Skip to Main content Skip to Navigation

Presentation

The LCAR (Laboratoire Collisions-Agrégats-Réactivité) is a laboratory centered in fundamental physics organized around two main fields

  1. The study of laser-matter interaction focuses on matter waves studies and strong-field physics
  2. The study of molecular structures and dynamics develops the study and measurement of the properties of clusters, molecules of biological interest, and nano-objects in their environment

Research teams in the lab

Publisher copyright policies & self-archiving

Search

New submit

Last submission

[hal-02156273] Non-adiabatic molecular dynamics investigation of the size dependence of the electronic relaxation in polyacenes

(10/05/2021)  
The Tully’s fewest switches surface hopping algorithm is implemented within the framework of the time-dependent density functional based tight binding method (TD-DFTB) to simulate the energy relaxation following absorption of a UV photon by polycyclic aromatic hydrocarbons (PAHs). This approach is used to study the size effect on the ultrafast dynamics in excited states for a special class of PAH species called polyacenes. We determine the dynamical relaxation times and discuss the underlying mechanisms. Our results show that there is a striking alternation in decay times of the brightest singlet state for neutral polyacenes with 3 to 6 aromatic cycles. The alternation corresponds to an order-of-magnitude variation between roughly 10 and 100 fs and is correlated with a qualitatively similar alternation of energy gaps between the brightest state and the state lying just below in energy.

[tel-03205698] Etude expérimentale des interactions du vent solaire avec la molécule prébiotique d'hydantoine (C3N2O2H4)

(26/04/2021)  

[hal-03134247] Fast and robust quantum state transfer in a topological Su-Schrieffer-Heeger chain with next-to-nearest-neighbor interactions

(09/02/2021)  

[tel-03131437] Développement d'une source de condensats de Bose-Einstein pour l'interférométrie atomique

(09/02/2021)  

[tel-02976831] Gaz quantique dans un potentiel périodique dépendant du temps : de la modulation perturbative aux résonances de l'effet tunnel assisté par le chaos

(09/04/2021)