). Transfert-de-matière-dans-le-filmtransfert-externe, 37 4.1.3 Transfert de matière dans l'adsorbant (transfert interne), p.37

. La-convergence-est-obtenue-au-bout-de-trois-cycles, La durée de la phase d'adsorption est de 1324 min, celle du pré-chauffage de 6 min, celle de la régénération de 163 min et celle du pré-refroidissement de 19 min. Le taux de travail est donc de 88% grâce à un temps d'immobilisation de la colonne (pré-chauffage, régénération et pré-refroidissement) faible devant le temps d'adsorption

D. Basmadjian, On the possibility of omitting the cooling step in thermal gas adsorption cycles, The Canadian Journal of Chemical Engineering, vol.65, issue.3, pp.234-238, 1975.
DOI : 10.1002/cjce.5450530216

D. Basmadjian, K. D. Ha, and C. Y. Et-pan, Nonisothermal Desorption by Gas Purge of Single Solutes in Fixed-Bed Adsorbers. I. Equilibrium Theory, Industrial & Engineering Chemistry Process Design and Development, vol.14, issue.3, pp.328-340, 1975.
DOI : 10.1021/i260055a023

D. Basmadjian, K. D. Ha, and D. P. Proulx, Nonisothermal Desorption by Gas Purge of Single Solutes from Fixed-Bed Adsorbers. II. Experimental Verification of Equilibrium Theory, Industrial & Engineering Chemistry Process Design and Development, vol.14, issue.3, pp.340-347, 1975.
DOI : 10.1021/i260055a024

D. Basmadjian and D. W. Et-wright, Non-isothermal sorption of ethane-carbon dioxide mixtures in beds of 5A molecular sieves, Chemical Engineering Science, vol.36, issue.5, pp.937-940, 1981.
DOI : 10.1016/0009-2509(81)85048-8

J. Bonjour, A. Mativet, J. B. Chalfen, and F. Meunier, Identification du coefficient de transfert de chaleur par convection à travers un milieu poreux, Proc. 3èmes Journées Tunisiennes sur les Écoulements et les Transferts, pp.167-171, 2000.

J. Bonjour, J. B. Chalfen, and F. Meunier, Temperature Swing Adsorption Process with Indirect Cooling and Heating, Industrial & Engineering Chemistry Research, vol.41, issue.23, pp.41-5802, 2002.
DOI : 10.1021/ie011011j

J. Bonjour, M. Clausse, and F. Et-meunier, Etude d'un procédé de capture de polluants par cycles TSA avec chauffage et refroidissement indirects, Partie 1 : analyse paramétrique des performances, SFGP2003, St Nazaire, 2003.

J. Bonjour, L. A. Rocha, A. Bejan, and F. Et-meunier, Dendritic fins optimization for a coaxial two-stream heat exchanger, International Journal of Heat and Mass Transfer, vol.47, issue.1, pp.111-124, 2004.
DOI : 10.1016/S0017-9310(03)00406-X

M. Bonnissel, L. Luo, and D. Et-tondeur, Fast thermal swing adsorption using thermoelectric devices and new adsorbent, Proc. 6 th Conf. Fundamentals of Adsorption (FOA6), pp.1065-1070, 1998.

V. Bourdin, P. G. Gray, and G. Ph, An apparatus for adsorption dynamics studies using infrared measurement of the adsorbent temperature, Review of Scientific Instruments, vol.69, issue.5, pp.2130-2136, 1998.
DOI : 10.1063/1.1148911

M. Clausse, J. Bonjour, and M. Et-meunier, Removal of pollutant mixtures from air streams with an indirect heating and cooling temperature swing adsorption process, Proc. Air Pollution, 2002.

M. Clausse, J. Bonjour, and M. Et-meunier, Influence of the presence of CO 2 in the feed of an indirect heating TSA process for VOC removal, Adsorption, vol.9, issue.1, pp.77-85, 2003.
DOI : 10.1023/A:1023819431640

M. Clausse, J. Bonjour, and F. Et-meunier, Etude d'un procédé de capture de polluants par cycles TSA avec chauffage et refroidissement indirects, analyse locale du comportement de l'adsorbeur, SFGP2003, St Nazaire, 2003.

