Sources, flux et bilan des retombées atmosphériques de métaux en Ile-de-France

Abstract : The urban atmosphere is submitted to large inputs of anthropogenic contaminants arising from both stationary (power plants, industries, etc.) and mobile (road traffic) sources. These small particles may be transported over long distances and affect ecosystems. Significant dry and wet atmospheric deposition also occurs locally and contributes to the contamination of urban runoff. The aim of this study is to compare heavy metal and hydrocarbon atmospheric deposition fluxes to other input ways on agricultural and urban areas to assess their importance. Moreover, a source investigation has been done to identify the main origins of these pollutants. Before the quantification of pollutant fluxes, a comparison of several sampling procedures was performed. As a result, the sampling of total atmospheric deposition is not affected by the funnel material (Teflon and polyethylene) or by the sampling duration (7 and 28 days). However, the rinsing step of the funnel walls showed a higher relative importance during short sampling periods. The relative amount contained in these solutions reached 24 to 40 % of the total flux during weekly sampling periods and 8 to 18 % during monthly sampling periods, whatever the element considered. The temporal evolution of atmospheric deposition showed no seasonal influence on flux variations during the 2001-2002 period. Considering an 8-year period behaviour, between 1994 and 2002, a significant decrease of the deposition fluxes of Cd, Cu, Pb and Zn occurred at the Créteil site which is placed in an industrialised area of the Paris suburb. The decreasing factor reached 16, 2.5, 4 and 7.5 for these elements respectively.
At the Ile-de-France scale, the deposition flux levels on urban and semi-urban areas were of the same order of magnitude (? 20 tonnes per year for Ba, Cu, Pb and Sr). Since semiurban surface area is four times higher than urban ones, the important influence of anthropogenic activities on atmospheric deposition of urban areas is evidenced. At the Seine River catchment scale, the atmospheric deposition levels were of the same order of magnitude as Seine River particle contents measured at the catchment estuary (Poses). The flux ratio between atmospheric inputs and Seine particles ranged between 0.8 and 4.8 for Al, Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. The importance of atmospheric deposition of metals was estimated on agricultural and urban areas. In the first case, the atmospheric fallout appears as the main input way of Cu, Ni and Pb to agrosystems while Cd is mainly introduced by fertilisers. These two input ways induced an increase of Cd, Ni and Pb in the cultivated horizon with an annual balance reaching 0.33, 0.014 and 0.014 %, respectively, of actual stocks while the Cu showed a
decrease with an annual balance reaching 0.024 %. In the second case, atmospheric deposition was compared to roof and street runoff. The atmospheric deposition is the main introducing way of most of considered elements, compared to roof runoff excepting Cu, Pb, Ti and Zn which are mainly emitted by the latter. Nevertheless, compared to street runoff, atmospheric deposition levels are 1.5 to 27 times lower than street cleaning ones showing that atmospheric
introducing way is not the main introducing way of metals in urban areas. The source investigation on atmospheric deposition was performed using several tools developed during this study. The results allow the characterisation of the anthropogenic sources considered using specific elements or ratios. These tools were applied to the atmospheric deposition data but they did not allowed the determination of anthropogenic activities becauseof the atmospheric mixture.
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  • HAL Id : tel-00007558, version 1

Citation

Sam Azimi. Sources, flux et bilan des retombées atmosphériques de métaux en Ile-de-France. Ecologie, Environnement. Ecole des Ponts ParisTech, 2004. Français. ⟨tel-00007558⟩

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