L. Lithographié-electronique-dans-une-résine-organique:-le and P. , 48 2.2.2.1 Dégradation du PMMA sous faisceau d'´ electrons, p.50

.. Réalisation-des-motifs-de-connexion, 57 2.3.1.1 Description des structures réalisées, p.58

L. Préparation-de, 95 3.3.3.1 Traitement de la surface par greffage de silane amine, p.98

.. Interprétation-de-la-localisation-du-dépôt, 110 3.5.1 Nature des interactions, p.113

L. Immobilisation-de, 147 4.3.2.1 Adsorption des anticorps sur la surface des dispositifs, p.148

D. Sélectivité-du, 154 4.4.2.1 Sélectivité visàvisà vis des matériaux, p.155

M. Pathogènes, Organismes microscopiques généralement unicellulaires , qui peuvent causer des maladies lorsqu'elles infectent un hôte. Paratope : Partie de l'anticorps qui se liè a l'´ epitope

. Protéine, Les protéines sont les produits de l'expression des g` enes. Elles constituent les agents d'exécution de la cellule. Ce sont des polymères d'acides aminés, donc des macromolécules. Réponse immune adaptative ou immunité adaptative

. E. Fig, 7 ? Exemples de structures correspondantsàcorrespondantsà des réseaux d'´ electrodes interdigitées au pas de 200nm et de 60nm de large répliquées dans un matériau polymère de type epoxy-siloxane [177]. Dans ces expériences, les moules ontétéontété réalisés par lithographiélithographié electronique et gravure RIE du substrat

E. M. Southern, U. Maskos, and J. K. Elder, Analyzing and comparing nucleic acid sequences by hybridization to arrays of oligonucleotides: Evaluation using experimental models, Genomics, vol.13, issue.4, p.1008, 1992.
DOI : 10.1016/0888-7543(92)90014-J

H. Zhu and M. Snyder, Protein chip technology, Current Opinion in Chemical Biology, vol.7, issue.1, pp.55-63, 2003.
DOI : 10.1016/S1367-5931(02)00005-4

P. Luppa, L. Sikoll, and D. Chan, Immunosensors???principles and applications to clinical chemistry, Clinica Chimica Acta, vol.314, issue.1-2, pp.1-26, 2001.
DOI : 10.1016/S0009-8981(01)00629-5

J. Homola, S. S. Yee, and G. Gauglitz, Surface plasmon resonance sensors: review, Sensors and Actuators B: Chemical, vol.54, issue.1-2, pp.3-15, 1999.
DOI : 10.1016/S0925-4005(98)00321-9

L. S. Jung, C. T. Campbell, T. M. Chinowsky, M. N. Mar, and S. S. Yee, Quantitative Interpretation of the Response of Surface Plasmon Resonance Sensors to Adsorbed Films, Langmuir, vol.14, issue.19, pp.5636-5648, 1998.
DOI : 10.1021/la971228b

W. Knoll, M. Zizlseperger, T. Liebermann, S. Arnold, A. Badia et al., Streptavidin arrays as supramolecular architectures in surface-plasmon optical sensor formats, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.161, issue.1, pp.115-137, 2000.
DOI : 10.1016/S0927-7757(99)00331-3

U. Kunz, A. Katerkamp, R. Renneberg, F. Spener, and K. Cammann, Sensing fatty acid binding protein with planar and fiber-optical surface plasmon resonance spectroscopy devices, Sensors and Actuators B: Chemical, vol.32, issue.2, pp.149-155, 1996.
DOI : 10.1016/0925-4005(96)80124-9

R. L. Edelstein, C. R. Tamanaha, P. E. Sheehan, M. M. Miller, D. R. Baselt et al., The BARC biosensor applied to the detection of biological warfare agents, Biosensors and Bioelectronics, vol.14, issue.10-11, pp.805-813, 2000.
DOI : 10.1016/S0956-5663(99)00054-8

