped and -functionalized poly(methyl methacrylate) films, Chemistry of Materials, vol.5, issue.2, pp.229-236, 1993.
DOI : 10.1021/cm00026a014

M. Hasegawa, N. Nemoto, Y. Nagase, Y. Shirai, T. Ikeda et al., Orientational dynamics in the crystalline and amorphous states of side-chain liquid crystalline polysiloxane probed by second harmonic generation, Polymer, vol.40, issue.1, pp.219-225, 1999.
DOI : 10.1016/S0032-3861(98)00237-7

K. Nakatani, J. A. Delaire, F. Poineau, K. Nakatani, J. A. Delaire et al., Reversible Photoswitching of Second-Order Nonlinear Optical Properties in an Organic Photochromic Crystal Photochromic materials for reversible switching of second order nonlinear optical properties Design, synthesis, structural and nonlinear optical properties of photochromic crystals: Toward reversible molecular switches, Chem. Mater. Molecular Crystals and Liquid Crystals Chemistry of Materials, vol.28, issue.91218, pp.2682-2684, 1997.

L. Sanguinet, J. L. Pozzo, V. Rodriguez, F. Adamietz, F. Castet et al., Acido- and Phototriggered NLO Properties Enhancement, Photochromism: Molecules and Systems Organic Photochromic and Thermochromic Compounds, pp.11139-11150, 1971.
DOI : 10.1021/jp0442450

URL : https://hal.archives-ouvertes.fr/hal-00108427

M. Irie, Photochromism:?? Memories and SwitchesIntroduction, Chemical Reviews, vol.100, issue.5, pp.1683-1683, 2000.
DOI : 10.1021/cr980068l

R. J. Guglielmetti, H. Durr, and H. Bouas-laurent, Spiropyrans and Related Compounds, Photochromism: Molecules and Systems, pp.855-876, 1990.
DOI : 10.1016/B978-044451322-9/50027-0

A. Gavazzotti and B. L. Feringa, Are Crystal-Structures Predictable Photochromism and thermochromism of Schiff bases in the solid state: structural aspects, Molecular Switches, pp.27-309, 1994.

E. Hadjoudis, Photochromic and Thermochromic Anils. Molecular Engineering, pp.301-337, 1995.

M. D. Cohen, G. M. Schmidt, S. Flavian, . Topochemistry, V. Part et al., * Experiments on Photochromy and Thermochromy of Crystalline Anils of Salicylaldehydes 2nd-Harmonic Generation of Light by Focused Laser Beams Relations between Microscopic and Macroscopic Lowest-Order Optical Nonlinearities of Molecular-Crystals with One- Dimensional or Two-Dimensional Units Molecular engineering for modern optics. L'écho des recherches, J. Chem. Soc. Physical Review Physical Review A Journal of the Optical Society of America B- Optical Physics, vol.145, issue.46 67, pp.2041-2051, 1964.

I. Ledoux and J. Zyss, Multipolar engineering of molecules and materials for quadratic nonlinear optics, Comptes Rendus Physique, vol.3, issue.4, pp.407-427, 2002.
DOI : 10.1016/S1631-0705(02)01332-4

C. Andraud, T. Zabulon, A. Collet, and J. Zyss, Nonlinear optical properties of polyenoctupoles: a multipolar tensorial quantum analysis, Chemical Physics, vol.245, issue.1-3, pp.1-3, 1999.
DOI : 10.1016/S0301-0104(99)00080-4

URL : https://hal.archives-ouvertes.fr/hal-01322790

B. H. Robinson, L. R. Dalton, A. W. Harper, A. Ren, F. Wang et al., The molecular and supramolecular engineering of polymeric electro-optic materials, Chemical Physics, vol.245, issue.1-3, pp.1-3, 1999.
DOI : 10.1016/S0301-0104(99)00079-8

L. Bozec, H. , L. Bouder, T. Maury, O. Ledoux et al., Coordination chemistry for nonlinear optics: a powerful tool for the design of octupolar molecules and supramolecules, Journal of Optics A: Pure and Applied Optics, vol.4, issue.6, pp.189-196, 2002.
DOI : 10.1088/1464-4258/4/6/351

L. Bozec, H. Renouard, T. Bourgault, M. Dhenaut, C. Brasselet et al., Molecular engineering of octupolar tris(bipyridyl) metal complexes, Synthetic Metals, vol.124, issue.1, pp.185-189, 2001.
DOI : 10.1016/S0379-6779(01)00439-8

L. Bouder, T. Maury, O. Bondon, A. Costuas, K. Amouyal et al., Synthesis, Photophysical and Nonlinear Optical Properties of Macromolecular Architectures Featuring Octupolar Tris(bipyridine) Ruthenium(II) Moieties:?? Evidence for a Supramolecular Self-Ordering in a Dentritic Structure, Harmonic Rayleigh-Scattering from Nonlinear Octupolar Molecular Media -the Case of Crystal Violet. Chemical Physics, pp.12284-12299, 1993.
DOI : 10.1021/ja030296j

J. O. Morley, D. Pugh, H. S. Nalwa, S. R. Miyata, M. A. Ratner et al., Nonlinear Optics of Organic Molecules and Polymers, Boca Raton. p. Special Issue on Optical Nonlinearities in Chemistry. Chemical Reviews, issue.1, pp.29-57, 1994.

