A. Baker and H. M. Bobonich, Magnetic Properties of Some High-Spin Complexes of Iron(II), Inorganic Chemistry, vol.3, issue.8, p.1184, 1964.
DOI : 10.1021/ic50018a027

G. Haasnoot, Magnetism : A Supramolecular Function, 1996.

Y. Sugano, H. Tanabe, and . Kamimura, Multiplets of Transition Metal Ions, Pure Appl, Phys, p.33, 1970.

L. Schläfer and G. Gliemann, Basic principles of ligand field theory, p.60, 1969.

E. König and K. Madeja, 5T2-1A1 Equilibriums in some iron(II)-bis(1,10-phenanthroline) complexes, Inorganic Chemistry, vol.6, issue.1, p.48, 1967.
DOI : 10.1021/ic50047a011

E. König and G. Ritter, Hysteresis effects at a cooperative high-spin (5T2) ??? low-spin (1A1) transition in dithiocyanatobis (4, 7-dimethyl-1, 10-phenanthroline) iron (II), Solid State Communications, vol.18, issue.3, p.279, 1976.
DOI : 10.1016/0038-1098(76)90002-8

A. Real, H. Bolvin, A. Bousseksou, A. Dworkin, O. Kahn et al., Two-step spin crossover in the new dinuclear compound [Fe(bt)(NCS)2]2bpym, with bt = 2,2'-bi-2-thiazoline and bpym = 2,2'-bipyrimidine: experimental investigation and theoretical approach, Journal of the American Chemical Society, vol.114, issue.12, p.4650, 1992.
DOI : 10.1021/ja00038a031

H. C. Bousseksou, F. Machado, and . Varret, A Simple Ising-Like Model for Spin Conversion Including Molecular Vibrations, Journal de Physique I, vol.5, issue.6, p.747, 1995.
DOI : 10.1051/jp1:1995165

URL : https://hal.archives-ouvertes.fr/jpa-00247099

P. Slichter and H. G. Drickamer, Pressure???Induced Electronic Changes in Compounds of Iron, The Journal of Chemical Physics, vol.56, issue.5, p.2142, 1972.
DOI : 10.1063/1.1677511

M. F. Rudolf, R. Bronisz, and Z. , Ciunik, 3 rd Spin Crossover Family Meeting, 1998.

A. Enachescu and . Hauser, TMR-Thermal and Optical Switching of Spin-State, 2002.

L. Xie and D. N. Hendrickson, Mechanism of spin-state interconversion in ferrous spin-crossover complexes: direct evidence for quantum mechanical tunneling, Journal of the American Chemical Society, vol.109, issue.23, p.6981, 1987.
DOI : 10.1021/ja00257a013

P. Hauser, H. Gütlich, and . Spiering, High-spin .fwdarw. low-spin relaxation kinetics and cooperative effects in the hexakis(1-propyltetrazole)iron bis(tetrafluoroborate) and [Zn1-xFex(ptz)6](BF4)2(ptz = 1-propyltetrazole) spin-crossover systems, Inorganic Chemistry, vol.25, issue.23, p.4245, 1986.
DOI : 10.1021/ic00243a036

URL : https://hal.archives-ouvertes.fr/hal-00906284

J. Hauser, P. Adler, and . Gütlich, Light-induced excited spin state trapping (LIESST) in [Fe(2-mephen)3]2+ embedded in polymer matrices, Chemical Physics Letters, vol.152, issue.6, p.468, 1988.
DOI : 10.1016/0009-2614(88)80443-3

J. Jeftic and A. Hauser, The HS ??? LS relaxation under external pressure in the Fe(II) spin-crossover system [Zn1???xFex(ptz)6](BF4)2(ptz = 1-propyltetrazole, x = 0.1), Chemical Physics Letters, vol.248, issue.5-6, p.458, 1996.
DOI : 10.1016/0009-2614(95)01297-4

K. Hoo, F. Boukheddaden, and . Varret, Two-variable macroscopic model for spin-crossover solids: Static and dynamic effects of the correlations, The European Physical Journal B, vol.17, issue.3, p.449, 2000.
DOI : 10.1007/s100510070124

A. Hauser, A. Vef, and P. Adler, 8710 ; b) e) A. Hauser, J. Chem. Phys. Comments Inorg. Chem. J. Phys. Chem. Solids Chem. Phys. Lett, vol.95, issue.507, p.173, 1990.

