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A. S. Rosenberg-p and . A. Et-kittrick-j, Illite equilibria in solution: I. Phase relationship in the system K 2 O-Al 2 O 3 -SiO 2 -H 2 O between 25°C and 250°C, Geochim. Cosmochim. Acta, pp.55-1353, 1991.

A. S. Rosenberg-p and . A. Et-kittrick-j, Illite equilibria in solution: II. Phase relationship in the system K 2 O-MgO-Al 2 O 3 -SiO 2 -H 2 O between 25°C and 250°C, Geochim. Cosmochim. Acta, pp.55-1365, 1991.

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A. G. Et and . Burnham-c, Feldspar solubility and the transport of aluminium under metamorphic conditions, Am. J. Sci, pp.283-283, 1983.

A. L. , P. H. , and G. A. Et-fouillac-c, Water-rock interaction processes in the Triassic sandstone and the granitic basement of the Rhine Graben: geochemical investigation of a geothermal reservoir, Geoch. Cosmoch. Acta, pp.61-4281, 1997.

B. A. Vidal-o and . Et-fritz-b, Etude expérimentale des transformations de phases dans un gradient thermique : application au granite de Soultz-sous-Forêts, France, C. R. Acad. Sci, pp.371-380, 2003.

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G. O. Petit-s, D. A. Et, and . Baronnet-a, The beidellite-saponite solidsolution : an experimental approach, Eur. J. Mineral, vol.5, pp.623-635, 1993.

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H. C. Et-weare-j, The prediction of mineral solubilities in natural waters: the Na-K-Mg-Ca-Cl-SO 4 -H 2 O system from zero to high concentration at 25°C, Geoch. Cosmoch. Acta, pp.44-981, 1980.

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H. S. Et and M. J. , The carbonic acid system and calcite solubility in aqueous Na-K- Ca-Mg-Cl-SO 4 solutions from 0 to 90°C, Geoch. Cosmoch. Acta, vol.57, pp.3533-3554, 1993.

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H. J. Eslinger-e and H. M. Et-perry-e, The mechanism of burial diagenetic reactions in argillaceous sediments, 1. Mineralogical and chemical evidence, 1976.

H. W. and L. J. Et-pevear-d, An experimentally derived kinetic model for smectite-to-illite conversion and its use as a geothermometer, Clays Clay Miner, vol.41, pp.162-177, 1993.

I. A. Et-utada-m, Further investigations of a conversion serie of dioctahedral mica/smectite in the Shinzan hydrothermal alteration area, northern Japan, Clays Clay. Miner, pp.31-401, 1983.

J. W. and P. D. Et-essene-e, Transmission electron microscopic study of coexisting pyrophyllite and muscovite: direct evidence for the metastability of illite, Clays Clay Miner, vol.42, pp.593-605, 1990.

J. M. Et-pozo-c, Évolution de l'argile FoCa compactée et resaturée dans un gradient thermique, Expérience in situ de Stripa. Note technique CEA/SESD, pp.97-62, 1997.

J. M. Pozo-c and P. C. Et-tessier-d, Texture influence on mass transfers and alteration processes in clayey engineered barrier under thermal gradient, European Union of Geosciences proceedings, vol.1, p.423, 1997.

K. A. Et and Y. B. , Fluid-rock interaction in the Rhine Graben: a thermodynamic model of the hydrothermal alteration observed in deep drilling, Geoch. Cosmoch. Acta, pp.61-515, 1997.

L. B. Et and . Velde-b, Decomposition of X-ray diffraction patterns : a convenient way to describe complex diagenetic smectite-to-illite evolution, Clays Clay. Miner, vol.40, pp.629-643, 1992.

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L. B. Dubois-j, G. A. Et, and . Meunier-a, Fractal analysis of fracture applied to Soultz-sous-Forêts Hot Dry Rock geothermal program, J. Volcanol. Geoth. Res, vol.57, pp.1-17, 1993.

L. B. , J. J. , A. A. Sardini, P. , G. A. Et et al., Organic matter in the Soultz HDR granite thermal exchanger (France) : natural tracers of fluid, J. Phys. Chem, vol.77, pp.268-277, 1996.

M. B. and C. A. Et-fritz-b, Modelling mineral-solutions interactions: the thermodynamic and kinetic code KINDISP, Comput. Geosci, vol.20, pp.1347-1363, 1994.

M. B. and C. A. Et-fritz-b, Modélisation thermodynamique et cinétique des réactions diagénétiques dans les bassins sédimentaires : présentation du modèle géochimique, KINDISP. Rev. Inst. Fr. du Pétrole, vol.49, pp.569-602, 1994.