J. L. Oudar and D. S. Chemla, Hyperpolarizabilities of the nitroanilines and their relations to the excited state dipole moment, The Journal of Chemical Physics, vol.66, issue.6, pp.66-2664, 1977.
DOI : 10.1063/1.434213

M. H. Cho, S. Y. An, H. Lee, I. Ledoux, and J. Zyss, Nonlinear optical properties of tetrahedral donor???acceptor octupolar molecules: Effective five-state model approach, The Journal of Chemical Physics, vol.116, issue.21, pp.116-9165, 2002.
DOI : 10.1063/1.1473818

L. Viau, S. Bidault, O. Maury, S. Brasselet, I. Ledoux et al., All-Optical Orientation of Photoisomerizable Octupolar Zinc(II) Complexes in Polymer Films, Journal of the American Chemical Society, vol.126, issue.27, pp.126-8386, 2004.
DOI : 10.1021/ja048143z

O. A. Aktsipetrov, N. N. Akhmediev, E. D. Mishina, and V. R. Novak, 2nd- Harmonic Generation on Reflection from a Monomolecular Langmuir Layer, Jetp Letters, vol.37, issue.4, pp.207-209, 1983.

P. M. Lundquist, S. Yitszchaik, T. Zhang, D. R. Kanis, M. A. Ratner et al., Dispersion of second-order optical nonlinearity in chromophoric self-assembled films by optical parametric amplification: experimental and theory Light-induced second-harmonic generation in an octupolar dye, Applied Physics Letters Optics Letters, issue.24, pp.20-2469, 1994.

J. L. Oudar, R. J. Hierle, I. Ledoux, R. B. Hierle, R. K. Raj et al., An efficient organic crystal for nonlinear optics: methyl-(2,4-dinitrophenyl)-aminopropanoate Optical Parametric Interactions in 3-Methyl-4-Nitropyridine-1-Oxide (Pom) Single-Crystals, Journal of Applied Physics Ieee Journal of Quantum Electronics, issue.8, pp.21-1286, 1977.

I. Ledoux, C. Lepers, A. Perigaud, J. Badan, and J. Zyss, Linear and nonlinear optical properties of N-4-nitrophenyl L-prolinol single crystals, Optics Communications, vol.80, issue.2, pp.149-154, 1990.
DOI : 10.1016/0030-4018(90)90377-6

S. R. Marder, J. W. Perry, Y. , C. P. Thakur, and M. , Organics salts with large second-order optical nonlinearities Nonlinear optical studies of single crystal films of N-(4-nitrophenyl)-L-prolinol, Chemistry of Materials Applied Physics Letters, issue.14, pp.69-1994, 1994.

R. Bavli and Y. B. Band, Relationship between second-harmonic generation and electric-field-induced second-harmonic generation, Physical Review A, vol.43, issue.1, pp.507-514, 1991.
DOI : 10.1103/PhysRevA.43.507

T. Kondo, R. Morita, N. Ogasawara, S. Umegaki, and R. Ito, Measurement of second-order nonlinear optical coefficients. Solid State Physics, pp.899-902, 1989.

R. W. Terhune, P. D. Maker, and C. M. Savage, Measurements of Nonlinear Light Scattering, Physical Review Letters, vol.14, issue.17, pp.14-681, 1965.
DOI : 10.1103/PhysRevLett.14.681

E. A. Guggenheim, A Proposed Simplification in the Procedure for Computing Electric Dipole Moments. Transactions of the Faraday Society, pp.45-714, 1949.

S. K. Kurtz and T. T. Perry, A Powder Technique for Evaluation of Nonlinear Optical Materials, Journal of Applied Physics, issue.8, pp.39-3798, 1968.

S. L. Gilat, S. H. Kawai, and J. M. And-lehn, Light-triggered electrical and optical switching devices, Journal of the Chemical Society, Chemical Communications, issue.18, pp.1439-1442, 1993.
DOI : 10.1039/c39930001439

E. Hendrickx, K. Clays, A. Persoons, C. Dehu, and J. L. Bredas, The Bacteriorhodopsin Chromophore Retinal and Derivatives: An Experimental and Theoretical Investigation of the Second-Order Optical Properties, Journal of the American Chemical Society, vol.117, issue.12, pp.3547-3555, 1994.
DOI : 10.1021/ja00117a024

K. Nakatani and J. A. Delaire, Reversible Photoswitching of Second-Order Nonlinear Optical Properties in an Organic Photochromic Crystal, Chemistry of Materials, vol.9, issue.12, p.2682, 1997.
DOI : 10.1021/cm970369w