M. M. Miller, P. E. Sheehan, R. L. Edelstein, C. R. Tamanaha, L. Zhong et al., A DNA array sensor utilizing magnetic microbeads and magnetoelectronic detection, Journal of Magnetism and Magnetic Materials, vol.225, issue.1-2, pp.138-144, 2001.
DOI : 10.1016/S0304-8853(00)01242-7
URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.462.8896

D. L. Graham, H. A. Ferreira, P. P. Freitas, and J. M. Cabral, High sensitivity detection of molecular recognition using magnetically labelled biomolecules and magnetoresistive sensors, Biosensors and Bioelectronics, vol.18, issue.4, pp.483-488, 2003.
DOI : 10.1016/S0956-5663(02)00205-1

A. A. Suleiman and G. G. Guibault, Recent developments in piezoelectric immunosensors. A review, The Analyst, vol.119, issue.11, p.2279, 1994.
DOI : 10.1039/an9941902279

G. Bidan, M. Billon, K. Galasso, T. Livache, G. Mathis et al., Electropolymerization as a Versatile Route for Immobilizing Biological Species onto Surfaces, Applied Biochemistry and Biotechnology, vol.89, issue.2-3, p.183, 2000.
DOI : 10.1385/ABAB:89:2-3:183

N. Barié and M. Rapp, Covalent bound sensing layers on surface acoustic wave (SAW) biosensors, Biosensors and Bioelectronics, vol.16, issue.9-12, p.979, 2001.
DOI : 10.1016/S0956-5663(01)00198-1

J. Fritz, M. K. Baller, H. P. Lang, H. Rothuizen, P. Vettiger et al., Translating Biomolecular Recognition into Nanomechanics, Science, vol.288, issue.5464, pp.316-318, 2000.
DOI : 10.1126/science.288.5464.316

S. G. Nilsson, E. Sarwe, and L. Montelius, Fabrication and mechanical characterization of ultrashort nanocantilevers, Applied Physics Letters, vol.83, issue.5, pp.990-992, 2003.
DOI : 10.1063/1.1592303

D. R. Thévenot, K. Toth, R. A. Durst, and G. S. Wilson, Electrochemical biosensors: recommended definitions and classification1International Union of Pure and Applied Chemistry: Physical Chemistry Division, Commission I.7 (Biophysical Chemistry); Analytical Chemistry Division, Commission V.5 (Electroanalytical Chemistry).1, Biosensors and Bioelectronics, vol.16, issue.1-2, pp.121-131, 2001.
DOI : 10.1016/S0956-5663(01)00115-4

P. Bergveld, Thirty years of ISFETOLOGY, Sensors and Actuators B: Chemical, vol.88, issue.1, pp.1-20, 2003.
DOI : 10.1016/S0925-4005(02)00301-5

P. Pandey, S. Upadhyay, and B. Upadhyay, Peroxide Biosensors and Mediated Electrochemical Regeneration of Redox Enzymes, Analytical Biochemistry, vol.252, issue.1, pp.136-142, 1997.
DOI : 10.1006/abio.1997.2291

K. Yagiuda, A. Hemmi, and S. Ito, Development of a conductivity-based immunosensor for sensitive detection of methamphetamine (stimulant drug) in human urine, Biosensors and Bioelectronics, vol.11, issue.8, pp.703-710, 1996.
DOI : 10.1016/0956-5663(96)85920-3

M. Lambert, Etude des propriétéspropriétésélectroniques de molécules organiques au sein d'un jonction métal-molécule-métal, 2003.

T. Heim, TransportélectroniqueTransportélectronique dans l'ADN, sciences et techniques de Lilles, 2002.

C. Vieu, F. Carcenac, A. Pépin, Y. Chen, M. Mejias et al., Electron beam lithography: resolution limits and applications, Applied Surface Science, vol.164, issue.1-4, pp.111-117, 2000.
DOI : 10.1016/S0169-4332(00)00352-4

F. Carcenac, C. Vieu, A. Lebib, Y. Chen, L. Manin-ferlazzo et al., Fabrication of high density nanostructures gratings (>500Gbit/in2) used as molds for nanoimprint lithography, Microelectronic Engineering, vol.53, issue.1-4, pp.163-166, 2000.
DOI : 10.1016/S0167-9317(00)00287-2

