P. G. De-gennes, Polymer solutions near an interface. Adsorption and depletion layers, Macromolecules, vol.14, issue.6, p.1637, 1981.
DOI : 10.1021/ma50007a007

D. H. Napper, Polumeric Stabilzation of Colloïdale Dispersions, 1983.

B. Fontana and J. Thomas, THE CONFIGURATION OF ADSORBED ALKYL METHACRYLATE POLYMERS BY INFRARED AND SEDIMENTATION STUDIES, The Journal of Physical Chemistry, vol.65, issue.3, p.480, 1961.
DOI : 10.1021/j100821a023

K. G. Barnett, T. Cosgrove, B. Vincent, D. S. Sissons, and M. Cohen-stuart, The measurement of the polymer-bound fraction at the solid-liquid interface by pulsed nuclear magnetic resonance, Macromolecules, vol.14, issue.4, p.1018, 1981.
DOI : 10.1021/ma50005a023

I. D. Robb and R. Smith, The adsorption of a copolymer of vinyl pyrrolidone and allylamine at the silica-solution interface, European Polymer Journal, vol.10, issue.11, p.1005, 1974.
DOI : 10.1016/0014-3057(74)90062-7

R. Varoqui and . Déjardin, Hydrodynamic thickness of adsorbed polymers, The Journal of Chemical Physics, vol.66, issue.10, p.4395, 1977.
DOI : 10.1063/1.433734

M. Kawaguchi, H. Hayakawa, and A. Takahashi, Adsorption of polystyrene onto a metal surface in good solvent conditions, Macromolecules, vol.16, issue.4, p.631, 1983.
DOI : 10.1021/ma00238a028

J. Pendfold, R. K. Thomas, and J. , The application of the specular reflection of neutrons to the study of surfaces and interfaces, Journal of Physics: Condensed Matter, vol.2, issue.6, p.1369, 1990.
DOI : 10.1088/0953-8984/2/6/001

S. H. Anastasiadis, T. P. Russel, S. K. Satija, and C. F. Majkrzak, Neutron reflectivity studies of the surface-induced ordering of diblock copolymer films, Physical Review Letters, vol.62, issue.16, p.1852, 1989.
DOI : 10.1103/PhysRevLett.62.1852

R. R. Highfield, R. K. Thomas, P. G. Cummins, D. P. Gregory, J. Mingins et al., Critical reflection of neutrons from Langmuir-Blodgett films on glass, Thin Solid Films, vol.99, issue.1-3, p.165, 1987.
DOI : 10.1016/0040-6090(83)90377-2

D. E. Graham and M. C. Phillips, Proteins at liquid interfaces, Journal of Colloid and Interface Science, vol.70, issue.3, p.415, 1979.
DOI : 10.1016/0021-9797(79)90049-3

J. R. Hunter, P. K. Kilpatrick, and R. G. , ??-casein adsorption at the air/water interface, Journal of Colloid and Interface Science, vol.142, issue.2, p.429, 1991.
DOI : 10.1016/0021-9797(91)90074-I

E. Dickinson, D. S. Horne, J. S. Phipps, and R. M. Richardson, A neutron reflectivity study of the adsorption of .beta.-casein at fluid interfaces, Langmuir, vol.9, issue.1, p.242, 1993.
DOI : 10.1021/la00025a046

G. Fragneto, R. K. Thomas, A. R. Rennie, and J. Pendfold, Neutron reflection study of bovine beta-casein adsorbed on OTS self-assembled monolayers, Science, vol.70, issue.7, p.657, 1995.
DOI : 10.1103/PhysRevLett.70.958

P. J. Atkinson, E. Dickinson, D. S. Horne, and R. M. Richardson, Neutron reflectivity of adsorbed ??-casein and ??-lactoglobulin at the air/water interface, J. Chem. Soc., Faraday Trans., vol.89, issue.17, p.2847, 1995.
DOI : 10.1039/FT9959102847

B. Harzallah, V. Aguié-beghin, R. Douillard, and L. Bosio, A structural study of ??-casein adsorbed layers at the air???water interface using X-ray and neutron reflectivity, International Journal of Biological Macromolecules, vol.23, issue.1, p.73, 1998.
DOI : 10.1016/S0141-8130(98)00035-X