J. E. Fritzche, Note sur les carbures d'hydrogène solides, tirés du gaudron de houille Comptes Rendus de l'Académie des Sciences, 1867. 69: p. 1035-1037, Uber phototropie. Zeitschrift fur physik Chemie, pp.1899-140

Y. Hirshberg and E. Fischer, Photochromism and reversible multiple internal transitions in some spiropyrans at low temperatures. Part I, Journal of the Chemical Society (Resumed), issue.jan, pp.297-303, 1954.
DOI : 10.1039/jr9540000297

Y. Hirshberg and E. Fischer, Photochromism and reversible multiple internal transitions in some spiropyrans at low temperatures. Part I, Journal of the Chemical Society (Resumed), issue.sep, pp.3129-3137, 1954.
DOI : 10.1039/jr9540000297

Y. Hirshberg, E. Fischer, and P. Thermochromism, Thermochromism and Photochromism, The Journal of Chemical Physics, vol.23, issue.9, pp.1723-1723, 1955.
DOI : 10.1063/1.1742422

N. Y. Chu, Chapitre 10, in Photochromism: Molecules and Systems, pp.879-881, 1990.

M. Irie, Diarylethenes for Memories and Switches, Chemical Reviews, vol.100, issue.5, pp.1685-1716, 2000.
DOI : 10.1021/cr980069d

Y. Yokoyama and M. Kose, Reversible control of properties of materials by thermally irreversible photochromism Journal of Photochemistry and Photobiology a-Chemistry-3): p. 9-18. 87. Yokoyama, Y., Fulgides for memories and switches, Chemical Reviews, vol.166, issue.15, pp.100-1717, 2000.

Y. Yokoyama and Y. Kurita, Photochromic Fulgides Applicable to Optical Information-Storage -Discovery of New Nondestructive Readout Method, Nippon Kagaku Kaishi, issue.10, pp.998-1006, 1992.

S. J. Luo, K. X. Chen, L. C. Cao, G. D. Liu, Q. S. He et al., Photochromic diarylethene for rewritable holographic data storage, Optics Express, vol.13, issue.8, pp.13-3123, 2005.
DOI : 10.1364/OPEX.13.003123

T. Shiono, T. Itoh, S. Y. Nishino, T. Goto, T. Inoue et al., Two-photon absorption recording in photochromic diarylethenes using laser diode for three-dimensional optical memory Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers Fulgides as Efficient Photochromic Compounds -Role of the Substituent on Furylalkylidene Moiety of Furylfulgides in the Photoreaction Perfect on/off switching of emission of fluorescence by photochromic reaction of a binaphthol-condensed fulgide derivative, Chemistry Letters Chemistry Letters, issue.5B64, pp.44-3559, 1988.

A. Senier, F. G. Shepheard, C. , and R. , CCVII.???Studies in phototropy and thermotropy. Part III. Arylideneamines, J. Chem. Soc., Trans., vol.101, issue.0, pp.1950-1958, 1912.
DOI : 10.1039/CT9120101950

R. V. Andes and D. M. Manikowski, Photochromism of Salicylidene Aniline, Applied Optics, vol.7, issue.6, pp.1179-1183, 1968.
DOI : 10.1364/AO.7.001179

A. E. Chichibabin, B. M. Kunidzhi, S. Benewolenskaja, W. Ber-naumov, P. Sekine et al., 28: p. 1580. 97 Structure of the photocolored 2-(2 ',4 '-dinitrobenzyl)pyridine crystal: Two-photon induced solidstate proton transfer with minor structural perturbation, Dtsch Chem. Ges. Journal of the American Chemical Society, issue.29, pp.124-8540, 1925.

S. Benard and P. Yu, A spirooxazine showing crystalline state photochromism, Chemical Communications, issue.1, pp.65-66, 2000.
DOI : 10.1039/a907675a

O. Godsi, U. Peskin, M. Kapon, N. A. Ezra, and Y. Eichen, Site effects in controlling the chemical reactivity in crystals: solid-state photochromism of N-(npropyl )nitrospiropyrane, Chemical Communications, issue.20, pp.2132-2133, 2001.

M. Irie, K. Uchida, T. Eriguchi, and H. Tsuzuki, Photochromism of Single Crystalline Diarylethenes, Chemistry Letters, vol.24, issue.10, pp.899-900, 1995.
DOI : 10.1246/cl.1995.899

M. Irie and S. Kobatake, Frontiers in Crystal Chemistry: Prediction of Structures and Properties. Part 2. Solid-State Properties and Reactions Predicted from Crystal Structures. Photochromism in a Crystalline Phase., Nihon Kessho Gakkaishi, vol.44, issue.1, pp.61-64, 2002.
DOI : 10.5940/jcrsj.44.61

E. Hadjoudis, Photochromism and thermochromism of N-salicylideneanilines and N-salicylideneamino-pyridines, Journal of Photochemistry, vol.17, issue.2, pp.355-363, 1981.
DOI : 10.1016/0047-2670(81)85377-4