I. Amlani, A. Rawlett, L. , and R. Tsui, Hybrid assembly technique using alternating current field for molecular electronic measurements, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.20, issue.6, pp.2802-2805, 2002.
DOI : 10.1116/1.1523025

I. Amlani, A. Rawlett, L. Nagahara, and R. Tsui, An approach to transport measurements of electronic molecules, Applied Physics Letters, vol.80, issue.15, pp.2761-2763, 2002.
DOI : 10.1063/1.1469655

G. Schmid and Y. P. Liu, Clusters and Their Electrical Properties at Room Temperature, Nano Letters, vol.1, issue.8, pp.405-407, 2001.
DOI : 10.1021/nl0100419

C. S. Wu, C. D. Chen, S. M. Shih, and W. F. Su, Single-electron transistors and memory cells with Au colloidal islands, Applied Physics Letters, vol.81, issue.24, pp.4595-4597, 2002.
DOI : 10.1063/1.1527236

A. Bezryadin, C. Dekker, and G. Schmid, Electrostatic trapping of single conducting nanoparticles between nanoelectrodes, Applied Physics Letters, vol.71, issue.9, pp.1273-1275, 1997.
DOI : 10.1063/1.119871

C. Zhou, C. Muller, M. Deshpande, J. Sleight, and M. Reed, Microfabrication of a mechanically controllable break junction in silicon, Applied Physics Letters, vol.67, issue.8, pp.1160-1162, 1995.
DOI : 10.1063/1.114994

C. Kergueris, J. P. Bourgoin, S. Palacin, D. Esteve, C. Urbina et al., Electron transport through a metal-molecule-metal junction, Physical Review B, vol.59, issue.19, pp.12505-12513, 1999.
DOI : 10.1103/PhysRevB.59.12505
URL : https://hal.archives-ouvertes.fr/cea-01057034

H. Park, A. K. Lim, A. P. Alivisatos, J. Park, and P. L. Mceuen, Fabrication of metallic electrodes with nanometer separation by electromigration, Applied Physics Letters, vol.75, issue.2, pp.301-303, 1999.
DOI : 10.1063/1.124354

M. Austin and S. Y. Chou, Fabrication of nanocontacts for molecular devices using nanoimprint lithography, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.20, issue.2, pp.665-667, 2002.
DOI : 10.1116/1.1463068

S. Khondaker and Z. Yao, Fabrication of nanometer-spaced electrodes using gold nanoparticles, Applied Physics Letters, vol.81, issue.24, pp.4613-4615, 2002.
DOI : 10.1063/1.1528285

D. D. Eley and D. I. Spivey, Semiconductivity of organic substances. Part 9.???Nucleic acid in the dry state, Trans. Faraday Soc., vol.58, issue.0, p.411, 1962.
DOI : 10.1039/TF9625800411

K. Yoo, D. H. Ha, J. Lee, J. W. Park, J. Kim et al., Electrical Conduction through Poly(dA)-Poly(dT) and Poly(dG)-Poly(dC) DNA Molecules, Physical Review Letters, vol.87, issue.19, p.198102, 2001.
DOI : 10.1103/PhysRevLett.87.198102
URL : http://hdl.handle.net/2003/1571

H. Lee, H. Tanaka, Y. Otsuka, K. Yoo, J. Lee et al., Control of electrical conduction in DNA using oxygen hole doping, Applied Physics Letters, vol.80, issue.9, pp.1670-1672, 2002.
DOI : 10.1063/1.1456972

P. J. Depablo, F. Moreno-herrero, J. Colchero, J. Gomez-herrero, P. Herrero et al., -DNA, Physical Review Letters, vol.85, issue.23, pp.4992-4995, 2000.
DOI : 10.1103/PhysRevLett.85.4992

A. J. Storm, J. Van-noort, S. De-vries, and C. Dekker, Insulating behavior for DNA molecules between nanoelectrodes at the 100 nm length scale, Applied Physics Letters, vol.79, issue.23, pp.3881-3883, 2001.
DOI : 10.1063/1.1421086