E. L. Cussler, Diffusion, mass transfer in fluid systems, 1997.

A. D?browski, Adsorption ??? from theory to practice, Advances in Colloid and Interface Science, vol.93, issue.1-3, pp.135-224, 2001.
DOI : 10.1016/S0001-8686(00)00082-8

D. Silva, F. A. , D. Silva, J. Et-rodrigues, and A. E. , A general package for the simulation of cyclic adsorption processes, Adsorption, vol.5, issue.3, pp.229-244, 1999.
DOI : 10.1023/A:1008974908427

F. Delage, Échauffement des lits de charbon actif lors de l'adsorption de composes organiques volatils : étude expérimentale et modélisation, Thèse de Doctorat, 2000.

D. D. Do, Adsorption Analysis: Equilibria and Kinetics, Series on Chemical Engineering, vol.2, issue.891, 1998.
DOI : 10.1142/9781860943829

C. C. Huang and J. R. Et-fair, Study of the adsorption and desorption of multiple adsorbates in a fixed bed, AIChE Journal, vol.34, issue.11, pp.1861-1876, 1988.
DOI : 10.1002/aic.690341112

C. C. Huang and J. R. Et-fair, Parametric analysis of thermal swing cycles for multicomponent adsorption, AIChE Journal, vol.35, issue.10, pp.1667-1677, 1989.
DOI : 10.1002/aic.690351011

K. S. Hwang, J. H. Jun, and W. K. Et-lee, Fixed-bed adsorption for bulk component system. Non-equilibrium, non-isothermal and non-adiabatic model, Chemical Engineering Science, vol.50, issue.5, pp.813-825, 1995.
DOI : 10.1016/0009-2509(94)00433-R

D. Ko, M. Kim, I. Moon, and D. Et-choi, -Xylene Purification, Industrial & Engineering Chemistry Research, vol.40, issue.22, pp.40-4973, 2001.
DOI : 10.1021/ie000515z

URL : https://hal.archives-ouvertes.fr/in2p3-00025600

D. Ko, M. Kim, I. Moon, and D. Et-choi, Analysis of purge gas temperature in cyclic TSA process, Chemical Engineering Science, vol.57, issue.1, pp.179-195, 2002.
DOI : 10.1016/S0009-2509(01)00358-X

R. Kumar and G. R. Et-dissinger, Nonequilibrium, nonisothermal desorption of single adsorbate by purge, Industrial & Engineering Chemistry Process Design and Development, vol.25, issue.2, pp.456-464, 1986.
DOI : 10.1021/i200033a018

F. W. Leavitt, Non-isothermal adsorption in large fixed bed, Chem. Eng. Prog, vol.58, issue.8, pp.54-59, 1962.

L. Cloirec and P. , Les composés organiques volatiles dans l'environnement, 1998.

M. D. Levan and T. A. Et-schweiger, Steam regeneration of adsorption beds: theory and experiments, Proc. 3 rd Conference on Fundamentals of Adsorption (FOA3), Engineering Fundation, pp.487-496, 1989.

A. Mativet, Étude expérimentale d'un procédé de chauffage et de refroidissement par changement de phase du fluide caloporteur, Thèse de Doctorat, 1997.

A. Mativet, F. Meunier, J. B. Chalfen, and C. Marvillet, Experimental study of heat transfer during film condensation in transient conditions in a vertical smooth tube, Exp. Heat Transfer, vol.12, issue.3, pp.247-263, 1999.

A. Mersmann, B. Fill, R. Hartmann, and S. Et-maurer, The Potential of Energy Saving by Gas-Phase Adsorption Processes, Chemical Engineering & Technology, vol.24, issue.11, pp.937-944, 2000.
DOI : 10.1002/1521-4125(200011)23:11<937::AID-CEAT937>3.0.CO;2-P

A. L. Myers and J. M. Et-prausnitz, Thermodynamics of mixed-gas adsorption, AIChE Journal, vol.11, issue.1, pp.121-127, 1965.
DOI : 10.1002/aic.690110125

J. A. Brien and A. L. Et-myers, Physical adsorption of gases on heterogeneous surfaces, J. Chem. Soc., Faraday Trans. 1, pp.80-1467, 1984.