M. D. Cohen, S. Flavian, and . Topochemistry, Absorption Spectra of Some N- Salicylideneanilines and Related Anils in Solution, Journal of the Chemical Society B-Physical Organic, vol.25, issue.19674, p.321

R. Nakagaki, T. Kobayashi, J. Nakamura, and S. Nagakura, -Salicylideneanilines and Related Compounds, Bulletin of the Chemical Society of Japan, vol.50, issue.8, pp.50-1909, 1977.
DOI : 10.1246/bcsj.50.1909

URL : https://hal.archives-ouvertes.fr/hal-01122055

. E. Hadjoudi and E. Hayon, Flash photolysis of some photochromic N-benzylideneanilines, The Journal of Physical Chemistry, vol.74, issue.17, pp.74-3184, 1970.
DOI : 10.1021/j100711a004

M. D. Cohen and G. M. Schmidt, Photochromy and Thermochromy of Anils, Journal of Physical Chemistry, issue.12, pp.66-2442, 1962.

S. Mitra and N. Tamai, Dynamics of photochromism in salicylideneaniline: A femtosecond spectroscopic study, Physical Chemistry Chemical Physics, vol.5, issue.20, pp.4647-4652, 2003.
DOI : 10.1039/b306125f

T. Fujiwara, J. Harada, and K. Ogawa, Solid-State Thermochromism Studied by Variable-Temperature Diffuse Reflectance Spectroscopy. A New Perspective on the Chromism of Salicylideneanilines, The Journal of Physical Chemistry B, vol.108, issue.13, pp.4035-4038, 2004.
DOI : 10.1021/jp037438g

M. D. Cohen, G. M. Schmidt, and Y. Hirshberg, Photoactivity of Anils of Salicylaldehydes in Rigid Solutions, Topochemistry . Journal of the Chemical Society, vol.7, pp.1964-2051

T. Sekikawa, T. Kobayashi, and T. Inabe, Femtosecond Fluorescence Study of Proton-Transfer Process in Thermochromic Crystalline Salicylideneanilines, The Journal of Physical Chemistry B, vol.101, issue.50, pp.10645-10652, 1997.
DOI : 10.1021/jp9715888

E. Hadjoudis, I. Moustakalimavridis, and J. Xexakis, Effect of Crystal and Molecular Structure on the Thermochromism and Photochromism of some Salicylidene-2-Aminopyridines, Israel Journal of Chemistry, vol.81, issue.3-4, pp.18-21, 1979.
DOI : 10.1002/ijch.197900029

H. Fukuda, K. Amimoto, H. Koyama, and T. Kawato, Crystalline photochromism of N-salicylidene-2,6-dialkylanilines: advantage of 2,6-dialkyl substituents of aniline for preparation of photochromic Schiff base crystals, Organic & Biomolecular Chemistry, vol.1, issue.9, pp.1578-1583, 2003.
DOI : 10.1039/b212295b

T. Kawato, H. Koyama, H. Kanatomi, H. Tagawa, and K. Iga, Photoisomerization and thermoisomerization III. tert-butyl method of selective preparation of photochromic crystalline salicylideneanilines and elucidation of substituent effects on the kinetics of the colour-change process, Journal of Photochemistry and Photobiology A: Chemistry, vol.78, issue.1, pp.78-71, 1994.
DOI : 10.1016/1010-6030(93)03711-O

T. Kawato, H. Koyama, H. Kanatomi, and M. Isshiki, Photoisomerization and thermoisomerization I: Unusual photochromism of N-(3,5-di-tert-butyl-salicylidene) amines, Journal of Photochemistry, vol.28, issue.1, pp.103-110, 1985.
DOI : 10.1016/0047-2670(85)87020-9

M. Ottolengi, D. S. Mcclure, and . Photochromism, Photochemistry of Salicylideneaniline, Journal of Chemical Physics, issue.212, pp.46-4620, 1967.

M. Ottolengi and D. S. Mcclure, Photochromism. I. The Spectroscopy and Energy Levels of Salicylideneaniline, The Journal of Chemical Physics, vol.46, issue.12, pp.46-4613, 1967.
DOI : 10.1063/1.1840611

D. Higelin and H. Sixl, Spectroscopic studies of the photochromism of N-salicylideneaniline mixed crystals and glasses, Chemical Physics, vol.77, issue.3, pp.391-400, 1983.
DOI : 10.1016/0301-0104(83)85093-9

M. Ziolek, J. Kubicki, A. Maciejewski, R. Naskrecki, and A. Grabowska, An ultrafast excited state intramolecular proton transfer (ESPIT) and photochromism of salicylideneaniline (SA) and its ''double'' analogue salicylaldehyde azine (SAA). A controversial case, Physical Chemistry Chemical Physics, issue.6, pp.4682-4689, 2004.