D. Ha, H. Nham, K. Yoo, H. So, T. Lee et al., Humidity effects on the conductance of the assembly of DNA molecules, Chemical Physics Letters, vol.355, issue.5-6, pp.405-409, 2002.
DOI : 10.1016/S0009-2614(02)00142-2

Y. Otsuka, H. Y. Lee, J. Gu, J. Lee, K. Yoo et al., Influence of Humidity on the Electrical Conductivity of Synthesized DNA Film on Nanogap Electrode, Japanese Journal of Applied Physics, vol.41, issue.Part 1, No. 2A, pp.891-894, 2002.
DOI : 10.1143/JJAP.41.891

Y. Cui, Q. Wei, H. Park, and C. M. Lieber, Nanowire Nanosensors for Highly Sensitive and Selective Detection of Biological and Chemical Species, Science, vol.293, issue.5533, pp.1289-1292, 2001.
DOI : 10.1126/science.1062711

J. Kong, N. R. Franklin, C. Zhou, M. G. Chapline, S. Peng et al., Nanotube Molecular Wires as Chemical Sensors, Science, vol.287, issue.5453, pp.622-625, 2000.
DOI : 10.1126/science.287.5453.622

R. J. Chen, Y. Zhang, D. Wang, and H. J. Dai, Noncovalent Sidewall Functionalization of Single-Walled Carbon Nanotubes for Protein Immobilization, Journal of the American Chemical Society, vol.123, issue.16, p.3838, 2001.
DOI : 10.1021/ja010172b

A. Star, J. Gabriel, K. Bradley, and G. Grüner, Electronic Detection of Specific Protein Binding Using Nanotube FET Devices, Nano Letters, vol.3, issue.4, pp.459-463, 2003.
DOI : 10.1021/nl0340172

O. A. Saleh and L. L. Sohn, An Artificial Nanopore for Molecular Sensing, Nano Letters, vol.3, issue.1, pp.37-38, 2003.
DOI : 10.1021/nl0255202

C. Yee, M. Scotti, A. Ulman, H. White, M. Rafailovich et al., One-Phase Synthesis of Thiol-Functionalized Platinum Nanoparticles, Langmuir, vol.15, issue.13, pp.4314-4316, 1999.
DOI : 10.1021/la9814283

M. J. Hosteler, J. E. Wingate, C. Zhong, J. E. Harris, R. W. Zashet et al., Alkanethiolate Gold Cluster Molecules with Core Diameters from 1.5 to 5.2 nm:?? Core and Monolayer Properties as a Function of Core Size, Langmuir, vol.14, issue.1, pp.17-30, 1998.
DOI : 10.1021/la970588w

P. Buining, B. Humbel, A. Philipse, and A. Verkleij, Preparation of Functional Silane-Stabilized Gold Colloids in the (Sub)nanometer Size Range, Langmuir, vol.13, issue.15, pp.3921-3926, 1997.
DOI : 10.1021/la962071a

K. Esumi, A. Suzuki, N. Aihara, K. Usui, and K. Torigoe, Preparation of Gold Colloids with UV Irradiation Using Dendrimers as Stabilizer, Langmuir, vol.14, issue.12, pp.3157-3159, 1998.
DOI : 10.1021/la980162x

M. Garcia, L. Baker, and R. Crooks, Preparation and Characterization of Dendrimer???Gold Colloid Nanocomposites, Analytical Chemistry, vol.71, issue.1, pp.256-258, 1999.
DOI : 10.1021/ac980588g

T. Teranishi, I. Kyosaka, and M. Miyake, Synthesis of Monodisperse Gold Nanoparticles Using Linear Polymers as Protective Agents, Advanced Materials, vol.10, issue.8, pp.596-599, 1998.
DOI : 10.1002/(SICI)1521-4095(199805)10:8<596::AID-ADMA596>3.0.CO;2-Y

C. M. Niemeyer, Nanoparticles, Proteins, and Nucleic Acids: Biotechnology Meets Materials Science, Angewandte Chemie International Edition, vol.2, issue.22, pp.4128-4158, 2001.
DOI : 10.1002/1521-3773(20011119)40:22<4128::AID-ANIE4128>3.0.CO;2-S