T. A. Payens and B. W. Van-markwijk, Some features of the association of ??-casein, Biochimica et Biophysica Acta, vol.71, p.517, 1963.
DOI : 10.1016/0006-3002(63)91124-7

E. Leclerc and P. Calmettes, -Casein, Physical Review Letters, vol.78, issue.1, p.150, 1997.
DOI : 10.1103/PhysRevLett.78.150

URL : https://hal.archives-ouvertes.fr/hal-01108789

E. Dickinson and D. J. Mc-clements, Advances in Food Colloids, 1995.
DOI : 10.1007/978-1-4613-1223-9

M. L. Anson and A. E. Et-mirsky, The Reversibility of Protein Coagulation, The Journal of Physical Chemistry, vol.35, issue.1, p.185, 1931.
DOI : 10.1021/j150319a015

M. L. Anson, Protein Denaturation and the Properties of Protein Groups, Adv. Protein Chem, vol.2, p.361, 1945.
DOI : 10.1016/S0065-3233(08)60629-4

K. A. Dill and D. Et-shortle, Denatured States of Proteins, Annual Review of Biochemistry, vol.60, issue.1, p.795, 1991.
DOI : 10.1146/annurev.bi.60.070191.004051

D. Shortle, Denatured states of proteins and their roles in folding and stability, Current Opinion in Structural Biology, vol.3, issue.1, p.66, 1993.
DOI : 10.1016/0959-440X(93)90204-X

T. R. Sosnick and A. Et-trewhella, Denatured states of ribonuclease A have compact dimensions and residual secondary structure, Biochemistry, vol.31, issue.35, p.8329, 1992.
DOI : 10.1021/bi00150a029

D. Neri, M. Billeter, D. Wider, and K. Et-wuthrich, NMR determination of residual structure in a urea-denatured protein, the 434-repressor, Science, vol.257, issue.5076, p.1559, 1992.
DOI : 10.1126/science.1523410

P. A. Evans, K. D. Topping, D. N. Woolfson, and C. M. Et-dobson, Hydrophobic clustering in nonnative states of a protein: Interpretation of chemical shifts in NMR spectra of denatured states of lysozyme, Proteins: Structure, Function, and Genetics, vol.31, issue.4, p.248, 1991.
DOI : 10.1002/prot.340090404

E. Dickinson, C. M. Et-woskett, and . In, Food Colloids, 1989.

D. F. Darling and R. J. Et-birkett, Food Emulsions and Foams" Special Publications N° 58, Royal Society of Chemistry, issue.1, 1986.

L. K. Brown, G. Narsimhan, and P. C. Et-wankat, Foam fractionation of globular proteins, Biotechnology and Bioengineering, vol.37, issue.9, p.947, 1990.
DOI : 10.1002/bit.260360910

F. Macritchie and A. E. Et-alexander, Kinetics of adsorption of proteins at interfaces. Part I. The role of bulk diffusion in adsorption, Journal of Colloid Science, vol.18, issue.5, p.453, 1963.
DOI : 10.1016/0095-8522(63)90036-9

S. Damodaran and K. B. Song, Kinetics of adsorption of proteins at interfaces: role of protein conformation in diffusional adsorption, Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology, vol.954, p.253, 1988.
DOI : 10.1016/0167-4838(88)90080-5

F. Macritchie, Proteins at Interfaces, Adv. Protein Chem, vol.32, p.283, 1978.
DOI : 10.1016/S0065-3233(08)60577-X

F. Macritchie and A. E. Et-alexander, Kinetics of adsorption of proteins at interfaces. Part II. The role of pressure barriers in adsorption, Journal of Colloid Science, vol.18, issue.5, p.458, 1963.
DOI : 10.1016/0095-8522(63)90037-0

F. Macritchie and A. E. Et-alexander, Kinetics of adsorption of proteins at interfaces. Part III. The role of electrical barriers in adsorption, Journal of Colloid Science, vol.18, issue.5, p.464, 1963.
DOI : 10.1016/0095-8522(63)90038-2

D. E. Graham and M. C. Phillips, Proteins at liquid interfaces, Journal of Colloid and Interface Science, vol.70, issue.3, pp.427-439, 1979.
DOI : 10.1016/0021-9797(79)90050-X