V. Vargas, Time-Resolved Fluorescence of Salicylideneaniline Compounds in Solution, The Journal of Physical Chemistry A, vol.108, issue.2, pp.281-288, 2004.
DOI : 10.1021/jp035461w

C. Okabe, T. Nakabayashi, Y. Inokuchi, N. Nishi, and H. Sekiya, -salicylideneaniline studied by femtosecond time-resolved REMPI spectroscopy, The Journal of Chemical Physics, vol.121, issue.19, pp.121-9436, 2004.
DOI : 10.1063/1.1801991

URL : https://hal.archives-ouvertes.fr/hal-00212212

M. Z. Zgierski and A. Grabowska, Photochromism of salicylideneaniline (SA). How the photochromic transient is created: A theoretical approach, The Journal of Chemical Physics, vol.112, issue.14, pp.112-6329, 2000.
DOI : 10.1063/1.481194

N. Otsubo, C. Okabe, H. Mori, K. Sakota, K. Amimoto et al., Excited-state intramolecular proton transfer in photochromic jet-cooled N-salicylideneaniline, Journal of Photochemistry and Photobiology A: Chemistry, vol.154, issue.1, pp.33-39, 2002.
DOI : 10.1016/S1010-6030(02)00306-4

M. D. Cohen, . Topochemistry, and X. Part, The system : 4-Chloro-N-salicylidene- aniline-4-Bromo-N-salicylideneaniline, J. Chem. Soc. B, pp.373-376, 1968.

I. Mooustakali-mavridis, B. Hadjoudis, and A. Mavridis, -(5-methoxysalicylidene)-3-aminopyridine, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.36, issue.5, pp.36-1126, 1980.
DOI : 10.1107/S0567740880005432

I. Moustakalimavridis and E. Hadjoudis, The Crystal-Structures of N-(4- Nitrobenzylidene)-2-Methoxy-5-Aminopyridine, Molecular Crystals and Liquid Crystals, issue.156, pp.35-38, 1988.

G. R. Artus, M. U. Rauch, H. , and W. A. , Crystal structure of 1,3-bis N

N. Gali, D. Matkovi-alogovi, and Z. Cimerman, Structural characteristics of N,N???-bis(salicylidene)-2,6-pyridinediamine, Journal of Molecular Structure, vol.406, issue.1-2, pp.153-158, 1997.
DOI : 10.1016/S0022-2860(96)09608-1

T. Goto and Y. Tashiro, Photochromism of N-salicylideneaniline single crystal, Journal of Luminescence, vol.72, issue.74, pp.72-76, 1997.
DOI : 10.1016/S0022-2313(96)00243-8

K. Ogawa, Y. Kasahara, Y. Ohtani, and J. Harada, -Salicylideneanilines. The First Observation by X-ray Diffraction, Journal of the American Chemical Society, vol.120, issue.28, pp.120-7107, 1998.
DOI : 10.1021/ja980972v

URL : https://hal.archives-ouvertes.fr/hal-00018442

J. Harada, H. Uekusa, and Y. Ohashi, X-ray analysis of structural changes in photochromic salicylideneaniline crystals. Solid-state reaction induced by twophoton excitation, Journal of the American Chemical Society, issue.24, pp.121-5809, 1999.

M. Kabak, A. Elmali, and Y. Elerman, Keto???enol tautomerism, conformations and structure of N-(2-hydroxy-5-methylphenyl), 2-hydroxybenzaldehydeimine, Journal of Molecular Structure, vol.477, issue.1-3, pp.1-3, 1999.
DOI : 10.1016/S0022-2860(98)00604-8

K. Ogawa, J. Harada, I. Tamura, and Y. Noda, X-Ray Crystallographic Analysis of the NH Form of a Salicylideneaniline at 15 K, Chemistry Letters, vol.29, issue.5, pp.528-529, 2000.
DOI : 10.1246/cl.2000.528

H. Nazir, M. Yildiz, H. Yilmaz, M. N. Tahir, and D. Ulku, Intramolecular hydrogen bonding and tautomerism in Schiff bases. Structure of N-(2-pyridil)-2-oxo-1-naphthylidenemethylamine, Journal of Molecular Structure, vol.524, issue.1-3, pp.241-250, 2000.
DOI : 10.1016/S0022-2860(00)00393-8

H. Ünver, M. Kabak, D. M. Zengin, and T. N. Durlu, Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone, Z. Naturforsch, pp.56-1003, 2001.

S. Sakagami, T. Koga, and A. Takase, Liquid Crystalline Properties and Photochromism of 4-Cyano- and 4-Nitro-N-(4-Alkoxysalicylidene) Anilines, Molecular Crystals and Liquid Crystals, vol.382, issue.1, pp.125-133, 2002.
DOI : 10.1080/713738753

T. Inabe, I. Luneau, T. Mitani, Y. Maruyama, and S. Takeda, -phenylenediamine Crystals, Bulletin of the Chemical Society of Japan, vol.67, issue.3, pp.67-612, 1994.
DOI : 10.1246/bcsj.67.612

URL : https://hal.archives-ouvertes.fr/in2p3-01005498

J. Bregman, . L. Leiserow, and K. Osaki, Topochemistry .10. Crystal + Molecular Structures of 2-Chloro-N-Salicylideneaniline, Journal of the Chemical Society, p.2086, 1964.