W. Fritzche and T. A. Taton, Metal nanoparticles as labels for heterogeneous, chip-based DNA detection, Nanotechnology, vol.14, issue.12, pp.63-73, 2003.
DOI : 10.1088/0957-4484/14/12/R01

L. A. Lyon, M. D. Musick, and M. J. Natan, Colloidal Au-Enhanced Surface Plasmon Resonance Immunosensing, Analytical Chemistry, vol.70, issue.24, pp.5177-5183, 1998.
DOI : 10.1021/ac9809940

L. He, M. D. Muick, S. R. Nicewarner, F. G. Salinas, S. J. Benkovix et al., Colloidal Au-Enhanced Surface Plasmon Resonance for Ultrasensitive Detection of DNA Hybridization, Journal of the American Chemical Society, vol.122, issue.38, pp.9071-9077, 2000.
DOI : 10.1021/ja001215b

W. C. Chan and S. M. Nie, Quantum Dot Bioconjugates for Ultrasensitive Nonisotopic Detection, Science, vol.281, issue.5385, pp.2016-2018, 1998.
DOI : 10.1126/science.281.5385.2016

J. C. Riboh, A. J. Haes-anda, C. Mcfarland, R. P. Ranjit-yonzon, and . Van-duyne, A Nanoscale Optical Biosensor:?? Real-Time Immunoassay in Physiological Buffer Enabled by Improved Nanoparticle Adhesion, The Journal of Physical Chemistry B, vol.107, issue.8, pp.1772-1780, 2003.
DOI : 10.1021/jp022130v

O. D. Vlev and E. W. Kaler, In Situ Assembly of Colloidal Particles into Miniaturized Biosensors, Langmuir, vol.15, issue.11, pp.3693-3698, 1999.
DOI : 10.1021/la981729c

V. Haguet, DétectionDétectionélectronique d'une interaction biomoléculaire entre desélecdesélectrodes nanostructurées, Sciences et Techniques de Lille 1, 2002.

A. N. Broers, W. W. Molzen, J. J. Cuomo, and N. D. , Electron???beam fabrication of 80????? metal structures, Applied Physics Letters, vol.29, issue.9, p.596, 1976.
DOI : 10.1063/1.89155

W. Chen and H. Ahmed, Fabrication of 5???7 nm wide etched lines in silicon using 100 keV electron???beam lithography and polymethylmethacrylate resist, Applied Physics Letters, vol.62, issue.13, p.1499, 1993.
DOI : 10.1063/1.109609

E. Kratschmer and M. Isaacson, Nanostructure fabrication in metals, insulators, and semiconductors using self-developing metal inorganic resist, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.4, issue.1, p.361, 1986.
DOI : 10.1116/1.583332

C. Vieu, M. Mejias, F. Carcenac, G. C. , and H. Launois, Novel nanofabrication method of high temperature metallic Coulomb blockade devices, Microelectronic Engineering, vol.30, issue.1-4, p.403, 1996.
DOI : 10.1016/0167-9317(95)00273-1

H. Hiraoka, Radiation Chemistry of Poly(methacrylates), IBM Journal of Research and Development, vol.21, issue.2, p.121, 1977.
DOI : 10.1147/rd.212.0121

J. O. Choi, J. A. Moore, J. C. Corelli, J. P. Silverman, and H. Bakrhu, Degradation of poly(methylmethacrylate) by deep ultraviolet, x-ray, electron beam, and proton beam irradiations, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.6, issue.6, p.2286, 1988.
DOI : 10.1116/1.584071

W. Chen, Nanotechnology Resolution limits and ultimate resolution, 1994.

A. N. Broers, Resolution Limits of PMMA Resist for Exposure with 50 kV Electrons, Journal of The Electrochemical Society, vol.128, issue.1, p.166, 1981.
DOI : 10.1149/1.2127360

M. G. Thomson, Incident dose modification for proximity effect correction, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.11, issue.6, pp.2768-2772, 1993.
DOI : 10.1116/1.586599