M. A. Et and . Velde-b, Solid solution in I/S mixed-layer minerals and illite, Am. Miner, vol.74, pp.1106-1112, 1989.

N. P. , T. J. Mchardy-w, . Et, and . J. Wilson-m, Interstratified XRD characteristics of physical mixtures of elementary clay particules, Clay Miner, vol.19, pp.67-76, 1984.

O. E. Et-helgeson-h, Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: aqueous tracer diffusion coefficient of ions to 1000°C and 5 kb, Geochim. Cosmochim. Acta, vol.1, pp.63-85, 1988.

P. D. Et-wesolowski-d, Aluminium speciation and equilibria in aqueous solutions : II. The solubility of gibbsite in acidic sodium chloride solutions from 30 to 70°C, Geoch. Cosmoch. Acta, pp.56-1093, 1992.

P. T. Vidal-o, . Et, and . Ph, A thermodynamic model for Fe-Mg dioctahedral K white micas using data from phase-equilibrium experiments and natural pelitic assemblages, Contrib. Mineral. Petr, vol.143, issue.6, pp.706-732, 2002.

P. H. and F. C. Et-criaud-a, Water-rock interactions during experiments within geothermal Hot Dry Rock borehole GPK-1, Soultz-sous-Forêts, Appl. Geochem, vol.7, pp.243-255, 1992.

P. H. and F. C. Et-fouillac-a, Chemistry and isotopes of deep geothermal saline fluids in the upper Rhine Graben: origin of compounds and water-rock interactions, Geoch. Cosmoch. Acta, vol.57, pp.2737-2749, 1993.

P. M. Et and . S. Small-j, Illite-smectite diagenesis and paleotemperatures in northern North Sea quaternary to mesozoic shale sequences, Clay Miner, vol.23, pp.109-132, 1988.

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P. K. Et and K. J. , Thermodynamics of electrolytes IV: Activity and osmotic coefficients for mixed electrolytes, J. Am. Chem. Soc, vol.96, pp.5701-5707, 1974.

P. K. Et-mayorga-g, Thermodynamics of electrolytes II: Activity and osmotic coefficients for strong electrolytes with one or both ions univalent, J. Phys. Chem, vol.77, pp.2300-2308, 1973.

P. K. Et-mayorga-g, Thermodynamics of electrolytes III: Activity and osmotic coefficients for 2-2 electrolytes, J. Solution. Chem, vol.3, pp.539-546, 1974.

P. K. and P. J. Et-busey-r, Thermodynamics properties of aqueous sodium chloride solutions at 25°C, J. Phys. Chem. Ref. Data, vol.13, pp.1-102, 1984.

P. C. Goffe-b, . Magonthier-m-c, and . Et-toulhoat-p, Hydrothermal alteration of a simulated nuclear waste glass: effects of a thermal gradient and of a chemical barrier, Eur. J. Mineral, vol.8, pp.533-548, 1996.

P. and F. W. Et-hägedorn-f, Heat Production and Temperature to 5 km Dpht at the HDR Site in Soultz-sous-Forêts, 1999.

P. K. Et-mcdowell-s, Illite/smectite geothermometry of the proterozoic Oronto group, midcontinent rift system, Clays Clay Miner, vol.41, pp.134-147, 1993.

P. R. Et-pitzer-k, Thermodynamics of aqueous magnesium chloride, calcium chloride and strontium chloride at elevated temperatures, J. Chem. Eng. Data, vol.32, pp.76-80, 1987.

P. A. Et-reynolds-jr-r, The thermal transformation of smectite to illite In: Thermal history of sedimentary basins, éds Naeser N.D. et McColloh T.H, pp.133-140, 1989.

R. B. Et-helgeson-h, Compositional end members ans thermodynamic components of illite and dioctahedral aluminous smectite solid solutions, Clays Clay Miner, vol.41, pp.537-550, 1993.

R. B. Et-helgeson-h, A chemical and thermodynamic model of aluminous dioctahedral 2:1 layer clay minerals in diagenetic processes: regular solution representation of interlayer dehydration in smectite, Am. J. Sci, vol.294, pp.449-484, 1994.

R. B. Et-helgeson-h, A chemical and thermodynamic model of dioctahedral 2:1 layer clay minerals in diagenetic processes; dehydration of dioctahedral aluminous smectite as a function of temperature and depth in sedimentary basins, Am. J. Sci, vol.295, pp.245-281, 1995.

R. S. Eggleton-r and . L. Et-walshe-j, The formation of hydrothermal cookeite in the breccia pipes of the Ardlethan tin field, Can. Mineral, vol.26, 1988.

R. J. Et and C. D. , Geothermal mineralization I: the mechanisms of formation of the Beowawe Nevada siliceous sinter deposits, Am. J. Sci, vol.283, pp.861-875, 1983.

R. C. Et-goffé-b, Zeolitisation of basalts in subaqueous freshwater settings : field observations and experimental study, Geochim. Cosmochim. Acta, vol.57, pp.3597-3612, 1993.