K. Bhat, K. J. Chang, M. D. Aggarwal, W. S. Wang, B. G. Penn et al., Synthesis and characterization of various Schiff bases for non-linear optical applications, Materials Chemistry and Physics, vol.44, issue.3, pp.44-261, 1996.
DOI : 10.1016/0254-0584(96)80066-6

M. C. Palazzotto, Second harmonic generation with Schiff bases, US Patent, vol.4733109, pp.1-16, 1986.

S. Létard, Travaux menés sur la synthèse du 3,5-di-tert-butylsalicylidène-4- Aminopyridine, 2002.

I. Moustakalimavridis and E. Hadjoudis, Crystal and Molecular-Structure of Some Thermochromic Schiff-Bases, Acta Crystallographica Section B-Structural Science, pp.34-3709, 1978.

T. Asahi, H. Masuhara, K. Nakatani, and M. Sliwa, Photochromic Dynamics of Salicylidene Aniline in Solid State by Using Femtosecond Transient Absorption Spectroscopy, Molecular Crystals and Liquid Crystals, vol.282, issue.1, pp.541-548, 2005.
DOI : 10.1063/1.481194

M. D. Cohen, S. Flavian, and . Topochemistry, Luminescence Properties of N- Salicylideneaniline and Related Anils in Solution, Journal of the Chemical Society B-Physical Organic, vol.24, issue.19674, p.317

E. Hadjoudis, Photochromism and thermochromism of N-salicylideneanilines and N-salicylideneaminopyridines, Journal of Photochemistry, vol.17, issue.1, pp.3-4, 1981.
DOI : 10.1016/0047-2670(81)85212-4

. Ledbette and . Jw, Substituent Effects on Tautomerism of Schiff Bases, Journal of Physical Chemistry, issue.12, pp.72-4111, 1968.

J. Ledbetter, Tautomerism of N-Omicron-Hydroxybenzylidene Anils in Nonacidic Solvents, Journal of Physical Chemistry, issue.7, pp.71-2351, 1967.

. Ledbette and . Jw, Spectroscopic Evidence for Enol Imine-Keto Enamine Tautomerism of N-(O-and P-Hydroxybenzylidene) Anils in Solution, Journal of Physical Chemistry, issue.7, pp.70-2245, 1966.

I. Maltey, J. A. Delaire, K. Nakatani, P. F. Wang, X. Y. Shi et al., Hyperpolarisability of (donor)2-acceptor???type molecules determined by EFISHG, Advanced Materials for Optics and Electronics, vol.6, issue.56, pp.5-6, 1996.
DOI : 10.1002/(SICI)1099-0712(199609)6:5/6<233::AID-AMO272>3.0.CO;2-1

C. Bosshard, G. Knopfle, P. Pretre, and P. Gunter, 2nd-Order Polarizabilities of Nitropyridine Derivatives Determined with Electric-Field-Induced 2nd- Harmonic Generation and a Solvatochromic Method -a Comparative-Study, Journal of Applied Physics, issue.4, pp.71-1594, 1992.

D. M. Burland, C. A. Walsh, F. Kajzar, and C. Sentein, Comparison of hyperpolarizabilities obtained with different experimental methods and theoretical techniques, Journal of the Optical Society of America B, vol.8, issue.11, pp.2269-2281, 1991.
DOI : 10.1364/JOSAB.8.002269

K. D. Singer and A. F. Garito, Measurements of Molecular 2nd Order Optical Susceptibilities Using Dc Induced 2nd Harmonic-Generation, Journal of Chemical Physics, issue.7, pp.75-3572, 1981.

C. S. Liu, R. Glaser, P. Sharp, and J. F. Kauffman, The Slope Ratio Method:?? A Simple and Accurate Method to Extract the First Hyperpolarizability from EFISH Measurements, The Journal of Physical Chemistry A, vol.101, issue.38, pp.101-7176, 1997.
DOI : 10.1021/jp9714983

I. Maltey-fanton, Hyperpolarisabilité de premier ordre de molécules organiques : complexes organométalliques, photochromes, molécules en lambda, in PPSM, Thèse de l'Ecole Normale Supérieure de Cachan, 1997.