M. Gentili, L. Grella, A. Lucchesini, L. Luciani, L. Maestrogiacomo et al., Energy density function determination in very-high-resolution electron-beam lithography, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, vol.8, issue.6, pp.1867-1871, 1990.
DOI : 10.1116/1.585175

Y. Xia and G. M. Whitesides, SOFT LITHOGRAPHY, Annual Review of Materials Science, vol.28, issue.1, pp.153-184, 1998.
DOI : 10.1146/annurev.matsci.28.1.153

J. W. Bressick and J. M. Calvert, Patterning of Self-Assembled Films Using Lithographic Exposure Tools, Japanese Journal of Applied Physics, vol.32, issue.Part 1, No. 12B, pp.5829-5839, 1993.
DOI : 10.1143/JJAP.32.5829

W. J. Albery and A. J. Hillman, Chapter 10. Modified electrodes, Annual Reports Section "C" (Physical Chemistry), vol.78, pp.377-437, 1981.
DOI : 10.1039/pc9817800377

M. J. Hostetler, J. E. Wingate, C. Zhong, J. E. Harris, R. W. Zashet et al., Alkanethiolate Gold Cluster Molecules with Core Diameters from 1.5 to 5.2 nm:?? Core and Monolayer Properties as a Function of Core Size, Langmuir, vol.14, issue.1, pp.17-30, 1998.
DOI : 10.1021/la970588w

A. Doron, E. Kats, and I. Willner, Organization of Au Colloids as Monolayer Films onto ITO Glass Surfaces: Application of the Metal Colloid Films as Base Interfaces To Construct Redox-Active Monolayers, Langmuir, vol.11, issue.4, pp.1313-1317, 1995.
DOI : 10.1021/la00004a044

M. A. Wood, M. Riehle, and C. D. Wilkinson, Patterning colloidal nanotopographies, Nanotechnology, vol.13, issue.5, pp.605-609, 2002.
DOI : 10.1088/0957-4484/13/5/312

E. T. Vandenberg, L. Bertilsson, B. Liedberg, K. Uvdal, R. Erlandsson et al., Structure of 3-aminopropyl triethoxy silane on silicon oxide, Journal of Colloid and Interface Science, vol.147, issue.1, p.103, 1991.
DOI : 10.1016/0021-9797(91)90139-Y

B. Martel, Textiles et matériaux polymères porteurs de cyclodextrines : nouvelles voies d'obtention et d'application, 2000.

T. Heim, TransportélectroniqueTransportélectronique dans l'ADN, 2002.

V. Haguet, DétectionDétectionélectronique d'une intéraction biomoléculaire entre desélecdesélectrodes nanostructurées, 2002.

I. I. Tarhan and G. H. Watson, Photonic Band Structure of fcc Colloidal Crystals, Physical Review Letters, vol.76, issue.2, p.315, 1996.
DOI : 10.1103/PhysRevLett.76.315

Z. Y. Li and Z. Q. Zhang, Photonic Bandgaps in Disordered Inverse-Opal Photonic Crystals, Advanced Materials, vol.13, issue.6, p.433, 2001.
DOI : 10.1002/1521-4095(200103)13:6<433::AID-ADMA433>3.0.CO;2-O

J. M. Weissman, H. B. Sunkara, A. S. Tse, and S. A. Asher, Thermally Switchable Periodicities and Diffraction from Mesoscopically Ordered Materials, Science, vol.274, issue.5289, p.959, 1996.
DOI : 10.1126/science.274.5289.959

M. A. Wood, M. Richle, and C. D. Wilkinson, Patterning colloidal nanotopographies, Nanotechnology, vol.13, issue.5, pp.605-609, 2002.
DOI : 10.1088/0957-4484/13/5/312

A. Van-blaaderen, R. Ruel, and P. Wiltzius, Template-directed colloidal crystallization, Nature, vol.385, issue.6614, pp.321-324, 1997.
DOI : 10.1038/385321a0

S. H. Park, D. Qin, and Y. Xia, Crystallization of Mesoscale Particles over Large Areas, Advanced Materials, vol.10, issue.13, pp.1028-1032, 1998.
DOI : 10.1002/(SICI)1521-4095(199809)10:13<1028::AID-ADMA1028>3.0.CO;2-P