M. Muramatsu and H. Et-saboca, Studies on unimolecular layers of modified proteins. I. Bovine serum albumin and its acetyl derivatives, Journal of Colloid Science, vol.18, issue.7, p.625, 1963.
DOI : 10.1016/0095-8522(63)90056-4

T. Yamashita and H. B. Bull, Films of lysozyme adsorbed at air-water surfaces, Journal of Colloid and Interface Science, vol.27, issue.1, p.19, 1968.
DOI : 10.1016/0021-9797(68)90004-0

C. A. Haynes and W. Et-norde, Globular proteins at solid/liquid interfaces, Colloids and Surfaces B: Biointerfaces, vol.2, issue.6, p.517, 1994.
DOI : 10.1016/0927-7765(94)80066-9

P. Y. Chou and G. D. Fasman, Conformational parameters for amino acids in helical, ??-sheet, and random coil regions calculated from proteins, Biochemistry, vol.13, issue.2, p.211, 1974.
DOI : 10.1021/bi00699a001

P. Y. Chou and G. D. Fasman, Prediction of protein conformation, Biochemistry, vol.13, issue.2, p.222, 1974.
DOI : 10.1021/bi00699a002

F. C. Church, G. L. Catignani, and H. E. Swaisgood, Hydrolysis of Milk Proteins by Immobilized Streptomyces griseus Pronase, Journal of Dairy Science, vol.64, issue.5, p.724, 1981.
DOI : 10.3168/jds.S0022-0302(81)82640-9

T. H. Snoeren, B. Van-marwijk, and R. Van-montfort, Some physicochemical properties of bovine ??s2-casein, Biochimica et Biophysica Acta (BBA) - Protein Structure, vol.622, issue.2, p.268, 1980.
DOI : 10.1016/0005-2795(80)90037-9

G. P. Berry and L. K. Creamer, Association of bovine ??-casein. Importance of the C-terminal region, Biochemistry, vol.14, issue.16, p.3542, 1975.
DOI : 10.1021/bi00687a005

K. S. Birdi, Lipid and biopolyrner at liquid interfaces, 1989.

A. Sadana, Protein adsorption and inactivation on surfaces. Influence of heterogeneities, Chemical Reviews, vol.92, issue.8, p.1799, 1992.
DOI : 10.1021/cr00016a006

P. M. Claesson, E. Blomberg, J. C. Fröberg, T. Nylander, and T. Arnebrant, Protein interactions at solid surfaces, Advances in Colloid and Interface Science, vol.57, p.161, 1995.
DOI : 10.1016/0001-8686(95)00241-H

V. Lzmaïlova and G. P. Yampolskaya, Protein at liquid interfaces, p.103, 1998.

A. L. Fink, B. A. In, and . Shirley-ed, Methods in Molecular Biology: Theory and Practice, p.343, 1995.

D. G. Dalgleish and J. Leaver, The possible conformations of milk proteins adsorbed on interfaces, Journal of Colloid and Interface Science, vol.141, issue.1, pp.288-294, 1991.
DOI : 10.1016/0021-9797(91)90324-2

D. E. Graham and M. C. Phillips, Proteins at liquid interfaces. IV. Dilatational properties, Journal of Colloid and Interface Science, vol.76, issue.1, pp.227-239, 1980.
DOI : 10.1016/0021-9797(80)90289-1

D. E. Graham and M. C. Phillips, Proteins at liquid interfaces. V. Shear properties, Journal of Colloid and Interface Science, vol.76, issue.1, pp.240-250, 1980.
DOI : 10.1016/0021-9797(80)90290-8

V. Aguié-béghin, E. Leclerc, M. Daoud, and R. Douillard, Asymmetric Multiblock Copolymers at the Gas???Liquid Interface: Phase Diagram and Surface Pressure, Journal of Colloid and Interface Science, vol.214, issue.2, p.143, 1999.
DOI : 10.1006/jcis.1999.6144

J. S. Richardson, D. C. Richardson, I. Fasman, and G. D. Ed, Prediction of protein structure and the principles of protein conformation -Plenum press, pp.1-98, 1989.