I. Tableau, 1 : Sélection de distances (Å) et d'angles (°) de liaison pour le composé, Fe

. La-distorsion-de, estimation du paramètre (formule II.1) [14] Par rapport à l'octaèdre parfait ( = 0°), la valeur obtenue ( = 92°) indique une forte distorsion. Cette valeur suggère également que l'ion Fe(II) de la forme hydratée se trouve dans l'état BS. La valeur des complexes [Fe(bpp) 2 ]X 2 ·solv dans l'état BS est en général, p.90

L. Figure and I. , Le taux d'occupation d'une des molécules d'eau est assez incertain. Ainsi, le nombre final de molécules d'eau par unité [Fe(bpp) 2 ]Br 2 peut être estimé à 5,5 ou à 6. Par ailleurs, on peut remarquer que les molécules d'eau s'agencent dans l'axe des unités cationiques. Trois des quatre groupes NH des ligands bpp présentent de très courtes distances (de l'ordre de 2,7 Å) avec les molécules d'eau et l'angle NHO est de l'ordre de 167° à 176°. Le quatrième groupe NH est, quant à lui, p.83

H. Sugiyarto and H. A. Goodwin, Coordination of Pyridine-Substituted Pyrazoles and Their Influence on the Spin State of Iron(II), Australian Journal of Chemistry, vol.41, issue.11, p.1645, 1988.
DOI : 10.1071/CH9881645

P. Buchen, H. A. Gütlich, and . Goodwin, Non-First-Order Kinetics of the High Spin-Low Spin Relaxation in [Fe(bpp)2](BF4)2 after LIESST and Thermal Spin Trapping, Inorganic Chemistry, vol.33, issue.20, p.4573, 1994.
DOI : 10.1021/ic00098a026

S. A. Lin and . Lang, Novel two step synthesis of pyrazoles and isoxazoles from aryl methyl ketones, Journal of Heterocyclic Chemistry, vol.97, issue.2, p.345, 1977.
DOI : 10.1002/jhet.5570140240

J. Morscheidt, E. Jeftic, J. Codjovi, A. Linares, H. Bousseksou et al., Optical detection of the spin transition by reflectivity: application to, Measurement Science and Technology, vol.9, issue.8, p.1311, 1998.
DOI : 10.1088/0957-0233/9/8/025

P. Slichter and H. G. Drickamer, Pressure???Induced Electronic Changes in Compounds of Iron, The Journal of Chemical Physics, vol.56, issue.5, p.2142, 1972.
DOI : 10.1063/1.1677511

). A. Hauser, A. Vef, P. Adler, A. Hauser, J. Jeftic et al., ) (1996) 1743 ; d) A. Hauser, J. Chem. Phys. Comments Inorg. Chem. J. Phys. Chem. Solids Chem. Phys. Lett. Coord. Chem. Rev, vol.95, issue.111, pp.173-275, 1990.

M. D. Cecconi, S. Vaira, A. Midollini, L. Orlandini, and . Sacconi, Singlet .dblharw. quintet spin transitions of iron(II) complexes with a P4Cl2 donor set. X-ray structures of the compound FeCl2(Ph2PCH:CHPPh2)2 and of its acetone solvate at 130 and 295 K, Inorganic Chemistry, vol.20, issue.10, p.3423, 1981.
DOI : 10.1021/ic50224a053

M. Guionneau, G. Marchivie, J. Bravic, D. Létard, and . Chasseau, ) analogues, J. Mater. Chem., vol.29, issue.8, p.2546, 2002.
DOI : 10.1039/B202610D

W. Müller, J. Ensling, H. Spiering, and P. Gütlich, High-spin .dblharw. low-spin transition in hexacoordinate complexes of iron(II) with monodentate 1-alkyltetrazole ligands: a variable-temperature Moessbauer, magnetic susceptibility, and far-infrared study, Inorganic Chemistry, vol.22, issue.14, pp.2074-2079, 1983.
DOI : 10.1021/ic00156a027

F. Enamullah, U. Renz, G. El-ayaan, W. Wiesinger, and . Linert, Experimental spin-crossover investigations on charged and neutral iron(II) complexes with 4-substituted-2,6-bis-(benzimidazol-2???-yl)pyridine, Vibrational Spectroscopy, vol.14, issue.1, p.95, 1997.
DOI : 10.1016/S0924-2031(96)00042-2

