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Caractérisation physico-chimique des interphases époxyde-amine / oxyde ou hydroxyde métallique, et de leurs constituants Physico-chemical characterization of epoxy-amine / metal interphases, characterization of their constituents NATURE : Doctorat Numéro d'ordre : 05 ,
et bis CLASSE : RESUME : Les caractéristiques des systèmes collés ou peints époxyde-amine/métal dépendent des caractéristiques de chacun des constituants mais aussi de leur "combinaison". En particulier, l'interphase possède des propriétés spécifiques. La chimisorption de l'amine sur le métal et la dissolution de la couche d'hydroxyde initialement présente à sa surface sont simultanées. Le complexe organométallique créé réagit avec le monomère époxyde pour former un réseau aux propriétés physico-chimiques spécifiques. Lorsque la configuration des complexes permet leur cristallisation, et que leur produit de solubilité est dépassé, les complexes précipitent pour donner naissance à des cristaux de facteur de forme très important, Quand un polymère est réalisé avec ces complexes, les cristaux jouent le rôle de charges ,