R. R. Et-kittrick-j, Illite solubility, Proc. Soil. Sci. Soc. Amer, vol.35, pp.714-718, 1971.

S. P. and L. B. Et-touchard-g, Quantification of microscopic porous network by image analysis and measurements of permeability in the Soultz-sous-Forêts granite (Alsace, France) In Fluid Flow and Transport in Rocks: Mechanisms and Effects, 1997.

S. M. Rosenberg-p and . A. Et-kittrick-j, The stability of illite/smectite during diagenesis: an experimental study, Geochim. Cosmochim. Acta, pp.51-2103, 1987.

S. T. Watanabe-t, . Et, and . Otsuka, Effects of layer charge location and energy change on expansion properties of dioctahedral smectites, Clays Clay. Miner, vol.40, pp.103-113, 1992.

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S. F. Et-géraud-y, Porosity and thermal conductivity of the Soultz-sous-Forêts Granite, Pure Appl. Geophys, vol.160, pp.1125-1136, 2003.

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T. Y. Et-fritz-b, An ideal solid solution model for calculating solubility of clay moinerals, Clay Miner, vol.16, pp.361-376, 1981.

T. E. Et-seyfried-w, Thermodiffusional transport in pelagic clays : implications for nuclear waste disposal in geological media, Science, vol.20, pp.1156-1158, 1983.

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V. Olphen and H. , Dispersion and floculation. Dans: Chemistry of clays and clay minerals, pp.203-224, 1987.

V. B. Et and . Vasseur-g, Estimation of the diagenetic smectite to illite transformation in time-temperature space, Am. Mineral, vol.77, pp.967-976, 1992.

V. O. Et-durin-l, Aluminium mass transfert and diffusion in water at 400 -550°C, 2 kbar in the K 2 O-Al 2 O 3 -SiO 2 -H 2 O system driven by a thermal gradient or by a variation of temperature with time, Mineral. Mag, pp.63-633, 1999.

V. O. Et-parra-t, Exhumation paths of high pressure metapelites obtained from local equilibria for chlorite-phengite assemblages, Geological Journal, vol.35, pp.139-161, 2000.

V. O. Parra-t and . Et-trotet-f, A thermodynamic model for Fe-Mg aluminous chlorites using data from phase equilibrium experiments and natural pelitic assemblages in the 100 degrees to 600 degrees C, 1 to 25 kb range, Am. J. Sci, vol.6, pp.557-592, 2001.

V. T. Et and B. F. , L'évolution du Fossé Rhénan au cours du Cénozoïque : un bilan de la déformation et des effets thermiques de l'extension, B. Soc. Geol. Fr, vol.8, issue.2, pp.245-255, 1987.

W. C. Et-pollard-l, The chemistry of clays minerals. Developments in sedimentology, 1975.

.. Le-mouvement-convectif-du-fluide, 44 7.2 -La diffusion de, .45 7.4 -Importance relative des modes de transport des éléments dans les expériences sous gradient thermique, p.46

R. Dans, L. Systeme-si-al-mg-h-2, and O. , 49 1 -Les expériences menées dans le système Si-Al-Mg, CHAPITRE, vol.5, issue.2, p.50

M. 1-etude-morphologique-au, 53 2.2 -Chimie semi-quantitative56 2.3 -Cristallographie par diffraction aux rayons X, .58 2.4 -Cristallographie par diffraction des RX et par diffraction électronique, p.62

M. 1-etude-morphologique-au, 96 2.2 -Chimie semi-quantitative, p.101

F. Résultats-expérience, 105 3.2 -Chimie semi-quantitative, p.112

F. Résultats-expérience, 124 6.2 -Chimie semi-quantitative, p.128

R. Dans, L. , and O. , 137 1 -Les expériences menées dans le système Si-Al-Mg, CHAPITRE, vol.7, issue.2, p.138

F. Meb and M. , 140 2.2 -Chimie semi-quantitative, p.144

L. Stabilite and T. , 153 1 -Utilisation des résultats expérimentaux pour développer un modèle de solution solide pour les smectites156 1.1 -Choix du type de solution solide et pôles utilisés, 156 1.2 -Propriétés thermodynamiques des pôles choisis, p.159

.. Interprétation-des-expériences-en-système-magnésien and .. De-la-température, 162 2.1 -Evolution de l'état d'hydratation des pôles en fonction, 2.2 -Interprétation des expériences 1 et 2 (gels de départ = Chl + Qtz) ...164 2.3 -Expériences 3 et 4 (composition de départ = Chl + Kln) ...................167 2.4 -Influence de la composition du fluide: diagrammes 162

.. Les-cristallisations-secondaires-observées, 207 2.1 -Etat des capsules après expérience, ., p.211