A. Hauser, spin crossover system (ptz=1???propyltetrazole), The Journal of Chemical Physics, vol.94, issue.4, p.2741, 1991.
DOI : 10.1063/1.459851

C. Xie and D. N. Hendrickson, Mechanism of spin-state interconversion in ferrous spin-crossover complexes: direct evidence for quantum mechanical tunneling, Journal of the American Chemical Society, vol.109, issue.23, p.6981, 1987.
DOI : 10.1021/ja00257a013

A. Hauser, Intersystem crossing in Fe(II) coordination compounds, Coordination Chemistry Reviews, vol.111, p.275, 1991.
DOI : 10.1016/0010-8545(91)84034-3

T. Buchen, P. G?-u-utlich, K. H. Sugiyarto, and H. A. Goodwin, High-Spin ??? Low-Spin Relaxation in [Fe(bpp)2](CF3SO3)2 H2O after LIESST and Thermal Spin-State Trapping???Dynamics of Spin Transition Versus Dynamics of Phase Transition, Chemistry - A European Journal, vol.14, issue.9, p.1134, 1996.
DOI : 10.1002/chem.19960020915

T. Buchen, P. G?-u-utlich, and H. A. Goodwin, Non-First-Order Kinetics of the High Spin-Low Spin Relaxation in [Fe(bpp)2](BF4)2 after LIESST and Thermal Spin Trapping, Inorganic Chemistry, vol.33, issue.20, p.4573, 1994.
DOI : 10.1021/ic00098a026

J. Zyss and I. Ledoux, Nonlinear optics in multipolar media: theory and experiments, Chemical Reviews, vol.94, issue.1, p.77, 1994.
DOI : 10.1021/cr00025a003

L. Angeloni, A. Caneschi, L. David, A. Fabretti, F. Ferraro et al., Crystal structures, magnetic and non-linear optical properties of methoxyphenyl nitronyl???nitroxide radicals, J. Mater. Chem., vol.175, issue.7, p.1047, 1994.
DOI : 10.1039/JM9940401047

Y. Lee, S. Jeon, and M. Cho, Molecular Polarizability and First Hyperpolarizability of Octupolar Molecules: Donor-Substituted Triphenylmethane Dyes, Journal of the American Chemical Society, vol.120, issue.42, p.10921, 1998.
DOI : 10.1021/ja9803456

J. Zyss, T. Chauvan, C. Dhenaut, and I. Ledoux, Harmonic rayleigh scattering from nonlinear octupolar molecular media: the case of crystal violet, Chemical Physics, vol.177, issue.1, p.281, 1993.
DOI : 10.1016/0301-0104(93)80196-G

V. Balzani, A. Credi, F. Raymo, and J. Stoddart, Artificial Molecular Machines, Angewandte Chemie, vol.406, issue.2, p.3348, 2000.
DOI : 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO;2-X

W. Baker and H. Bobonich, Magnetic Properties of Some High-Spin Complexes of Iron(II), Inorganic Chemistry, vol.3, issue.8, p.1184, 1964.
DOI : 10.1021/ic50018a027

E. K?-o-onig, Some aspects of the chemistry of bis(2,2???-dipyridyl) and bis(1,10-phenanthroline) complexes of iron(II), Coordination Chemistry Reviews, vol.3, issue.4, p.471, 1968.
DOI : 10.1016/S0010-8545(00)80097-1

H. Goodwin, Spin Transitions in six-coordinate iron(II) complexes, Coordination Chemistry Reviews, vol.18, issue.3, p.293, 1976.
DOI : 10.1016/S0010-8545(00)80430-0

S. Decurtins, P. G?-u-utlich, C. K?-o-ohler, H. Spiering, and A. Hauser, Light-induced excited spin state trapping in a transition-metal complex: The hexa-1-propyltetrazole-iron (II) tetrafluoroborate spin-crossover system, Chemical Physics Letters, vol.105, issue.1, p.1, 1984.
DOI : 10.1016/0009-2614(84)80403-0

A. Hauser, Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1???xFex(ptz)6(BF4)2 spin-crossover systems, Chemical Physics Letters, vol.124, issue.6, p.543, 1986.
DOI : 10.1016/0009-2614(86)85073-4

A. Hauser, Intersystem crossing in Fe(II) coordination compounds, Coordination Chemistry Reviews, vol.111, p.275, 1991.
DOI : 10.1016/0010-8545(91)84034-3