E. J. Verwey, J. G. Th, and . Overbeek, Theory of Stability of Lyophobic Colloids, 1948.

J. N. Israelachvili, Intermolecular et Surface Forces, volume Second Edition, 1991.

E. M. Hoeck, S. Bhattacharjee, and M. , Effect of Membrane Surface Roughness on Colloid???Membrane DLVO Interactions, Langmuir, vol.19, issue.11, pp.4836-4847, 2003.
DOI : 10.1021/la027083c

R. H. French, Origins and Applications of London Dispersion Forces and Hamaker Constants in Ceramics, Journal of the American Ceramic Society, vol.82, issue.1, pp.2117-2146, 2000.
DOI : 10.1111/j.1151-2916.2000.tb01527.x

E. Kumacheva, R. K. Golding, M. Allard, and E. H. Sargent, Colloid Crystal Growth on Mesoscopically Patterned Surfaces: Effect of Confinement, Advanced Materials, vol.51, issue.3, pp.221-224, 2002.
DOI : 10.1002/1521-4095(20020205)14:3<221::AID-ADMA221>3.0.CO;2-V

I. Amlani, A. M. Rawlett, L. A. Nagahara, and R. K. Tsui, An approach to transport measurements of electronic molecules, Applied Physics Letters, vol.80, issue.15, pp.2761-2763, 2002.
DOI : 10.1063/1.1469655

D. L. Klein, P. L. Mceuen, J. E. Bowen-katari, R. Roth, and A. P. , An approach to electrical studies of single nanocrystals, Applied Physics Letters, vol.68, issue.18, p.2574, 1996.
DOI : 10.1063/1.116188

R. Stratton, Volt-current characteristics for tunneling through insulating films, Journal of Physics and Chemistry of Solids, vol.23, issue.9, pp.1177-1190, 1962.
DOI : 10.1016/0022-3697(62)90165-8

R. H. Fowler and L. W. Nordheim, Electron Emission in Intense Electric Fields, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.119, issue.781, pp.173-181, 1928.
DOI : 10.1098/rspa.1928.0091

Q. H. Wei, D. M. Cupid, and X. L. Xu, Applied Physics Letters, pp.16413461-3473, 2000.

C. Vieu and L. Malaquin, Alternative Lithography, 2003.

D. Juncker, H. Schmid, A. Bernard, I. Caelen, B. Michel et al., Soft and rigid two-level microfluidic networks for patterning surfaces, Journal of Micromechanics and Microengineering, vol.11, issue.5, pp.532-541, 2001.
DOI : 10.1088/0960-1317/11/5/314

B. Fethi and . Voltampérométrie, théorie et mise en oeuvre expérimentale Techniques de l'ingénieur, traité Analyse et Caractérisation, p.126

K. C. Grabar, P. C. Smith, M. D. Musick, J. A. Davis, D. G. Walter et al., Kinetic Control of Interparticle Spacing in Au Colloid-Based Surfaces:?? Rational Nanometer-Scale Architecture, Journal of the American Chemical Society, vol.118, issue.5, pp.1148-1153, 1996.
DOI : 10.1021/ja952233+

J. P. Renault, A. Bernard, A. Bietsch, B. Michel, H. R. Bosshard et al., Fabricating Arrays of Single Protein Molecules on Glass Using Microcontact Printing, The Journal of Physical Chemistry B, vol.107, issue.3, pp.703-711, 2003.
DOI : 10.1021/jp0263424

R. S. Kane, S. Takayama, E. Ostuni, D. E. Ingber, and G. M. Whitesides, Patterning proteins and cells using soft lithography, Biomaterials, vol.20, issue.23-24, pp.2363-2376, 1999.
DOI : 10.1016/S0142-9612(99)00165-9

I. Caelen, A. Bernard, D. Junker, B. Michel, H. Heinzlmann et al., Formation of Gradients of Proteins on Surfaces with Microfluidic Networks, Langmuir, vol.16, issue.24, pp.9125-9130, 2000.
DOI : 10.1021/la000851k