J. A. Brien and A. L. Et-myers, Rapid calculations of multicomponent adsorption equilibria from pure isotherm data, Industrial & Engineering Chemistry Process Design and Development, vol.24, issue.4, pp.1188-1191, 1985.
DOI : 10.1021/i200031a049

J. A. Brien and A. L. Et-myers, A comprehensive technique for equilibrium calculations in adsorbed mixtures: the generalized FastIAS method, Industrial & Engineering Chemistry Research, vol.27, issue.11, pp.2085-2092, 1988.
DOI : 10.1021/ie00083a021

C. Y. Pan and D. Et-basmadjian, Constant-pattern adiabatic fixed-bed adsorption, Chemical Engineering Science, vol.22, issue.3, 1967.
DOI : 10.1016/0009-2509(67)80115-5

C. Y. Pan and D. Et-basmadjian, An analysis of adiabatic sorption of single solutes in fixed beds: pure thermal wave formation and its practical implications, Chemical Engineering Science, vol.25, issue.11, pp.1653-1664, 1970.
DOI : 10.1016/0009-2509(70)80056-2

C. Y. Pan and D. Et-basmadjian, An analysis of adiabatic sorption of single solutes in fixed beds: equilibrium theory, Chemical Engineering Science, vol.26, issue.1, pp.45-57, 1971.
DOI : 10.1016/0009-2509(71)86080-3

S. V. Patankar, Numerical heat transfer and fluid flow, Series in computational methods in mechanics and thermal sciences, 1980.

R. H. Perry, Perry's chemical engineer's handbook 7th ed, Chemical Engineering Series, 1997.

M. Ratto, G. Lodi, and P. Et-costa, Sensitivity analysis of a fixed-bed gas-solid TSA: the problem of design with uncertain models, Separations Technology, vol.6, issue.4, pp.235-245, 1996.
DOI : 10.1016/S0956-9618(96)00162-2

H. K. Rhee and N. R. Et-amundson, An analysis of an adiabatic adsorption column: Part II. Adiabatic adsorption of a single solute, The Chemical Engineering Journal, vol.1, issue.4, pp.279-290, 1970.
DOI : 10.1016/0300-9467(70)85015-8

H. K. Rhee, E. D. Heerdt, and N. R. Et-amundson, An analysis of an adiabatic adsorption column: Part 1. Theoretical development, The Chemical Engineering Journal, vol.1, issue.3, pp.241-254, 1970.
DOI : 10.1016/0300-9467(70)80007-7

E. Richter, W. Schütz, and A. L. Et-myers, Effect of adsorption equation on prediction of multicomponent adsorption equilibria by the ideal adsorbed solution theory, Chemical Engineering Science, vol.44, issue.8, pp.1609-1616, 1989.
DOI : 10.1016/0009-2509(89)80003-X

D. M. Ruthven, Principles of adsorption and adsorption processes, 1984.

A. Salden, T. Boger, and G. Eigenberger, Combined vacuum and temperature swing adsorption process for the removal and recovery of organic components from waste-air systems, Proc. 6 th Conf. Fundamentals of Adsorption (FOA6), pp.915-920, 1998.

S. Saysset, Procédé d'adsorption sur adsorbant carboné avec régénération thermique par effet joule direct, Thèse de Doctorat, 1999.

J. M. Schork and J. R. Et-fair, Parametric analysis of thermal regeneration of adsorption beds, Industrial & Engineering Chemistry Research, vol.27, issue.3, pp.457-469, 1988.
DOI : 10.1021/ie00075a016

S. Sircar, R. Kumar, and K. J. Et-anselmo, Effects of column nonisothermality or nonadiabaticity on the adsorption breakthrough curves, Industrial & Engineering Chemistry Process Design and Development, vol.22, issue.1, pp.10-15, 1983.
DOI : 10.1021/i200020a002

S. Sircar and R. Et-kumar, Adiabatic adsorption of bulk binary gas mixtures. Analysis by constant pattern model, Industrial & Engineering Chemistry Process Design and Development, vol.22, issue.2, pp.271-280, 1983.
DOI : 10.1021/i200021a017

S. Sircar and R. Et-kumar, Equilibrium theory for adiabatic desorption of bulk binary gas mixtures by purge, Industrial & Engineering Chemistry Process Design and Development, vol.24, issue.2, pp.358-364, 1985.
DOI : 10.1021/i200029a023

S. Sircar and A. L. Et-myers, Gas adsorption operations: equilibrium, kinetics, column dynamic and design, Adsorpt. Sci. Technol, vol.2, pp.69-87, 1985.

L. M. Sun and F. Meunier, Adsorption, aspects théoriques, Techniques de l'ingénieur, JP, vol.16, 2003.

R. T. Yang, Gas separation by adsorption processes, Series on Chemical Engineering, vol.1, issue.352, 1997.

J. H. Yun, D. K. Choi, and H. Et-moon, Benzene adsorption and hot purge regeneration in activated carbon beds, Chemical Engineering Science, vol.55, issue.23, pp.5857-5872, 2000.
DOI : 10.1016/S0009-2509(00)00189-5