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Thermochimica Acta 70 (1983) 173-188
A general method of calculating phase equilibria in a multicomponent system by means of a hill-climbing minimization procedure
Jean-Noel Barbier1, Pierre-Yves Chevalier1, Ibrahim Ansara1

A generalization of the method of calculating the state of equilibrium of a multicomponent system, using a hill-climbing minimization procedure, is proposed. Moreover, an original method of calculating values for partial free energies from the state of equilibrium has been made an essential part of the general schedule.
1 :  LTPCM - Laboratoire de thermodynamique et physico-chimie métallurgiques
Phase equilibria – Thermodynamic calculation – Multicomponent system – Minimization