I. Vikholm and W. M. Albers, Oriented Immobilization of Antibodies for Immunosensing, Langmuir, vol.14, issue.14, pp.3865-3872, 1998.
DOI : 10.1021/la971412x

Y. Zhou, Z. Wu, G. Shen, and R. Yu, An amperometric immunosensor based on Nafion-modified electrode for the determination of Schistosoma japonicum antibody, Sensors and Actuators B: Chemical, vol.89, issue.3, pp.292-298, 2003.
DOI : 10.1016/S0925-4005(03)00004-2

J. L. Tan, J. Tien, and C. S. Chen, Microcontact Printing of Proteins on Mixed Self-Assembled Monolayers, Langmuir, vol.18, issue.2, pp.519-523, 2002.
DOI : 10.1021/la011351+

A. Bernard, E. Delamarche, H. Schmid, B. Michel, H. R. Bosshard et al., Printing Patterns of Proteins, Langmuir, vol.14, issue.9, pp.2225-2229, 1998.
DOI : 10.1021/la980037l

P. M. John, R. Davis, N. Cady, J. Czajka, C. A. Batt et al., Diffraction-Based Cell Detection Using a Microcontact Printed Antibody Grating, Analytical Chemistry, vol.70, issue.6, pp.1108-1111, 1998.
DOI : 10.1021/ac9711302

K. Gasperi, Micro et nano tamponnage de biomolécules, LAAS- CNRS, 2003.

L. Malaquin, Développement d'une nouvelle technique de lithographie douce : le micro/nano tamponnage moléculaire, 2000.

J. L. Tucker, Improving low current measurements on nanoelectronic and molecular electronic devices. White paper, 2002.

C. Vieu and L. Malaquin, Using PDMS as thermocurable resist for mold assisted imprint process, pp.164-199, 2003.

D. Juncker, H. Schmid, A. Bernard, B. Caelen, N. Michel et al., Soft and rigid two-level microfluidic networks for patterning surfaces, Journal of Micromechanics and Microengineering, vol.11, issue.5, pp.532-541, 2001.
DOI : 10.1088/0960-1317/11/5/314

J. C. Mcdonal, D. C. Duffy, J. R. Anderson, D. T. Chiu, H. Wu et al., Fabrication of microfluidic systems in poly(dimethylsiloxane), Electrophoresis, vol.66, issue.1, pp.27-40, 2000.
DOI : 10.1002/(SICI)1522-2683(20000101)21:1<27::AID-ELPS27>3.0.CO;2-C

M. K. Chaudhury and G. M. Whitesides, Direct measurement of interfacial interactions between semispherical lenses and flat sheets of poly(dimethylsiloxane) and their chemical derivatives, Langmuir, vol.7, issue.5, pp.1013-1025, 1991.
DOI : 10.1021/la00053a033

K. Hosokawa, K. Hanada, and R. Maeda, A polydimethylsiloxane (PDMS) deformable diffraction grating for monitoring of local pressure in microfluidic devices, Journal of Micromechanics and Microengineering, vol.12, issue.1, pp.1-6, 2002.
DOI : 10.1088/0960-1317/12/1/301

J. S. Kim and D. R. Knapp, Miniaturized multichannel electrospray ionization emitters on poly(dimethylsiloxane) microfluidic devices, ELECTROPHORESIS, vol.73, issue.18, pp.3993-3999, 2001.
DOI : 10.1002/1522-2683(200110)22:18<3993::AID-ELPS3993>3.0.CO;2-X

A. Foulani, Electronic behaviour and field emission of metal???semiconductor???insulator???metal (MSIM) heterostructures based on a-C:H films, Applied Surface Science, vol.206, issue.1-4, pp.294-299, 2003.
DOI : 10.1016/S0169-4332(02)01231-X

S. Y. Chou, P. R. Krauss, and P. J. Renstrom, Imprint of sub???25 nm vias and trenches in polymers, Applied Physics Letters, vol.67, issue.21, p.3114, 1995.
DOI : 10.1063/1.114851