G. M. Janini and A. H. Katrib, Determination of the dipole moment of polar compounds in nonpolar solvents, Journal of Chemical Education, vol.60, issue.12, pp.60-1087, 1983.
DOI : 10.1021/ed060p1087

G. S. Chen, C. S. Liu, R. Glaser, and J. F. Kauffman, Dipole moments of the nonlinear optical materials NPO and POM, Chemical Communications, issue.15, pp.1719-1720, 1996.
DOI : 10.1039/cc9960001719

K. Bhat, J. Choi, S. D. Mccall, M. D. Aggarwal, B. H. Cardelino et al., Theoretical and experimental study of the second-order polarizabilities of Schiff's bases for nonlinear optical applications, Computational Materials Science, vol.8, issue.4, pp.309-316, 1997.
DOI : 10.1016/S0927-0256(97)00043-8

Y. Zhang, C. Y. Zhao, W. H. Fang, and X. Z. You, A molecular design view on the first hyperpolarizability of salicylideneaniline derivatives, Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta), vol.96, issue.2, pp.129-134, 1997.
DOI : 10.1007/s002140050213

C. Curran and E. P. Chaput, Electric Moments of Ortho-Substituted Phenols and Anisoles .3. Nitriles and Anils, Journal of the American Chemical Society, issue.5, pp.69-1134, 1947.

W. P. Anderson, W. D. Edwards, and M. C. Zerner, Calculated Spectra of Hydrated Ions of the 1st Transition-Metal Series, Inorganic Chemistry, issue.16, pp.25-2728, 1986.

M. C. Zerner, G. H. Loew, R. F. Kirchner, and U. T. Muellerwesterhoff, An intermediate neglect of differential overlap technique for spectroscopy of transition-metal complexes. Ferrocene, Journal of the American Chemical Society, vol.102, issue.2, pp.589-599, 1980.
DOI : 10.1021/ja00522a025

J. F. Ward, Calculation of Nonlinear Optical Susceptibilities Using Diagrammatic Perturbation Theory, Reviews of Modern Physics, vol.37, issue.1, p.1, 1965.
DOI : 10.1103/RevModPhys.37.1

X. L. Zhu, X. Z. You, Y. Zhong, Z. Yu, and S. L. Guo, An improved calculation method on optical second-order susceptibilities of organic materials, Chemical Physics, vol.253, issue.2-3, pp.241-248, 2000.
DOI : 10.1016/S0301-0104(99)00393-6

L. Floc-'h and V. , Caractérisation de l'organisation moléculaire par microscopie nonlinéaire cohérente et incohérente, in LPQM, Thèse de l'ENS Cachan, 2004.

L. Floc-'h, V. Brasselet, S. Zyss, J. Cho, B. R. Lee et al., High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy, Advanced Materials, issue.2, pp.17-196, 2005.

S. Brasselet, L. Floc-'h, V. Treussart, F. Roch, J. F. Zyss et al., In situ diagnostics of the crystalline nature of single organic nanocrystals by nonlinear microscopy, Physical Review Letters, p.92, 1920.

F. Treussart, E. Botzung-appert, N. T. Ha-duong, A. Ibanez, J. F. Roch et al., Second Harmonic Generation and Fluorescence of CMONS Dye Nanocrystals Grown in a Sol-Gel Thin Film, ChemPhysChem, vol.7, issue.7, pp.757-760, 2003.
DOI : 10.1002/cphc.200300681

L. Floc-'h, V. Brasselet, S. Roch, J. F. Zyss, and J. , Monitoring of Orientation in Molecular Ensembles by Polarization Sensitive Nonlinear Microscopy, The Journal of Physical Chemistry B, vol.107, issue.45, pp.12403-12410, 2003.
DOI : 10.1021/jp034950t

N. Coste, Microscopie de fluorescence résolue en temps pour l'étude de la diffusion dans la cuticule des feuilles, in PPSM, Thèse de l'ENSde Cachan, 1999.

P. F. Barbara, P. M. Rentzepis, and L. E. Brus, Photochemical kinetics of salicylidenaniline, Journal of the American Chemical Society, vol.102, issue.8, pp.102-2786, 1980.
DOI : 10.1021/ja00528a045

C. V. Vargas, Time-Resolved Fluorescence of Salicylideneaniline Compounds in Solution, The Journal of Physical Chemistry A, vol.108, issue.2, pp.281-288, 2004.
DOI : 10.1021/jp035461w

H. Miyasaka, T. Nobuto, A. Itaya, N. Tamai, and M. Irie, Picosecond laser photolysis studies on a photochromic dithienylethene in solution and in crystalline phases, Chemical Physics Letters, vol.269, issue.3-4, pp.3-4, 1997.
DOI : 10.1016/S0009-2614(97)00282-0

M. Suzuki, T. Asahi, and H. Masuhara, Photochromic reactions of crystalline spiropyrans and spirooxazines induced by intense femtosecond laser excitationDedicated to Professor Frank Wilkinson on the occasion of his retirement., Physical Chemistry Chemical Physics, vol.4, issue.2, pp.185-192, 2002.
DOI : 10.1039/b108108j

R. S. Becker, C. Lenoble, and A. Zein, A comprehensive investigation of the photophysics and photochemistry of salicylideneaniline and derivatives of phenylbenzothiazole including solvent effects, The Journal of Physical Chemistry, vol.91, issue.13, pp.91-3509, 1987.
DOI : 10.1021/j100297a011