A. Poupon and J. P. Mornon, Populations of hydrophobic amino acids within protein globular domains: Identification of conserved ???topohydrophobic??? positions, Proteins: Structure, Function, and Genetics, vol.13, issue.3, pp.329-342, 1998.
DOI : 10.1002/(SICI)1097-0134(19981115)33:3<329::AID-PROT3>3.0.CO;2-E

B. A. Shirley, B. A. In, and . Shirley-ed, Protein stability and folding : theory and practice, pp.177-190, 1985.
DOI : 10.1385/0896033015

P. Calmettes, B. Roux, D. Durand, D. Desmadril, and J. C. Smith, Configurational Distribution of Denatured Phosphoglycerate Kinase, Journal of Molecular Biology, vol.231, issue.3, pp.840-848, 1993.
DOI : 10.1006/jmbi.1993.1330

J. M. Zhou, Y. X. Fan, H. Kihara, K. Kimura, and Y. Amemiya, Unfolding of dimeric creatine kinase in urea and guanidine hydrochloride as measured using small angle X-ray scattering with synchrotron radiation, FEBS Letters, vol.131, issue.2, pp.183-185, 1997.
DOI : 10.1016/S0014-5793(97)01120-4

B. Duplantier and H. Et-saleur, point in two dimensions, Physical Review Letters, vol.59, issue.5, p.539, 1987.
DOI : 10.1103/PhysRevLett.59.539

E. H. Lucassen-reynders, . H. Ine, and . Lucassen, Anionic Surfactants, p.173, 1981.

J. P. Cotton, in : Neutrons, X-ray and light scattering, pp.3-131, 1991.

J. P. Cotton, Diffusion des neutrons aux petits angles, J. Physique Paris, vol.9, 1999.
URL : https://hal.archives-ouvertes.fr/jpa-00214765

M. Bonetti, G. Romet-lemonne, P. Calmettes, and M. Bellissent-funel, Small-angle neutron scattering from heavy water in the vicinity of the critical point, The Journal of Chemical Physics, vol.112, issue.1, p.268, 2000.
DOI : 10.1063/1.480633

J. Yvon, Les corrélations et l'entropie en mécanique statistique classique, 1966.
DOI : 10.1063/1.3047878

P. A. Egelstaff, An introduction to the liquid state, 2 éme édition, 1992.

B. Mandelbrot, Les Objets Fractals, 1984.

J. Des-cloizeaux and G. Et-jannink, Les Polymères en solution, Les éditions de Physique, 1987.

M. Adam and D. Et-lairez, FRACTAL CONFORMATION OF POLYMERS, Fractals, vol.01, issue.02, p.149, 1993.
DOI : 10.1142/S0218348X93000174

J. Debye, Applied Phys, p.338, 1944.

M. Rawiso, R. Duplessix, and C. Et-picot, Scattering function of polystyrene, Macromolecules, vol.20, issue.3, p.630, 1987.
DOI : 10.1021/ma00169a028

P. Calmettes, D. Durand, M. Desmadril, P. Minard, V. Receveur et al., How random is a highly denatured protein?, Biophysical Chemistry, vol.53, issue.1-2, p.105, 1994.
DOI : 10.1016/0301-4622(94)00081-6

P. J. Flory, Principles of polymers chemistry, 1979.

L. Guillou and J. C. Zinn-justin, -Vector Model in Three Dimensions from Field Theory, Physical Review Letters, vol.39, issue.2, p.95, 1977.
DOI : 10.1103/PhysRevLett.39.95

URL : https://hal.archives-ouvertes.fr/hal-01009436

H. Benoit and P. Doty, Light Scattering from Non-Gaussian Chains, The Journal of Physical Chemistry, vol.57, issue.9, p.958, 1953.
DOI : 10.1021/j150510a025

P. Sharp and V. A. Bloomfield, Light scattering from wormlike chains with excluded volume effects, Biopolymers, vol.18, issue.8, p.1201, 1968.
DOI : 10.1002/bip.1968.360060814

H. Utiyama, Y. Tsunashima, and M. Kurate, Rayleigh Scattering by Linear Flexible Macromolecules, The Journal of Chemical Physics, vol.55, issue.7, p.3133, 1971.
DOI : 10.1063/1.1676559

H. Benoit and M. Benmouna, Scattering from a polymer solution at an arbitrary concentration, Polymer, vol.25, issue.8, p.1059, 1984.
DOI : 10.1016/0032-3861(84)90339-2