S. Hayami, Z. Gu, Y. Einaga, Y. Kobayasi, Y. Ishikawa et al., A Novel LIESST Iron(II) Complex Exhibiting a High Relaxation Temperature, Inorganic Chemistry, vol.40, issue.13, p.3240, 2001.
DOI : 10.1021/ic000708e

S. Marcen, L. Lecren, L. Capes, H. Goodwin, and J. , Critical temperature of the LIESST effect in a series of hydrated and anhydrous complex salts [Fe(bpp)2]X2, Chemical Physics Letters, vol.358, issue.1-2, p.87, 2002.
DOI : 10.1016/S0009-2614(02)00590-0

URL : https://hal.archives-ouvertes.fr/hal-00716814

V. Ksenofontov, G. Levchenko, H. Spiering, P. G?-u-utlich, J. Bouhedja et al., Spin crossover behavior under pressure of Fe(PM-L)2(NCS)2 compounds with substituted 2???-pyridylmethylene 4-anilino ligands, Chemical Physics Letters, vol.294, issue.6, p.545, 1998.
DOI : 10.1016/S0009-2614(98)00901-4

H. Daubric, J. Kliava, P. Guionneau, D. Chasseau, J. Kahn et al., ion, Journal of Physics: Condensed Matter, vol.12, issue.25, p.5481, 2000.
DOI : 10.1088/0953-8984/12/25/312

P. Guionneau, J. Yufit, D. Chasseau, D. Bravic, G. Goeta et al., Structural approach of the features of the spin crossover transition in iron (II) compounds, Journal of Materials Chemistry, vol.9, issue.4, p.985, 1999.
DOI : 10.1039/a808075e

P. Guionneau, M. Marchivie, G. Bravic, L. Etard, J. Chasseau et al., ) analogues, J. Mater. Chem., vol.29, issue.8, p.2546, 2002.
DOI : 10.1039/B202610D

J. Ferguson and F. Herren, The electronic structure of the metal-to-ligand charge-transfer states of M(bpy)2+3 (M = Fe, Ru, Os), Chemical Physics Letters, vol.89, issue.5, p.371, 1982.
DOI : 10.1016/0009-2614(82)80003-1

A. Hauser and J. Adler, Light-induced excited spin state trapping (LIESST) in [Fe(2-mephen)3]2+ embedded in polymer matrices, Chemical Physics Letters, vol.152, issue.6, p.468, 1988.
DOI : 10.1016/0009-2614(88)80443-3

P. G?-u-utlich, H. Spiering, and A. Hauser, Inorganic Electronic Structure and Spectroscopy, p.575, 1999.

C. Slichter and H. Drickamer, Pressure???Induced Electronic Changes in Compounds of Iron, The Journal of Chemical Physics, vol.56, issue.5, p.2142, 1972.
DOI : 10.1063/1.1677511

L. Capes, J. Kahn, and O. , Photomagnetic Properties in a Series of Spin Crossover Compounds [Fe(PM-L)2(NCX)2] (X=S, Se) with Substituted 2???-Pyridylmethylene- 4-amino Ligands, Chemistry - A European Journal, vol.6, issue.12, p.2246, 2000.
DOI : 10.1002/1521-3765(20000616)6:12<2246::AID-CHEM2246>3.0.CO;2-X

A. Hauser, A. Vef, and P. Adler, Intersystem crossing dynamics in Fe(II) coordination compounds, The Journal of Chemical Physics, vol.95, issue.12, p.8710, 1991.
DOI : 10.1063/1.461255

O. Kahn, A. Desaix, O. Roubeau, J. Jeftic, J. Haasnoot et al., Molecular Magnetism, Eur Phys J B, vol.35, issue.6, p.183, 1993.

C. Enachescu, H. Constant-machado, E. Codjovi, J. Linares, K. Boukheddaden et al., Direct access to the photo-excitation and relaxation terms in photo-switchable solids: non-linear aspects, Journal of Physics and Chemistry of Solids, vol.62, issue.8, p.1409, 2001.
DOI : 10.1016/S0022-3697(01)00056-7

J. Jeftic, M. Matsarski, A. Hauser, A. Goujon, E. Codjovi et al., Quasi-static nature of the light induced thermal hysteresis in [Fe(ptz)6](BF4)2 spin-transition solid, Polyhedron, vol.20, issue.11-14, p.1599, 2001.
DOI : 10.1016/S0277-5387(01)00660-X