M. D. Cohen, G. M. Schmidt, S. Flavian, and . Topochemistry, Experiments on Photochromy + Thermochromy of Crystalline Anils of Salicylaldehydes, Journal of the Chemical Society, issue.6, pp.1964-2041

J. W. Ledbetter, Infrared spectra of N-aryl imines of o-hydroxybenzaldehyde between 2000 and 1500 cm-1, The Journal of Physical Chemistry, vol.81, issue.1, pp.54-59, 1977.
DOI : 10.1021/j100516a013

T. Yuzawa, H. Takahashi, and H. Hamaguchi, Submicrosecond time-resolved infrared study on the structure of the photoinduced transient species of salicylideneaniline in acetonitrile, Chemical Physics Letters, vol.202, issue.3-4, pp.202-205, 1993.
DOI : 10.1016/0009-2614(93)85269-T

I. Krol-starzomska, A. Filarowski, M. Rospenk, A. Koll, and S. Melikova, Proton Transfer Equilibria in Schiff Bases with Steric Repulsion, The Journal of Physical Chemistry A, vol.108, issue.11, pp.2131-2138, 2004.
DOI : 10.1021/jp035009c

A. Spangenberg, Etude de matériaux organiques photochromes et thermochromes actifs en optique non linéaire, Rapport de DEA, 2005.

K. Amimoto, H. Kanatomi, A. Nagakari, H. Fukuda, H. Koyama et al., Deuterium isotope effect on the solid-state thermal isomerization of photocoloured cis-keto species of N-salicylideneaniline, Chemical Communications, issue.7, pp.2003-870

M. I. Knyazhansky, A. V. Metelitsa, M. E. Kletskii, A. A. Millov, and S. O. Besugliy, The structural transformations and photo-induced processes in salicylidene alkylimines, Journal of Molecular Structure, vol.526, issue.1-3, pp.65-79, 2000.
DOI : 10.1016/S0022-2860(00)00439-7

M. I. Knyazhansky, A. V. Metelitsa, A. J. Bushkov, and S. M. And-aldoshin, Role of structural flexibility in fluorescence and photochromism of the salicylideneaniline: the ???aldehyde??? ring rotation, Journal of Photochemistry and Photobiology A: Chemistry, vol.97, issue.3, pp.97-121, 1996.
DOI : 10.1016/1010-6030(96)04330-4

P. Feneyrou, F. Soyer, L. Barny, P. Ishow, E. Sliwa et al., Photochromic compounds as optical limiters in the nanosecond time range: the example of mercury dithizonate complex, Photochemical & Photobiological Sciences, issue.23, pp.195-202, 2003.

I. Texier, J. A. Delaire, and C. Giannotti, Reactivity of the charge transfer excited state of sodium decatungstate at the nanosecond time scale, Physical Chemistry Chemical Physics, vol.78, issue.6, pp.1205-1212, 2000.
DOI : 10.1039/a908588b

A. Grabowska, K. Kownacki, J. Karpiuk, S. Dobrin, and L. Kaczmarek, Photochromism and proton transfer reaction cycle of new internally H-bonded Schiff bases, Chemical Physics Letters, vol.267, issue.1-2, pp.132-140, 1997.
DOI : 10.1016/S0009-2614(97)00059-6

G. Wettermark and L. Dogliotti, Transient Species in the Photolysis of Anils, The Journal of Chemical Physics, vol.40, issue.6, p.1486, 1964.
DOI : 10.1063/1.1725350

A. Ohshima, A. Momotake, and T. Arai, Photochromism, thermochromism, and solvatochromism of naphthalene-based analogues of salicylideneaniline in solution, Journal of Photochemistry and Photobiology A: Chemistry, vol.162, issue.2-3, pp.473-479, 2004.
DOI : 10.1016/S1010-6030(03)00388-5

S. Mitra and N. Tamai, A combined experimental and theoretical study on the photochromism of aromatic anils, Chemical Physics, vol.246, issue.1-3, pp.463-475, 1999.
DOI : 10.1016/S0301-0104(99)00178-0

S. Mitra and N. Tamai, Femtosecond spectroscopic study on photochromic salicylideneaniline, Chemical Physics Letters, vol.282, issue.5-6, pp.5-6, 1998.
DOI : 10.1016/S0009-2614(97)01279-7

K. Ogawa and T. Fujiwara, Tautomerism of a nitro derivative of Nsalicylideneaniline in crystals, Chemistry Letters, issue.7, pp.657-658, 1999.

H. Kasai, H. Oikawa, S. Okada, and H. Nakanishi, Crystal Growth of Perylene Microcrystals in the Reprecipitation Method, Bulletin of the Chemical Society of Japan, vol.71, issue.11, pp.71-2597, 1998.
DOI : 10.1246/bcsj.71.2597