B. H. Zimm, The Scattering of Light and the Radial Distribution Function of High Polymer Solutions, The Journal of Chemical Physics, vol.16, issue.12, p.1093, 1948.
DOI : 10.1063/1.1746738

H. Yamakawa, Modern theory of polymer solutions, 1971.

H. Yamakawa, On the theory of the second virial coefficient for polymer chains, Macromolecules, vol.25, issue.7, p.1912, 1992.
DOI : 10.1021/ma00033a012

L. T. Lee, E. Mann, D. Langevin, and B. Famoux, Neutron reflectivity and ellipsometry studies of a polymer molecular layer spread on the water surface, Langmuir, vol.7, issue.12, p.3076, 1991.
DOI : 10.1021/la00060a029

J. S. Pedersen and J. , Model-independent determination of the surface scattering-length-density profile from specular reflectivity data, Journal of Applied Crystallography, vol.25, issue.2, p.129, 1992.
DOI : 10.1107/S0021889891010907

K. Kunz, Model-free analysis of neutron reflectivity data from polymer thin films with the simulated annealing technique, Macromolecules, vol.26, issue.16, p.4316, 1993.
DOI : 10.1021/ma00068a038

D. S. Sivia, Analysis of neutron reflectivity data: maximum entropy, Bayesian spectral analysis and speckle holography, Physica B: Condensed Matter, vol.173, issue.1-2, p.121, 1991.
DOI : 10.1016/0921-4526(91)90042-D

S. Labourdenne, N. Gaudry-rolland, S. Letellier, M. Lin, A. Cagna et al., The oil-drop tensiometer: potential applications for studying the kinetics of (phospho)lipase action, Chemistry and Physics of Lipids, vol.71, issue.2, p.163, 1994.
DOI : 10.1016/0009-3084(94)90068-X

H. Mckenzie and A. Sawyer, Milk Proteins, 1971.
DOI : 10.1016/S0065-3233(08)60041-8

Y. Nozaki, [3] The preparation of guanidine hydrochloride, Methods Enzymol, vol.26, p.43, 1970.
DOI : 10.1016/S0076-6879(72)26005-0

N. Puff, A. Cagna, V. Aguié-béghin, and R. Douillard, Effect of Ethanol on the Structure and Properties of ??-Casein Adsorption Layers at the Air/Buffer Interface, Journal of Colloid and Interface Science, vol.208, issue.2, p.405, 1998.
DOI : 10.1006/jcis.1998.5846

S. W. An, R. K. Thomas, F. L. Baines, N. C. Billingham, S. P. Armes et al., Neutron Reflectivity of an Adsorbed Water-Soluble Block Copolymer:?? A Surface Transition to Micelle-like Aggregates at the Air/Water Interface, The Journal of Physical Chemistry B, vol.102, issue.2, pp.387-393, 1998.
DOI : 10.1021/jp971277x

S. W. An, R. K. Thomas, F. L. Baines, N. C. Billingham, S. P. Armes et al., Neutron Reflectivity of an Adsorbed Water-Soluble Block Copolymer at the Air/Water Interface:?? The Effects of pH and Ionic Strength, The Journal of Physical Chemistry B, vol.102, issue.26, pp.5120-5126, 1998.
DOI : 10.1021/jp9809033

S. W. An, R. K. Thomas, F. L. Baines, N. C. Billingham, S. P. Armes et al., Neutron Reflectivity of Adsorbed Water-Soluble Block Copolymers at the Air/Water Interface:?? the Effects of Composition and Molecular Weight, Macromolecules, vol.31, issue.22, pp.7877-7885, 1998.
DOI : 10.1021/ma980548e

M. Puggelli, M. Noncentini, G. Gabielli, and L. Poletti, Monolayers of proteins: ??-lactoglobulin and its interactions with phospholipids, Il Nuovo Cimento D, vol.86, issue.9, pp.1529-1536, 1994.
DOI : 10.1007/BF02462038

R. S. Clegg, S. M. Reed, and J. E. Hutchison, Self-Assembled Monolayers Stabilized by Three-Dimensional Networks of Hydrogen Bonds, Journal of the American Chemical Society, vol.120, issue.10, pp.2486-2487, 1998.
DOI : 10.1021/ja9800277